Balance (New 3)

Material Molecular Formula Molecular Weight (g/mol)
Oxygen O2 31.99
Nitrogen N2 28.01
Cumene C9H12 120.19
Cumene Hydroperoxide C9H12O2 152.2
Acetone C3H6O 58.08
Phenol C6H6O 94.046
Alpha-methyl Styrene C9H10 118.179

Water
Sulphuric Acid H2SO4 98.072
Sodium Hydroxide NaOH 39.99
142.036 (Anhydrous)
Sodium Sulphate Na2SO4 322.20 (Decahydrate)
Apearance Odor Density (g/cm3)
Colourless Odorless 1.14
Colourless Odorless 0.807-1.251
Colourless Aromatic odor 0.865
Colourless to pale yellow liquid Sharp irritating odor 1.04
Colourless Fruity scent 0.791 @ 20C
Transparent crystalline solid or in solution will be Sharp burning taste 1.071 @ 25/4C
colourless to slight pink
Colourless Unpleasant odor 911 @ 20C
Colourless Odorless 1.8302

Colourless to white Odorless 2.13
White Powder (soluble in water) Odorless 2.671

Critical Temperature Boiling Point (C) Flash Point (C) Viscosity
- -182.9 N/A
- -195.7 N/A
357.85 152 43
331.85 153 57
508.2 56.3 -20
421.1 182 79
654 165.3 45
340 337 N/A

N/A 1388 N/A
N/A 1429 N/A

Molecular Weight
Cumene
Oxygen
Nitrogen
Cumene Hydroperoxide (CHP)
Air
Assume:
Mole of Pure Cumene fed(Stream 1a)
Mole of Cumene fed into reactor (Stream 1c)
Oxygen Required for reaction

Oxygen per 1kmol of Air
Nitrogen per 1kmol of Air
Air Required for reaction
Percentage Excess of Air
Total Amount of Air fed (Stream 2)
Oxygen in stream 2
Nitrogen in stream 2
Fractional Conversion of cumene in both reactors

Fractional Conversion in 1st reactor
Fractional Conversion in 1nd reactor
Ratio of conversion in 1st reactor

Air fed into 1st reactor (Stream 3)
Oxygen fed into 1st reactor (Stream 3)
Nitrogen fed into 1st reactor (Stream 3)
Ratio of conversion in 2nd reactor

Air fed into 1st reactor (Stream 4)
Oxygen fed into 1st reactor (Stream 4)
Nitrogen fed into 1st reactor (Stream 4)
Cumene consumed in 1st reactor
Stoichiometric ratio of Cumene to Oxygen

Oxygen consumed in reactor
Oxygen balance around 1st reactor

Oxygen in Stream 6
Stoichiometric ratio of Cumene to CHP

CHP produced in 1st reactor
Cumene balance around 1st reactor

Unconverted Cumene
Nitrogen balance around 1st reactor

Nitrogen in Stream 6
Mole Fraction in Stream 5

Mole fraction of liquid Cumene in Stream 5 (xC)
Mole fraction of liquid CHP in Stream 5 (XCHP)
Assume:
1st reactor Operating Temperature
2nd reactor Operating Pressure
Vapour pressure of Cumene at 80C

Vapour pressure of CHP at 80C
Partial pressure of Oxygen and Nitrogen in 1st reactor
Total molar flow rate in Stream 6

Cumene in Stream 6
CHP in Stream 6

Mole Fraction of vapour Cumene in Stream 6a & 6b (yC)
Mole Fraction of vapour CHP in Stream 6a & 6b (yCHP)
Assume:
Total condensation occurs in the separator therefore all of the cumene and cumene hydroperoxide is
(Cumene and cumene hydroperoxide is negligible in negible concentration in vapour s
Mole Fraction of Cumene leaving the 1st separator Stream 7a & 7b (xc)
Mole Fraction of CHP leaving the 1st separator Stream 7a & 7b (xc)
Assume:
1st Separator Operating Temperature
2nd SeparatorOperating Pressure

Vapour pressure of CHP at 50C
Total molar flow rate in Stream 8a &8b

Cumene in Stream 8a &8b
CHP in Stream 8a &8b
Mole Fraction in Stream 8a &8b

Mole Fraction of vapour Cumene in Stream 8a &8b (yC)
Mole Fraction of oxygen and nitrogen CHP in Stream 8 (yO2+N2)
Oxygen in Stream 8a &8b
Mole Fraction of oxygen CHP in Stream 8 (yO2)

Nitrogen in Stream 8a &8b
Mole Fraction of nitrogen CHP in Stream 8 (yN2)
Molar flowrate of Stream7a & 7b

Cumene in Stream7a & 7b
Cumene Hydroperoxide in Stream7a & 7b
Brine was the cooling medium that was used. However, the salt present is used to lower the freezing
solution allowing for the heat transfer ability to be improved. Un fortunately, excess salt must be r
osmosis in order to prevent corrosiion of equipment.
Assume:
1st Separator Operating Temperature
2nd Separator Operating Pressure
Mole Fraction of Cumene leaving the 2nd separator Stream 8a (xc)
Total molar flow rate in Stream 10a

Cumene in Stream 10a
Mole Fraction in Stream 10a

Mole Fraction of vapour Cumene in Stream 10a (yC)
Mole Fraction of oxygen and nitrogen in Stream 10a (yO2+N2)
Oxygen in Stream 10a
Mole Fraction of oxygen CHP in Stream 8b (yO2)

Nitrogen in Stream 10a
Mole Fraction of nitrogen CHP in Stream 8b (yN2)
Cumene Stream 9a & 9b
Weight percent lost in Stream 10a & 10b
Moles of Cumene in Stream 5
Moles of CHP in Stream 5
Stream
9a Condenser 2
Stream
7a Condenser 1
Stream
7a Condenser 1
Stream 6a
Stream 6
Stream Stream
1a 1c Reactor 1
Stream
1b
Stream 3
Stream 2
120.00 kg/kmol
32.00 kg/kmol
28.02 kg/kmol
152.00 kg/kmol
28.90 kg/kmol
216.6666666667 kmol/hr
26000 kg/hr
927.36 kmol/hr
111282.80 kg/hr
927.36 kmol/hr
21% kmol/kmol
79% kmol/kmol
4415.98 kmol/hr
60%
7065.57 kmol/hr
204195.11 kg/hr
1483.77 kmol/hr
47480.66 kg/hr
5581.80 kmol/hr
156402.15 kg/hr
25%
17%
8%
0.68
4804.59 kmol/hr
138852.67 kg/hr
1008.96 kmol/hr
32286.85 kg/hr
3795.63 kmol/hr
106353.46 kg/hr
0.32
2260.98 kmol/hr
65342.43 kg/hr
474.81 kmol/hr
15193.81 kg/hr
1786.18 kmol/hr
50048.69 kg/hr
157.65 kmol/hr
18918.08 kg/hr
1.00
157.65 kmol/hr
5044.82 kg/hr
851.31 kmol/hr
27242.03 kg/hr
1.00
157.65 kmol/hr
23962.90
769.71 kmol/hr
3795.63 kmol/hr
106353.46 kg/hr
0.82
0.18
80.00 C
5.00 atm
3800.00 mmHg
72.53 mmHg
7.91 mmHg
3738.96 mmHg
4722.80 kmol/hr
74.11 kmol/hr
8893.41 kg/hr
1.75 kmol/hr
265.95 kg/hr
0.016
0.0004
and cumene hydroperoxide is condensed to liquid.
ble concentration in vapour stream).
0.98
0.02
50.00 C
5.00 atm
3800.00 mmHg
18.61 mmHg
0.52 mmHg
3781.81 mmHg
2334.65 kmol/hr
11.17 kmol/hr
1340.48 kg/hr
0.0074 kmol/hr
1.13 kg/hr
0.0048 Negligible Amount

0.99522
425.66 kmol/hr
13621.01 kg/hr
0.18
1897.81 kmol/hr
53176.73 kg/hr
0.81
26.75 kmol/h
26.14 kmol/h
3136.27 kg/hr
0.62 kmol/h
93.79 kg/hr
t is used to lower the freezing temperature of the

unately, excess salt must be removes by reverse
n of equipment.
5.00 C
5.00 atm
3800.00 mmHg
1.00
1.18 mmHg
3798.82 mmHg
2324.19 kmol/hr
0.72 kmol/hr
86.4886 kg/hr
0.0003 Negligible Amount

0.99969
425.65671 kmol/hr
13621.01472 kg/hr
0.21
1897.81 kmol/hr
53176.73 kg/hr
0.79
10.46 kmol/hr
1254.88 kg/hr
0.0000006 kg/kg
0.56 ppm
695.59 kmol/hr
83471.32 kg/hr
164.78 kmol/hr
25046.71 kg/hr
Stream 10a
ser 2
Stream 8a
Stream 7b
er 1
Stream 7b
er 1
Stream 5
or 1
Stream 4
Recycle
Cumene (Stream 27)
Cumene Hydroperoxide (Stream 27)
Single Pass Conversion 1st Reactors

Single Pass Conversion 2nd Reactors
Single Pass Conversion Reactor and Concentrator
Overall conversion
Oxygen in Stream 6a & 6b
Nitrogen in Stream 6a & 6b
Total molar flow rate in Stream 6a & 6b

Cumene in Stream 6a & 6b
CHP in Stream 6a & 6b

Negligible Amount
Stream 10b
Condenser 2 Stream 9b
Stream 8b
tream 7b
Condenser 1
tream 7b
Condenser 1
Stream 6b
5
710.69 kmol/hr
8.88 kmol/hr
719.57
0.17
0.08
0.3441908829
0.9900978184
Assume:
Offgas consist of 79% of the Air fed and the excess oxygen within the system
Offgas Flowrate = Total Amount of Air fed - Amount of Oxygen required for Reaction
Offgas 203267.7 kg/hr
Material Balance:
Cumene fed + Total Amount of Air fed = Offgas + Liquid out of Concentator
Liquid out of Concentator = Cumene fed + Total Amount of Air fed -Offgas
Liquid out of Concentator 112210.2 kg/hr

425.66 kmol/hr
13621.01 kg/hr
1897.81 kmol/hr
53176.73 kg/hr
A B C
Cumene 6.93666 1460.793 207.777
CHP 6.95989 1116.91 104.264
2361.40 kmol/hr
37.06 kmol/hr
4446.70 kg/hr
0.87 kmol/hr
132.97 kg/hr
A B C
Cumene 6.93666 1460.793 207.777
CHP 6.95989 1116.91 104.264
A B C
Cumene 6.93666 1460.793 207.777
Cumene consumed in 2nd reactor 55.65
6677.71
Stoichiometric ratio of Cumene to Oxygen 1.00
Oxygen consumed in reactor 55.65
1780.72
Oxygen balance around 2nd reactor
Oxygen in Stream 12 419.16
13413.09
Stoichiometric ratio of Cumene to CHP 1.00
CHP produced in 2nd reactor 55.65
8458.43
Total CHP in reactor 2 Stream 11 220.43
33505.138
Cumene balance around 2nd reactor
Unconverted Cumene Stream 11 639.95
76793.61
Nitrogen balance around 2nd reactor
Nitrogen in Stream 12 1786.18
50048.69
Mole fraction of liquid Cumene in Stream 10 (xC) 0.74
Mole fraction of liquid CHP in Stream 10 (XCHP) 0.26
Assume:
1st reactor Operating Temperature 80
2nd reactor Operating Pressure 5.00
3800.00
Vapour pressure of Cumene at 110C 72.53

Vapour pressure of CHP at 110C 7.91
Partial pressure of Oxygen and Nitrogen in 1st reactor 3744.02
Total molar flow rate in Stream 12 2238.31

Cumene in Stream 12 31.7778
3813.34
CHP in Stream 12 1.1944

181.54
Mole Fraction in Stream 12a & 12b
Mole Fraction of vapour Cumene in Stream 12a & 12b (yC) 0.014
Mole Fraction of vapour CHP in Stream 12a & 12b (yCHP) 0.0005
Assume:
Total condensation occurs in the separator therefore all of the cumene and
cumene hydroperoxide is condensed to liquid. (Cumene and cumene
hydroperoxide is negligible in negible concentration in vapour stream).
Mole Fraction of Cumene leaving the 1st separator Stream 13a & 13b (xc) 0.96
Mole Fraction of CHP leaving the 1st separator Stream 13a & 13b (xc) 0.04
Assume:
1st Separator Operating Temperature 50.00
2nd Separator Operating Pressure 5.00
3800.00

Vapour pressure of CHP at 50C 0.52
Total molar flow rate in Stream 14a &14b 1107.90

Cumene in Stream 14a &14b 5.23
627.55
CHP in Stream 14a &14b 0.0055

0.84
Mole Fraction in Stream 14a &14b
Mole Fraction of vapour Cumene in Stream 14a &14b (yC) 0.0047
Mole Fraction of oxygen and nitrogen CHP in Stream 14a &14b (yO2+N2) 0.99528
Oxygen in Stream 14a &14b 209.58
6706.55
Mole Fraction of oxygen CHP in Stream 12 (yO2) 0.21
Nitrogen in Stream 14a &14b 893.09
25024.34
Mole Fraction of nitrogen CHP in Stream 12 (yN2) 0.79
Molar flowrate of Stream 13a & 13b 11.25

Cumene in Stream 13a & 13b 10.84
1301.21
Cumene Hydroperoxide in Stream 13a & 13b 0.41
61.95
Brine was the cooling medium that was used. However, the salt present is
used to lower the freezing temperature of the solution allowing for the heat
transfer ability to be improved. Un fortunately, excess salt must be removes
by reverse osmosis in order to prevent corrosiion of equipment.
Assume:
1st reactor Operating Temperature 5.00
2nd reactor Operating Pressure 5.00
3800.00
Mole Fraction of Cumene leaving the 2nd separator Stream 12a (xc) 1.00
Total molar flow rate in Stream 16 a & 16b 1103.01

Cumene in Stream 16 a & 16b 0.3420
41.0456
Mole Fraction in Stream 16 a & 16b

Mole Fraction of vapour Cumene in Stream 16 a & 16b (yC) 0.0003
Mole Fraction of oxygen and nitrogen CHP in Stream 16 a & 16b (yO2+N2) 0.99969
Oxygen in Stream 16 a & 16b 209.58
6706.55
Mole Fraction of oxygen CHP in Stream 16 a & 16b (yO2) 31.99
Nitrogen in Stream 16 a & 16b 893.09
25024.34
Mole Fraction of nitrogen CHP in Stream 12b (yN2) 28.01
Cumene in Stream 15 a & 15b 4.89

587.17
Weight percent lost in Stream 16 a & 16b 0.0000007
0.74
Moles of Cumene in Stream 11 608.17

72980.27
Moles of CHP in Stream 11 219.23
6142.94
Stream 16a
Stream
15a Condenser 2
Stream 14a
Stream
13a Condenser 1
Stream 12a
Stream 12
Stream 5
Reactor 1
Stream 4
kmol/hr
kg/hr
kmol/hr
kg/hr
kmol/hr Oxygen in Stream 12a & 12b 209.58

kg/hr 6706.55
kmol/hr
kg/hr
kmol/hr
kg/hr
kmol/hr
kg/hr
kmol/hr Nitrogen in Stream 12a & 12b 893.09

kg/hr 25024.34
The stream leaving the reactor (stream 10) is assumed to be all liquid based
actuality there would minute amounts of oxygen, nitrogen, cumene and CHP tr
mole fraction that is used initally is an assumed value using the flow rates o
amount of cumene and CHP leaving in vapour phase (stream 9). This comopos
is determ
C
atm
mmHg
mmHg Cumene
mmHg CHP
mmHg
kmol/hr Total molar flow rate in Stream 12a & 12b 1119.15
kmol/hr Cumene in Stream 12a & 12b 15.89
kg/hr 1906.67
kmol/hr CHP in Stream 12a & 12b 0.5972

kg/hr 90.7724
C
atm
mmHg
mmHg Cumene
mmHg CHP
mmHg
kmol/hr
kmol/hr
kg/hr
kmol/hr Negligible Amount

kg/hr
Negligible Amount
kmol/hr
kg/hr
kmol/hr
kg/hr
kmol/h
kmol/h
kg/hr
kmol/h
kg/hr
C
atm
mmHg
mmHg Cumene
mmHg
kmol/hr
kmol/hr
kg/hr
Negligible Amount
kmol/hr
kg/hr
kmol/hr
kg/hr
kmol/hr
kg/hr
kg/kg
ppm
kmol/hr
kg/hr
kmol/hr
kg/hr
Stream 16a
Stream 16b
Condenser 2 Stream 15b
Stream 14b
Stream 14a Stream 14b
Stream 13b
Condenser 1
Stream 12b
Stream 11
kmol/hr
kg/hr
kmol/hr
kg/hr
o be all liquid based on the streams composition and boiling point of components. However, in
, cumene and CHP trapped in the vapour phase. These amounts are assumed negible hence the
sing the flow rates of cumene and CHP leaving as liquid without taking into consideration the
am 9). This comoposition is recalculated when the actual value of the vapour stream (stream 9)
is determine.
A B C
6.93666 1460.793 207.777
6.95989 1116.91 104.264
kmol/hr
kmol/hr
kg/hr
kmol/hr
kg/hr
A B C
6.93666 1460.793 207.777
6.95989 1116.91 104.264
A B C
6.93666 1460.793 207.777
Total mole of Stream 11 827.40 kmol/hr
Moles of Cumene in Stream 11 608.17 kmol/hr
72980.27 kg/hr
Moles of CHP in Stream 11 219.23 kmol/hr
6142.94 kg/hr
Mole Fraction of Cumene in Stream 11 0.74 kmol/hr
Mole Fraction of CHP in Stream 11 0.26 kmol/hr
Temperature (C) 95.89

Pressure mmHg 112.5 0.148026
Vapour pressure of Cumene at 95.89C 133.71 mmHg

Vapour pressure of CHP at 95.89C 23.97 mmHg
Component xFj Kj L
Cumene 0.735 1.188
CHP 0.265 0.213 812.732
Cumene Leaving Tops Stream 18 12.774153061

CHP Leaving Tops Stream 18 0.8399521304
Cumene Leaving Bottoms Stream 17 595.39480373
CHP Leaving Bottoms Stream 17 218.39421336
A B C
Cumene 6.93666 1460.793 207.777
CHP 6.95989 1116.91 104.264
xj D yj
0.733 0.871
0.269 14.6715589456084 0.057
1.001 0.928
Stream 18
D
yDC
yDCHP
F Stream
xFC 11
xFCHP
Stream 17
W
xWC
xWCHP
Concentrator
Assume:
Mole Fraction of Cumene in Tops xDC 0.99
Mole Fraction of CHP in Tops xDCHP 0.01
Mole Fraction of Cumene Bottoms xWC 0.01
Mole Fraction of CHP Bottoms xWCHP 0.99
Feed Flow Rate Stream 17 813.789

Mole of Cumene in Feed Stream 17 595.39
Mole of Cumene Hydroperoxide in Feed Stream 17 218.39
Mole Fraction of Cumene in Feed Stream 17 xFC 0.732
Mole Fraction of Cumene Hydroperoxide in Feed Stream 17 xFCHP 0.268
Stream 20
F Stream
xFC 17
xFCHP
Stream 19
Mole of Cumene in Stream 19 2.145

Mole of Cumene Hydroperoxide in Stream 19 212.402
Mole of Cumene in Stream 20 593.249
Mole of Cumene Hydroperoxide in Stream0 20 5.992
Total Balance
F = D + W
From Hysys
From Hysys
813.79 = D + W
Sepecification
kmol/hr
kmol/hr
kmol/hr D = 813.79 - W
Cumene Balance
F xFC = D xDC
D 595.394803725 = D 0.99
yDC
yDCHP 595.394803725 = 805.6511 -
595.394803725 = 805.6511 -
0.98 W = 210.2563
W (Stream 19) = 214.5473 kmol/hr
Therefore
D (Stream 20) = 599.242 kmol/hr
CHP in distillate and cumene in the bottoms are assumed to ne negligible
W
xWC
xWCHP
kmol/hr
kmol/hr
kmol/hr
kmol/hr
+ W xWC
+ W 0.01
0.99 W + W 0.01
0.98 W
Pure CHP(Cumene present negible)
Cumene
ed to ne negligible
All recycle streams are sent to a storage tank before it is recycled.
Recycle Streams
1st Oxidizer and Separator
Molar flowrate of Stream 7a 26.75
Cumene in Stream 7a 26.14
3136.27
Cumene Hydroperoxide in Stream 7a 0.62
93.79
Cumene Stream 9a 10.46
1254.88
2nd Oxidizer and Separator

Molar flowrate of Stream 13a 11.25
1301.21
Cumene Hydroperoxide in Stream 13a 0.41
61.95
587.17
1st Oxidizer and Condenser (1&2)

Molar flowrate of Stream 21 37.21
4391.15
Cumene Hydroperoxide in Stream 21 0.62
93.79
1st Oxidizer and Condenser (3&4)
4391.15
93.79
2nd Oxidizer and Condenser (5&6)
1888.38
61.95
3rd Oxidizer and Condenser (7&8)

1888.38
61.95
Concentrator
Cumene leaving concentrator Distillate Stream 20 593.249
CHP leaving concentrator Distillate Stream 20 5.992
Flash
Cumene Leaving Tops Stream 18 12.7741530615
CHP Leaving Tops Stream 18 0.8399521304
Contents are stored in the vessel before it is recycle
Moles of Cumene in Stream 1b 710.68

Moles of CHP in Stream 1b 8.88
Total flow in Stream 1b 719.56

1st Oxidizer and Separator
kmol/h Molar flowrate of Stream 7a 26.75
kmol/h Cumene in Stream 7a 26.14
kg/hr 3136.27
kmol/h Cumene Hydroperoxide in Stream 7a 0.62
kg/hr 93.79
kmol/hr Cumene Stream 9a 10.46
kg/hr 1254.88
2nd Oxidizer and Separator

kmol/h Molar flowrate of Stream 13a 11.25
kmol/h Cumene in Stream 13a 10.84
kg/hr 1301.21
kmol/h Cumene Hydroperoxide in Stream 13a 0.41
kg/hr 61.95
kmol/hr Cumene in Stream 15a 4.89
kg/hr 587.17
kmol/h
kmol/h
kg/hr
kmol/h
kg/hr
kmol/h
kmol/h
kg/hr
kmol/h
kg/hr
kmol/h
kmol/h
kg/hr
kmol/h
kg/hr
kmol/h
kmol/h
kg/hr
kmol/h
kg/hr
kmol/hr
kmol/hr
kmol/hr
kmol/hr
kmol/hr
kmol/hr
kmol/hr
Recycle
Component Approximated Value Calculated Value with
Recycle
Cumene 710.69 710.68

CHP 8.88 8.88
kmol/h
kmol/h Stream 21
kg/hr
kmol/h Stream 22
kg/hr
kmol/hr Stream 23 Recycle Storage Tank
kg/hr Stream 24
Stream 18
kmol/h
kmol/h Stream 20
kg/hr
kmol/h
kg/hr
kmol/hr
kg/hr
Difference Between Squared of
Approximated Value and the
Calculated Values difference
0.0 0.000
0.0 0.000
0.000
Stream 1b
cle Storage Tank
The following equations are taking place in the reactors that are place in parallell with ea
Main Reaction
=( )/( )
=( )/( )
=Conversion
=/
Studies completed by Armstrong, Hall and Quin have deduce that the yield of acetone @
MAIN REACTION
Acetone Yield 74%
Residue at the bottom of the concentrator Stream 19 212.40
3 equally sized PFRs are in parrallel with 3 feed streans of equal flowrate.
Moles of CHP reactor 1, 2 and 3 (Stream 25, 26 and 27) 70.8006
Moles of Acetone leaving PFR (Stream 32, 33 and 34) 52.39244
Using the stoiochmetric realationship of CHP, acetone and phenol the amount of moles
Moles of CHP reacting in MAIN REACTION 52.39244
Moles of Phenol leaving PFR (Stream 32, 33 and 34) 52.39244
Hock and Lang stated that 0.1 mole conc. of H2SO4 should be added to the reactor to obt
yield of 74%
Half of the amount of CHP that reacted. Two H + ions are released from H2SO4
Moles of Aqueous H2SO4 added in reactor 1, 2 and 3 (29, 30 and 31) 7.08006
Moles of H2SO4 added (29, 30 and 31) 0.708006
Moles of H2SO4 Fed from Storage (Stream 28) 2.124018
Moles of water in reactor 1, 2 and 3 (29, 30 and 31) 6.372054
Moles of water Fed from Storage (Stream 28) 19.11616
Moles of H2SO4 leaving PFR (Stream 32, 33 and 34) 0.708006
SIDE REACTION
Remaining Moles of CHP reacting for SIDE REACTION 18.40816
Using the stoiochmetric realationship of CHP, AMS and Water the amount of moles of AMS, Water and
or returned to the beginning of the
Moles of AMS generated from reactor 1 (Stream 32, 33 and 34) 18.40816
Moles of H2O generated in reactor 1 from 2nd reaction 18.40816
Moles of O2 generated from reactor 1 9.204078
Moles of H2O leaving reactor 1 (Stream 32, 33 and 34) 24.78021
Total flow out of reactor 1 (Stream 32, 33 and 34) 148.6813
This flowrate would be similar for streams 23 and 24
Combine flow rate out of Cleavage Section
Moles of Acetone in Stream 35 157.1773

Moles of Phenol in Stream 35 157.1773
Moles of AMS in Stream 35 55.22447
Moles of H2O in Stream 35 74.34063
Moles of H2SO4 in Stream 35 2.124018
Total Flow of Stream 35 446.0438

e place in parallell with each other @60C
Side Reaction
that the yield of acetone @60C is 74%.
kmol/hr Assume the cumene that in stream is negible hence for calculation purpos
streans of equal flowrate.
kmol/hr
kmol/hr Acetone generated from reactor 1
henol the amount of moles of phenol that is generated and CHP consumed is calculated
kmol/hr
kmol/hr Phenol generated from reactor 1
ed to the reactor to obtain a
kmol/hr H2SO4 is added in a ratio with the CHP entering

kmol/hr
kmol/hr
kmol/hr Water in 40% mole conc. of H2SO4 added
kmol/hr
kmol/hr
Overall Side Reaction:
2 2+2_2 +_2
kmol/hr
of moles of AMS, Water and Oxygen that is generated is calculated. (The oxygen is removed by a vent
ed to the beginning of the process.)
kmol/hr
kmol/hr
kmol/hr
kmol/hr
kmol/hr
kmol/hr
kmol/hr
kmol/hr
kmol/hr
kmol/hr
kmol/hr
Reaction Other Reactions (These are
Other byproducts include dicu

dicumylphenol that are present
nce for calculation purpose consider CHP only Stream 31

Stream 27
3rd PFR
Stream 28
Stream 30
lated Stream 19 Stream 26
2nd PFR
Stream 29
1st PFR
Stream 25
(Equivalent to 10% of H2SO4 fed) Assume H2SO4 feed is half the feed of
CHP ie amount needed to turn all of the
feed to acetone and phenol.
Assume H2SO4 feed is half the feed of
CHP ie amount needed to turn all of the
feed to acetone and phenol.
removed by a vent
eactions (These are assumed to be negilible )
products include dicumylperoxide and

enol that are present in trace quantities
Stream 31
Stream 34
3rd PFR
Stream 30
Stream 33 Stream 35
2nd PFR
Stream 29
1st PFR
Stream 32
Flow into the mixer Stream 35 446.0438 kmoles/hr
Moles of H2SO4 in Stream 35 2.124018 kmoles/hr

Moles of H2SO4 Consumed 2.124018 kmoles/hr
Based on the Stiochiometric realationship double the amount of NaOH is needed.
Assume:
Conversion of the reaction 100%
Moles of NaOH fed into mixer Stream 36 4.248036 kmoles/hr

Chemical re
Moles of NaOH consumed 4.248036 kmoles/hr 100% Conversion _2 _4
Moles of Water fed into mixer Stream 36 0.04248 kmoles/hr 1% water in solution
_4+ 2
Moles of aqueous Na2SO4 generated 2.124018 kmoles/hr
Moles of aqueous Water generated 4.248036 kmoles/hr
Moles of aqueous Na2SO4 in Stream 37 2.124018 kmoles/hr

Moles of Acetone in Stream 37 157.1773 kmoles/hr
Moles of Water in Stream 37 78.63114 kmoles/hr
Moles of AMS in Stream 37 55.22447 kmoles/hr
Moles of Phenol in Stream 37 157.1773 kmoles/hr
Total Flow of Stream 37 450.3343 kmoles/hr

Stream 35
Mixer
Chemical reaction occuring in mixer:
_2 _4+2 _2
_4+ 2 _2
Stream 36
Stream 37
Mixer
A liquid/ liquid coalescer is used to remove the aqueous sodium salts.

Only the Na2SO4 is removed


Saturation of Sodium Sulfate at 25C (kg/100kg H2O) 28.11 http://chemicals.etacude.com/s/m
Amount of NaSO4 leaving Coalescer 2.124018 kmol/hr
301.6106 kg/hr
Amount of H2O leaving with NaSO4 Stream 30 1072.965 kg/hr
59.60918 kmol/hr
Stream 37
Coalescer
Stream 38
cals.etacude.com/s/more/na2so4.html
Stream 39
Stream 38
Storage tank is used to store the material before it is fed to distillation columns. A valve would be use



A valve would be used to manipulate the flow rate.
Stream 39
Storage Tank
Stream 40
ank
Feed conditions
Pressure 1.65 bar 1237.6023
Temperature 150 C 383
Feed rate 446.04 kmol/h
Antoine Coefficients
Component A B C
ACETONE 7.6313 1566.69 273.419
WATER 8.14019 1810.94 244.485
AMS 7.0924 1582.7 206.01
PHENOL 7.1345 1516.07 174.57
LKC- Water
HKC- AMS
Boiling point of the feed 102.1525768961 C

Component z P*(mmHg) k=P*/P
ACETONE 0.40 2882.824429365 2.3293625338
WATER 0.0489498392 823.9222467763 0.6657407204
AMS 0.1421109436 90.4637568492 0.0730959831
PHENOL 0.4044696086 45.2726662663 0.0365809487
Component Fi xF Di
ACETONE 157.177 0.40 157.177
WATER 19.022 0.05 16.16866655
AMS 55.224 0.14 2.7612233464
PHENOL 157.177 0.40 0
388.601 1.00 176.107
Condenser type to be used was determine by figure 7.16 in Seader and Henly
Performing bubble point pressure calculations (Trial).
Condenser pressure 536.81097597 mmHg
Temperature 49 C
Component z D P*/mmHg k=P*/P
ACETONE 0.8925093 591.7333788936 1.1023123695
WATER 0.0918115 93.2655642178 0.173740047
AMS 0.0156792 7.6908921718 0.0143270025
PHENOL 0.0000000 2.2558639279 0.0042023432
Since pressure is <215 psia a total condenser is used at a pressure of 30 psia . A dew point calculation
Tops Temperature (Dew Point Calculations)
Temperature 99.5654112962 C
Component zD P*/mmHg k=P*/P
ACETONE 0.8925093 2697.0137840486 1.7383266413
WATER 0.0918115 752.663550369 0.4851199164
AMS 0.0156792 81.844804565 0.0527520493
PHENOL 0.0000000 40.1911958716 0.0259047347
Tops Pressure 30.0010109267 psia
Bottoms Pressure 35.0010109267 psia
Bottom Temperature (Bubble Point Calculations)

Bottoms Pressure 1810.07462 mmHg
Components xW P* k
ACETONE 0.00 24454.3602748974 13.510139308
WATER 0.01 14218.6390218383 7.8552778238
AMS 0.25 1927.8449755342 1.0650638124
PHENOL 0.74 1545.4526084477 0.8538060207
Alpha Average
Component average
ACETONE 23.704998973
WATER 8.5166558819
AMS 1
PHENOL 0.5818731039
Using underwood to calculate the minimum reflux ratio

Component RMM/ kg/kmole Mass Flowrate of Feed kg/h xFM
ACETONE 58.08 9128.8592653098 0.2965820997
WATER 18 342.3952916526 0.0111238778
AMS 118.18 6526.4275015198 0.2120332361
PHENOL 94.05 14782.5277875755 0.4802607864
30780.2098460577
Heat of solution
q 0.9069002683 kJ/kg
1.7124377802 From Goal Seek =(_(,) (__ )+
First equation
=(_(,) (__ )+
LHS1 0.09
RHS1 0.09
Second equation
Rmin + 1 = LHS
LHS2 1.0322490498
Rmin 0.0322490498
Using R as 1.5Rmin
R 0.0483735747
Using Gilliland to calculate the no. of stages (_)/(+1)=0.75[1((_)/

(+1))^0.5667 ]
Where,
=(_)/(+1)
X 0.0153805144
RHS 0.6795927064
Therefore
N - NMin
N - 2.1844015544
N - 0.6795927064 N
0.3204072936 N
N
Stream 40
ASSUME: Tops specification- 95% of the water in the feed must be recovered
mmHg the bottoms
K Water 85% of feed
AMS 5% of feed
Feed enters as subcooled liquid
ACTUAL COMPOSITIONS
COMP FEED FMF TOPS
ACETONE 157.177 0.40 154.268
WATER 19.022 0.05 16.17
AMS 55.224 0.14 2.761
PHENOL 157.177 0.40 2.49
388.601 1.00 175.692
375.3025769 K
y=kz feed
0.9421563524 31.8671756488
0.0325879012 9.1077606709
0.0103877391 1
0.014795882 0.5004508749
0.9999278747 By Goal Seek
Using Fenske equation to fin

xD Wi xw Nmin=ln(((Dx
0.89250929 0 0 (Dxd/Wxw)LKC
0.09181149 2.853 0.0134276539 (Wxw/Dxd)HKC
0.01567922 52.463 0.2468929782 Nmin
0 157.18 0.7396793679
1.000 212.494 1.000
Phenol ln(DxD,HHKC/Wxw,HHKC
10.380194622 psia DxD,HHKC=(WxW,HHKC
DxD,HHKC
zP* 157.18
528.12753818 Sub Eq. 1 in Eq.2 157.18
8.5628506222 157.18
0.1205871693 Wxw,HHKC
0 DxD,HHKC
a . A dew point calculation is completed. Total Distillate Flow Rate:

30.001010927 psia ASSUMED Total Bottoms Flowrate:
x=z/k tops
0.5134301 32.9527793289
0.1892553 9.1962288183
0.2972248 1
0.0000000 0.4910659398
0.9999 Using Goal Seek
1551.5 mmHg
1810.07462 mmHg
y=kx bottoms
0 12.6848167696
0.1054779519 7.375405804
0.2629567766 1
0.6315426977 0.8016477611
Hv /kJ/kg Hv,feed /kJ/kg Cp kJ/kg K Cp,feed kJ/kg C
1475 2.87 Taken from Hysys by sim
=(_(,) (__ )+)/

=(_(,) (__ )+)/
_)/
= 0.6795927064 N + 0.6795927064
= 0.6795927064 N + 0.6795927064
= 2.1844015544 + 0.6795927064
= 2.8639942608
= 8.9386050745
Stream 42
Stream
41
ed must be recovered in the tops and 95% of the AMS in the feed goes to
the bottoms
TMF BOTTOMS BMF

0.87806 2.910 0.0137
0.09203 2.85 #
0.01572 52.463 #
0.01420 154.68 #
1.00 212.909 1.00
Fenske equation to find minimum reflux ratio

Nmin=ln(((Dxd/Wxw)LKC)*((Wxw/Dxd)HKC))/lnLCK,H
5.66667
19.00000 2.11875=Wxw,HHKC
2.1844015544
Using fenske to calculate the dist

HHKC
/Wxw,HHKC)=Nminlni,H+ln(DxD,H/WxW,H)
C
=(WxW,HHKC)exp(Nminlni,H+ln(DxD,H/WxW,H))
= 0.01612638 Wxw,HHKC
= DxD,HHKC + Wxw,HHKC
= 0.01612638 Wx w,HHKC +
= 1.01612638 Wxw,HHKC
= 154.6828541977
= 2.4944747505
istillate Flow Rate: 175.69214031 388.60109

ottoms Flowrate: 212.908945158
Algorithm that was used.
n from Hysys by simulating feed stream

5=Wxw,HHKC + 0.00038669Wxw,HHKC
Using fenske to calculate the distribution of the non key components.

Acetone
Eq. 1 DxD,HHKC
Eq. 2 157.18
Wxw,HHKC Sub Eq. 1 in Eq.2 157.18
157.18
Wxw,HHKC
DxD,HHKC
DxD,LLKC =
2.11875=DxD,LLKC+ Wxw,LLKC
2.11875 =
Wxw,LLKC 0.039221
DxD,LLKC 2.079529
2.11875
= 53.0211206695 Wxw,HHKC Eq. 1
= DxD,HHKC + Wxw,HHKC Eq. 2
= 53.0211 Wx w,HHKC + Wxw,HHKC
= 54.0211 Wxw,HHKC
= 2.9095532821
= 154.267775666
Wxw,LLKC
54.0211206695 Wxw,LLKC
Feed conditions
Pressure 30.0010109267 psia 1551.3523
Temperature 80 C 353.15
Component A B C
ACETONE 7.6313 1566.69 273.419
WATER 8.14019 1810.94 244.485
AMS 7.0924 1582.7 206.01
PHENOL 7.1345 1516.07 174.57
LKC- Acetone
HKC- Water

ACETONE 0.88 1722.9847908325 1.1106341342
WATER 0.0920283999 408.5086726962 0.263324249
AMS 0.0157162599 41.4071500909 0.0266910042
PHENOL 0.0141979871 17.7665486045 0.011452298
Sharp Separation
Component Fi xF Di
ACETONE 154.268 0.88 152.725
WATER 16.169 0.09 0.162
AMS 2.761 0.016 0
PHENOL 2.494 0.014 0
175.692 1.00 152.887
Temperature 49 C
ACETONE 0.9989424 591.7333788936 1.0008916664
WATER 0.0010576 93.2655642178 0.1577547073
AMS 0.0000000 7.6908921718 0.0130088147
PHENOL 0.0000000 2.2558639279 0.0038156972
ACETONE 0.9989424 1557.1089035553 1.0036151489
WATER 0.0010576 355.5962182943 0.2291951133
AMS 0.0000000 35.4304648685 0.0228362648
PHENOL 0.0000000 14.717606517 0.00948605

Components xW P* k
ACETONE 0.07 5528.0180786509 3.0540277277
WATER 0.70 1983.3499273668 1.0957282675
AMS 0.12 236.8913287793 0.1308737917
PHENOL 0.11 140.5816699192 0.077666229
Alpha Average
Component average
ACETONE 3.7199523398
WATER 1
AMS 0.1064505391
PHENOL 0.050342765

ACETONE 58.08 8959.8724106839 0.9131698901
WATER 18 291.0359979047 0.0296617293
AMS 118.18 326.321375076 0.033257935
PHENOL 94.05 234.6053502833 0.0239104456
9811.8351339479
Heat of solution
q 1.0053011191 kJ/kg
1.0744000346 From Goal Seek
=(_(,) (__ )+)/
First equation
=(_(,) (__ )+)/
LHS1 -0.005
RHS1 -0.005
Second equation
Rmin + 1 = LHS
LHS2 1.390414056
Rmin 0.390414056
Using R as 1.5Rmin
R 0.585621084

(+1))^0.5667 ]
Where,
=(_)/(+1)
X 0.1231107671
RHS 0.5211599533
Therefore
N - NMin
N - 6.9956335187
N - 0.5211599533 N
0.4788400467 N
N
Stream 42
mmHg to the bottoms
K Acetone 99.0% of feed
Water 1.00% of feed
ACTUAL COMPOSITIONS
COMP FEED FMF TOPS
ACETONE 154.268 0.87806 152.7250979
WATER 16.169 0.09203 0.16
AMS 2.761 0.01572 4.36E-09
PHENOL 2.494 0.01420 2.09E-11
175.692 1.00 152.887
356.20048471 K
y=kz feed
0.975200468 4.2177434801
0.0242333093 1
0.0004194828 0.1013617405
0.0001625996 0.0434912397

0.99894244 1.543 0.0676454152 (Dxd/Wxw)LKC
0.00105756 16.007 0.7018956454 (Wxw/Dxd)HKC
0 2.761 0.1210778458 Nmin
0 2.494 0.1093810936
1.000 22.805 1.000
AMS ln(DxD,HHKC/Wxw,HHKC
DxD,HHKC
zP* 2.7612
591.10758643 Sub Eq. 1 in Eq.2 2.7612
0.0986337578 2.7612
0 Wxw,HHKC
0 DxD,HHKC

x=z/k tops
0.9953441 4.3788680066
0.0046142 1
0.0000000 0.0996367876
0.0000000 0.041388535
1551.5 mmHg 2.0820701583 psia
1810.07462 mmHg 2.4290701583 psia
y=kx bottoms
0.2065909735 2.7872126862
0.7690868995 1
0.0158459168 0.1194400068
0.0084952171 0.0708809212
Hv /kJ/kg Hv,feed /kJ/kg Cp kJ/kg C Cp,feed kJ/kg C
1987 3.453 Taken from Hysys by sim
=(_(,) (__ )+)/

=(_(,) (__ )+)/
_)/
_)/
= 0.5211599533 N + 0.5211599533
= 0.5211599533 N + 0.5211599533
= 6.9956335187 + 0.5211599533
= 7.516793472
= 15.6979215149
Stream 44
Stream
43
ed must be recovered in the tops and 95% of the AMS in the feed goes
to the bottoms
TMF BOTTOMS BMF

0.999 1.543 0.0676
0.00 16.007 0.70
2.85E-11 2.761 0.121
1.37E-13 2.49 0.11
1.00 22.81 1.00
8870.273686577 0.999672
2.910359979 0.000328
5.15572387E-007 5.810E-011
0.000000002 2.217E-013
8873.184047074 1

99.00000
99.00000 2.11875=Wxw,HHKC
6.9956335187
Using fenske to calculate the distri

HHKC
C
= 0.00000000 Wxw,HHKC
= 0.00000000 Wx w,HHKC +
= 1.00000000 Wxw,HHKC
= 2.761223342
= 4.36263962E-009



Phenol
Eq. 1 DxD,HHKC
Eq. 2 2.4945
2.4945
Wxw,HHKC
DxD,HHKC
DxD,LLKC =
2.11875 =
Wxw,LLKC 2.11875
DxD,LLKC 1.78E-011
2.11875
= 8.386722E-012 Wxw,HHKC Eq. 1
= 8.39E-12 Wx w,HHKC + Wxw,HHKC
= 1.00000000 Wxw,HHKC
= 2.4944747505
= 2.092047E-011
Wxw,LLKC
1 Wxw,LLKC
Feed conditions
Pressure 35.0010109267 psia 1809.9023
Component A B C
ACETONE 7.6313 1566.69 273.419
WATER 8.14019 1810.94 244.485
AMS 7.0924 1582.7 206.01
PHENOL 7.1345 1516.07 174.57
LKC- Water
HKC- AMS

ACETONE 0.01367 21821.9074981889 12.056953461
WATER 0.0134014759 12249.069332378 6.7678070255
AMS 0.2464116458 1649.741657015 0.9115086929
PHENOL 0.7265211618 1297.4729830589 0.7168746075
Sharp Separation
Component Fi xF Di
ACETONE 2.9096 0.0137 2.9096
WATER 2.853 0.01 2.825
AMS 52.463 0.246 0.525
PHENOL 154.683 0.727 0
212.909 1.00 6.259
Temperature 49 C
ACETONE 0.4648631 591.7333788936 1.8618982773
WATER 0.4513157 93.2655642178 0.293461548
AMS 0.0838212 7.6908921718 0.0241995118
PHENOL 0.0000000 2.2558639279 0.0070981109
ACETONE 0.4648631 5659.3049234923 3.6477567559
WATER 0.4513157 2046.7903222597 1.3192774249
AMS 0.0838212 245.1282682027 0.1579996675
PHENOL 0.0000000 146.2969550105 0.0942970406

Components xW P* k
ACETONE 0.00 26106.375867977 14.423231831
WATER 0.00 15487.030801813 8.5562636791
AMS 0.25 2107.4306676356 1.164311785
PHENOL 0.75 1707.5907103313 0.943408492
Alpha Average
Component average
ACETONE 15.5816431036
WATER 7.6947407482
AMS 1
PHENOL 0.7245220159

ACETONE 58.08 168.9868546259 0.0080591299
WATER 18 51.3592937479 0.0024493693
AMS 118.18 6200.1061264438 0.2956884457
PHENOL 94.05 14547.9224372923 0.6938030552
20968.3747121098
Heat of solution
q 1.0944618917 kJ/kg
=(_(,) (__ )+)/
First equation
=(_(,) (__ )+)/
LHS1 -0.094
RHS1 -0.094
Second equation
Rmin + 1 = LHS
LHS2 2.1334526843
Rmin 1.1334526843
Using R as 1.5Rmin
R 1.7001790265

(+1))^0.5667 ]
Where,
=(_)/(+1)
X 0.2098847286
RHS 0.4403808561
Therefore
N - NMin
N - 3.3466594307
N - 0.4403808561 N
0.5596191439 N
N
Stream 41
mmHg to the bottoms
K Water 99.0% of feed
AMS 1.00% of feed
ACTUAL COMPOSITIONS
COMP FEED FMF TOPS
ACETONE 2.9096 0.01367 2.8804577
WATER 2.853 0.01340 2.825
AMS 52.463 0.24641 0.525
PHENOL 154.683 0.72652 0.53
212.909 1.00 6.759
475.5803899 K
y=kz feed
0.1647669077 13.2274695286
0.0906986027 7.4248409018
0.2246063572 1
0.5208245727 0.7864704013

0.4649 0 0 (Dxd/Wxw)LKC
0.4513 0.029 0.0001380738 (Wxw/Dxd)HKC
0.0838 51.939 0.2513361315 Nmin
0 154.683 0.7485257947
1.000 206.650 1.000
Acetone ln(DxD,HHKC/Wxw,HHKC
DxD,HHKC
zP* 2.90955
275.07499733 Sub Eq. 1 in Eq.2 2.90955
42.09221588 2.90955
0.6446598086 Wxw,HHKC
0 DxD,HHKC

x=z/k tops
0.1274381 23.0871166552
0.3420931 8.3498746891
0.5305150 1
0.0000000 0.5968179683
1551.448 mmHg 2.0820003758 psia
1810.02262 mmHg 2.4290003758 psia
y=kx bottoms
0 12.3877744919
0.0011813954 7.3487735752
0.2926336199 1
0.7061655912 0.8102713587
520.5 2.192 Taken from Hysys by sim
=(_(,) (__ )+)/

=(_(,) (__ )+)/
_)/
_)/
= 0.4403808561 N + 0.4403808561
= 0.4403808561 N + 0.4403808561
= 3.3466594307 + 0.4403808561
= 3.7870402869
= 6.7671742973
Stream 46
Stream
45
ed must be recovered in the tops and 95% of the AMS in the feed goes
to the bottoms
TMF BOTTOMS BMF

0.42614 0.0290955 0.0001411
0.4179 0.029 0.0001
0.0776 51.939 0.252
0.0784 154.15 0.75
1.00 206.15 1.00
167.2969860796 0.5070357
50.8457008104 0.1541007
62.000536632 0.1879083
49.8078873036 0.1509554
329.9511108256 1

99.00000
99.00000 2.11875=Wxw,HHKC
3.3466594307
Using fenske to calculate the distri

HHKC
C
= 99.00000000 Wxw,HHKC
= 99.00000000 Wx w,HHKC +
= 100.00000000 Wxw,HHKC
= 0.0290955328
= 2.8804577493



Phenol
Eq. 1 DxD,HHKC
Eq. 2 154.68
154.68
Wxw,HHKC
DxD,HHKC
DxD,LLKC =
2.11875 =
Wxw,LLKC 2.111496
DxD,LLKC 0.007254
2.11875
= 0.00343562 Wxw,HHKC Eq. 1
= 1.00343562 Wxw,HHKC
= 154.153242228
= 0.5296119697
Wxw,LLKC
1.00343562 Wxw,LLKC
Feed conditions
Pressure 35.0000054143 psia 1809.8503
Component A B C
ACETONE 7.6313 1566.69 273.419
WATER 8.14019 1810.94 244.485
AMS 7.0924 1582.7 206.01
PHENOL 7.1345 1516.07 174.57
LKC- AMS
HKC- Phenol

ACETONE 0.0001411 26068.6241889556 14.403746253
WATER 0.000138409 15457.7793362887 8.5409160677
AMS 0.251946358 2103.2853543437 1.1621322369
PHENOL 0.747774095 1703.8318710158 0.9414214479
Sharp Separation
Component Fi xF Di
ACETONE 0.0290955 0.0001411 0.0291
WATER 0.029 0.00 0.0285
AMS 51.939 0.252 51.419
PHENOL 154.153 0.748 1.542
206.149 1.00 53.018
Temperature 49 C
ACETONE 0.0005488 591.7333788936 74.908343906
WATER 0.0005382 93.2655642178 11.806616304
AMS 0.9698376 7.6908921718 0.9736006389
PHENOL 0.0290754 2.2558639279 0.2855729235
ACETONE 0.0005488 626.2560766504 79.278619791
WATER 0.0005382 100.9388978036 12.777994178
AMS 0.9698376 8.4273602736 1.0668311508
PHENOL 0.0290754 2.5279200964 0.3200128888

Components xW P* k
ACETONE 0.000000 8088.5068470747 30.353825381
WATER 0.000000 3299.5405489411 12.382220792
AMS 0.003392 410.533576527 1.5406137042
PHENOL 0.996608 266.0606351323 0.9984485656
Alpha Average
Component average
ACETONE 48.6619198785
WATER 16.5004634554
AMS 1.8517793886
PHENOL 1

ACETONE 58.08 1.6898685463 8.187974E-005
WATER 18 0.5135929375 2.488528E-005
AMS 118.18 6138.1050651794 0.2974115645
PHENOL 94.05 14498.1124315408 0.7024816705
20638.4209582039
Heat of solution
q 1.0211814216 kJ/kg
=(_(,) (__ )+)
First equation
=(_(,) (__ )+)
LHS1 -3.62
RHS1 -0.02
Second equation
Rmin + 1 = LHS
LHS2 2.3592835849
Rmin 1.3592835849
Using R as 1.5Rmin
R 2.0389253774

(+1))^0.5667 ]
Where,
=(_)/(+1)
X 0.2236454365
RHS 0.4290355457
Therefore
N - NMin
N - 2.3656329095
N - 0.4290355457 N
0.5709644543 N
N
Stream 45
ASSUME: Tops specification- 95% of the water in the feed must be recovere
mmHg the bottoms
K AMS 99.0% of feed
Phenol 1.00% of feed
ACTUAL COMPOSITIONS
COMP FEED FMF TOPS
ACETONE 0.0290955 0.0001411 2.88E-02
WATER 0.0285329 0.00014 0.025
AMS 51.9386111 0.25195 43.935
PHENOL 154.1532422 0.74777 2.000
206.149 1.00 45.989
487.00980854 K
y=kz feed
0.0020329164 15.2999979824
0.0011821395 9.0723618916
0.2927949846 1.2344441903
0.7039705712 1

0.0005 0 0 (Dxd/Wxw)LKC
0.0005 0 0 (Wxw/Dxd)HKC
0.9698 0.519 0.0033917743 Nmin
0.0291 152.612 0.9966082257
1.000 153.131 1.000
Acetone ln(DxD,HHKC/Wxw,HHKC
DxD,HHKC
zP* 0.0290955
0.3247325931 Sub Eq. 1 in Eq.2 0.0290955
0.0501927924 0.0290955
7.4589165316 Wxw,HHKC
0.065590216 DxD,HHKC

x=z/k tops
0.0000069 247.7357087108
0.0000421 39.9296235457
0.9090826 3.3337130733
0.0908571 1
7.8994321332 mmHg
266.47405213 mmHg
y=kx bottoms
0 30.4009905225
0 12.4014608448
0.0052254139 1.5430075792
0.9950620535 1
414.2 2.273 Taken from Hysys by sim
=(_(,) (__ )+)/

=(_(,) (__ )+)/
_)/
_)/
= 0.4290355457 N + 0.4290355457
= 0.4290355457 N + 0.4290355457
= 2.3656329095 + 0.4290355457
= 2.7946684552
= 4.8946452517
Stream 48
Stream
47
ed must be recovered in the tops and 95% of the AMS in the feed goes to
the bottoms
TMF BOTTOMS BMF

6.26E-04 2.91E-04 1.82E-06
0.00055 0.00329 2.06E-05
0.95534 8.004 0.050
0.04349 152.153 0.950
1.00 160.16 1.00
1.6729698608 0.0003108215
0.4543210072 8.44084E-005
5192.194365 0.9646591096
188.092 0.0349456604
5382.413655868 1

99.00000
99.00000 2.11875=Wxw,HHKC
2.3656329095
Using fenske to calculate the dist

HHKC
C
= 99.000 Wxw,HHKC
= 99.000 Wx w,HHKC +
= 100.000 Wxw,HHKC
= 0.0002909553
= 0.0288045775



Water
Eq. 1 DxD,HHKC
Eq. 2 0.02853
0.02853
Wxw,HHKC
DxD,HHKC
DxD,LLKC =
2.11875 =
Wxw,LLKC 0.244517
DxD,LLKC 1.874233
2.11875
= 7.6650280339 Wxw,HHKC Eq. 1
= 8.66502803 Wxw,HHKC
= 0.003292885
= 0.025240056
Wxw,LLKC
8.6650280339 Wxw,LLKC
Conversions
Single-Pass Conversion 1st Oxidizer Reactor 17%
Single-Pass Conversion 2nd Oxidizer Reactor 8%
Single-Pass Conversion Both Oxidizer Reactor 23%
Overall Conversion Oxidizer Reaction 99%
Single-Pass Conversion 1st Cleavage Reactor 100%
Single-Pass Conversion 2nd Cleavage Reactor 100%
Single-Pass Conversion 3rd Cleavage Reactor 100%
Overall Conversion Cleavage Reaction 100%
Yield
Yield 1st Oxidizer Reactor 0.179576
Yield 2nd Oxidizer Reactor 0.316892
Yield Both Oxidizer Reactor 0.239582
Selectivity
Residence time ranges between 1 to 3h
1st reactor
Residence time (hr) 2 hr =(
Estimated Flow rate of Feed (kg/hr) 112632.56

Density of Feed (kg/m3) 825.3 From Hysys
Volumetric Flow Rate (m3/hr) 136.4746879922
Volume of liquid present (m3) 272.9493759845
Actual Volume Reactor (m3) 300.2443135829 110% Over Design
2nd Reactor
Residence time (hr) 2
Estimated Flow rate of Feed (kg/hr) 112632.56

Density of Feed (kg/m3) 825.3
Actual Volume Reactor (m3) 300.2443135829 110% Over Design
Height of Reactor (m) 10 Assumed

Diameter of Reactor (m) 6.1829033078
Area of Reactor (m2) 30.0244313583
Cost Index in 2001 397

Cost Index in 2006 499.6
Cost of Reactor ($) 2006 $ 849,128.1
Cost of Reactor ($) 2015 $ 946,346.1
Cost of Platform Ladder $ in 2001 $ 2,286.77
Total Cost of Oxidizers Reactors ($) $ 1,899,106.63

grey text for equipment design
=( )/( )
% Over Design
% Over Design
From Chemical Engineering Design

Principles, Practice and Economics
of Plant and Process Design
_=+^
CS: Siever Tray Cost
a: 14000
b: 15400
S: diameter between 0.5 and 100
m3
n: 0.7
_= 1580(_ ) ^0.20294
CPL: Platform and ladder cost
Residence time ranges between 20 to 30min
1st reactor
Residence Time (hr) 0.416667 =( )/(
Flow rate of Reactants (kg/hr) 10761.69

Density of Reaactants (kg/m3) 1259 From hysys
Volume of reactor (m3) 4.095825 From timmerhaus 15% greater
2nd reactor
Residence Time (hr) 0.416667

Density of Reaactants (kg/m3) 1259
3rd reactor
Residence Time (hr) 0.416667

Density of Reaactants (kg/m3) 1259
)/( )
Height of Reactor (m) 2.5 Assumed

Radius of Reactor (m) 0.7221472345

Cost of Reactor ($) 2006 $ 55,319.9
Cost of Reactor ($) 2015 $ 61,653.6
Total Cost of Oxidizers Reactors ($) $ 192,123.71
$ 64,041.24
Principles, Practice and Economics of
Plant and Process Design
_=+^
a: 14000
b: 15400
S: diameter between 0.5 and 100 m3
n: 0.7
_= 1580(_ ) ^0.20294
Residence time ranges between 10 to 30min
1st reactor
Residence Time (hr) 0.3333333333 =( )/(

Density of Reaactants (kg/m3) 946.1 From hysys
Height of Reactor (m) 3 Assumed

Diameter of Reactor (m) 2.3451885445

Cost of Reactor ($) 2006 $ 106,537.4

Cost of Reactor ($) 2007 Stainless Steel $ 138,498.65
Cost of Reactor ($) 2015 $ 154,355.6
Total Cost of Oxidizers Reactors ($) $ 156,990

=( )/( )
rhaus 15% greater

Principles, Practice and Economics of
Plant and Process Design
_=+^
a: 14000
b: 15400
S: diameter between 0.5 and 100 m3
n: 0.7
_= 1580(_ ) ^0.20294
Reactor Reactor Description Residence Time Volumetric Flow Reactor Volume
(h) (m3/s) (m3)
R1 Oxidation Reactor 1 2.000 0.038 272.949
R2 Oxidation Reactor 2 2.000 0.038 272.949
R3 PFR 1 0.417 0.002 3.562
R4 PFR 2 0.417 0.002 3.562
R5 PFR 3 0.417 0.002 3.562
R6 CSTR 0.333 0.009 11.269
Actual Reactor
Volume (m3)
313.892
313.892
4.096
4.096
4.096
12.959
Reactor Reactor Description Actual Reactor Cost of Reator ($)
Volume (m3)
R1 Oxidation Reactor 1 57.641 949,553
R2 Oxidation Reactor 2 57.641 949,553
R3 PFR 1 2.023 64,041
R4 PFR 2 2.023 64,041
R5 PFR 3 2.023 64,041
R6 CSTR 11.178 156,990
$ 2,248,220
Operating Temperature (K) 323.15
Operating Pressure (bar) 5.06625
Molar Flow Inlet (kmol/s) 0.6559446479
Mass Flow Inlet (kg/s) 19.816517918
Density of material (kg/m3) 25.32
Volumetric Flow Rate (m3/s) 0.7826428877
Gas Constant (J/kgK) 8.314
Density of Gas (kg/m3) 4.778
Density of liquid (kg/m3) 875.2
Gas Compressibility
Interpolation is required
Pressure (bar)
Temperature (K)
5
300 0.999
350 1
Interpolate wrt Pressure
Temperature (K) Z Value
300 0.9989735
350 1
Gas Compressibility @ 323.15 and 5.06625bar 0.9994487695
T (R) 581.67
Qg (MMscf/D) 10.092519256
Z 0.9994487695
P (psia) 73.479743878
g (lbm/ft3) 0.2982804132
l (lbm/ft3) 54.636881047
dm (ft) 6.56E-04
Re 10000
CD 0.0024
d2 (ft2) 57.182257347
d (ft) 7.5618950896
d (in.) 90.742741076
Since the ratio of length to diameter

Operating Pressure L/D
0-20 3
20-35 4
>35 5
L/D 3
L (ft) 22.685685269
L (in.) 272.22822323
Stress Assumption (psig) 13750
Column Shell Thickness (in.) 0.0036809129

Column Shell Thickness (m) 0.000093
Shell Volume (m3) 0.0020309816
Density of Stainless Steel 302 (kg/m3) 7861.092935
Weight of Column (kg) 15.965735323
Capital cost of Shell using CEPCI equation (yellow book)

K1 3.4974
K2 0.4485
K3 0.1074
log Cp 4.1925093026
Cost of Shell $ in 2001 $ 15,578

Cost of Shell $ in 2015 $ 21,848.32
Total Cost of the Separator ($) $ 24,473.51

Standard Temp 273.15
Operating Pressure (atm) 5 Standard Presure 1.01325 Equation for sizing
^2=5.054 (_
(_/_ )]^(12)
From Hysys
Standard Volumetric Flow 3.307735 d: vessel internal d
T: operating tempe
Z: gas compressib
From Hysys
Qg: gas flow rate
From Hysys P: operating press
g: gas density
REDO l: liquid density
Pressure (bar) CD: drag coefficien
10 dm: drop diameter
0.997 Z value
1 Z value _=24/
Re: reynolds numb
Standard Volume
_=(_/)
200m
d (m) 2.304866
_=(0.22(_+18) ^2)/(_^2 )
Tw: Wall thickness
h: Column Height
S: Maximum Allowable Stress
_=__
ro: Outside radius
ri: Inlet radius
_=2 (__)/2
Vs: Shell Volume
Assumed =_ _
L (m) 6.914597 W: Mass of empty shell
ss: Density of Stainless Steel
_10 _^=_1+_2 _10 ()+_3 [ _10
()]^2
CP: Cost of column shell
_= 1580(_ ) ^0.20294
=_ _
W: Mass of empty shell
_10 _^=_1+_2 _10 ()+_3 [ _10
()]^2
_= 1580(_ ) ^0.20294
From yellow book

PDF Online
Equation for sizing vertical columns,
^2=5.054 (_)/ [((|_ |)/(|__ |))
(_/_ )]^(12)
d: vessel internal diameter

T: operating temperature
Z: gas compressibility
Qg: gas flow rate
P: operating pressure
g: gas density
l: liquid density
CD: drag coefficient
dm: drop diameter
_=24/
Re: reynolds number
Standard Volume Flow:
_=(_/)(/_ " " )
()+_3 [ _10
()+_3 [ _10
Molar Flow Inlet (kmol/s) 0.6485112992
Gas Compressibility
Pressure (bar)
Temperature (K)
5
300 0.999
350 1
300 0.9989735
350 1
Gas Compressibility @ 323.15 and 5.06625bar 0.9985249195
T (R) 500.67
Qg (MMscf/D) 18.768535443
Z 0.9985249195
P (psia) 73.479743878
g (lbm/ft3) 0.2982804132
l (lbm/ft3) 54.636881047
dm (ft) 6.56E-04
Re 10000
CD 0.0024
d2 (ft2) 91.446137818
d (ft) 9.562747399
d (in.) 114.75296879
Since the ratio of length to diameter

Operating Pressure L/D
0-20 3
20-35 4
>35 5
L/D 3
L (ft) 28.688242197
L (in.) 344.25890637


K1 3.4974
K2 0.4485
K3 0.1074
log Cp 4.289669848

Cost of Shell $ in 2015 $ 27,326.16

Operating Pressure (atm) 5 Standard Presure 1.01325
From Hysys
Standard Volumetric Flow 6.1512233
From Hysys
From Hysys
Pressure (bar)
10
0.997 Z value
1 Z value
200m
d (m) 2.914725
_=(0.22(_+18) ^2)/(_^2 )
Tw: Wall thickness
h: Column Height
_=__
ro: Outside radius
ri: Inlet radius
_=2 (__)/2
Vs: Shell Volume
Assumed =_ _
L (m) 8.744176 W: Mass of empty shell
_10 _^=_1+_2 _10 ()+_3 [ _10 (
_= 1580(_ ) ^0.20294
=_ _
_10 _^=_1+_2 _10 ()+_3 [ _10 (
_= 1580(_ ) ^0.20294
From yellow book

PDF Online
^2=5.054 (_)/ [((|_ |)/(|__ |))
(_/_ )]^(12)

Qg: gas flow rate
g: gas density
l: liquid density
dm: drop diameter
_=24/
Re: reynolds number
_=(_/)(/_ " " )
2)/(_^2 )
tress
Steel
_10 ()+_3 [ _10 ()]^2
20294
cost
Steel
_10 ()+_3 [ _10 ()]^2
20294
cost
Molar Flow Inlet (mol/s) 0.6559446479
Gas Compressibility
Pressure (bar)
Temperature (K)
5
300 0.999
350 1
300 0.9989735
350 1
Gas Compressibility @ 323 and 5.06625bar 0.9994487695
T (R) 581.67
Qg (MMscf/D) 10.092519256
Z 0.9994487695
P (psia) 73.479743878
g (lbm/ft3) 0.2982804132
l (lbm/ft3) 54.636881047
dm (ft) 6.56E-04
Re 10000
CD 0.0024
d2 (ft2) 57.182257347
d (ft) 7.5618950896
d (in.) 90.742741076
Since the ratio of length to foameter ranged from 3 to 5

L/D 3
L (ft) 22.685685269
L (in.) 272.22822323

Column Shell Thickness (m) 9.34952E-005

K1 3.4974
K2 0.4485
K3 0.1074
log Cp 4.1925093026

Cost of Shell $ in 2015 $ 21,848.32

^2=5.054 (_
(_/_ )]^(12)
From Hysys
T: operating tempe
Z: gas compressib
From Hysys
Qg: gas flow rate
g: gas density
l: liquid density
0.997 Z value
1 Z value _=24/
Re: reynolds numb
Standard Volume
_=(_/)
d (m) 2.304866
Assumed
L (m) 6.914597
_=(0.22(_+18) ^2)/(_^2 )
Tw: Wall thickness
h: Column Height
_=__
ro: Outside radius
ri: Inlet radius
_=2 (__)/2
Vs: Shell Volume
_=(0.22(_+18) ^2)/(_^2 )
Tw: Wall thickness
h: Column Height
_=__
ro: Outside radius
ri: Inlet radius
_=2 (__)/2
Vs: Shell Volume
=_ _
_10 _^=_1+_2 _10 ()+_3
[ _10 ()]^2
_= 1580(_ ) ^0.20294
From yellow book

PDF Online
^2=5.054 (_)/ [((|_ |)/(|__ |))
(_/_ )]^(12)

Qg: gas flow rate
g: gas density
l: liquid density
dm: drop diameter
_=24/
Re: reynolds number
_=(_/)(/_ " " )
Gas Compressibility
Pressure (bar)
Temperature (K)
5
300 0.999
350 1
300 0.9989735
350 1
T (R) 500.67
Qg (MMscf/D) 18.768535443
Z 0.9985249195
P (psia) 73.479743878
g (lbm/ft3) 0.2982804132
l (lbm/ft3) 54.636881047
dm (ft) 6.56E-04
Re 10000
CD 0.0024
d2 (ft2) 91.446137818
d (ft) 9.562747399
d (in.) 114.75296879

L/D 3
L (ft) 28.688242197
L (in.) 344.25890637


K1 3.4974
K2 0.4485
K3 0.1074
log Cp 4.289669848

Cost of Shell $ in 2015 $ 27,326.16

From Hysys
From Hysys
From Hysys
Pressure (bar)
10
0.997 Z value
1 Z value
d (m) 2.914725
Assumed
L (m) 8.744176
_=(0.22(_+18) ^2)/(_^2 )
Tw: Wall thickness
h: Column Height
_=__
ro: Outside radius
ri: Inlet radius
_=2 (__)/2
Vs: Shell Volume
_=(0.22(_+18) ^2)/(_^2 )
Tw: Wall thickness
h: Column Height
_=__
ro: Outside radius
ri: Inlet radius
_=2 (__)/2
Vs: Shell Volume
=_ _
_10 _^=_1+_2 _10 ()+_3
[ _10 ()]^2
_= 1580(_ ) ^0.20294
From yellow book

PDF Online
^2=5.054 (_)/ [((|_ |)/(|__ |))
(_/_ )]^(12)

Qg: gas flow rate
g: gas density
l: liquid density
dm: drop diameter
_=24/
Re: reynolds number
_=(_/)(/_ " " )
3
Gas Compressibility
Pressure (bar)
Temperature (K)
5
300 0.999
350 1
300 0.9989735
350 1
T (R) 581.67
Qg (MMscf/D) 4.7690789747
Z 0.9994487695
P (psia) 73.479743878
g (lbm/ft3) 0.3931083637
l (lbm/ft3) 54.618152683
dm (ft) 6.56E-04
Re 10000
CD 0.0024
d2 (ft2) 31.052335118
d (ft) 5.5724622133
d (in.) 66.869546559

L/D 3
L (ft) 16.71738664
L (in.) 200.60863968


K1 3.4974
K2 0.4485
K3 0.1074
log Cp 4.0769270227

Cost of Shell $ in 2015 $ 16,743.10

From Hysys
From Hysys
From Hysys
Pressure (bar)
10
0.997 Z value
1 Z value
d (m) 1.698486
Assumed
L (m) 5.095459
_=(0.22(_+18) ^2)/(_^2 )
Tw: Wall thickness
h: Column Height
_=__
ro: Outside radius
ri: Inlet radius
_=2 (__)/2
Vs: Shell Volume
=_ _
Tw: Wall thickness
h: Column Height
_=__
ro: Outside radius
ri: Inlet radius
_=2 (__)/2
Vs: Shell Volume
=_ _
_10 _^=_1+_2 _10 ()+_3
[ _10 ()]^2
_= 1580(_ ) ^0.20294
From yellow book

PDF Online
^2=5.054 (_)/ [((|_ |)/(|__ |))
(_/_ )]^(12)

Qg: gas flow rate
g: gas density
l: liquid density
dm: drop diameter
_=24/
Re: reynolds number
_=(_/)(/_ " " )
^2 )
10 ()+_3
Gas Compressibility
Pressure (bar)
Temperature (K)
5
300 0.999
350 1
300 0.9989735
350 1
T (R) 500.67
Qg (MMscf/D) 8.9131121325
Z 0.9985249195
P (psia) 73.479743878
g (lbm/ft3) 0.3931083637
l (lbm/ft3) 54.618152683
dm (ft) 6.56E-04
Re 10000
CD 0.0024
d2 (ft2) 49.907106882
d (ft) 7.0644962228
d (in.) 84.773954674

L/D 3
L (ft) 21.193488668
L (in.) 254.32186402


K1 3.4974
K2 0.4485
K3 0.1074
log Cp 4.1657421183

Cost of Shell $ in 2015 $ 20,542.38

^2=5.054 (_
(_/_ )]^(12)
From Hysys
T: operating tempe
Z: gas compressib
From Hysys
Qg: gas flow rate
g: gas density
l: liquid density
0.997 Z value
1 Z value _=24/
Re: reynolds numb
Standard Volume
_=(_/)
d (m) 2.153258
Assumed
L (m) 6.459775
_=(0.22(_+18) ^2)/(_^2 )
Tw: Wall thickness
h: Column Height
_=__
ro: Outside radius
ri: Inlet radius
_=2 (__)/2
Vs: Shell Volume
=_ _
Tw: Wall thickness
h: Column Height
_=__
ro: Outside radius
ri: Inlet radius
_=2 (__)/2
Vs: Shell Volume
=_ _
_10 _^=_1+_2 _10 ()+_3
[ _10 ()]^2
_= 1580(_ ) ^0.20294
From yellow book

PDF Online
^2=5.054 (_)/ [((|_ |)/(|__ |))
(_/_ )]^(12)

Qg: gas flow rate
g: gas density
l: liquid density
dm: drop diameter
_=24/
Re: reynolds number
_=(_/)(/_ " " )
3
Gas Compressibility
Pressure (bar)
Temperature (K)
5
300 0.999
350 1
300 0.9989735
350 1
T (R) 581.67
Qg (MMscf/D) 4.7690789747
Z 0.9994487695
P (psia) 73.479743878
g (lbm/ft3) 0.3931083637
l (lbm/ft3) 54.618152683
dm (ft) 6.56E-04
Re 10000
CD 0.0024
d2 (ft2) 31.052335118
d (ft) 5.5724622133
d (in.) 66.869546559

L/D 3
L (ft) 16.71738664
L (in.) 200.60863968


K1 3.4974
K2 0.4485
K3 0.1074
log Cp 4.0769270227

Cost of Shell $ in 2015 $ 16,743.10

^2=5.054 (_
(_/_ )]^(12)
From Hysys
T: operating tempe
Z: gas compressib
From Hysys
Qg: gas flow rate
g: gas density
l: liquid density
0.997 Z value
1 Z value _=24/
Re: reynolds numb
Standard Volume
_=(_/)
d (m) 1.698486
Assumed
L (m) 5.095459
_=(0.22(_+18) ^2)/(_^2 )
Tw: Wall thickness
h: Column Height
_=__
ro: Outside radius
ri: Inlet radius
_=2 (__)/2
Vs: Shell Volume
_=(0.22(_+18) ^2)/(_^2 )
Tw: Wall thickness
h: Column Height
_=__
ro: Outside radius
ri: Inlet radius
_=2 (__)/2
Vs: Shell Volume
=_ _
_10 _^=_1+_2 _10 ()+_3
[ _10 ()]^2
_= 1580(_ ) ^0.20294
From yellow book

PDF Online
^2=5.054 (_)/ [((|_ |)/(|__ |))
(_/_ )]^(12)

Qg: gas flow rate
g: gas density
l: liquid density
dm: drop diameter
_=24/
Re: reynolds number
_=(_/)(/_ " " )
3
Gas Compressibility
Pressure (bar)
Temperature (K)
5
300 0.999
350 1
300 0.9989735
350 1
T (R) 500.67
Qg (MMscf/D) 8.9131121325
Z 0.9985249195
P (psia) 73.479743878
g (lbm/ft3) 0.3931083637
l (lbm/ft3) 54.618152683
dm (ft) 6.56E-04
Re 10000
CD 0.0024
d2 (ft2) 49.907106882
d (ft) 7.0644962228
d (in.) 84.773954674

L/D 3
L (ft) 21.193488668
L (in.) 254.32186402


K1 3.4974
K2 0.4485
K3 0.1074
log Cp 4.1657421183

Cost of Shell $ in 2015 $ 20,542.38

From Hysys
From Hysys
From Hysys
Pressure (bar)
10
0.997 Z value
1 Z value
d (m) 2.153258
Assumed
L (m) 6.459775
_=(0.22(_+18) ^2)/(_^2 )
Tw: Wall thickness
h: Column Height
_=__
ro: Outside radius
ri: Inlet radius
_=2 (__)/2
Vs: Shell Volume
_=(0.22(_+18) ^2)/(_^2 )
Tw: Wall thickness
h: Column Height
_=__
ro: Outside radius
ri: Inlet radius
_=2 (__)/2
Vs: Shell Volume
=_ _
_10 _^=_1+_2 _10 ()+_3
[ _10 ()]^2
_= 1580(_ ) ^0.20294
From yellow book

PDF Online
^2=5.054 (_)/ [((|_ |)/(|__ |))
(_/_ )]^(12)

Qg: gas flow rate
g: gas density
l: liquid density
dm: drop diameter
_=24/
Re: reynolds number
_=(_/)(/_ " " )
^2 )
^2 )
10 ()+_3
Operating Pressure (bar) 1
Gas Compressibility
Pressure (bar)
Temperature (K)
5
300 0.999
350 1
300 1.0006
350 1
T (R) 536.67
Qg (MMscf/D) 4.6338969232
Z 1.0006222
P (psia) 73.479743878
g (lbm/ft3) 0.033548743
l (lbm/ft3) 56.58463092
dm (ft) 6.56E-04
Re 10000
CD 0.0024
d2 (ft2) 7.9727445837
d (ft) 2.8236048916
d (in.) 33.883258699

L/D 3
L (ft) 8.4708146747
L (in.) 101.6497761


K1 3.4974
K2 0.4485
K3 0.1074
log Cp 3.8558067155

Cost of Shell $ in 2015 $ 10,062.72

From Hysys
From Hysys
From Hysys
Pressure (bar)
10
0.997 Z value
1 Z value
d (m) 0.860635
Assumed
L (m) 2.581904
_=(0.22(_+18) ^2)/(_^2 )
Tw: Wall thickness
h: Column Height
_=__
ro: Outside radius
ri: Inlet radius
_=2 (__)/2
Vs: Shell Volume
_=(0.22(_+18) ^2)/(_^2 )
Tw: Wall thickness
h: Column Height
_=__
ro: Outside radius
ri: Inlet radius
_=2 (__)/2
Vs: Shell Volume
=_ _
_10 _^=_1+_2 _10 ()+_3
[ _10 ()]^2
_= 1580(_ ) ^0.20294
From yellow book

PDF Online
^2=5.054 (_)/ [((|_ |)/(|__ |))
(_/_ )]^(12)

Qg: gas flow rate
g: gas density
l: liquid density
dm: drop diameter
_=24/
Re: reynolds number
_=(_/)(/_ " " )
^2 )
^2 )
10 ()+_3
Operating Pressure (bar) 1
Density of material (kg/m3) 549
Gas Compressibility
Pressure (bar)
Temperature (K)
5
300 0.999
350 1
300 1.0006
350 1
T (R) 536.67
Qg (MMscf/D) 0.0448829463
Z 1.0006222
P (psia) 73.479743878
g (lbm/ft3) 0.0905828547
l (lbm/ft3) 58.788335103
dm (ft) 6.56E-04
Re 10000
CD 0.0024
d2 (ft2) 0.1245481956
d (ft) 0.3529138642
d (in.) 4.2349663705

L/D 3
L (ft) 1.0587415926
L (in.) 12.704899112

Shell Volume (m3) 6.80544E-005

K1 3.4974
K2 0.4485
K3 0.1074
log Cp 3.3834861197

Cost of Shell $ in 2015 $ 3,391.52

From Hysys
From Hysys
From Hysys
Pressure (bar)
10
0.997 Z value
1 Z value
USE SIMILAR SIZE TO FLASH DRUM

d (m) 0.107568
Assumed
L (m) 0.322704
_=(0.22(_+18) ^2)/(_^2 )
Tw: Wall thickness
h: Column Height
_=__
ro: Outside radius
ri: Inlet radius
_=2 (__)/2
Vs: Shell Volume
_=(0.22(_+18) ^2)/(_^2 )
Tw: Wall thickness
h: Column Height
_=__
ro: Outside radius
ri: Inlet radius
_=2 (__)/2
Vs: Shell Volume
=_ _
_10 _^=_1+_2 _10 ()+_3 [ _10 ()]^2
_= 1580(_ ) ^0.20294
From yellow book

PDF Online
^2=5.054 (_)/ [((|_ |)/(|__ |))
(_/_ )]^(12)

Qg: gas flow rate
g: gas density
l: liquid density
dm: drop diameter
_=24/
Re: reynolds number
_=(_/)(/_ " " )
_3 [ _10 ()]^2
Volumetric Flow
Separator Separator Description (m3/s) Height (m)
S1 Removal of Cumene and CHP 0.783 6.915
S2 Removal of Cumene 1.253 8.744
S9 Flash Column 1.680 2.582
S10 Removal of NaSO4 1.6796844263 2.582
Total
Separator
Diameter (m) Volume (m3) Total Cost of Column ($)
2.305 50.068 24,474
2.915 80.069 30,079
2.305 50.068 24,474
2.915 80.069 30,079
1.698 27.189 19,211
2.1532584487 43.698 23,132
1.6984864826 27.189 19,211
2.1532584487 43.698 23,132
0.860634771 6.981 12,212
0.860634771 6.981 12,212
$ 218,215
Separator Separator Description Height (m) Diameter (m)
S5 Removal of NaSO4 0.323 0.108
Total Cost of Column ($)
24,474
24,474
23,132
19,211
$ 4,801
$ 96,090
Number of Stages 9
Plate Spacing (m) 1.3
Tops
At 97.15C
Density of Vapour (v) (kg/m3) 0.83
Density of Liquid (l) (kg/m3) 946.60
Vapor Rate in Tops (kg/hr) 12251.392

Vapor Rate in Tops (kg/s) 3.403
Maximum Allowable Vapor Velocity (m/s) 0.5067418702

Diameter of Column (m) 3.2100840812
Aream of column (m2) 8.0932451802
Height of column (m) 11.7
Diameter of Column (ft) 10.531772257

Aream of column (ft2) 87.114971676
Height of column (ft) 38.385828


K1 3.4974
K2 0.4485
K3 0.1074
log Cp 4.5285692228

Cost of Shell $ in 2015 $ 47,367.23

Cost of Condenser $ in 2001 $ 5,325.97
Cost of Reboiler $ in 2001 $ 8,402.59
Cost of one Sieve Trays $ in 2006 $ 1,336.56
Cost of Sieve Trays $ in 2015 $ 1,489.58
Toal cost of Colum $ in 2001 $ 50,840.02
Toal cost of Colum $ in 2015 $ 70,919.13

Typically lies between 0.5 and 1.5
Formulae used in calculation:

_=( 0.171 _^2+0.27_0.047) ((__)/_
From Hysys )
From Hysys Where,
uf: Maximum allowable vapour velocity, m/s
lt: Plate spacing, m (Initial Guess 0.5m)
_=((4)_/( _ _ ))
Where,
Dc: Column Diameter, m
Vw:Maximum vapour rate, kg/s
_=(0.22(_+18) ^2)/(_^2 )
Tw: Wall thickness
h: Column Height
_=__
ro: Outside radius
ri: Inlet radius
_=2 (__)/2
Vs: Shell Volume
=_ _
_10 _^=_1+_2 _10 ()+_3 [

_10 ()]^2
_= 1580(_ ) ^0.20294
_=4080(/50)^0.48
CC: Condenser Cost
_=12,300(/400)^0.25
CR: Reboiler Cost
From yellow book From Chemical Engineering Design Principles,
PDF Online Practice and Economics of Plant and Process Design
PDF Online _=+^
a: 100
b: 120
S: diameter between 0.5 and 5 m
n: 2
b: 120
n: 2
Dc in ft
Dc in ft
Dc in ft
alculation:
^2+0.27_0.047) ((__)/_
able vapour velocity, m/s

(Initial Guess 0.5m)
_ _ ))
ter, m
ur rate, kg/s
8) ^2)/(_^2 )
able Stress
shell
nless Steel
_1+_2 _10 ()+_3 [
shell
) ^0.20294
adder cost
.48
t
)^0.25
ineering Design Principles,

mics of Plant and Process Design
st
en 0.5 and 5 m
en 0.5 and 5 m
Number of Stages 16
Tops
At 56.7C





K1 3.4974
K2 0.4485
K3 0.1074
log Cp 4.9467761551

Cost of Shell $ in 2015 $ 124,075.17

Cost of one Sieve Trays $ in 2001 $ 148.45
Cost of Sieve Trays $ in 2015 $ 165.45
Toal cost of Column $ in 2001 $ 94,918.79

Formulae used to calculate column diameter

From Hysys _=( 0.171 _^2+0.27_0.047)
From Hysys ((__)/_ )
Where,
_=((4)_/( _ _ ))
Where,
_=(0.22(_+18) ^2)/(_^2 )
Tw: Wall thickness
h: Column Height
_=__
ro: Outside radius
ri: Inlet radius
_=2 (__)/2
Vs: Shell Volume
=_ _
_10 _^=_1+_2 _10 ()+_3 [
_10 ()]^2
_= 1580(_ ) ^0.20294
_=4080(/50)^0.48
CC: Condenser Cost
_=12,300(/400)^0.25
CR: Reboiler Cost
From Chemical Engineering Design Principles,
Practice and Economics of Plant and Process
Design
_=+^
From yellow book
PDF Online a: 100
PDF Online b: 120
n: 2
n: 2
Dc in ft
Dc in ft
Dc in ft
calculate column diameter
^2+0.27_0.047)
wable vapour velocity, m/s

m (Initial Guess 0.5m)
_ _ ))
eter, m
our rate, kg/s
8) ^2)/(_^2 )
able Stress
shell
ainless Steel
_1+_2 _10 ()+_3 [
n shell
) ^0.20294
ladder cost
0.48
st
)^0.25
gineering Design Principles,

omics of Plant and Process
st
en 0.5 and 5 m
Number of Stages 7
Tops
At 121C





K1 3.4974
K2 0.4485
K3 0.1074
log Cp 3.9860105513

Cost of Shell $ in 2015 $ 13,580.61


Formulae used to calculate column diameter

From Hysys _=( 0.171 _^2+0.27_0.047)
From Hysys ((__)/_ )
Where,
_=((4)_/( _ _ ))
Where,
_=(0.22(_+18) ^2)/(_^2 )
Tw: Wall thickness
h: Column Height
_=__
ro: Outside radius
ri: Inlet radius
_=2 (__)/2
Vs: Shell Volume
=_ _
_10 _^=_1+_2 _10 ()+_3 [
_10 ()]^2
_= 1580(_ ) ^0.20294
_=4080(/50)^0.48
CC: Condenser Cost
_=12,300(/400)^0.25
CR: Reboiler Cost
Design
_=+^
From yellow book CS: Siever Tray Cost
PDF Online a: 100
PDF Online b: 120
n: 2
n: 2
Dc in ft
Dc in ft
Dc in ft
alculate column diameter
^2+0.27_0.047)
able vapour velocity, m/s

(Initial Guess 0.5m)
_ _ ))
er, m
ur rate, kg/s
) ^2)/(_^2 )
ble Stress
hell
nless Steel
1+_2 _10 ()+_3 [
shell
) ^0.20294
adder cost
.48
t
^0.25
ineering Design Principles,

mics of Plant and Process
n 0.5 and 5 m
Number of Stages 5
Tops
At 97.15C





K1 3.4974
K2 0.4485
K3 0.1074
log Cp 3.7924528751

Cost of Shell $ in 2015 $ 8,696.84

Toal cost of Column$ in 2015 $ 32,149.35

From Hysys Formulae used to calculate column diameter

From Hysys _=( 0.171 _^2+0.27_0.047) ((__)/_ )
Where,
_=((4)_/( _ _ ))
Where,
_=(0.22(_+18) ^2)/(_^2 )
Tw: Wall thickness
h: Column Height
_=__
ro: Outside radius
ri: Inlet radius
_=2 (__)/2
Vs: Shell Volume
=_ _
_10 _^=_1+_2 _10 ()+_3 [ _10
()]^2
_= 1580(_ ) ^0.20294
_=4080(/50)^0.48
CC: Condenser Cost
_=12,300(/400)^0.25
CR: Reboiler Cost
From Chemical Engineering Design Principles, Practice and
Economics of Plant and Process Design
_=+^
From yellow book a: 100
PDF Online b: 120
PDF Online S: diameter between 0.5 and 5 m
n: 2
Dc in ft
Dc in ft
Dc in ft
lculate column diameter
2+0.27_0.047) ((__)/_ )
ble vapour velocity, m/s

Initial Guess 0.5m)
_ _ ))
er, m
r rate, kg/s
^2)/(_^2 )
ble Stress
hell
less Steel
1+_2 _10 ()+_3 [ _10
hell
^0.20294
dder cost
48
^0.25
neering Design Principles, Practice and

and Process Design
n 0.5 and 5 m
Number of Stages 4
Tops
At 97.15C





K1 3.4974
K2 0.4485
K3 0.1074
log Cp 4.1537861579

Cost of Shell $ in 2015 $ 19,984.57


From Hysys Formulae used to calculate column diameter

From Hysys _=( 0.171 _^2+0.27_0.047)
((__)/_ )
Where,
_=((4)_/( _ _ ))
Where,
_=(0.22(_+18) ^2)/(_^2 )
Tw: Wall thickness
h: Column Height
_=__
ro: Outside radius
ri: Inlet radius
_=2 (__)/2
Vs: Shell Volume
=_ _
_10 _^=_1+_2 _10 ()+_3 [
_10 ()]^2
_= 1580(_ ) ^0.20294
_=4080(/50)^0.48
CC: Condenser Cost
_=12,300(/400)^0.25
CR: Reboiler Cost
Design
From yellow book _=+^
PDF Online CS: Siever Tray Cost
PDF Online a: 100
b: 120
n: 2
n: 2
Dc in ft
Dc in ft
Dc in ft
lculate column diameter
2+0.27_0.047)
ble vapour velocity, m/s

Initial Guess 0.5m)
_ _ ))
er, m
r rate, kg/s
^2)/(_^2 )
ble Stress
hell
less Steel
1+_2 _10 ()+_3 [
hell
^0.20294
dder cost
48
^0.25
neering Design Principles,

mics of Plant and Process
n 0.5 and 5 m
n 0.5 and 5 m
Column Column Description Vapour Velocity Column Height
(m/s) (m)
C1 Crude Acetone 0.507 11.700
C2 Acetone Removal 0.280 20.800
C3 Water Removal 0.415 9.100
C4 AMS and Phenol Removal 0.583 6.500
C5 CHP Concemtration 0.603 5.200
Column Diameter Shell Volume
(m) (m3)
3.210 0.006
0.635 0.017
2.900 0.001
3.191 0.000
3.034 0.002
Column Column Description Cost of Column Cost of Ladder and
Shell ($) Platform ($)
C1 Crude Acetone 47,367 2,808
C2 Acetone Removal 124,075 2,021
C3 Water Removal 13,581 2,750
C4 AMS and Phenol Removal 8,697 2,804
C5 CHP Concemtration 19,985 2,776
Cost of Cost of Cost of Sieve Total Cost of
Condenser ($) Reboiler ($) Trays ($) Column ($)
7,470 11,785 1,490 70,919
1,578 5,243 165 133,083
6,776 11,201 1,236 35,544
7,426 11,749 1,473 32,149
7,076 11,457 1,343 42,637
Total $ 314,332
Recycle (Tank 1)
Density of Mixture (kg/m3) 861 From hysys
Total Flow in (kg/hr) 86631.87
Hold up time (hrs) 1.5
Volumetric Flow (m3/hr) 100.6177

Volume of Vessel (m3) 150.9266
Scale up 110%
Actual Volume (m3) 166.0193
Sulphuric Acid (Tank 2)

Density of Mixture (kg/m3) 1274 0.1M H2SO4 from hysys
Hold up time (hrs) 2

Scale up 110%
Sodium Hydroxide (Tank 3)


Scale up 110%
Pre-Distillation (Tank 4)
Density of Mixture (kg/m3) 939.9 From hysys
Hold up time (hrs) 0.5

Scale up 110%
Acetone Storage (Tank 5)


Scale up 110%
AMS Storage (Tank 6)


Scale up 110%
Phenol Storage (Tank 7)


Scale up 110%
Sodium Sulphate Storage (Tank 7)

Density of Mixture (kg/m3) 2660

Scale up 110%
Recycle (Tank 1)

Cost of Tank with Conical Roof ($) (2006) $ 30,773
Sulphuric Acid (Tank 2)

Sodium Hydroxide (Tank 3)
Cost of Tank with Conical Roof ($) (2006 $ 5,972

Pre-Distillation (Tank 4)

Acetone Storage (Tank 5)

AMS Storage (Tank 6)



Principles, Practice and Economics
of Plant and Process Design
_=+^
CS: Conical Tanks
a: 5700
b: 700
S: volume between 10 to4000 m3
n: 2
Storage Tanks Storage Tank Description Mass Flow Rate (kg/hr)
ST1 Recycle (Tank 1) 86631.87
ST2 Sulphuric Acid (Tank 2) 32542.53
ST3 Sodium Hydroxide (Tank 3) 170.67
ST4 Pre-Distillation (Tank 4) 30779.53
ST5 Acetone Storage (Tank 5) 682.98
ST6 AMS Storage (Tank 6) 9301.99
ST7 Phenol Storage (Tank 7) 2670.03
Density (m3/hr) Assumed Hold up Time (hr) Design Volume (m3)
861.00 1.50 150.93
1274.00 2.00 51.09
1447.00 2.00 0.24
939.90 0.50 16.37
777.70 12.00 10.54
905.40 1.00 10.27
1075.00 2.00 4.97
From Hysys
Actual Volume (m3)
Storage Tanks Storage Tank Description Actual Volume (m3)
ST1 Recycle 166.02
ST2 Sulphuric Acid 56.20
ST3 Sodium Hydroxide 0.26
ST4 Pre-Distillation 18.01
ST5 Acetone Storage 11.59
ST6 AMS Storage 11.30
ST7 Phenol Storage 5.46
ST8 Sodium Sulphate Storage 6.82
Cost of Tank with Conical Roof ($)
34,296
19,443
6,656
12,255
10,689
10,612
8,914
9,344
$ 112,210.03
Equipment No. Breif Description Flow Rate (m3/s) Power (kW)
Pum 1 0.0083494153 4.635641105
Pum 2 0.0360800926 24.11978902
Pum 3 0.0086513692 3.255522081
Pum 4 0.0001277612 0.0348018
Pum 5 0.0019625266 0.487674411
Pum 6 0.0181536238 4.789572514
Total
Equipment No. Energy Needed (kW)

Pum 1 4.6356411045
Pum 2 24.1197890207
Pum 3 3.2555220811
Pum 4 0.0348017997
Pum 5 0.4876744109
Pum 6 4.7895725136
Total 37.3230009306
Cost of Pump ($)
4,361
7,632
6,102
3,682
3,798
5,412
$ 30,987
Equipment No. Breif Description
FirFur 1
Het 1
Het 2
HetEx 1
HetEx 2a
HetEx 2b
HetEx 3
Cool 1
Total
Water Requirements
Equipment No. Molar Flow
HetEx 1 650.2608122618
HetEx 2a 3744.8934856159
HetEx 2b 2239.1786169696
HetEx 3 712.6146321207
Total Water Required 7346.947546968
Equipment No. Energy Needed (KW)

Het 1 800.9390857579
Het 2 332.6754166365
Cool 1 54730.8640148449
Total Power Required 55864.4785172393
Cost of Heating/ Cooling Equipment ($)
459,672
123,456
154,819
18,485
23,539
23,822
17,060
14,756,356
15,577,208
Mass Flow
11704.6946207128
67408.0827410858
40305.2151054531
12827.0633781723
132245.055845424
Equipment No. Breif Description Cost of Compressor ($)
Comp 1 135,259
Total $ 135,258.96
Equipment No. Energy Needed (KW)

Comp 1 400.5248840756
Molecular Weight
Cumene 120.00
Oxygen 32.00
Nitrogen 28.00
Cumene Hydroperoxide (CHP) 152.00
Air 28.90
Acetone 58.08
Water 18.00
AMS 118.18
Phenol 94.05
Sulphuric Acid 98.08
Sodium Hydroxide 40.00
Sodium Sulphate 142.04
Stream Component Molar Flowr Rate (kmolh-1)

Cumene 216.667
1a
Total 216.667
Cumene 710.682
1b Cumene Hydroperoxide 8.881
Total 719.564
Cumene 927.357
1c Cumene Hydroperoxide 8.880
Total 936.237
Oxygen 1483.771
2 Nitrogen 5581.804
Total 7065.575
Oxygen 1008.964
3 Nitrogen 3795.627
Total 4804.591
Oxygen 474.807
4 Nitrogen 1786.177
Total 2260.984
Cumene 695.594
5 Cumene Hydroperoxide 164.781
Total 860.375
Cumene 74.112
Cumene Hydroperoxide 1.750
6 Oxygen 851.313
Nitrogen 3795.627
Total 4722.801
Cumene 37.056
6a Oxygen 425.657
Nitrogen 1897.813
Total 2361.401
Cumene 37.056
6b
6b Oxygen 425.657
Nitrogen 1897.813
Total 2361.401
Cumene 26.136
7a Cumene Hydroperoxide 0.617
Total 26.753
Cumene 26.136
Total 26.753
Cumene 11.171
Oxygen 425.657
8a
Nitrogen 1897.813
Total 2334.641
Cumene 11.171
Oxygen 425.657
8b
Nitrogen 1897.813
Total 2334.641
Cumene 10.457
9a
Total 10.457
Cumene 10.457
9b
Total 10.457
Cumene 0.721
Oxygen 425.657
10a
Nitrogen 1897.813
Total 2324.191
Cumene 0.721
Oxygen 425.657
10b
Nitrogen 1897.813
Total 2324.191
Cumene 608.169
Total 827.403
Cumene 31.778
12 Oxygen 419.159
Nitrogen 1786.177
Total 2238.309
Cumene 15.889
12a Oxygen 209.580
Nitrogen 893.089
Total 1119.154
Cumene 15.889
12b Oxygen 209.580
Nitrogen 893.089
12b
Total 1119.154
Cumene 10.843
13a Cumene Hydroperoxide 0.408
Total 11.251
Cumene 10.843
Total 11.251
Cumene 5.230
Oxygen 209.580
14a
Nitrogen 893.089
Total 1107.898
Cumene 5.230
Oxygen 209.580
14b
Nitrogen 893.089
Total 1107.898
Cumene 4.893
15a
Total 4.893
Cumene 4.893
15b
Total 4.893
Cumene 0.342
Oxygen 209.580
16a
Nitrogen 893.089
Total 1103.010
Cumene 0.342
Oxygen 209.580
16b
Nitrogen 893.089
Total 1103.010
Cumene 595.395
Total 813.789
Cumene 12.774
Total 13.614
Cumene (Negible) 2.145
Total 214.547
Cumene 593.249
Total 599.242
Cumene 36.593
Total 37.210
Cumene 36.593
Total 37.210
Cumene 15.736
23
Total 16.144
Cumene 15.736
Total 16.144
25
Total 70.801
26
Total 70.801
27
Total 70.801
H2SO4 2.124
28 Water 19.116
Total 21.240
H2SO4 0.708
29 Water 6.372
Total 7.080
H2SO4 0.708
30 Water 6.372
Total 7.080
H2SO4 0.708
31 Water 6.372
Total 7.080
Acetone 52.392
Phenol 52.392
AMS 18.408
32
Water 24.780
H2SO4 0.708
Total 148.681
Acetone 52.392
Phenol 52.392
AMS 18.408
33
Water 24.780
H2SO4 0.708
Total 148.681
Acetone 52.392
Phenol 52.392
AMS 18.408
34
Water 24.780
H2SO4 0.708
Total 148.681
Acetone 157.177
Phenol 157.177
AMS 55.224
35
Water 74.341
35
H2SO4 2.124
Total 446.044
NaOH 4.248
36 Water 0.042
Total 4.291
Acetone 157.177
Phenol 157.177
AMS 55.224
37
Water 78.631
Na2SO4 2.124
Total 450.334
Na2SO4 2.124
38 Water 59.609
Total 61.733
Acetone 157.177
Water 19.022
39 AMS 55.224
Phenol 157.177
Total 388.601
Acetone 157.177
Water 19.022
40 AMS 55.224
Phenol 157.177
Total 388.601
Acetone 2.910
Water 2.853
41 AMS 52.463
Phenol 154.683
Total 212.909
Acetone 154.268
Water 16.169
42 AMS 2.761
Phenol 2.494
Total 175.692
Acetone 1.543
Water 16.007
43 AMS 2.761
Phenol 2.494
Total 22.805
Acetone 152.725
Water 0.162
44 AMS 0.000
Phenol 0.000
Total 152.887
Acetone 0.029
Water 0.029
45
45 AMS 51.939
Phenol 154.153
Total 206.149
Acetone 2.880
Water 2.825
46 AMS 0.525
Phenol 0.530
Total 6.759
Acetone 0.000
Water 0.003
47 AMS 8.004
Phenol 152.153
Total 160.160
Acetone 0.029
Water 0.025
48 AMS 43.935
Phenol 2.000
Total 45.989
Acetone 4.423
Water 18.832
49 AMS 3.286
Phenol 3.024
Total 29.565
kg/kmol
kg/kmol
kg/kmol
kg/kmol
kg/kmol
kg/kmol
kg/kmol
kg/kmol
kg/kmol
kg/kmol
kg/kmol
kg/kmol
Mass Flow Rate (kgh-1) Mole Fraction Mass Fraction

26000.000 1.000 1.000
26000.000 1.000 1.000
85281.880 0.988 0.984
1349.988 0.012 0.016
86631.867 1.000 1.000
111282.800 0.991 0.988
1349.760 0.009 0.012
112632.560 1.000 1.000
Balances: Ass
47480.661 0.210 0.233 Mixing point 1 (M1
156290.510 0.790 0.767 Cumene
203771.172 1.000 1.000 CHP
32286.850 0.210 0.233
106277.547 0.790 0.767 Spliting point 1 (S1
138564.397 1.000 1.000 O2
15193.812 0.210 0.233 N2
50012.963 0.790 0.767
65206.775 1.000 1.000
83471.316 0.808 0.769 1st Reactor (M
25046.711 0.192 0.231 O2
108518.028 1.000 1.000 N2
8893.408 0.016 0.062 Cumene
265.945 3.70E-04 0.002 CHP
27242.029 0.180 0.191
106277.547 0.804 0.745 Spliting point 2 (S2
142678.929 1.000 1.000 O2
4446.704 0.016 0.062 N2
132.973 0.000 0.002 Cumene
13621.015 0.180 0.191 CHP
53138.773 0.804 0.745
71339.465 1.000 1.000 1st Separator (
4446.704 0.016 0.062 O2
132.973 0.000 0.002 N2
13621.015 0.180 0.191 Cumene
53138.773 0.804 0.745 CHP
71339.465 1.000 1.000
3136.273 0.977 0.971 2nd Separator (
93.786 0.023 0.029 O2
3230.059 1.000 1.000 N2
3136.273 0.977 0.971 Cumene
93.786 0.023 0.029
3230.059 1.000 1.000 3rd Separator (
1340.475 0.005 0.020 O2
13621.015 0.182 0.200 N2
53138.773 0.813 0.780 Cumene
68100.264 1.000 1.000 CHP
1340.475 0.005 0.020
13621.015 0.182 0.200 4th Separator (
53138.773 0.813 0.780 O3
68100.264 1.000 1.000 N3
1254.879 1.000 1.000 Cumene
1254.879 1.000 1.000
1254.879 1.000 1.000 2nd Reactor (M
1254.879 1.000 1.000 O2
86.489 0.000 0.001 N2
13621.015 0.183 0.204 Cumene
53138.773 0.817 0.795 CHP
66846.277 1.000 1.000
86.489 0.000 0.001 Spliting point 3 (S3
13621.015 0.183 0.204 O2
53138.773 0.817 0.795 N2
66846.277 1.000 1.000 Cumene
72980.275 0.735 0.687 CHP
33323.593 0.265 0.313
106303.868 1.000 1.000 5th Separator (
3813.336 0.014 0.057 O2
181.545 0.001 0.003 N2
13413.090 0.187 0.199 Cumene
50012.963 0.798 0.742 CHP
67420.935 1.000 1.000
1906.668 0.014 0.057 6th Separator (
90.772 0.001 0.003 O2
6706.545 0.187 0.199 N2
25006.482 0.798 0.742 Cumene
33710.467 1.000 1.000
1906.668 0.014 0.057 7th Separator (
90.772 0.001 0.003 O2
6706.545 0.187 0.199 N2
25006.482 0.798 0.742 Cumene
33710.467 1.000 1.000 CHP
1301.209 0.964 0.955
61.948 0.036 0.045 8th Separator (
1363.156 1.000 1.000 O2
1301.209 0.964 0.955 N2
61.948 0.036 0.045 Cumene
1363.156 1.000 1.000
627.551 0.005 0.019 Flash (Mole
6706.545 0.189 0.207 Cumene
25006.482 0.806 0.773 CHP
32340.578 1.000 1.000
627.551 0.005 0.019
6706.545 0.189 0.207 Concentrator (M
25006.482 0.806 0.773 Cumene
32340.578 1.000 1.000 CHP
587.170 1.000 1.000
587.170 1.000 1.000 Recycle Storage Ta
587.170 1.000 1.000 Cumene
587.170 1.000 1.000 CHP
41.046 3.10E-04 0.001
6706.545 0.190 0.211 Spliting Point 2 (S2
25006.482 0.810 0.788 CHP
31754.072 1.000 1.000
41.046 3.10E-04 0.001 Spliting Point 3 (S3
6706.545 0.190 0.211 H2SO4
25006.482 0.810 0.788 Water
31754.072 1.000 1.000
71447.376 0.732 0.683 PFR 1 (Mole
33195.920 0.268 0.317 Acetone
104643.297 1.000 1.000 Phenol
1532.898 0.938 0.923 AMS
127.673 0.062 0.077 Water
1660.571 1.000 1.000 H2SO4
257.457 0.010 0.008 CHP
32285.073 0.990 0.992
32542.530 1.000 1.000 PFR 2 (Mole
71189.920 0.990 0.987 Acetone
910.847 0.010 0.013 Phenol
72100.767 1.000 1.000 AMS
4391.152 0.983 0.979 Water
93.786 0.017 0.021 H2SO4
4484.938 1.000 1.000 CHP
4391.152 0.983 0.979
93.786 0.017 0.021
4484.938 1.000 1.000 PFR 3 (Mole
1888.379 0.975 0.968 Acetone
61.948 0.025 0.032 Phenol
1950.327 1.000 1.000 AMS
1888.379 0.975 0.968 Water
61.948 0.025 0.032 H2SO4
1950.327 1.000 1.000 CHP
10761.691 1.000 1.000
10761.691 1.000 1.000
10761.691 1.000 1.000 Mixing Point 3 (M3
10761.691 1.000 1.000 Acetone
10761.691 1.000 1.000 Phenol
10761.691 1.000 1.000 AMS
208.322 0.100 0.377 Water
344.091 0.900 0.623 H2SO4
552.412 1.000 1.000
83.671 0.100 0.422 CSTR (Mole
114.697 0.900 0.578 Acetone
198.368 1.000 1.000 Phenol
69.441 0.100 0.377 AMS
114.697 0.900 0.623 Water
184.137 1.000 1.000 H2SO4
69.441 0.100 0.377 NaOH
114.697 0.900 0.623 Na2SO4
184.137 1.000 1.000
3042.953 0.352 0.285
4927.300 0.352 0.462 Coalescer (M
2175.457 0.124 0.204 Acetone
446.044 0.167 0.042 Phenol
69.441 0.005 0.007 AMS
10661.194 1.000 1.000 Water
3042.953 0.352 0.285 Na2SO4
4927.300 0.352 0.462
2175.457 0.124 0.204
446.044 0.167 0.042 Storage Tank (M
69.441 0.005 0.007 Acetone
10661.194 1.000 1.000 Water
3042.953 0.352 0.285 AMS
4927.300 0.352 0.462 Phenol
2175.457 0.124 0.204
446.044 0.167 0.042 Column 1 (Mo
69.441 0.005 0.007 Acetone
10661.194 1.000 1.000 Water
9128.859 0.352 0.285 AMS
14781.899 0.352 0.462 Phenol
6526.372 0.124 0.204
1338.131 0.167 0.042 Column 2 (Mo
208.322 0.005 0.007 Acetone
31983.583 1.000 1.000 Water
169.909 0.990 0.996 AMS
0.765 0.010 0.004 Phenol
170.673 1.000 1.000
9128.859 0.349 0.284 Column 3 (Mo
14781.899 0.349 0.460 Acetone
6526.372 0.123 0.203 Water
1415.361 0.175 0.044 AMS
301.696 0.005 0.009 Phenol
32154.187 1.000 1.000
301.696 0.034 0.219 Column 4 (Mo
1072.965 0.966 0.781 Acetone
1374.661 1.000 1.000 Water
9128.859 0.404 0.297 AMS
342.395 0.049 0.011 Phenol
6526.372 0.142 0.212
14781.899 0.404 0.480
30779.526 1.000 1.000
9128.859 0.404 0.297
342.395 0.049 0.011
6526.372 0.142 0.212
14781.899 0.404 0.480
30779.526 1.000 1.000
168.987 0.014 0.014
51.359 0.013 0.004
3047.065 0.246 0.249
8983.980 0.727 0.733
12251.392 1.000 1.000
8959.872 0.878 0.938
291.036 0.092 0.030
160.372 0.016 0.017
144.879 0.014 0.015
9556.159 1.000 1.000
89.599 0.068 0.131
288.126 0.702 0.422
160.372 0.121 0.235
144.879 0.109 0.212
682.975 1.000 1.000
8870.274 0.999 1.000
2.910 0.001 0.000
0.000 0.000 0.000
0.000 0.000 0.000
8873.184 1.000 1.000
1.690 0.000 0.000
0.514 0.000 0.000
3016.595 0.252 0.252
8953.220 0.748 0.748
11972.018 1.000 1.000
167.297 0.426 0.599
50.846 0.418 0.182
30.471 0.078 0.109
30.760 0.078 0.110
279.373 1.000 1.000
0.017 0.000 0.000
0.059 0.000 0.000
464.850 0.050 0.050
8837.060 0.950 0.950
9301.986 1.000 1.000
1.673 0.001 0.001
0.454 0.001 0.000
2551.745 0.955 0.956
116.160 0.043 0.044
2670.032 1.000 1.000
256.896 0.150 0.267
338.971 0.637 0.352
190.843 0.111 0.198
175.639 0.102 0.183
962.349 1.000 1.000
Balances: Assume no steady state conditions therefore no accumulation oc
Mixing point 1 (M1) (Moles) Mixing point 1 (M1)
927.35 = 927.36 0.0 Compoonent Input
8.88 = 8.88 0.0 Cumene 927.35
927.35
Spliting point 1 (S1) (Moles) CHP 8.88
1483.77 = 1483.77 0.0 8.88
5581.80 = 5581.80 0.0
Spliting point 1 (S1)
Compoonent Input
1st Reactor (Moles) O2 1483.77
1008.96 = 1008.96 0.0 1483.77
3795.63 = 3795.63 0.0 N2 5581.80
927.36 = 927.36 0.0 5581.80
166.53 = 166.53 0.0
1st Reactor (Mo
Spliting point 2 (S2) (Moles) 0.0 Compoonent Input
74.11 = 74.11 0.0 O2 1008.96
3795.63 = 3795.63 0.0 1008.96
74.11 = 74.11 0.0 N2 3795.63
1.75 = 1.75 0.0 3795.63
Cumene 927.36
1st Separator (Moles) 927.36
425.66 = 425.66 0.0 CHP 8.88
1897.81 = 1897.81 0.0 166.53
37.06 = 37.31 -0.3
0.87 = 0.62 0.3 Spliting point 2 (S2)
Compoonent Input
2nd Separator (Moles) O2 851.31
425.66 = 425.66 0.0 851.31
1897.81 = 1897.81 0.0 N2 3795.63
11.17 = 11.18 0.0 3795.63
Cumene 74.11
3rd Separator (Moles) 74.11
425.66 = 425.66 0.0 CHP 1.75
1897.81 = 1897.81 0.0 1.75
37.06 = 37.31 -0.3
0.87 = 0.62 0.3 1st Separator (Mo
Compoonent Input
4th Separator (Moles) O2 425.66
425.66 = 425.66 0.0 425.66
1897.81 = 1897.81 0.0 N2 1897.81
11.17 = 11.18 0.0 1897.81
Cumene 37.06
2nd Reactor (Moles) 37.06
474.81 = 474.81 0.0 CHP 0.87
1786.18 = 1786.18 0.0 0.87
695.59 = 695.59 0.0
220.43 = 220.43 0.0 2nd Separator (M
Compoonent Input
Spliting point 3 (S3) (Moles) 0.0 O2 425.66
419.16 = 419.16 0.0 425.66
1786.18 = 1786.18 0.0 N2 1897.81
31.78 = 31.78 0.0 1897.81
1.19 = 1.19 0.0 Cumene 11.17
11.17
5th Separator (Moles)
209.58 = 209.58 0.0 3rd Separator (M
15.89 = 16.07 -0.2 O2 425.66
0.60 = 0.41 0.2 425.66
N2 1897.81
6th Separator (Moles) 1897.81
209.58 = 209.58 0.0 Cumene 37.06
893.09 = 893.09 0.0 37.06
5.23 = 5.24 0.0 CHP 0.87
0.87
209.58 = 209.58 0.0 4th Separator (M
15.89 = 16.07 -0.2 O2 425.66
0.60 = 0.41 0.2 425.66
N2 1897.81
8th Separator (Moles) 1897.81
209.58 = 209.58 0.0 Cumene 11.17
893.09 = 893.09 0.0 11.17
5.23 = 5.24 0.0
2nd Reactor (Mo
Flash (Moles) Compoonent Input
608.17 = 608.17 0.0 O2 474.81
219.23 = 219.23 0.0 474.81
N2 1786.18
1786.18
Concentrator (Moles) Cumene 695.59
608.17 = 608.17 0.0 695.59
219.23 = 219.23 0.0 CHP 164.78
220.43
Recycle Storage Tank (Moles)
710.68 = 710.68 0.0 Spliting point 2 (S2)
O2 419.16
Spliting Point 2 (S2) (Moles) 419.16
212.40 = 212.40 0.0 N2 1786.18
1786.18
Spliting Point 3 (S3) (Moles) Cumene 31.78
2.12 = 2.12 0.0 31.78
19.12 = 19.12 0.0 CHP 1.19
1.19
PFR 1 (Moles)
52.392 = 52.392 0.0 5th Separator (M
18.408 = 18.408 0.0 O2 209.58
24.780 = 24.780 0.0 209.58
0.708 = 0.708 0.0 N2 893.09
70.801 = 70.801 0.0 893.09
Cumene 15.89
PFR 2 (Moles) 15.89
52.392 = 52.392 0.0 CHP 0.60
52.392 = 52.392 0.0 0.60
18.408 = 18.408 0.0
24.780 = 24.780 0.0 6th Separator (M
70.801 = 70.801 0.0 O2 209.58
209.58
N2 893.09
PFR 3 (Moles) 893.09
52.392 = 52.392 0.0 Cumene 5.23
52.392 = 52.392 0.0 5.23
18.408 = 18.408 0.0
24.780 = 24.780 0.0
0.708 = 0.708 0.0
70.801 = 70.801 0.0 7th Separator (M
Compoonent Input
O2 209.58
Mixing Point 3 (M3) (Moles) 209.58
157.177 = 157.177 0.0 N2 893.09
157.177 = 157.177 0.0 893.09
55.224 = 55.224 0.0 Cumene 15.89
74.341 = 74.341 0.0 15.89
2.124 = 2.124 0.0 CHP 0.60
0.60
CSTR (Moles)
157.177 = 157.177 0.0 8th Separator (M
55.224 = 55.224 0.0 O2 209.58
78.631 = 78.631 0.0 209.58
2.124 = 2.124 0.0 N2 893.09
4.248 = 4.248 0.0 893.09
2.124 = 2.124 0.0 Cumene 5.23
5.23
Coalescer (Moles) Flash (Moles)

157.177 = 157.177 0.0 Cumene 608.17
55.224 = 55.224 0.0 608.17
78.631 = 78.631 0.0 CHP 219.23
2.124 = 2.124 0.0 219.23
Concentrator (Mo
Storage Tank (Moles) Compoonent Input
157.177 = 157.177 0.0 Cumene 595.39
19.022 = 19.022 0.0 595.39
55.224 = 55.224 0.0 CHP 218.39
157.177 = 157.177 0.0 218.39
Column 1 (Moles) Recycle Storage Tank

19.022 = 19.022 0.0 Cumene 710.68
55.224 = 55.224 0.0 710.68
157.177 = 157.177 0.0 CHP 7.86
7.86
Column 2 (Moles)
154.268 = 154.268 0.0 Spliting Point 2 (S2)
2.761 = 2.761 0.0 CHP 212.40
2.494 = 2.494 0.0 212.40
Column 3 (Moles) Spliting Point 2 (S2)

2.853 = 2.853 0.0 H2SO4 2.12
52.463 = 52.463 0.0 2.12
154.683 = 154.683 0.0 Water 19.12
19.12
Column 4 (Moles)
3E-02 = 3E-02 0.0 PFR 1 (Moles
3E-02 = 0.029 0.0 Compoonent Input
5E+01 = 51.939 0.0 Acetone 0.00
2E+02 = 154.153 0.0 52.39
Phenol 0.00
52.39
AMS 0.00
18.41
CHP 70.80
70.80
Water 6.37
24.78
H2SO4 0.71
0.71
PFR 2 (Moles
Compoonent Input
Acetone 0.00
52.39
Phenol 0.00
52.39
AMS 0.00
18.41
CHP 70.80
70.80
Water 6.37
24.78
H2SO4 0.71
0.71
PFR 3 (Moles
Compoonent Input
Acetone 0.00
52.39
Phenol 0.00
52.39
AMS 0.00
18.41
CHP 70.80
70.80
Water 6.37
24.78
H2SO4 0.71
0.71
Mixing Point 3 (M3)

Compoonent Input
Acetone 157.18
157.18
Phenol 157.18
157.18
AMS 55.22
55.22
Water 74.34
74.34
H2SO4 2.12
2.12
CSTR (Moles)
Compoonent Input
Acetone 157.18
157.18
Phenol 157.18
157.18
AMS 55.22
55.22
Water 74.38
78.63
H2SO4 2.12
2.12
NaOH 4.25
4.25
Na2SO4 0.00
2.12
Coalescer (Mole
Compoonent Input
Acetone 157.18
157.18
Phenol 157.18
157.18
AMS 55.22
55.22
Water 78.63
78.63
Na2SO4 2.12
2.12
Storage Tank (Mo

Compoonent Input
Acetone 157.18
157.18
Water 19.02
19.02
AMS 55.22
55.22
Phenol 157.18
157.18
.
o accumulation occurs in equipment.

Mixing point 1 (M1) (Moles)
Generation = Output Consumption
0.00 = 927.36 0.00
927.35 = 927.36 0.0
0.00 = 8.88 0.00
8.88 = 8.88 0.0
Spliting point 1 (S1) (Moles)

0.00 = 1483.77 0.00
1483.77 = 1483.77 0.0
0.00 = 5581.80 0.00
5581.80 = 5581.80 0.0
1st Reactor (Moles) 1st Reactor

Generation = Output Consumption Compoonent
0.00 = 851.31 157.65 O
1008.96 = 1008.96 0.0
0.00 = 3795.63 0.00 N
3795.63 = 3795.63 0.0
0.00 = 769.71 157.65 C
927.36 = 927.36 0.0
157.65 = 166.53 0.00 H
166.53 = 166.53 0.0
Spliting point 2 (S2) (Moles) 2nd Reacto

0.00 = 851.31 0.00 O
851.31 = 851.31 0.0
0.00 = 3795.63 0.00 N
3795.63 = 3795.63 0.0
0.00 = 74.11 0.00 C
74.11 = 74.11 0.0
0.00 = 1.75 0.00 H
1.75 = 1.75 0.0
1st Separator (Moles) 1st PFR(M

0.00 = 425.66 0.00 O
425.66 = 425.66 0.0
0.00 = 1897.81 0.00 C
1897.81 = 1897.81 0.0
0.00 = 37.31 0.00 H
37.06 = 37.31 -0.3
0.00 = 0.62 0.00 S
0.87 = 0.62 0.3
2nd Separator (Moles) 2nd PFR (

0.00 = 425.66 0.00 O
425.66 = 425.66 0.0
0.00 = 1897.81 0.00 C
1897.81 = 1897.81 0.0
0.00 = 11.18 0.00 H
11.17 = 11.18 0.0
S
3rd Separator (Moles)
0.00 = 425.66 0.00 3rd PFR (
425.66 = 425.66 0.0 Compoonent
0.00 = 1897.81 0.00 O
1897.81 = 1897.81 0.0
0.00 = 37.31 0.00 C
37.06 = 37.31 -0.3
0.00 = 0.62 0.00 H
0.87 = 0.62 0.3
S
0.00 = 425.66 0.00 CSTR (M
425.66 = 425.66 0.0 Compoonent
0.00 = 1897.81 0.00 O
1897.81 = 1897.81 0.0
0.00 = 11.18 0.00 C
11.17 = 11.18 0.0
H
2nd Reactor (Moles)
Generation = Output Consumption S
0.00 = 474.81 0.00
474.81 = 474.81 0.0 Na
0.00 = 1786.18 0.00
1786.18 = 1786.18 0.0
0.00 = 639.95 55.65
695.59 = 695.59 0.0
55.65 = 220.43 0.00
220.43 = 220.43 0.0
Spliting point 2 (S2) (Moles)

0.00 = 419.16 0.00 0.0
419.16 = 419.16
0.00 = 1786.18 0.00 0.0
1786.18 = 1786.18
0.00 = 31.78 0.00 0.0
31.78 = 31.78
0.00 = 1.19 0.00 0.0
1.19 = 1.19

0.00 = 209.58 0.00
209.58 = 209.58 0.0
0.00 = 893.09 0.00
893.09 = 893.09 0.0
0.00 = 16.07 0.00
15.89 = 16.07 -0.2
0.00 = 0.41 0.00
0.60 = 0.41 0.2

0.00 = 209.58 0.00
209.58 = 209.58 0.0
0.00 = 893.09 0.00
893.09 = 893.09 0.0
0.00 = 5.24 0.00
5.23 = 5.24 0.0
C
7th Separator (Moles) Compoonent
Generation = Output Consumption Acetone
0.00 = 209.58 0.00
209.58 = 209.58 0.0 Water
0.00 = 893.09 0.00
893.09 = 893.09 0.0 AMS
0.00 = 16.07 0.00
15.89 = 16.07 -0.2 Phenol
0.00 = 0.41 0.00
0.60 = 0.41 0.2
C
8th Separator (Moles) Compoonent
Generation = Output Consumption Acetone
0.00 = 209.58 0.00
209.58 = 209.58 0.0 Water
0.00 = 893.09 0.00
893.09 = 893.09 0.0 AMS
0.00 = 5.24 0.00
5.23 = 5.24 0.0 Phenol

Flash (Moles)
Generation = Output Consumption C
0.00 = 608.17 0.00 Compoonent
608.17 = 608.17 0.0 Acetone
0.00 = 219.23 0.00
219.23 = 219.23 0.0 Water

Concentrator (Moles) AMS
0.00 = 595.39 0.00 Phenol
595.39 = 595.39 0.0
0.00 = 218.39 0.00
218.39 = 218.39 0.0 C
Compoonent
Recycle Storage Tank (Moles) Acetone
0.00 = 710.68 0.00 Water
710.68 = 710.68 0.0
0.00 = 8.88 0.00 AMS
7.86 = 8.88 -1.0
Phenol
Spliting Point 2 (S2) (Moles)
0.00 = 212.40 0.00
212.40 = 212.40 0.0
Spliting Point 2 (S2) (Moles)

0.00 = 2.12 0.00
2.12 = 2.12 0.0
0.00 = 19.12 0.00
19.12 = 19.12 0.0
PFR 1 (Moles)
52.39 = 52.39 0.00
= 52.39 0.0
52.39 = 52.39 0.00
= 52.39 0.0
18.41 = 18.41 0.00
= 18.41 0.0
0.00 = 0.00 70.80
= 70.80 0.0
18.41 = 24.78 0.00
= 24.78 0.0
0.00 = 0.71 0.00
0.71 = 0.71 0.0
PFR 2 (Moles)
52.39 = 52.39 0.00
52.39 = 52.39 0.0
52.39 = 52.39 0.00
52.39 = 52.39 0.0
18.41 = 18.41 0.00
18.41 = 18.41 0.0
0.00 = 0.00 70.80
70.80 = 70.80 0.0
18.41 = 24.78 0.00
24.78 = 24.78 0.0
0.00 = 0.71 0.00
0.71 = 0.71 0.0
PFR 3 (Moles)
52.39 = 52.39 0.00
52.39 = 52.39 0.0
52.39 = 52.39 0.00
52.39 = 52.39 0.0
18.41 = 18.41 0.00
18.41 = 18.41 0.0
0.00 = 0.00 70.80
70.80 = 70.80 0.0
18.41 = 24.78 0.00
24.78 = 24.78 0.0
0.00 = 0.71 0.00
0.71 = 0.71 0.0
Mixing Point 3 (M3) (Moles)

0.00 = 157.18 0.00
157.18 = 157.18 0.0
0.00 = 157.18 0.00
157.18 = 157.18 0.0
0.00 = 55.22 0.00
55.22 = 55.22 0.0
0.00 = 74.34 0.00
74.34 = 74.34 0.0
0.00 = 2.12 0.00
2.12 = 2.12 0.0
CSTR (Moles)
0.00 = 157.18 0.00
157.18 = 157.18 0.0
0.00 = 157.18 0.00
157.18 = 157.18 0.0
0.00 = 55.22 0.00
55.22 = 55.22 0.0
4.25 = 78.63 0.00
78.63 = 78.63 0.0
0.00 = 0.00 2.12
2.12 = 2.12 0.0
0.00 = 0.00 4.25
4.25 = 4.25 0.0
2.12 = 2.12 0.00
2.12 = 2.12 0.0
Coalescer (Moles)
0.00 = 157.18 0.00
157.18 = 157.18 0.0
0.00 = 157.18 0.00
157.18 = 157.18 0.0
0.00 = 55.22 0.00
55.22 = 55.22 0.0
0.00 = 78.63 0.00
78.63 = 78.63 0.0
0.00 = 2.12 0.00
2.12 = 2.12 0.0
Storage Tank (Moles)

0.00 = 157.18 0.00
157.18 = 157.18 0.0
0.00 = 19.02 0.00
19.02 = 19.02 0.0
0.00 = 55.22 0.00
55.22 = 55.22 0.0
0.00 = 157.18 0.00
157.18 = 157.18 0.0
1st Reactor (Moles) (Atomic Balance)
Input Generation = Output Consumption
2035.69 0.00 = 2035.69 0.00
2035.69 = 2035.69 0
7591.25 0.00 = 7591.25 0.00
7591.25 = 7591.25 0
8426.13 1418.86 = 8426.13 1418.86
9844.99 = 9844.99 0
11234.84 1891.81 = 11234.84 1891.81
13126.65 = 13126.65 0
2nd Reactor (Moles) (Atomic Balance)

1279.18 0.00 = 1279.18 0.00
1279.18 = 1279.18 0
3572.35 0.00 = 3572.35 0.00
3572.35 = 3572.35 0
7743.38 500.83 = 7743.38 500.83
8244.21 = 8244.21 0
10324.50 667.77 = 10324.50 667.77
10992.27 = 10992.27 0
1st PFR(Moles) (Atomic Balance)

150.81 141.60 = 150.81 141.60
292.41 = 292.41 0
637.21 637.21 = 637.21 637.21
1274.41 = 1274.41 0
863.77 849.61 = 863.77 849.61
1713.37 = 1713.37 0
0.71 0.00 = 0.71 0.00
0.71 = 0.71 0
2nd PFR (Moles) (Atomic Balance)

150.81 141.60 = 150.81 141.60
292.41 = 292.41 0
637.21 637.21 = 637.21 637.21
1274.41 = 1274.41 0
863.77 849.61 = 863.77 849.61
1713.37 = 1713.37 0
0.71 0.00 = 0.71 0.00
0.71 = 0.71 0
3rd PFR (Moles) (Atomic Balance)

150.81 141.60 = 150.81 141.60
292.41 = 292.41 0
637.21 637.21 = 637.21 637.21
1274.41 = 1274.41 0
863.77 849.61 = 863.77 849.61
1713.37 = 1713.37 0
0.71 0.00 = 0.71 0.00
0.71 = 0.71 0
CSTR (Moles) (Atomic Balance)

401.44 12.74 = 401.48 12.74
414.18 = 414.23 0
1911.62 0.00 = 1911.62 0.00
1911.62 = 1911.62 0
2595.55 8.50 = 2595.63 8.50
2604.05 = 2604.13 0
2.12 2.12 = 2.12 2.12
4.25 = 4.25 0
4.25 4.25 = 4.25 4.25
8.50 = 8.50 0
Column 1 (Moles)
157.18 0.00 = 157.18 0.00
157.18 = 157.18 0
19.02 0.00 = 19.02 0.00
19.02 = 19.02 0
55.22 0.00 = 55.22 0.00
55.22 = 55.22 0
157.18 0.00 = 157.18 0.00
157.18 = 157.18 0
Column 2 (Moles)
154.27 0.00 = 154.27 0.00
154.27 = 154.27 0
16.17 0.00 = 16.17 0.00
16.17 = 16.17 0
2.76 0.00 = 2.76 0.00
2.76 = 2.76 0
2.49 0.00 = 2.49 0.00
2.49 = 2.49 0
Column 3 (Moles)
2.91E+00 0.00 = 2.91E+00 0.00
2.91E+00 = 2.91E+00 0
2.85 0.00 = 2.85 0.00
2.85 = 2.85 0
52.46 0.00 = 52.46 0.00
52.46 = 52.46 0
154.68 0.00 = 154.68 0.00
154.68 = 154.68 0
Column 4 (Moles)
2.91E-02 0.00 = 2.91E-02 0.00
2.91E-02 = 2.91E-02 0
2.85E-02 0.00 = 2.85E-02 0.00
2.85E-02 = 2.85E-02 0
51.94 0.00 = 51.94 0.00
51.94 = 51.94 0
154.15 0.00 = 154.15 0.00
154.15 = 154.15 0
Discripencies in separators by +/- 0.3 & +/- 0.2 due to the assumed temperatures and pressures of th
Streams
Temperature (K)
Pressure (kPa)
Vapour Fraction
Liquid Fraction
Cumene (kmol/hr)
Cumene Hydroperoxide (kmol/hr)
Oxygen (kmol/hr)
Nitrogen (kmol/hr)
Sulphuric Acid (kmol/hr)
Water (kmol/hr)
Acetone (kmol/hr)
Phenol (kmol/hr)
Alpha-methyl Styrene (kmol/hr)
Sodium Hydroxide (kmol/hr)
Sodium Sulphate (kmol/hr)
Total Flowrate (kmol/hr)
Streams
Temperature (K)
Pressure (atm)
Vapour Fraction
Liquid Fraction
Cumene (kmol/hr)
Oxygen (kmol/hr)
Nitrogen (kmol/hr)
Acetone (kmol/hr)
Water (kmol/hr)
Phenol (kmol/hr)
Sodium Sulphate(kmol/hr)
Streams
Temperature (K)
Pressure (atm)
Vapour Fraction
Liquid Fraction
Cumene (kmol/hr)
Oxygen (kmol/hr)
Nitrogen (kmol/hr)
Acetone (kmol/hr)
Water (kmol/hr)
Phenol (kmol/hr)
Streams
Temperature (K)
Pressure (atm)
Vapour Fraction
Liquid Fraction
Cumene (kmol/hr)
Oxygen (kmol/hr)
Nitrogen (kmol/hr)
Acetone (kmol/hr)
Water (kmol/hr)
Phenol (kmol/hr)
3 & +/- 0.2 due to the assumed temperatures and pressures of the separators.
S-001 S-002 S-003 S-004
300.15 300.15 389.65 352.95
101.30 506.60 465.30 18.59
0.00 0.00 0.00 0.00
1.00 1.00 1.00 1.00
216.67 216.67 216.67 927.36
0.00 0.00 0.00 8.88
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00
216.67 216.67 216.67 936.24
S-023 S-024 S-025 S-026

353.15 353.15 353.15 353.15
465.30 465.30 465.30 465.30
1.00 1.00 1.00 1.00
0.00 0.00 0.00 0.00
0.00 0.00 0.00 31.78
0.00 0.00 0.00 1.19
1483.77 1008.96 474.81 419.16
5581.80 3795.63 1786.18 1786.18
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00
7065.57 4804.59 2260.98 2238.31
S-045 S-046 S-047 S-048

278.15 349.81 342.29 411.95
20.00 202.60 202.60 294.70
0.00 0.00 0.00 0.00
1.00 1.00 1.00 1.00
2.15 593.25 710.68 2.1454726856
212.40 5.99 8.88 212.40179588
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00
214.55 599.24 719.56 214.55
S-067 S-068 S-069 S-070

300.15 300.15 300.15 361.93
101.30 101.30 282.70 241.30
0.00 0.00 0.00 0.00
1.00 1.00 1.00 1.00
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00
0.00 157.18 157.18 157.18
59.61 19.02 19.02 19.02
0.00 55.22 55.22 55.22
0.00 157.18 157.18 157.18
0.00 0.00 0.00 0.00
2.12 0.00 0.00 0.00
61.73 388.60 388.60 388.60
S-005 S-006 S-007 S-008 S-009
353.15 353.15 353.15 353.15 353.15
506.60 465.30 465.30 465.30 465.30
0.00 1.00 0.00 1.00 1.00
1.00 0.00 1.00 0.00 0.00
927.36 74.11 695.59 37.06 37.06
8.88 1.75 164.78 0.87 0.87
8.88 851.31 0.00 425.66 425.66
0.00 3795.63 0.00 1897.81 1897.81
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
945.12 4722.80 860.38 2361.40 2361.40
S-027 S-028 S-029 S-030 S-031

353.15 353.15 353.15 323.15 323.15
465.30 465.30 465.30 465.30 465.30
0.00 1.00 1.00 1.00 0.00
1.00 0.00 0.00 0.00 1.00
608.17 15.89 15.89 5.23 10.84
219.23 0.60 0.60 0.00 0.41
0.00 209.58 209.58 209.58 0.00
0.00 893.09 893.09 893.09 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
827.40 1119.15 1119.15 1107.90 11.25
S-049 S-050 S-051 S-052 S-053

333.15 333.15 333.15 333.15 300.15
253.00 253.00 253.00 253.00 101.30
0.00 0.00 0.00 0.00 0.00
1.00 1.00 1.00 1.00 1.00
2.15 0.00 0.00 0.00 0.00
212.40 70.80 70.80 70.80 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 2.12
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 19.12
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
214.55 70.80 70.80 70.80 21.24
S-071 S-072 S-073 S-074 S-075

372.72 417.05 352.67 402.61 403.67
220.63 255.11 220.63 255.11 220.63
0.00 0.00 0.00 0.00 0.00
1.00 1.00 1.00 1.00 1.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
154.27 2.91 152.73 1.54 2.88
16.17 2.85 0.16 16.01 2.82
2.76 52.46 0.00 2.76 0.52
2.49 154.68 0.00 2.49 0.53
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
175.69 212.91 152.89 22.81 6.76
S-010 S-011 S-012 S-013 S-014
323.15 323.15 278.15 278.15 300.65
465.30 465.30 465.30 465.30 465.30
1.00 0.00 1.00 0.00 0.00
0.00 1.00 0.00 1.00 1.00
11.17 26.14 0.72 10.46 36.59
0.00 0.62 0.00 0.00 0.62
425.66 0.00 425.66 0.00 0.00
1897.81 0.00 1897.81 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
2334.64 26.75 2324.19 10.46 37.21
S-032 S-033 S-034 S-035 S-036

278.15 278.15 300.65 323.15 323.15
465.30 465.30 465.30 465.30 465.30
1.00 0.00 0.00 1.00 0.00
0.00 1.00 1.00 0.00 1.00
0.34 0.00 15.74 5.23 10.84
0.00 4.89 0.41 0.00 0.41
209.58 0.00 0.00 209.58 0.00
893.09 0.00 0.00 893.09 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
1103.01 4.89 16.14 1107.90 11.25
S-054 S-055 S-056 S-057 S-058

300.15 300.15 300.15 300.15 333.15
253.30 253.30 253.30 253.30 253.30
0.00 0.00 0.00 0.00 0.00
1.00 1.00 1.00 1.00 1.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
2.12 0.71 0.71 0.71 0.71
0.00 0.00 0.00 0.00 52.39
19.12 6.37 6.37 6.37 24.78
0.00 0.00 0.00 0.00 18.41
0.00 0.00 0.00 0.00 52.39
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
21.24 7.08 7.08 7.08 148.68
S-076 S-077 S-078 S-079

278.15 403.14 473.10 489.62
255.11 237.87 220.63 255.11
0.00 0.00 0.00 0.00
1.00 1.00 1.00 1.00
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00
0.03 4.42 0.03 0.00
0.03 18.83 0.03 0.00
51.94 3.29 43.94 8.00
154.15 3.02 2.00 152.15
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00
206.15 29.56 45.99 160.16
S-015 S-016 S-017 S-018 S-019
323.15 323.15 278.15 278.15 300.65
465.30 465.30 465.30 456.30 456.30
1.00 0.00 1.00 0.00 0.00
0.00 1.00 0.00 1.00 1.00
11.17 26.14 0.72 10.46 36.59
0.00 0.62 0.00 0.00 0.62
425.66 0.00 425.66 0.00 0.00
1897.81 0.00 1897.81 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
2334.64 26.75 2324.19 10.46 37.21
S-037 S-038 S-039 S-040 S-041

278.15 278.15 300.65 373.15 369.03
465.30 465.30 465.30 423.90 15.00
1.00 0.00 0.00 0.00 0.00
0.00 1.00 1.00 1.00 1.00
0.34 4.89 15.74 608.17 608.17
0.00 0.00 0.41 219.23 219.23
209.58 0.00 0.00 0.00 0.00
893.09 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
1103.01 4.89 16.14 827.40 827.40
S-059 S-060 S-061 S-062 S-063

333.15 333.15 333.15 329.06 300.15
253.30 253.30 253.30 142.70 101.30
0.00 0.00 0.00 0.00 0.00
1.00 1.00 1.00 1.00 1.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.71 0.71 2.12 2.12 2.12
52.39 52.39 157.18 157.18 157.18
24.78 24.78 74.34 74.34 74.34
18.41 18.41 55.22 55.22 55.22
52.39 52.39 157.18 157.18 157.18
0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
148.68 148.68 446.04 446.04 446.04
S-020 S-021 S-022
300.15 540.75 423.15
101.30 548.00 506.60
1.00 1.00 1.00
0.00 0.00 0.00
0.00 0.00 0.00
0.00 0.00 0.00
1483.77 1483.77 1483.77
5581.80 5581.80 5581.80
0.00 0.00 0.00
0.00 0.00 0.00
0.00 0.00 0.00
0.00 0.00 0.00
0.00 0.00 0.00
0.00 0.00 0.00
0.00 0.00 0.00
7065.57 7065.57 7065.57
S-042 S-043 S-044

369.03 369.03 349.73
15.00 15.00 10.00
1.00 0.00 0.00
0.00 1.00 1.00
12.77 595.39 593.25
0.84 218.39 5.99
0.00 0.00 0.00
0.00 0.00 0.00
0.00 0.00 0.00
0.00 0.00 0.00
0.00 0.00 0.00
0.00 0.00 0.00
0.00 0.00 0.00
0.00 0.00 0.00
0.00 0.00 0.00
13.61 813.79 599.24
S-064 S-065 S-066

300.15 300.15 300.15
101.30 101.30 101.30
0.00 0.00 0.00
1.00 1.00 1.00
0.00 0.00 0.00
0.00 0.00 0.00
0.00 0.00 0.00
0.00 0.00 0.00
0.00 0.00 0.00
0.00 157.18 157.18
0.04 78.63 19.02
0.00 55.22 55.22
0.00 157.18 157.18
4.25 0.00 0.00
0.00 2.12 0.00
4.29 450.33 388.60
Reactors
Equipment No. Reactor Description Cost of Reators ($)
R1 Oxidation Reactor 1 949,553
R2 Oxidation Reactor 2 949,553
R3 PFR 1 64,041
R4 PFR 2 64,041
R5 PFR 3 64,041
R6 CSTR 156,990
Total $ 2,248,220
Separators
Equipment No. Description Cost of Separators ($)
S1 Removal of Cumene and CHP 24,474
S2 Removal of Cumene 30,079
S9 Flash Separator 12,212
S10 Removal of NaSO4 12,212
Total $ 218,215
Columns
Equipment No. Description Cost of Columns ($)
C1 Crude Acetone 70,919
C2 Acetone Removal 133,083
C3 Water Removal 35,544
C4 AMS and Phenol Removal 32,149
C5 CHP Concentration 42,637
Total $ 314,332.22
Storage Tanks
Equipment No. Description Cost of Storage Tanks ($)
ST1 Recycle 34,296
ST2 Sulphuric Acid 19,443
ST3 Sodium Hydroxide 6,656
ST4 Pre-Distillation 12,255
ST5 Acetone Storage 10,689
ST6 AMS Storage 10,612
ST7 Phenol Storage 8,914
ST8 Sodium Sulphate Storage 9,344
Total $ 112,210
Pumps
Equipment No. Breif Description Cost of Pump
Pum 1 $ 4,361
Pum 2 $ 7,632
Pum 3 $ 6,102
Pum 4 $ 3,682
Pum 5 $ 3,798
Pum 6 $ 5,412
Total $ 30,987
Cost of Heating/ Cooling
Equipment No. Breif Description Equipment ($)
FirFur 1 459,672
Het 1 123,456
Het 2 154,819
HetEx 1 18,485
HetEx 2a 23,539
HetEx 2b 23,822
HetEx 3 17,060
Cool 1 14,756,356
Total 15,577,208
Equipment No. Breif Description Cost of Compressor ($)
Comp 1 135,259
Total $ 135,259
Overall Equipment Cost $ 18,636,431.48
Costs
Equipment Cost ce $ 18,636,431
Using the factorial method of cost estimation to determine the ISBL cost of the plant
Item
Total Purchase Cost of Major Equipment, Ce $ 18,636,431
Equipment Erection, fer 0.3
Piping, fP 0.8
Instrumentation and Control, fi 0.3
Electical, fel 0.2
Civil, fc 0.3
Structure and Buildings, fs 0.2
Lagging and Paint,fl 0.1
Material (Assuming that carbon steel is used g), f m 1 Assuming that carbon stee
Total Plant ISBL Capital Cost $ 59,636,581
Total Plant OSBL Investment $ 23,854,632 Assume OSBL cost is 40%
Engineering Costs $ 8,349,121

Assume Engineering cost
Contingency Charges $ 5,963,658 Assume Contingency Cha

ISBL
Total Fixed Captial Cost $ 97,803,992
Working Capital Cost $ 12,523,682 Asumme Working Capital

capital (ISBL Cos
ssuming that carbon steel is used for pipping
From chemeng design and ec
ssume OSBL cost is 40% of the ISBL cost
Assume Engineering cost is 10% of the ISBL cost
Assume Contingency Charges cost is 10% of the

ISBL cost
Asumme Working Capital Cost is 15% of the fixed

capital (ISBL Costs+OSBL Cost)
rom chemeng design and econ book
Variable Costs of Production
Raw Materials $/yr
Cumene $ 76,952,345.71
Sodium Hydroxide $ 495,265.74
Sulphuric Acid $ 34,445.28
Raw Materials $ 76,952,345.71
Utilities
Steam
Price of Fuel ($/MMBtu) 3.382 http://www.indexmundi.com/c
Heating Rate (MMBtu/Mlb) 900 Assumed
Boiler Efficiency 85% Based on book with black cov
Price of High-Pressured Steam ($/Mlb) $ 3,580.94
Required Stream (kg/yr) 98,319,435
Required Stream (Mlb/yr) 36.70
Price of Steam ($/yr) $ 131,410
Fuel
Price of Fuel ($/MMBtu) 3.382 http://www.central-bank.org.t
Heating Value of Natural Gas (MMBTU/scf) 0.00106
Quanity of Natural Gas Required (scf/yr) 160794887.654591
Quanity of Heat Required (MMBTU/yr) 170442.580913866
Cost of Fuel ($/yr) $ 576,437
Electricity Requirement
Power Requirement (kW) 56302.33
Electricity Rate in T&T ($/kWyr) $ 168 https://ttec.co.tt/default/tariff
Cost of Electricity ($/yr) $ 9,458,791
Actual Cost of Electricity ($/yr) $ 10,404,670
Raw Water
Price of Boiler Water Feed ($/m3 yr) 6.24 http://www.wasa.gov.tt/Forms
Density of Water (kg/m3) 996.52 http://antoine.frostburg.edu/c
Price of Water ($/kg yr) $ 0.0063
Mass of Water (kg) 210000
Water Purchased ($/yr) $ 1,315
Consubles $ 529,711
Total Variable Cost $ 88,595,888.91

$/kg Average Assumed
$ 0.07 $ 0.35 $ 0.21 $ 0.47
$ 0.35
$ 0.02
ttp://www.indexmundi.com/commodities/?commodity=natural-gas
ased on book with black cover
ttp://www.central-bank.org.tt/statistics/data-centre/monthly-data.php
ttps://ttec.co.tt/default/tariffs-2#industriald4
ttp://www.wasa.gov.tt/Forms/Policies/puc_order_1983.pdf
ttp://antoine.frostburg.edu/chem/senese/javascript/water-density.html
Fixed Costs of Production SEADER BOOK
Operating Labour Cost
Process Type of Processing
Oxidation Unit Fluids Processing
Recovery/ Recycle Unit Fluids Processing
Concentration Unit Fluids Processing
Cleavage Unit Fluids Processing
Washing Unit Fluids Processing
Distillation Unit Fluids Processing
Total Amount of Operatos per Shift
Hours worked Weekly (hr/wk) 40

Plant Operating Schedule (months/year) 11
Plant Operating Schedule (hr/year) 2464
Hourly Wages ($/hr) $ 25
Number of Shifts (Shifts) 5
Direct Wages and Benefits Cost (Operators) $ 3,080,000
Supervision Cost $ 770,000
Direct Salary Overhead $ 1,540,000
Maintainenance and Repairs $ 1,789,097
Property Taxes and Insurance $ 596,366
Rent of Land (and/or buildings) $ 596,366
General Plant Overhead $ 2,664,413
Environmental Charges $ 834,912
Operating Supplies $ 268,365
Laboratory Charges $ 462,000
Administrative Costs $ 666,103

Distribution and Selling $ 469,206
Research and Development $ 234,603
Total Fixed Cost $ 13,971,431

Operators per Shift
1
2
1
2
2
2
10
Assume Supervision cost is 25% of the operating

labour.
Assume Direct Salarary overhead cost is 40% of the

operating labour plus supervision.
Assume Maintenance cost is 4% of the ISBL cost.

Since there aren't any moving parts in process.
Assume Property tax and insurance cost is 1% of the

ISBL cost.
Assume Renting of land cost is 1% of the ISBL cost.
Assume General plant overhead cost is 65% of total

labour (including supervision and direct overhead)
plus maintenance.
Assume Environmental Charges cost is 1% of the

ISBL cost.
(15% of Maintenance and Repairs)
(15% of Operating Labour)
(25% of Overhead)
(10% of Total Expenses)
(5% of Toal Expenses)

Capital
Fixed Capital, CFC $ 97,803,992
Working Capital, CEC $ 9,780,399 10% of Fixed Capital
Total Capital Investment, CTC $ 107,584,392

Manufacturing Expenses Annual Costs
Direct Expenses $/yr
Raw Materials
Cumene $ 76,952,346
Consumables
Sodium Hydrixide $ 495,266
Sulphuric Acid $ 34,445
Direct Wages and Benefits Cost (Operators) $ 3,080,000
Supervision Cost $ 770,000 Assume Maintenance cost is 25
Direct Salary Overhead $ 1,540,000 Assume Direct Salarary overhe
Utilities
Steam $ 131,410
Fuel $ 576,437
Electricity $ 10,404,670
Raw Water $ 1,315
Maintainenance and Repairs $ 1,789,097 Assume Maintenance cost is 4%

Operating Supplies $ 268,365 (15% of Maintenance and Repa
Laboratory Charges $ 462,000 (15% of Operating Labout)
Total, ADME $ 96,505,351

Indirect Expenses
General Overhead $ 2,664,413 Assume General plant overhea
Property Taxes and Insurance $ 596,366 Assume Property tax and insur
Rent of Land (and/or buildings) $ 596,366 Assume Renting of land cost is
Environmental Charges $ 834,912 Assume Environmental Charge
Total, ADME $ 4,692,057

Total Manufacturing Expenses, AME $ 101,197,408
General Expenses
Administrative Costs $ 666,103 (25% of Overhead)
Distribution and Selling $ 469,206 (10% of Total Expenses)
Research and Development $ 234,603 (5% of Toal Expenses)
BOOK FROM ALICIA
0% of Fixed Capital
Unit Price
$/kg
$ 0.35 http://www.icis.com/resources/news/2012/04/06/9548399/us-april-cumene-price
$ 0.35 http://www.intratec.us/chemical-markets/caustic-soda-prices
$ 0.02 icis
ssume Maintenance cost is 25% of the operating labour.

ssume Direct Salarary overhead cost is 40% of the operating labour plus supervision.
ssume Maintenance cost is 4% of the ISBL cost. Since there aren't any moving parts in process.
15% of Maintenance and Repairs)
15% of Operating Labout)
ssume General plant overhead cost is 65% of the ISBL cost.

ssume Property tax and insurance cost is 1% of the ISBL cost.
ssume Renting of land cost is 1% of the ISBL cost.
ssume Environmental Charges cost is 1% of the ISBL cost.
25% of Overhead)
10% of Total Expenses)
5% of Toal Expenses)
399/us-april-cumene-prices-assessed-at-rollover-on-feedstocks/
in process.
Profit and Loss Statement
Phenol Production Capacity 74,231,307 kg/yr

Acetone Prodection Capacity 74,510,299 kg/yr
AMS Production Capacity 21,434,656 kg/yr
Na2SO4 Production Capacity 2,534,242
Fixed Capital $ 97,803,992
Working Capital $ 12,523,682
Annual Fixed Costs $ 13,971,431
Annual Variable Costs $ 88,595,889 Based on 100% capacity
Salvage Value $ 34,102,144
Selling Rate of Phenol $ 1.26 /kg
Selling Rate of Acetone $ 1.23 /kg
Selling Rate of AMS $ 0.53 /kg
Sales Rate Na2SO4 $ 0.11
Annual Sales 50% of plant capacity for the first
100% of plant capacity thereafter
Tax Rate 25% https://www2.deloitte.com/co
Discount Rate 10%
Years 10
Years 1 2
Fixed- Capital Investment ($48,901,996) ($48,901,996)
Working Capital ($12,523,682)
Forecasting Sales of Phenol (% of capacity)
Forecasting Sales of Acetone (% of capacity)
Forecasting Sales of AMS (% of capacity)
Forecasting Sales of Na2SO4 (% of capacity)
Forecasting Sales of Phenol (kg)
Forecasting Sales of Acetone (kg)
Forecasting Sales of AMS (kg)
Forecasting Sales of Na2SO4 (kg)
Forecast Selling Price of Phenol per kg
Forecast Selling Price of Acetone per kg

Forecast Selling Price of AMS per kg
Forecasting Selling Price of Na2SO4 per kg
Sales Income of Phenol
Sales Income of Acetone
Sales Income of AMS
Sales Income of Na2SO4
Total Income
Fixed Costs
Variable Costs
Depreciation
Income (For Tax Purposes) ($48,901,996) ($61,425,678)
Taxes
Income (After Tax) ($48,901,996) ($61,425,678)
Net Cash Flow ($48,901,996) ($61,425,678)
Cummulative Cash Flow ($48,901,996) ($110,327,674)
Discounted Cash Flow ($44,456,360) ($50,765,023)
Cummulative Discounted Cash Flow ($44,456,360) ($95,221,383)
NPV @10% $169,175,252
IRR 30%
Payback Period 4.3
ROI 53%
Analysis Graphs
Years -2 -1
Cummulative Discounted Cash Flow 0 ($44,456,360)
ROI 0 -140%
AMS 600 tonne
1 tonne
1000 kg
1 kg
on 100% capacity
ICIS
ICIS
http://www.icis.com/resources/news/2000/05/22/115657/alpha-methylstyrene/
http://www.icis.com/resources/news/2007/09/10/9060326/chemical-profile-sodium-sulfate/
capacity for the first 3 years
capacity thereafter
www2.deloitte.com/content/dam/Deloitte/global/Documents/Tax/dttl-tax-corporate-tax-rates.pdf
3 4 5 6 7
50% 50% 100% 100% 100%
50% 50% 100% 100% 100%
50% 50% 100% 100% 100%
50% 50% 100% 100% 100%
37,115,653 37,115,653 74,231,307 74,231,307 74,231,307
37,255,149 37,255,149 74,510,299 74,510,299 74,510,299
10,717,328 10,717,328 21,434,656 21,434,656 21,434,656
1,267,121 1,267,121 2,534,242 2,534,242 2,534,242
$ 1.26 $ 1.26 $ 1.26 $ 1.26 $ 1.26
$ 1.23 $ 1.23 $ 1.23 $ 1.23 $ 1.23

$ 0.53 $ 0.53 $ 0.53 $ 0.53 $ 0.53
$ 0.11 $ 0.11 $ 0.11 $ 0.11 $ 0.11
$46,757,715 $46,757,715 $93,515,430 $93,515,430 $93,515,430
$45,833,448 $45,833,448 $91,666,895 $91,666,895 $91,666,895
$5,713,534 $5,713,534 $11,427,069 $11,427,069 $11,427,069
$137,182 $137,182 $274,364 $274,364 $274,364
$98,441,879 $98,441,879 $196,883,758 $196,883,758 $196,883,758
($13,971,431) ($13,971,431) ($13,971,431) ($13,971,431) ($13,971,431)
($88,595,889) ($88,595,889) ($88,595,889) ($88,595,889) ($88,595,889)
$6,370,185 $6,370,185 $6,370,185 $6,370,185 $6,370,185
($10,495,626) ($10,495,626) $87,946,253 $87,946,253 $87,946,253
($2,623,906) ($2,623,906) $21,986,563 $21,986,563 $21,986,563
($7,871,719) ($7,871,719) $65,959,690 $65,959,690 $65,959,690
($1,501,534) ($1,501,534) $72,329,875 $72,329,875 $72,329,875
($111,829,209) ($113,330,743) ($41,000,869) $31,329,006 $103,658,881
($1,128,125) ($1,025,568) $44,911,162 $40,828,329 $37,116,662
($96,349,509) ($97,375,077) ($52,463,915) ($11,635,587) $25,481,076
0 1 2 3 4
($95,221,383) ($96,349,509) ($97,375,077) ($52,463,915) ($11,635,587)
-186% -187% -188% -148% -111%
= $ 325,000
= $ 541.67
= $ 541.67
= $ 0.53
dium-sulfate/
8 9 10 11 12
$ 12,523,682
100% 100% 100% 100% 100%
100% 100% 100% 100% 100%
100% 100% 100% 100% 100%
100% 100% 100% 100% 100%
74,231,307 74,231,307 74,231,307 74,231,307 74,231,307
74,510,299 74,510,299 74,510,299 74,510,299 74,510,299
21,434,656 21,434,656 21,434,656 21,434,656 21,434,656
2,534,242 2,534,242 2,534,242 2,534,242 2,534,242
$ 1.26 $ 1.26 $ 1.26 $ 1.26 $ 1.26
$ 1.23 $ 1.23 $ 1.23 $ 1.23 $ 1.23

$ 0.53 $ 0.53 $ 0.53 $ 0.53 $ 0.53
$ 0.11 $ 0.11 $ 0.11 $ 0.11 $ 0.11
$93,515,430 $93,515,430 $93,515,430 $93,515,430 $93,515,430
$91,666,895 $91,666,895 $91,666,895 $91,666,895 $91,666,895
$11,427,069 $11,427,069 $11,427,069 $11,427,069 $11,427,069
$274,364 $274,364 $274,364 $274,364 $274,364
$196,883,758 $196,883,758 $196,883,758 $196,883,758 $196,883,758
($13,971,431) ($13,971,431) ($13,971,431) ($13,971,431) ($13,971,431)
($88,595,889) ($88,595,889) ($88,595,889) ($88,595,889) ($88,595,889)
$6,370,185 $6,370,185 $6,370,185 $6,370,185 $6,370,185
$87,946,253 $87,946,253 $87,946,253 $87,946,253 $100,469,935
$21,986,563 $21,986,563 $21,986,563 $21,986,563 $25,117,484
$65,959,690 $65,959,690 $65,959,690 $65,959,690 $75,352,451
$72,329,875 $72,329,875 $72,329,875 $72,329,875 $81,722,636
$175,988,756 $248,318,631 $320,648,505 $392,978,380 $474,701,016
$33,742,420 $30,674,928 $27,886,298 $25,351,180 $26,039,350
$59,223,496 $89,898,424 $117,784,722 $143,135,902 $169,175,252
5 6 7 8 9
$25,481,076 $59,223,496 $89,898,424 $117,784,722 $143,135,902
-77% -46% -19% 7% 30%
10
$169,175,252
53%
Cash Flow
200000000
175000000
150000000
125000000
$MM
100000000
75000000
50000000
25000000
0
-3 -2 -1 0 1 2 3 4 5 6 7 8 9 10 11
-25000000
-50000000
-75000000
-100000000
-125000000
Years
Rate of Investment
80%
60%
40%
20%
Percentage %
0%
-3 -2 -1 0 1 2 3 4 5 6 7 8 9 10 11
-20%
-40%
-60%
-80%
-100%
-120%
-140%
Years
-160%
-180%
-200%
-220%

Balance (New 3)

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Balance (New 3)

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Material Molecular Formula Molecular Weight (g/mol)

Alpha-methyl Styrene C9H10 118.179

Colourless Odorless 1.8302

White Powder (soluble in water) Odorless 2.671

340 337 N/A

N/A 1429 N/A

Mole of Cumene fed into reactor (Stream 1c)

Oxygen Required for reaction

Percentage Excess of Air

Total Amount of Air fed (Stream 2)

Fractional Conversion of cumene in both reactors

Ratio of conversion in 1st reactor

Oxygen fed into 1st reactor (Stream 3)

Nitrogen fed into 1st reactor (Stream 3)

Ratio of conversion in 2nd reactor

Nitrogen fed into 1st reactor (Stream 4)

Cumene consumed in 1st reactor

Stoichiometric ratio of Cumene to Oxygen

Oxygen balance around 1st reactor

Stoichiometric ratio of Cumene to CHP

Cumene balance around 1st reactor

Nitrogen balance around 1st reactor

Mole Fraction in Stream 5

Vapour pressure of Cumene at 80C

Partial pressure of Oxygen and Nitrogen in 1st reactor

Total molar flow rate in Stream 6

Mole Fraction in Stream 6

Vapour pressure of Cumene at 50C

Partial pressure of Oxygen and Nitrogen in 1st reactor

Total molar flow rate in Stream 8a &8b

CHP in Stream 8a &8b

Mole Fraction in Stream 8a &8b

Mole Fraction of oxygen CHP in Stream 8 (yO2)

Mole Fraction of nitrogen CHP in Stream 8 (yN2)

Molar flowrate of Stream7a & 7b

Cumene Hydroperoxide in Stream7a & 7b

Mole Fraction of Cumene leaving the 2nd separator Stream 8a (xc)

Vapour pressure of Cumene at 5C

Partial pressure of Oxygen and Nitrogen in 1st reactor

Total molar flow rate in Stream 10a

Mole Fraction in Stream 10a

Mole Fraction of oxygen CHP in Stream 8b (yO2)

Mole Fraction of nitrogen CHP in Stream 8b (yN2)

Cumene Stream 9a & 9b

Weight percent lost in Stream 10a & 10b

Moles of Cumene in Stream 5

Moles of CHP in Stream 5

0.0048 Negligible Amount

t is used to lower the freezing temperature of the

0.0003 Negligible Amount

Single Pass Conversion 1st Reactors

Nitrogen in Stream 6a & 6b

Total molar flow rate in Stream 6a & 6b

CHP in Stream 6a & 6b

Liquid out of Concentator 112210.2 kg/hr

Vapour pressure of Cumene at 110C 72.53

Partial pressure of Oxygen and Nitrogen in 1st reactor 3744.02

Total molar flow rate in Stream 12 2238.31

CHP in Stream 12 1.1944

Vapour pressure of Cumene at 50C 18.61

Partial pressure of Oxygen and Nitrogen in 1st reactor 3782.04

Total molar flow rate in Stream 14a &14b 1107.90

CHP in Stream 14a &14b 0.0055