9)

GAS A.G Mi Ri Ni Xi A.V

N2 56% 28 0.297 2 0.64 64

CO2 28% 44 0.189 0.64 0.20 20

O2 16% 32 0.260 0.5 0.16 16

TOTAL 3.14 1 100

P= 20 PSIA
T= 90 F
= 550 R

mm = Nm . Mm = 3.14 x 104 = 326.56 g

Clculo de V (pies3)
m = 0.30 lb
T = 90F = 550 R
P = 20 PSIA

Pm = Nm . Ru.T
V
V = Nm . Ru.t
P
V = 3.14 mol x 10.73 ft3.PSI x 550 R
mol x R________
20 PSI

V = 926.54 pies3

10)
P= 20 PSIA

CO= 0.42 Lb
O2 = 0,1616 = 190.51g = 72.57 g = 399.16 g
CO2= 0.88 Lb

a)
GAS Mi Ri Ni Xi A.V Rm=YiRi
CO 28 0.297 6.80 0.37 37
O2 32 0.260 2.27 0.13 13
CO2 44 0.189 9.07 0.5 50
TOTAL 1 100

Ni (co) = mi = 0.42 Lb = 0.015 = 6.80

Mi 28

Ni (o2) = mi = 0.16 Lb= 0.005 = 2.27

Mi 32

Ni(co2)= mi = 0.88Lb= 0.02 = 9.07

Mi 44

C)
Vm = Nm x Ru.T
P

Vm = 0.04 Lb x 10.73 pie3xpsi x 550 R

Lb x R________
20 psi

Vm = 11.803 pies3

11) Resolucin:

GAS A.V Xi Mi XiMi Yi A.G

N2 50% 0.5 28 14 0.40 40
CO2 40% 0.4 44 17.6 0.51 51
O2 10% 0.1 32 3.2 0.09 9
TOTAL 100% 1 34.8 1 100

Yi(N2) = XiMi = 14 = 0.4023

XiMi 34.8

Yi(CO2) = XiMi = 17.6 = 0.5057

XiMi 34.8

Yi(O2) = XiMi = 3.2 = 0.0919

XiMi 34.8

Calculo de m

P. V = m. R. T
m= P. V
R. T

m = 30 psia x 1000 pies3

10.73 pies3. psi x 540 R
Lb. R

m = 5.18 Lb
14)
N (N2) = mi = 0.70 kg = 0.025 x x1000 = 25 mol
Mi 2.82 g/mol
N totales = 50 mol
N (co2) = mi = 1.10kg = 0.025 x x1000 = 25 mol
Mi 44g/mol

Pt = Nt x R x T = 50 mol x 8.314 L x kpa x 300 k

V mol x k______
100 L
Pt = 12471 = 1247.1 kpa
10

Ahora:

Pa(N2) = 623.55 kpa

Calculo del volumen de cada componente

Pi.V = Ni. Ru. T

V(N2) = Ni. Ru. T

Pi

V(N2) = 25 mol x 8.314 kpa. L x 300 k

mol. k_______
623.55 kpa

V(N2) = 100 L = 0.1 m3

13) Resolucin:

GAS A.G Mi Ri Ni Xi A.V Rm=YiRi

O2 32% 32 0.260 1 0.19 19 0.083
CO2 56% 44 0.189 1.27 0.24 24 0.106
He 12% 4 2.078 3 0.57 57 0.249
Total 100% 5.27 1 100 0.438

Rm = 32 x 0.260 KJ
Kg.K

P = 120 Kpa
T=
M = 0.050 Kg

V = 0.063 m3 x 1000L = 63L

1m3

5) Pregunta:
 GAS A.V Xi Mi XiMi Yi A.G
N2 70% 0.7 28 19.6 0.60 60
CO2 20% 0.2 44 8.8 0.27 27
CO2 10% 0.1 44 4.4 0.13 13
TOTAL 100% 1 32.8 1 100

Calculo de Yi:

Yi(co2) = XiMi = 19.6 = 0.60

XiMi 32.8

Yi(N2) = XiMi = 8.8 = 0.27

XiMi 32.8

Yi(H2O) = XiMi = 4.4 = 0.13

XiMi 32.8

6) Resolucin:

GAS A.V Xi Mi XiMi Yi A.V

CO2 50% 0.5 44 22 0.63 63
N2 40% 0.5 28 11.2 0.32 32
H2O 10% 0.1 18 1.8 0.05 5
Total 100% 1 35 1 100

Calculo de Yi:

Yi(co2) = XiMi = 22 = 0.6285

XiMi 35

Yi(N2) = XiMi = 11.2 = 0.32

XiMi 35

Yi(H2O) = XiMi = 1.8 = 0.0514

 XiMi 35

a) la masa molar aparente

XiMi= 35

b)
V = 0.077 m3
m = 0.060 kg = 60
T = 77 C = 350k

P.V = N. R. T

P = m. R. T = 60g x 8.314 L. Kpa x 350 K

V mol. K .
77 L

P = 24942 = 2267.5 Kpa

11

Pregunta N 07:

a) La fraccin msica de cada componente

masa de soluto
Fraccin masica=
masade soluto+ masa de disolvente

70
C H 4 F m= =0.412
1) 70+100
10
C 2 H 3 F m= =0.09
2) 10+100
20
N 2 F m= =0.16
3) 20+100

b) El flujo msico en :
 m= pv
m=5 x 120
kg
m=600
s

Pregunta 08:

GAS AG Mi Ri Ni Xi AV
N2 60 28.00 0.297 2.14 0.68 68
CO2 30 44.00 0.189 0.68 0.22 22
O2 10 32.00 0.260 0.31 0.10 10
a) L
100 3.13 1.00 100
a
CO2
presin de componente :

Vm=15 psia

T =140 F R=140+460=600 R

F t3
9 v =20
s

N i RU T
P i=
V

0.68 x 10.73 x 600

P i=
20

psia
Pi=218.89
molxs

b) Flujo msico de la mezcla sobre lbm/s:

 m= pv

1
m=218.19 x 15 x 144 x 32.174 x
6.0022 ( 30 ) x 10 23

lb m
m=8.42 x 1019
s

1) Resolucin:

GAS AV Xi Mi Mm Ru Ni Mi AG
CH4 40 0.40 16 6.4 0.518 0.058 0.93 0.25
CO 60 0.60 28 16.8 0.297 0.101 0.80
100 1.00 0.16 3.72 1.00

2) Resolucin:

GAS A.G Mi Ri Ni Xi A.V mi (kg)

N2 56% 28 0.297 2 0.62 62 56

CO 20% 28 0.297 0.71 0.22 22 19.88
O2 16% 32 0.260 0.5 0.16 16 16

TOTAL 3.21 1 100 91.88

Ni = mi
Mi
mi(N2) = Ni x mi = 56 kg
mi(Co) = Ni x mi = 19.88 mm = 91.88 kg
mi(O2) = Ni x mi = 16
Calculo de V (m3)
m = 0.20 kg
T = 67 C
P = 140 kpa

P x V = Nm x R x T
V = Nm x R x T
P
V = 3.21 mol x 8.314 L . kpa x 340 R = 64.8 L = 0.065m3
mol . R________
140 kpa

3) Resolucin:

GAS mi Mi Ni Xi AV Rm=YiR AG
i
CO 0.28 28 0.01 0.33 33 0.0008 0.28
O2 0.16 32 0.005 0.17 17 0.0004 0.16
CO2 0.66 44 0.15 0.50 50 0.0012 0.66
0.03 1.00 100

4) Resolucin:
Gas AV Xi Mi Ni Mm Nm mm AG
CO 60 0.60 28 1.42 16.8 1.020 17.136 0.40
CO2 33 0.33 44 1.22 14.52 1.603 23.28 0.54
O2 7 0.07 32 0.19 2.24 1.166 2.612 0.06
100 1 2.83 3.789 43.028
12) Resolucin:

T = 300 K

P = 160 Kpa

GAS A.V Xi Mi XiMi Yi A.G

O2 60% 0.6 32 19.2 0.52 52
CO2 40% 0.4 44 17.6 0.48 48
TOTAL 100 1 36.8 1 100

Clculo de Yi:

Yi(O2) = XiMi = 19.2 = 0.5217

XiMi 36.8

Yi(co2) = XiMi = 17.6 = 0.4783

XiMi 36.8

Clculo de presin parcial O2 (Kpa):

Pa = Pt . Xa = 160 Kpa x 0.6 = 96 Kpa

Clculo de volumen:

P. V = N. R. T

V= N. R. T = V= m. R. T
P P

V= 130g x 8.314 L.Kpa x 300k

Mol.k______
160 Kpa
V= 162123 = 2026.54 L = 2.03 m3
80

16) Resolucin:

GAS A.G Mi Ri Ni Xi AV Rm=YiRi

O2 24% 32 0.260 0.75 0.11 11 0.0624
CO2 56% 44 0.189 1.27 0.18 18 0.1058
H2 20% 4 2.078 5 0.71 71 0.4156
TOTAL 100 7.02 1 100 0.5838

Calculo de T

T= P.V = 23 psia x 1.90 pies3

N. R 0.10 Lb x 10.73 pies3. Psia
Lb-mol.R
T= 41 R = 419 F

17) Resolucin:

GAS A.G Mi Ri Ni Xi XiMi Rm=YiR

i
O2 80% 32 0.260 2.5 0.2 6.4 0.208
H2 20% 2 4.124 10 0.8 1.6 0.8248
TOTAL 12.5 1 8 1.0328

a) Ptotal= 50 psia x 0.2 = 10 psia

b) XiMi = 0.018 Lb/mol

c) Rm= YiRi = 1.0328 Btu/Lm.R

d) Clculo de temperatura (F)

mm= 0.14 Lb

T= 50 psia x 2 pies3
 0.14 Lb x 10.73 pies3. Psia
Lb-
T= 67R = - 393F

15) Resolucin:

V= 0.1 m3 = 100 L
CO2= 1.10 Kg
T= 27C =300K

GAS Yi Mi Ri Ni Xi Rm=YiRi
N2 0.39 28 0.297 25 0.5 0.1158
CO2 0.68 44 0.189 25 0.5 0.1153
1 50 1 0.2311

Clculo de Ni:

N(N2) = O.70 kg = 0.025 X 1000 = 25 mol

28
N(CO2) = 1.10 kg = 0.025 X 1000 = 25 mol
44

Clculo de Yi:

Yi(N2) = 0.70 kg = 0.39

1.8 kg

Yi(CO2) = 1.10 kg = 0.61

1.8 kg

Clculo de presin total:

Pt = 50mol x L.Kpa x 300K
Mol.K_______
100L
Pt = 124.7 Kpa

Clculo de presin parcial de N2 ( Kpa)

a) Pa= 124.7 Kpa x 0.5= 62.35 Kpa

b) Clculo del volumen de cada componente

 V= 25mol x 8.314 L. Kpa x 300k
Mol.K_____________
62.35 Kpa

Clculo de Pa (Co2)

V= 25 x 8.314 x 300
62.35

V= 1000 = 1m3