S GD & T QUNG BNH K THI CHN HC SINH GII TNH NM HC 2013-2014

Kha ngy 28 3 2014

CHNH THC Mn: Ha
LP 12 THPT
H v tn:.. Thi gian 180 pht (khng k thi gian giao )
S bo danh:.. gm c 01 trang
Cu 1 (2,0 im)
1. Hon thnh phng trnh ha hc ca cc phn ng sau:
to
a) Cu2O + H2SO4 (long) b) Pb + H2SO4 (c)
c) Na[Cr(OH)4] + Br2 + NaOH d) FeCl3 + dung dch CH3NH2
e) NaNO2 + PbO2 + H2SO4 (long) f) Au + KCN + H2O2
g) FeCl3 + dung dch Na2S h) K2Cr2O7 + dung dch KOH
2. Vit phng trnh ha hc xy ra trong cc trng hp sau:
a) Glucoz tc dng vi dung dch bc nitrat trong amoniac (un nng).
b) Trng hp metyl metacrylat.
c) Natri aminoaxetat tc dng vi dung dch HCl d.
d) Buta-1,3-ien tc dng vi dung dch KMnO4 nhit thng.
e) Axit axetyl salixylic tc dng vi dung dch NaOH d (un nng).
f) Anlyl clorua tc dng vi dung dch nc clo.
Cu 2 (1,75 im)
1. Hon thnh phng trnh ha hc ca phn ng theo cc s sau:
Br
NaOH CuO O2 NaOH
a) C3H6 CCl2
4
B t 0 C 0t D xt, t0 E NaOH F CaO, t 0 CH4
H SO
c
A H2O B 21704o C
H SO
c
b) But-1-en 2 4 C
2. Thy phn hon ton 0,1 mol tripeptit Glu-Ala-Gly trong dung dch KOH d (un nng). Vit phng
trnh ha hc ca phn ng xy ra v tnh khi lng ca mi mui thu c sau phn ng.
Cu 3 (2,0 im)
1. C 200 ml dung dch A cha hn hp bari nitrat v st (III) nitrat. Cho dung dch natri cacbonat d vo
dung dch A, thu c 3,04 gam kt ta. Ly ton b lng kt ta trn cho tc dng vi dung dch HCl
d thy thot ra 0,224 lt kh (ktc). Xc nh nng mol ca cc cht trong dung dch A.
2. Ngi ta m niken ln mu vt kim loi bng phng php m in trong b m cha dung dch NiSO 4,
vi cng dng in I = 9A. Cn m mt mu vt kim loi hnh tr, c bn knh 2,5 cm, cao 20 cm,
ngi ta ph ln mu vt mt lp niken dy 0,4 mm trn. Hy:
a) Vit qu trnh xy ra trn cc in cc ca b m in.
b) Tnh thi gian ca qu trnh m in trn. Cho khi lng ring ca Ni l 8,9 g/cm3.
Cu 4 (2,25 im)
1. Cho 33,5 gam hn hp X gm Fe, Cr, Sn tc dng vi dung dch HCl d (un nng), sau khi cc phn
ng xy ra hon ton thu c 11,2 lt kh (ktc). Mt khc, nu cho 33,5 gam hn hp X tc dng vi
dung dch H2SO4 c, nng, d, sau khi cc phn ng xy ra hon ton th thu c 17,92 lt kh SO 2 (sn
phm kh duy nht, o ktc).
a) Vit phng trnh ha hc ca cc phn ng xy ra.
b) Tnh % v khi lng mi kim loi trong hn hp ban u.
2. Oxi ha 0,8 mol mt ancol n chc, thu c hn hp X gm mt axit cacboxylic, mt anehit, ancol
d v nc. Ngng t ton b X ri chia lm hai phn bng nhau. Phn mt cho tc dng ht vi Na d,
thu c 5,04 lt kh H2 (ktc). Phn hai cho phn ng trng bc hon ton thu c 97,2 gam Ag. Tnh
thnh phn % theo khi lng cc cht c trong X.
Cu 5 (2,0 im)
1. Tnh tan ca PbI2:
a) Trong nc nguyn cht; b) Trong dung dch KI 0,1M. Bit TPbI2 10 .
7,86

2. Trn 10 ml dung dch NaOH 10-3M vi 10 ml dung dch CH3COOH 1,01.10-3M, pha long thnh 1 lt
dung dch A. Tnh pH ca dung dch A. Bit Ka (CH3COOH) = 10-4,76.
Cho: H = 1; C = 12; N = 14; O = 16; K = 39; Cr = 52; Fe = 56; Ni = 59; Ag = 108; Sn = 119; Ba = 137.
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