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Classification of functional groups for purposes of nomenclature

Functional group class Structure Name when used Name when used
as suffix as prefix
Principal groups
Carboxylic acids -COOH -oic acid Carboxy

O O
Acid anhydrides || || -oic anhydride
-C-O-C-

Esters -COOR -oate Alkoxycarbonyl

Acyl chloride -COCl -carbonyl halide Halocarbonyl

Amides -CONH2 -amide Carbomyl

Nitriles C N -nitrile Cyano

Aldehydes -CHO -al Formyl

O
Ketones || -one Oxo
-C-

Alcohols -OH -ol Hydroxyl

Amines -NH2 -amine Amino

Alkenes C=C -ene Alkenyl

Alkynes C C -yne Alkynyl

Alkanes -ane Alkyl


C-C
Subordinate groups

Ether Alkoxy
-OR
Halides Halo
-F , -Cl , -Br , -I
Nitro Nitro
-NO2
Principal functional groups are listed in order of decreasing priority, but the subordinate groups have no
established priority order. Principal functional groups may be cited either as prefixes or as suffixes;
subordinate functional groups may be cited only as prefixes.

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