10.

PRACTICAL ORTANIC CHEMISTRY

10.1 (D)

10.2 (B)

10.3 (A)

10.4 (C)

10.5 (B)

10.6 (C)

10.7 (A)

10.8 (C)

10.9 (A)

10.10 (B)

10.11 (B)

10.12 (C)
 (I) gives immediately turbidity by Lucas reagent and (II) does not give turbidity
appriciably.

10.13 (B)

10.14 (D) There is no COOH group or NH2 group.

Regents 1 and 8 will fall to give test.

10.15 (C)

10.16 (C)

OH

10.17 (C) The compound gives positive test with Na metal, 2, 4-DNP and it
O

gives single product with O3

10.18 (B) The compound C30H60 O has one degree of unsaturation since it gives
negative test with Br2/H2O, 2, 4 [MP and Na metal it must be an epoxide.

10.19 (B) - NO2 group gives +ve test with Zn/NH4CI followed by AgNO3 + NH4OH
solution.

10.20 (A, B, C)
2D, 3L, 4D, 5D, 6-Pentahydroxy hexanal = D-Glucose
10.21 (C, D)

10.22 (B, C)

'P' has optical and geometrical isomers.

10.23 (A, C) By the condition of the question.

I & IV both compounds do not give iodoform test and I & II both give similar
test.

10.24 (A, B)
10.25 (C) Statement-1 True, CH3CHO gives positive test with tollens reagent, feeling
solution, 2, 4-D.N.P. as well as lodoform test.
Statement- 2 False, all aldehydes do not give iodoform test.

10.26 D Picric acid gives CO2 gas with NaHCO3 due to stronger acidic nature of
picric acid.

10.27 (B)

Other Functional isomers of X are None of these will give

14
+ve test with NaH CO3

Higher homolog of X: 4 isomeric form

10.28 (B)
10.29 (D)
10.30 (B)
10.31 (B)

1032 (D)

10.33 (B)

10.34 (A p) ; (B r, s) ; (C q, t) ; (D r)

C8H14; DU = 2
Ozonolysis product Y[C8H14O2] has 8 C atoms indicates (X) is cyclic compound with
one double bond. Thus A is symmetrical cyclohexene.

[X] [Y] [Z]

10.35 (A X, Y, Z, W); (B Z) ; (C X, Z) ; (D Y)
a protic acid gives positive test with Na metal.
a carboxylic functional group gives positive test with NaHCO3.
a carbonyl group gives yellow ppt. with 2, 4-DNP en alcohol gives positive test with
Lucas Reagent.

X Y Z W
10.36
4 1 5 2

X = 4: a- Naphthylamine is soluble in aqueous HCl solution.

Y = 1: Benzoic acid is soluble in aqueous NaHCO3 solution.
Z = 5: Naphthalene insoluble in aqueous HCl, NaOH of NaHCO3 solution.
W = 2: Salicylaldehyde has lower b.p. than p-hydroxy benzaldehyde

10.37 3

10.38 Zero.

10.39 3

10.40 Zero, (None)