S GD&T CN TH THI TH THPT QUC GIA THNG 3 - 2015

TTLT H DIU HIN MN: Ha Hc

43D ng 3/2 TPCT Thi gian lm bi: 90 pht.
T: 0949.355.366 0964.222.333
H, tn:......................................................................S bo danh:........................... M thi 416
NI DUNG
( thi gm 50 cu trc nghim c in trn 04 trang giy)
Cu 1: Cho hn hp gm Mg v Cu tc dng vi 200ml dung dch cha hn hp hai mui AgNO3 0,3M v
Cu(NO3)2 0,25M. Sau khi cc phn ng xy ra hon ton, thu c dung dch A v cht rn B. Cho A tc dng
vi NaOH d, lc ly kt ta em nung n khi lng khng i c 3,6 gam hn hp X gm hai oxit. Ha
tan hon ton B trong dung dch H2SO4 c, nng c 2,016 lt kh SO2 ( ktc). Phn trm khi lng ca
Mg trong hn hp u l
A. 56,8% B. 63,5% C. 42,4% D. 32,5%
Cu 2: Cho dy cc cht : CH3COOCH3, C2H5OH, H2NCH2COOH, CH3NH2. S cht trong dy phn ng
c vi dung dch NaOH l
A. 2 B. 1 C. 4 D. 3
Cu 3: Hp cht hu c X c cng thc phn t C6H10O5 tha mn cc tnh cht sau:
toC 1:1
X + 2NaOH 2Y + H2O ; Y + HCl Z + NaCl.
Khi cho 0,1 mol Z tc dng vi Na d th s mol H2 thu c l
A. 0,15. B. 0,05. C. 0,1. D. 0,2.
Cu 4: Ha tan hon ton m gam hn hp gm Na2O v Al2O3 vo nc thu c dung dch X trong sut.
Thm t t dung dch HCl 1M vo X, khi ht 100 ml th bt u xut hin kt ta; khi ht 300 ml hoc 700 ml
th u thu c a gam kt ta. Gi tr ca a v m ln lt l:
A. 23,4 v 56,3. B. 15,6 v 27,7. C. 23,4 v 35,9. D. 15,6 v 55,4.
Cu 5: X phng ha hon ton 0,1 mol mt este no n chc, mch h bng 26 gam dung dch MOH 28% (M
l kim loi kim) ri tin hnh chng ct sn phm thu c 26,12 gam cht lng X v 12,88 gam cht rn khan
Y. t chy hon ton cht rn ny thu c 8,97 gam mt mui duy nht. Kim loi M v cng thc thu gn
ca este ban u ln lt l:
A. Na v C2H5COOCH3. B. K v C2H5COOC4H9. C. K v CH3COOC2H5. D. Na v CH3COOC4H9.
Cu 6: Cho m gam Fe vo bnh cha dung dch gm H2SO4 v HNO3, thu c dung dch X v 2,24 lt kh
NO. Thm tip dung dch H2SO4 d vo bnh thu c 0,896 lt kh NO v dung dch Y. Bit trong c hai
trng hp NO l sn phm kh duy nht, o iu kin tiu chun. Dung dch Y ha tan va ht 4,16 gam Cu
(khng to thnh sn phm kh ca N+5). Bit cc phn ng u xy ra hon ton. Gi tr ca m l
A. 7,84 B. 4,80 C. 8,40 D. 8,12
Cu 7: Cho hn hp E gm 3 kim loi dng bt l K, Al, Fe c chia lm 3 phn bng nhau. Phn (1), cho
tc dng vi H2O ly d gii phng ra 4,48 lt kh (kc). Phn (2), cho tc dng vi dung dch KOH ly d gii
phng ra 7,84 lt kh (kc). Phn (3), ha tan hon ton trong 0,5 lt dung dch H2SO4 1,2M gii phng ra 10,08
lt kh (kc) v to ra dung dch A. Cho dung dch A tc dng vi 240 gam dung dch NaOH 20% thu c kt
ta, lc, ra ri nung kt ta trong khng kh n khi lng khng i thu c m gam cht rn. Tnh m ?
A. 13,1 gam B. 8 gam C. 14,5 gam D. 5,1 gam
2+
Cu 8: Phn ng no sau y chng t Fe c tnh kh yu hn so vi Cu?
A. Cu2+ + 2Fe2+ 2Fe3+ + Cu. B. Fe2++ Cu Cu2+ + Fe. C. 2Fe3+ + Cu 2Fe2+ + Cu2+. D. Fe + Cu2+ Fe2+ + Cu.
Cu 9: Cho 66,2 gam hn hp X gm Fe3O4, Fe(NO3)2, Al tan hon ton trong dung dch cha 3,1 mol KHSO4 long.
Sau khi cc phn ng xy ra hon ton thu c dung dch Y ch cha 466,6 gam mui sunfat trung ha v 10,08 lt
(ktc) kh Z gm 2 kh trong c mt kh ha nu trong khng kh. Bit t khi ca Z so vi He l 23/18. Phn trm khi
lng ca Al trong hn hp gn nht vi gi tr no sau y?
A. 15. B. 20. C. 25. D. 30.
Cu 10: X l hn hp cc mui Cu(NO3)2, Fe(NO3)3, Fe(NO3)2 trong oxi chim 9,6% v khi lng. Cho
KOH d vo dung dch cha 50 gam hn hp X th thu c kt ta. Lc kt ta thu c em nung trong chn
khng n khi lng khng i thu c m gam oxit. Gi tr ca m l
A. 44,6. B. 46,0. C. 43,8. D. 48,6.
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Cu 11: Cho cc cht sau: CH3CHO, HCHO, HCOOH, HCOONH4, (CHO)2, CH2(CHO)2, HCOONa. S cht
tha mn iu kin: khi tc dng vi lng d dung dch AgNO3/NH3 th sn phm mui thu c cho tc
dng vi dung dch NaOH hoc H2SO4 long u c kh v c thot ra l
A. 2. B. 4. C. 5. D. 3.
Cu 12: Oxi ha m gam ancol etylic mt thi gian thu c hn hp X. Chia X thnh 3 phn bng nhau.
- Phn 1: tc dng va vi dung dch NaHCO3 thu c 4,48 lt kh.
- Phn 2: tc dng vi lng d Na thy thot ra 8,96 lt kh.
- Phn 3: tc dng ht vi dung dch AgNO3/NH3 to thnh 21,6 gam Ag.
Bit cc th tch kh o ktc. Phn trm ancol etylic tham gia phn ng oxi ha l
A. 33,33%. B. 50%. C. 42,86%. D. 60%.
Cu 13: Cu no sau y ng:
A. Cc protein thc vt u tan trong nc nng.
B. Cc amin u lm qu tm ha xanh.
C. Cc peptit u c kh nng to kt ta vng vi HNO3 c.
D. Tht s lu mm khi nu trong nc cng.
Cu 14: S oxi ha ca crom trong hp cht Cr2O2 l
A. +4 B. +6 C. +2 D. +3
Cu 15: S ancol ng vi cng thc phn t C3H8Ox c th ha tan Cu(OH)2 l
A. 4. B. 3. C. 5. D. 2.
Cu 16: Cho 1,008 lt (ktc) kh CO2 c hp th t t vo dung dch X cha 0,04 mol NaOH v 0,03 mol
Na2CO3. Khi CO2 c hp th ht thu c dung dch Y, lm bay hi cn thn dung dch Y thu c m gam
cht rn khan. Gi tr ca m l
A. 6,43. B. 4,20. C. 2,65. D. 6,85.
Cu 17: Hn hp X (c M X = 31,6) gm hai hirocacbon mch h k tip nhau trong dy ng ng. Cho 6,32
gam X vo 200 gam nc cha mt lng nh cht xc tc thch hp (khi lng xc tc khng ng k) th
thu c dung dch Z (gi s ch gm cc sn phm chnh) v thot ra 2,688 lt kh kh Y ( ktc) c M Y = 33.
Bit rng dung dch Z cha anehit nng C%. Gi tr ca C l
A. 4,407. B. 1,406. C. 1,208. D. 1,305.
Cu 18: Cho Cu ln lt tc dng vi cc dung dch sau: (1) FeCl3, (2) AgNO3, (3) KHSO4 + KNO3,
(4) Al2(SO4)3, (5) H2SO4 long. S dung dch c phn ng vi Cu l
A. 3. B. 4. C. 5. D. 2.
Cu 19: Phn ng no sau y khng ng:
A. Na2SiO3 + 2H2O 2NaOH + H2SiO3. B. SiO2 + H2O H2SiO3.
o
t
C. Na2SiO3 + CO2 + H2O Na2CO3 + H2SiO3. D. SiO2 + Na2CO3 Na2SiO3 + CO2.
Cu 20: Ha tan hon ton 3,79 gam hn hp X gm Al v Zn (t l s mol 2 : 5) vo dung dch cha 0,394
mol HNO3 thu c dung dch Y v V ml kh N2 (ktc). phn ng ht vi cc cht trong Y n khi thu c
dung dch trong sut cn va 3,88 lt NaOH 0,125M. Gi tr ca V l
A. 358,4. B. 112,0. C. 268,8. D. 352,8.
Cu 21: Cho 2-metylbut-2-en tc dng vi HBr. Sn phm chnh ca phn ng l
A. 2-brom-3-metylbutan B. 1-brom-2-metylbutan
C. 2-brom-2-metylbutan D. 1-brom-3-metylbutan
Cu 22: Nhit phn hon ton hn hp NH4NO3, Cu(NO3)2, AgNO3, Fe(NO3)2 cht rn thu c sau phn ng gm
A. CuO, FeO, Ag. B. NH4NO2, CuO, Fe2O3, Ag.
C. CuO, Fe2O3, Ag. D. CuO, Fe2O3, Ag2O.
Cu 23: Vinyl axetat c cng thc l
A. C2H5COOCH3 B. HCOOC2H5 C. CH3COOCH3 D. CH3COOCH=CH2.
Cu 24: C 100 gam dung dch 23% ca mt axit hu c no, n chc X (dung dch X). Thm vo dung dch
X 30 gam mt axit Y l ng ng k tip ca axit X (dung dch Z). Ly 1/10 dung dch Z em trung ha va
bng 50 ml dung dch NaOH 2M. CTPT ca X v Y ln lt l:
A. C3H7COOH, C4H9COOH. B. C2H5COOH, C3H7COOH.
C. CH3COOH, C2H5COOH. D. HCOOH, CH3COOH.

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Cu 25: Thm NaOH vo mu th ca dung dch X thy xut hin kh mi khai. Cn khi thm dung dch
AgNO3 vo mu th ca dung dch X th c kt ta mu vng xut hin. Dung dch X cha cht no trong cc
cht sau:
A. (NH4)3PO4. B. Na3PO4. C. NH4Cl. D. KI.
Cu 26: Cho m gam hn hp hi X gm 2 ancol (n chc, bc I, l ng ng k tip) phn ng vi CuO d,
thu c hn hp hi Y gm nc v anehit. T khi hi ca Y so vi kh hiro bng 14,5. Cho ton b Y
phn ng hon ton vi lng d dung dch AgNO3 trong NH3, thu c 97,2 gam Ag. Gi tr ca m l
A. 14,0 B. 18,9 C. 10,1 D. 14,7
2+ 10
Cu 27: Cation X c cu hnh electron: [Kr]3d . X thuc:
A. chu k 5, nhm IIB. B. chu k 4, nhm IIB. C. chu k 4, nhm IIA. D. chu k 5, nhm IIA.
Cu 28: Dung dch X gm AgNO3 v Cu(NO3)2 c cng nng mol/lt. Ly mt lng hn hp gm 0,03
mol Al v 0,05 mol Fe cho vo 100 ml dung dch X cho ti khi phn ng kt thc thu c cht rn Y cha 3
kim loi. Cho Y vo dung dch HCl d gii phng 0,07 gam kh. Nng mol/lt ca mi mui trong X l
A. 0,3 M. B. 0,45 M. C. 0,4 M. D. 0,42 M.
Cu 29: Trong mt cc nc c cha 0,01 mol Na ; 0,02 mol Ca ; 0,01 mol Mg2+; 0,05 mol HCO3- v 0,02
+ 2+

mol Cl-. Vy nc trong cc thuc loi nc

A. C cng ton phn B. c cng tm thi
C. mm D. C cng vnh cu
Cu 30: un este n chc A vi dung dch NaOH n khi kt thc phn ng thu c X. trung ha lng NaOH
d trong X cn 100ml dung dch HCl 1M. C cn dung dch thu c 15,25 gam hn hp mui khan v hi ancol B.
Dn ton b ancol B qua CuO d, nung nng thu c anehit E. Cho E tc dng vi lng d dung dch AgNO3/NH3
thu c 43,2 gam Ag. Bit rng cc phn ng xy ra hon ton. Cng thc ca este A l
A. CH3COOCH3 B. C2H3COOCH3 C. C2H5COOCH3 D. C2H3COOC2H5
Cu 31: X l mt anehit, mch h c cng thc CnHn+1O2 v tha mn s sau:
+NaOH, t o C +CuO, t o C +O2 , t o C
Cn H 2n Br2 (A) Cn H 2n + 2O2 X Cn H 2n - 2 O3 .
Cc cht A v X ln lt l:
A. CH2Br-CH2Br, (CHO)2. B. CH3-CH2-CHBr2, CH3-CH2-CH(OH)2.
C. CH3-CHBr-CH2Br, CH2(CHO)2. D. BrCH2-CH2-CH2Br, CH2(CHO)2.
Cu 32: Cu no sau y ng?
A. Cc mui sunfua kim loi u tc dng vi axit HCl to kh H2S.
B. Tnh axit ca cc axit HX ( X l halogen) tng t HF n HI.
C. Cc phi kim u to ra oxit axit.
D. Tt c cc mui AgX (X l halogen) u khng tan trong nc.
Cu 33: Cho hn hp X (Cu, Zn) vo 500 ml dung dch Fe2(SO4)3 0,5M, khi phn ng kt thc thu c dung dch Y
v cht rn Z. Cho Z vo dung dch H2SO4 long khng thy kh thot ra. Dung dch Y cho tc dng vi dung dch
NH3 d c m gam kt ta. Gi tr ca m l
A. 27,5. B. 90,0. C. 69,5. D. 45,0.
Cu 34: Hp cht hu c X c cng thc phn t C5H11O2N. un nng X vi dung dch NaOH thu c mt
cht Y c cng thc phn t C2H4O2NNa v cht Z. Cho hi Z vo CuO c nung nng thu c sn phm c
kh nng cho phn ng trng gng. Cng thc cu to ca X l
A. H2N-CH2CH2COOC2H5. B. NH2CH2COOCH(CH3)2.
C. NH2-CH2COOCH2CH2CH3. D. CH3(CH2)4NO2.
Cu 35: Mt hn hp X gm axetilen, propilen v metan. t chy hon ton 11 gam X thu c 12,6 gam
H2O. Mt khc, 5,6 lt ( ktc) X lm mt mu va dung dch cha 50 gam brom. Phn trm th tch ca
axetilen v propilen trong hn hp X ln lt l:
A. 50%; 25%. B. 40%; 40%. C. 25%; 25%. D. 25%; 50%.
Cu 36: Cht khng phi l axit bo l
A. axit stearic B. axit oleic C. axit axetic D. axit panmitic
Cu 37: Kim loi Fe phn ng c vi dung dch no sau y to thnh mui st(III)?
A. Dung dch HNO3 (long, d) B. Dung dch HCl
C. Dung dch CuSO4 D. Dung dch H2SO4 (long)
Cu 38: X l hn hp gm HCHO v CH3CHO. Khi oxi ho p gam X bng O2 thu c (p+1,6) gam Y gm
hai axit tng ng (hiu sut 100%). Cho p gam X tc dng vi dung dch AgNO3trong NH3 d, thu c
25,92 gam Ag. Phn trm khi lng HCHO trong hn hp X l
A. 26,83%. B. 85,44%. C. 73,17%. D. 14,56%.
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Cu 39: Hn hp bt A gm 3 kim loi Mg, Zn, Al. Khi ha tan ht 7,5 gam A vo 1 lt dung dch HNO3 thu
c 1 lt dung dch B v hn hp kh D gm NO v N2O. Thu kh D vo bnh dung tch 3,20 lt c cha sn N2
00C v 0,23atm th nhit trong bnh tng ln n 27,30C, p sut tng ln n 1,10atm, khi lng bnh
tng thm 3,72 gam. Nu cho 7,5 gam A vo 1 lt dung dch KOH 2M th sau khi kt thc phn ng khi lng
dung dch tng thm 5,7 gam. Tng s mol kim loi c trong A gn nht l:
A. 0,18 B. 0,15 C. 0,25 D. 0,21
Cu 40: Cho vo 3 ng nghim, mi ng 1 ml etyl axetat v 1 ml nc. Sau thm tip vo ng nghim th
hai 5 git H2SO4 m c v ng nghim th ba 2 ml NaOH 3M. Ngm c 3 ng nghim trn vo mt cc nc
nng khong 70oC, gi nhit ca nc trong cc khng thay i trong sut thi gian kho st (khong 5
pht). Tc thy phn este trong cc ng nghim l:
A. (1) > (2) > (3). B. (2) > (1) > (3). C. (3) > (2) > (1). D. (2) > (3) > (1).
Cu 41: Cht lm mn nc c tnh cng ton phn l
A. CaSO4 B. CaCO3 C. Na2CO3 D. NaCl
Cu 42: X phng ha hon ton m gam mt este no, n chc mch h E bng 26 gam dung dch MOH 28% (M l kim
loi kim). C cn hn hp sau phn ng thu c 24,72 gam cht lng X v 10,08 gam cht rn khan Y. t chy hon
ton Y, thu c sn phm gm CO2, H2O, v 8,97 gam mui cacbonat khan. Mt khc, cho X tc dng vi Na d, thu
c 12,768 lt H2 (ktc). Phn trm khi lng mui trong Y c gi tr gn nht vi
A. 67,5. B. 85,0. C. 80,0. D. 97,5.
Cu 43: Hai este X, Y l dn xut ca benzen c CTPT l C9H8O2. X v Y u cng vi nc brom theo t l
s mol 1:1. X tc dng vi NaOH thu c 1 mui v 1 anehit. Y tc dng vi NaOH d cho 2 mui v nc.
Bit cc mui u c khi lng mol ln hn 82). Cng thc cu to ca ca X v Y c th l:
A. HCOOCH=CH-C6H5 v HCOOC6H4CH=CH2. B. C6H5COOCH=CH2 v CH2=CH-COOC6H5.
C. HOOC-C6H4-CH=CH2 v CH2=CH-COOC6H5. D. C6H5COOCH=CH2 v C6H5CH=CH-COOH.
Cu 44: Hn hp X gm H2 v hai olefin l ng ng k tip nhau. Cho 8,96 lt hn hp X i qua xc tc Ni
nung nng thu c hn hp Y. Dn Y qua dung dch Br2 d thy khi lng bnh tng 1,82 gam v thot ra
5,6 lt hn hp kh Z. T khi ca Z i vi H2 l 7,72. Bit tc phn ng ca 2 olefin vi hiro l nh nhau.
Cng thc phn t v % th tch ca anken c t nguyn t cacbon hn trong X l
A. C2H4; 17,5% B. C2H4; 20,0% C. C3H6; 17,5% D. C3H6; 20,0%
Cu 45: phn bit hai dung dch cha trong cc l ring bit sau: FeCl2, FeSO4, ta c th dng thuc th
no sau y?
A. Dung dch KMnO4/H2SO4. B. Dung dch NaOH.
C. Dung dch H2SO4 c. D. Dung dch NH3.
Cu 46: C 6 l ng 6 dung dch ring bit: C6H5ONa, C6H5NH2, C2H5OH, C6H6, NH4HCO3 v NaAlO2. Ha
cht no sau y c th dng nhn bit 6 l mt nhn ni trn:
A. Dung dch HCl. B. Dung dch nc brom. C. Dung dch NaOH. D. Kh CO2.
Cu 47: Pht biu no sau y l ng:
A. Trong n mn in ho trn cc m xy ra qu trnh oxi ho.
B. Than cc l nguyn liu cho qu trnh sn xut thp.
C. Trong in phn dung dch NaCl trn catot xy ra qu trnh oxi ho nc.
D. Criolit c tc dng h nhit nng chy ca Al.
Cu 48: Dy gm cc cht no sau y khi phn ng vi dung dch Ba(HCO3)2 u to kt ta?
A. Ca(OH)2, CaCl2, H2SO4. B. HCl, H2SO4, KHCO3.
C. Na2SO3, Ba(OH)2, KHSO4. D. Na2S, CaCl2, KHSO4.
Cu 49: Ho tan hon ton hn hp gm 0,12 mol FeS2 v a mol Cu2S vo dung dch cha axit HNO3 va
th thu c dung dch X ch cha hai mui sunfat v V lt (ktc) kh NO (l sn phm kh duy nht). S mol
HNO3 phn ng v khi lng mui thu c sau phn ng l
A. 0,06 v 43,2 gam. B. 0,8 v 43,2 gam. C. 0,12 v 22,4 gam. D. 0,075 v 17,92 gam.
Cu 50: Trong bnh kn dung tch 10,6 lt kh CO v mt lng hn hp A gm Fe3O4 v FeCO3 28,60C p
sut trong bnh l 1,4atm (th tch rn coi nh khng ng k). Nung nng bnh nhit cao cc phn ng
xy ra hon ton. Hn hp sau phn ng c t khi so vi H2 l 20,5. Ha tan hon ton hn hp A trong dung
dch HNO3 long, thu c 0,896 lt hn hp kh gm NO v CO2 00C v 1,5atm. Th tch dung dch HCl
0,5M ha tan ht hn hp A gn nht l:
A. 2 lt B. 1,5 lt C. 2,5 lt D. 3 lt
------------------------------- HT -------------------------------
Cn b coi thi khng gii thch thi !

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1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A
B
C
D

21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40
A
B
C
D

41 42 43 44 45 46 47 48 49 50
A
B
C
D

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