benzene) © _ In BH, bridge bond is broken by a base. 1 © Borax. NazB407.10H,0 or Na2[B,0;(OH),].8H,0 Na,B,0;—*->NaBO, +B,0, [Borzx bead test] glassy mass HA 7} | BH, Lewis acid sp’ Hy. BUH, B B H Se Nu] BH, not acid sp’ Hyb. H © 3-Centre 2e~ Bond in ByHy © Boron: Borns (Tincal) (Naz6,0,-10H,0), colemanite (Cez80 45H,0) ‘N © Aluminium: Co: ndum (Al,Qs), Diaspare (AlO3.H0), Ba exyolite (Na AlFy) xite (Alz05,2H,0), © Alreacs with Ny 8 Oy directly. @ Siruenure oftNag{8,0,(0H),1 84,0 on oS wee poem on 4r 3 NaOH +P, +H,O——>PH, +NaH,PO, Phosphene NaOQH—22->HCOONa NaOH—“°2_5 NaNO, +NaNO, bh Reaction with Halogens X2+2NaOH(cold) —>NaX +NaXO+H,0 s0d.hyponate 3X2 +6NaOH(hot)—>5NaX + NaXO, +3H,0 (6c halal) PF Solubility in liquid Ny ° in liquid NH to pre blue coloured solution, which to an appreciable degr ° arts changing to that ypper after which ni NH, ceases, ° om is converted into ed metall in i.e., M* (NH) and the electron set free combines with NHy molecule to produce ammonia solveted electron, Nat («++ y)NHj —>INa(NHs 21" #[e(NH3)y I~ @ Iris the ammoniated electron which is responsible for blue colour, paramagnetic nature and reducing power of alkali me iductance the Is in ammonia is due to presence of ed cation and © Concentrated Amonia solution is having bronze color and diamagnetic behaviour7) (© =~ When burnt in air (O,), lithium forms lithium oxide (Li,0), sodium form sodium peroxide (Na,O,) and other alkali metals form super oxide (MO, ie.KO,, RbO, or CsO,). i Li,0. Na—»Na,O and Na,O, K, Cs, Rb —+K,0, K,O, & KO, Volume Strength of Hy 09 © —‘20V'H,O, means at NTP | liter of HO, will give 20 litre 0, Normality Molarity Density d= Mx34 12 Percent strength = 12 xv 56 Example: Find out normality of ‘10V’ Hp, 0 Solution: N: Ordinary Hy is an equilibrium mixture of ortho and para hydrogen, In ortho hydrogen, spin of protons are in same direction. While in para hydrogen, spin of protons are in opposite direction. Para ‘Ortho In ordinary hydrogen 75% is ortho and 25% is para, Means maximum properties of para are lower than ortho. kL Deuterium (,H? ) is known as heavy hydrogen.