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  • Unifac N-Hexano y N-Hexanamina

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    Jose Rodrigo Quisbert Plata
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    Calculo de la fraccion molar de una mezcla de gases como n-hexano y n hexalamina, utilizando el metodo de UNIFAC con la descripcion paso por paso de un punto cuando X1=0,9 y X2=0,1 a una T=315K y una P=760mmHg

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    unifac n-hexano y n-hexanamina

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    Calculo de la fraccion molar de una mezcla de gases como n-hexano y n hexalamina, utilizando el metodo de UNIFAC con la descripcion paso por paso de un punto cuando X1=0,9 y X2=0,1 a una T=315K y una P=760mmHg

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    © All Rights Reserved
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    29 views5 pages

    Unifac N-Hexano y N-Hexanamina

    Uploaded by

    Jose Rodrigo Quisbert Plata
    Calculo de la fraccion molar de una mezcla de gases como n-hexano y n hexalamina, utilizando el metodo de UNIFAC con la descripcion paso por paso de un punto cuando X1=0,9 y X2=0,1 a una T=315K y una P=760mmHg

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    © All Rights Reserved
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    of 5

    UNIFAC P 760 T 345.

    15

    Compuesto1. n hexano i1 CH3 ((CH2)) 4 CH3 x1 0.9

    Compuesto2. n hexilamina i2 CH3 ((CH2)) 5 NH2 x2 0.1

    k1 CH3 ki Comp.1 Comp.2


    k2 CH2 CH3 2 1
    k3 CH2NH2 CH2 4 4
    CH2NH2 0 1

    R1 0.9011 Q1 0.848 11 2 21 4 31 0
    R2 0.6744 Q2 0.540
    R3 1.3692 Q3 1.236 12 1 22 4 32 1

    r1 11 R1 + 21 R2 + 31 R3 = 4.4998
    r2 12 R1 + 22 R2 + 32 R3 = 4.9679

    q1 11 Q1 + 21 Q2 + 31 Q3 = 3.856
    q2 12 Q1 + 22 Q2 + 32 Q3 = 4.244
    q1 x1 r1 x1
    1 = 0.891 1 = 0.8907
    q1 x1 + q2 x2 r1 x1 + r2 x2

    q2 x2 r2 x2
    2 = 0.109 2 = 0.1093
    q1 x1 + q2 x2 r1 x1 + r2 x2

    l1 5 ((r1 q1)) ((r1 1)) = 0.2808 l2 5 ((r2 q2)) ((r2 1)) = 0.3484
    1 1 1
    ln1c ln + 5 q1 ln + l1 ((x1 l1 + x2 l2)) = 5.2271 10 5
    x1 1 x1
    2 2 2
    ln2c ln + 5 q2 ln + l2 ((x1 l1 + x2 l2)) = 0.004
    x2 2 x2

    Parte residual
    anm CH3 CH2 CH2NH2
    CH3 0 0 391.5 a11 0 a21 0 a31 30.48
    CH2 0 0 391.5 a12 0 a22 0 a32 30.48
    CH2NH2 30.48 30.48 0 a13 391.5 a23 391.5 a33 0
    a11 a21 a31

    T T T
    11 e =1 21 e =1 31 e = 1.0923
    a12 a22 a32

    T T T
    12 e =1 22 e =1 32 e = 1.0923
    a13 a23 a33

    T T T
    13 e = 0.3217 23 e = 0.3217 33 e =1

    11 x1 + 12 x2
    X1 = 0.3167
    11 x1 + 12 x2 + 21 x1 + 22 x2 + 31 x1 + 32 x2

    21 x1 + 22 x2
    X2 = 0.6667
    11 x1 + 12 x2 + 21 x1 + 22 x2 + 31 x1 + 32 x2

    31 x1 + 32 x2
    X3 = 0.0167
    11 x1 + 12 x2 + 21 x1 + 22 x2 + 31 x1 + 32 x2

    Q1 X1
    1 = 0.4137
    Q1 X1 + Q2 X2 + Q3 X3

    Q2 X2
    2 = 0.5546
    Q1 X1 + Q2 X2 + Q3 X3
    Q3 X3
    3 = 0.0317
    Q1 X1 + Q2 X2 + Q3 X3

    1 11 2 12 3 13
    ln1 Q1 1 ln ((1 11 + 2 21 + 3 31)) + + = 0.0016
    1 11 + 2 21 + 3 31 1 12 + 2 22 + 3 32 1 13 + 2 23 + 3 33

    1 21 2 22 3 23
    ln2 Q2 1 ln ((1 12 + 2 22 + 3 32)) + + = 0.001
    1 11 + 2 21 + 3 31 1 12 + 2 22 + 3 32 1 13 + 2 23 + 3 33

    1 31 2 32 3 33
    ln3 Q3 1 ln ((1 13 + 2 23 + 3 33)) + + = 1.1402
    1 11 + 2 21 + 3 31 1 12 + 2 22 + 3 32 1 13 + 2 23 + 3 33

    Ahora por com ponentes puros


    x1' 1 x2' 0
    11 x1' + 12 x2'
    X1' = 0.3333
    11 x1' + 12 x2' + 21 x1' + 22 x2' + 31 x1' + 32 x2'

    21 x1' + 22 x2'
    X2' = 0.6667
    11 x1' + 12 x2' + 21 x1' + 22 x2' + 31 x1' + 32 x2'

    31 x1' + 32 x2'
    X3' = 0
    11 x1' + 12 x2' + 21 x1' + 22 x2' + 31 x1' + 32 x2'

    Q1 X1'
    1' = 0.4398
    Q1 X1' + Q2 X2' + Q3 X3'

    Q2 X2'
    2' = 0.5602
    Q1 X1' + Q2 X2' + Q3 X3'

    Q3 X3'
    3' = 0
    Q1 X1' + Q2 X2' + Q3 X3'
    1' 11 2' 12 3' 13
    ln11' Q1 1 ln ((1' 11 + 2' 21 + 3' 31)) + + = 0
    1' 11 + 2' 21 + 3' 31 1' 12 + 2' 22 + 3' 32 1' 13 + 2' 23 + 3' 33

    1' 21 2' 22 3' 23


    ln21' Q2 1 ln ((1' 12 + 2' 22 + 3' 32)) + + = 0
    1' 11 + 2' 21 + 3' 31 1' 12 + 2' 22 + 3' 32 1' 13 + 2' 23 + 3' 33

    1' 31 2' 32 3' 33


    ln31' Q3 1 ln ((1' 13 + 2' 23 + 3' 33)) + + = 1.2879
    1' 11 + 2' 21 + 3' 31 1' 12 + 2' 22 + 3' 32 1' 13 + 2' 23 + 3' 33

    x1' 0 x2' 1
    11 x1' + 12 x2'
    X1' = 0.1667
    11 x1' + 12 x2' + 21 x1' + 22 x2' + 31 x1' + 32 x2'

    21 x1' + 22 x2'
    X2' = 0.6667
    11 x1' + 12 x2' + 21 x1' + 22 x2' + 31 x1' + 32 x2'

    31 x1' + 32 x2'
    X3' = 0.1667
    11 x1' + 12 x2' + 21 x1' + 22 x2' + 31 x1' + 32 x2'

    Q1 X1'
    1' = 0.1998
    Q1 X1' + Q2 X2' + Q3 X3'

    Q2 X2'
    2' = 0.509
    Q1 X1' + Q2 X2' + Q3 X3'

    Q3 X3'
    3' = 0.2912
    Q1 X1' + Q2 X2' + Q3 X3'

    1' 11 2' 12 3' 13


    ln12' Q1 1 ln ((1' 11 + 2' 21 + 3' 31)) + + = 0.0872
    1' 11 + 2' 21 + 3' 31 1' 12 + 2' 22 + 3' 32 1' 13 + 2' 23 + 3' 33
    1' 21 2' 22 3' 23
    ln22' Q2 1 ln ((1' 12 + 2' 22 + 3' 32)) + + = 0.0555
    1' 11 + 2' 21 + 3' 31 1' 12 + 2' 22 + 3' 32 1' 13 + 2' 23 + 3' 33

    1' 31 2' 32 3' 33


    ln32' Q3 1 ln ((1' 13 + 2' 23 + 3' 33)) + + = 0.421
    1' 11 + 2' 21 + 3' 31 1' 12 + 2' 22 + 3' 32 1' 13 + 2' 23 + 3' 33

    ln1R 11 ((ln1 ln11')) + 21 ((ln2 ln21')) + 31 ((ln3 ln31')) = 0.0073

    ln2R 12 ((ln1 ln12')) + 22 ((ln2 ln22')) + 32 ((ln3 ln32')) = 0.4155

    ln1 ln1c + ln1R = 0.0072 1 e ln1 = 1.0073

    ln2 ln2c + ln2R = 0.4116 2 e ln2 = 1.5092

    A1 6.9895 B1 1216.92 C1 227.451


    B1
    A1
    T 273 + C1
    Pv1 10 = 846.6381

    A2 7.34589 B2 1579.36 C2 222.214

    B2
    A2
    T 273 + C2
    Pv2 10 = 95.6225

    Pv1
    y1 1 x1 = 1.0099
    P

    Pv2
    y2 2 x2 = 0.019
    P

    y1 + y2 = 1.029

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