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T-404A (HP62)ENG
DuPont Suva
refrigerants
Thermodynamic
Properties
of
DuPont
Suva 404A (HP62)
Refrigerant
(R-404A)
New tables of the thermodynamic properties of Suva Reference point for enthalpy and entropy:
404A (HP62) refrigerant [ASHRAE designation: R-404A hf = 0.0 Btu/lb at 40F
(44/52/4)], a near azeotropic blend of HFC-125/HFC-143a/ sf = 0.0 Btu/(lb) (R) at 40F
HFC-134a, have been developed and are presented here.
These tables are based on extensive experimental measure- Equations
ments. Equations have been developed, based on the Peng-
Robinson-Stryjek-Vera (PRSV) equation of state, which The Peng-Robinson-Stryjek-Vera (PRSV) equation of state
represent the data with accuracy and consistency through- was used to calculate the tables of thermodynamic proper-
out the entire range of temperature, pressure, and density ties. It was chosen as the preferred equation of state
presented in these tables. because it provided an accurate fit of the thermodynamic
data over the entire range of temperatures and pressures
Physical Properties presented in these tables.
Chemical Formula CHF2CF3/CH3CF3/CH2FCF3 The constants for the PRSV equation of state were cal-
(44/52/4% by weight) culated in SI units. For conversion of thermodynamic
Molecular Weight 97.60 properties to Engineering (I/P) units, conversion factors
Boiling Point at are provided for each property derived from the PRSV
One Atmosphere 51.62F (46.45C) equation of state.
Critical Temperature, Tc 161.73F (72.07C) 1. Equation of State (PRSV)
621.40R (345.22 K)
Critical Pressure, Pc 541.2 psia (3731.5 kPa P = RT/(V b) a/(V2 + 2bV b2)
[abs])
where P is in kPa, T is in K, V is in m3/mole, and
Critical Density, Dc 30.23 lb/ft3 (484.5 kg/m3) R = 0.008314 kJ/(mole) (K). The constants a and b are
Critical Volume, Vc 0.0331 ft3/lb (0.00206 m3/kg) calculated as follows:
3 3 3
Units and Factors a = xi xj aij b = x i bi
i=1 j=1 i=1
t = temperature in F where
T = temperature in R = F + 459.67
pf = pressure of saturated liquid (bubble point) in psia aij = (ai aj)0.5 (1 kij) bi = 0.077796 RTci/Pci
pg = pressure of saturated vapor (dew point) in psia xi = mole fraction of component i
vf = volume of saturated liquid in ft3/lb
vg = volume of saturated vapor in ft3/lb xj = mole fraction of component j
V = volume of superheated vapor in ft3/lb ai = (0.457235 R2 Tci2/Pci) ai
df = 1/vf = density of saturated liquid in lb/ft3
dg = 1/vg = density of saturated vapor in lb/ft3 aj = (0.457235 R2 Tcj2/Pcj) aj
hf = enthalpy of saturated liquid in Btu/lb
kij = binary interaction parameter for components i and
hfg = enthalpy of vaporization in Btu/lb
hg = enthalpy of saturated vapor in Btu/lb j
H = enthalpy of superheated vapor in Btu/lb i = [1 + i (1 Tri0.5)]2
sf = entropy of saturated liquid in Btu/(lb) (R)
sg = entropy of saturated vapor in Btu/(lb) (R) i = 0i + 1i [(1 + Tri0.5) (0.7 Tri)]
S = entropy of superheated vapor in Btu/(lb) (R) (Note: i = 0i for Tr > 0.7)
Cp = heat capacity at constant pressure in Btu/(lb) (F) 0i = 0.378893 + 1.4897153i 0.17131848i2
Cv = heat capacity at constant volume in Btu/(lb) (F) + 0.019655i3
The gas constant, R = 10.732 (psia) (ft3)/(lb-mole) (R)
1i = adjustable parameter for component i
for Suva 404A (HP62), R = 0.1100 (psia) (ft3)/(lb) (R)
Conversion factor from Work Units to Heat Units: Tri = Ti/Tci for component i
J = 0.185053
Btu/lb = [(psia) (ft3)/lb] J
One atmosphere = 14.696 psia
2
3. Density of the Saturated Liquid df and Dc are in kg/m3 in SI units and lb/ft3 in I/P
units; T and Tc are in K in SI units and R in I/P
df/Dc = a0 + a1 z + a2 z2 + a3 z3 + a4 z4
units; a0, a1, a2, a3, a4, and t0 are constants:
where z = (1 T/Tc)1/3 t0
a0 = 1.0002 E+00 a3 = 1.3781 E+01
Because both density and temperature appear in the a1 = 1.9300 E01 a4 = 7.6142 E+00
reduced form in the equation, the same constants can be
used for either SI or I/P units. a2 = 9.0829 E+00 t0 = 0.0000
3
Table 1
Suva 404A (HP62) Saturation PropertiesTemperature Table
PRESSURE VOLUME DENSITY ENTHALPY ENTROPY
TEMP. psia ft3/lb lb/ft3 Btu/lb Btu/(lb)(R) TEMP.
F LIQUID VAPOR LIQUID VAPOR LIQUID VAPOR LIQUID LATENT VAPOR LIQUID VAPOR F
pf pg vf vg 1/vf 1/vg hf hfg hg sf sg
150 0.39 0.36 0.0111 94.3396 89.78 0.0106 30.6 99.0 68.4 0.0842 0.2369 150
149 0.42 0.38 0.0111 90.0901 89.73 0.0111 30.4 98.9 68.5 0.0834 0.2364 149
148 0.44 0.40 0.0112 86.2069 89.69 0.0116 30.1 98.8 68.7 0.0825 0.2358 148
147 0.46 0.42 0.0112 81.9672 89.64 0.0122 29.9 98.7 68.8 0.0817 0.2352 147
146 0.48 0.44 0.0112 78.1250 89.58 0.0128 29.6 98.6 69.0 0.0809 0.2347 146
145 0.51 0.46 0.0112 74.6269 89.53 0.0134 29.3 98.4 69.1 0.0800 0.2341 145
144 0.53 0.49 0.0112 71.4286 89.48 0.0140 29.1 98.3 69.3 0.0792 0.2336 144
143 0.56 0.51 0.0112 68.0272 89.42 0.0147 28.8 98.2 69.4 0.0784 0.2331 143
142 0.59 0.54 0.0112 64.9351 89.37 0.0154 28.6 98.1 69.6 0.0776 0.2325 142
141 0.61 0.56 0.0112 62.1118 89.31 0.0161 28.3 98.0 69.7 0.0768 0.2320 141
140 0.64 0.59 0.0112 59.5238 89.25 0.0168 28.0 97.9 69.9 0.0759 0.2315 140
139 0.67 0.62 0.0112 56.8182 89.19 0.0176 27.8 97.8 70.0 0.0751 0.2310 139
138 0.71 0.65 0.0112 54.3478 89.13 0.0184 27.5 97.7 70.2 0.0743 0.2305 138
137 0.74 0.68 0.0112 52.0833 89.07 0.0192 27.2 97.5 70.3 0.0735 0.2300 137
136 0.77 0.71 0.0112 49.7512 89.01 0.0201 27.0 97.4 70.4 0.0727 0.2295 136
135 0.81 0.75 0.0112 47.6190 88.95 0.0210 26.7 97.3 70.6 0.0719 0.2290 135
134 0.85 0.78 0.0113 45.6621 88.88 0.0219 26.5 97.2 70.7 0.0711 0.2286 134
133 0.89 0.82 0.0113 43.6681 88.82 0.0229 26.2 97.1 70.9 0.0703 0.2281 133
132 0.93 0.86 0.0113 41.8410 88.75 0.0239 25.9 97.0 71.0 0.0694 0.2276 132
131 0.97 0.90 0.0113 40.1606 88.68 0.0249 25.7 96.9 71.2 0.0686 0.2272 131
130 1.01 0.94 0.0113 38.4615 88.62 0.0260 25.4 96.7 71.3 0.0678 0.2267 130
129 1.06 0.98 0.0113 36.9004 88.55 0.0271 25.1 96.6 71.5 0.0670 0.2263 129
128 1.10 1.02 0.0113 35.4610 88.48 0.0282 24.9 96.5 71.6 0.0662 0.2258 128
127 1.15 1.07 0.0113 34.0136 88.40 0.0294 24.6 96.4 71.8 0.0654 0.2254 127
126 1.20 1.12 0.0113 32.6797 88.33 0.0306 24.3 96.3 71.9 0.0646 0.2250 126
125 1.25 1.17 0.0113 31.3480 88.26 0.0319 24.1 96.2 72.1 0.0638 0.2245 125
124 1.31 1.22 0.0113 30.1205 88.19 0.0332 23.8 96.1 72.2 0.0630 0.2241 124
123 1.36 1.27 0.0113 28.9855 88.11 0.0345 23.5 95.9 72.4 0.0623 0.2237 123
122 1.42 1.33 0.0114 27.8552 88.04 0.0359 23.3 95.8 72.6 0.0615 0.2233 122
121 1.48 1.38 0.0114 26.8097 87.96 0.0373 23.0 95.7 72.7 0.0607 0.2229 121
120 1.54 1.44 0.0114 25.7732 87.88 0.0388 22.7 95.6 72.9 0.0599 0.2225 120
119 1.61 1.50 0.0114 24.8139 87.81 0.0403 22.5 95.5 73.0 0.0591 0.2221 119
118 1.67 1.56 0.0114 23.8663 87.73 0.0419 22.2 95.4 73.2 0.0583 0.2217 118
117 1.74 1.63 0.0114 22.9885 87.65 0.0435 21.9 95.2 73.3 0.0575 0.2214 117
116 1.81 1.70 0.0114 22.1239 87.57 0.0452 21.7 95.1 73.5 0.0567 0.2210 116
115 1.89 1.77 0.0114 21.3220 87.49 0.0469 21.4 95.0 73.6 0.0559 0.2206 115
114 1.96 1.84 0.0114 20.5339 87.40 0.0487 21.1 94.9 73.8 0.0552 0.2202 114
113 2.04 1.91 0.0115 19.7628 87.32 0.0506 20.8 94.8 73.9 0.0544 0.2199 113
112 2.12 1.99 0.0115 19.0476 87.24 0.0525 20.6 94.7 74.1 0.0536 0.2195 112
111 2.20 2.07 0.0115 18.3824 87.16 0.0544 20.3 94.5 74.2 0.0528 0.2192 111
110 2.29 2.15 0.0115 17.7305 87.07 0.0564 20.0 94.4 74.4 0.0520 0.2188 110
109 2.38 2.24 0.0115 17.0940 86.99 0.0585 19.8 94.3 74.5 0.0513 0.2185 109
108 2.47 2.32 0.0115 16.5017 86.90 0.0606 19.5 94.2 74.7 0.0505 0.2181 108
107 2.56 2.41 0.0115 15.9236 86.81 0.0628 19.2 94.1 74.8 0.0497 0.2178 107
106 2.66 2.51 0.0115 15.3610 86.73 0.0651 18.9 93.9 75.0 0.0489 0.2175 106
105 2.76 2.60 0.0115 14.8368 86.64 0.0674 18.7 93.8 75.2 0.0482 0.2172 105
104 2.86 2.70 0.0116 14.3266 86.55 0.0698 18.4 93.7 75.3 0.0474 0.2168 104
103 2.97 2.80 0.0116 13.8504 86.46 0.0722 18.1 93.6 75.5 0.0466 0.2165 103
102 3.08 2.91 0.0116 13.3869 86.37 0.0747 17.8 93.5 75.6 0.0459 0.2162 102
101 3.19 3.02 0.0116 12.9366 86.29 0.0773 17.6 93.3 75.8 0.0451 0.2159 101
100 3.31 3.13 0.0116 12.5000 86.19 0.0800 17.3 93.2 75.9 0.0443 0.2156 100
99 3.43 3.25 0.0116 12.0919 86.10 0.0827 17.0 93.1 76.1 0.0436 0.2153 99
98 3.55 3.36 0.0116 11.6959 86.01 0.0855 16.7 93.0 76.2 0.0428 0.2150 98
97 3.68 3.49 0.0116 11.3122 85.92 0.0884 16.5 92.9 76.4 0.0420 0.2147 97
96 3.81 3.61 0.0117 10.9409 85.83 0.0914 16.2 92.7 76.5 0.0413 0.2144 96
95 3.94 3.74 0.0117 10.5820 85.74 0.0945 15.9 92.6 76.7 0.0405 0.2142 95
94 4.08 3.87 0.0117 10.2459 85.64 0.0976 15.6 92.5 76.9 0.0398 0.2139 94
93 4.22 4.01 0.0117 9.9206 85.55 0.1008 15.4 92.4 77.0 0.0390 0.2136 93
92 4.37 4.15 0.0117 9.6061 85.45 0.1041 15.1 92.2 77.2 0.0382 0.2133 92
91 4.52 4.30 0.0117 9.3023 85.36 0.1075 14.8 92.1 77.3 0.0375 0.2131 91
4
Table 1 (continued)
Suva 404A (HP62) Saturation PropertiesTemperature Table
5
Table 1 (continued)
Suva 404A (HP62) Saturation PropertiesTemperature Table
PRESSURE VOLUME DENSITY ENTHALPY ENTROPY
TEMP. psia ft3/lb lb/ft3 Btu/lb Btu/(lb)(R) TEMP.
F LIQUID VAPOR LIQUID VAPOR LIQUID VAPOR LIQUID LATENT VAPOR LIQUID VAPOR F
pf pg vf vg 1/vf 1/vg hf hfg hg sf sg
30 25.27 24.56 0.0127 1.8222 79.02 0.5488 3.2 83.6 86.8 0.0076 0.2025 30
29 25.87 25.15 0.0127 1.7816 78.91 0.5613 3.5 83.4 87.0 0.0083 0.2024 29
28 26.48 25.75 0.0127 1.7422 78.80 0.5740 3.8 83.3 87.1 0.0090 0.2023 28
27 27.11 26.36 0.0127 1.7036 78.69 0.5870 4.2 83.1 87.3 0.0097 0.2022 27
26 27.74 26.99 0.0127 1.6664 78.58 0.6001 4.5 83.0 87.4 0.0104 0.2021 26
25 28.39 27.62 0.0127 1.6300 78.47 0.6135 4.8 82.8 87.6 0.0111 0.2020 25
24 29.04 28.27 0.0128 1.5946 78.36 0.6271 5.1 82.7 87.7 0.0118 0.2019 24
23 29.71 28.93 0.0128 1.5601 78.25 0.6410 5.9 82.0 87.9 0.0136 0.2018 23
22 30.39 29.60 0.0128 1.5267 78.14 0.6550 6.2 81.9 88.0 0.0143 0.2017 22
21 31.08 30.28 0.0128 1.4943 78.03 0.6692 6.5 81.7 88.2 0.0150 0.2016 21
20 31.78 30.97 0.0128 1.4626 77.92 0.6837 6.8 81.6 88.4 0.0157 0.2015 20
19 32.50 31.67 0.0129 1.4316 77.81 0.6985 7.1 81.4 88.5 0.0164 0.2015 19
18 33.22 32.39 0.0129 1.4015 77.70 0.7135 7.4 81.3 88.7 0.0170 0.2014 18
17 33.96 33.11 0.0129 1.3723 77.59 0.7287 7.7 81.1 88.8 0.0177 0.2013 17
16 34.71 33.85 0.0129 1.3437 77.48 0.7442 8.0 81.0 89.0 0.0184 0.2012 16
15 35.48 34.61 0.0129 1.3158 77.37 0.7600 8.3 80.8 89.1 0.0191 0.2011 15
14 36.25 35.37 0.0129 1.2885 77.26 0.7761 8.6 80.7 89.3 0.0198 0.2011 14
13 37.04 36.15 0.0130 1.2620 77.15 0.7924 8.9 80.5 89.4 0.0205 0.2010 13
12 37.85 36.95 0.0130 1.2362 77.03 0.8089 9.2 80.3 89.6 0.0211 0.2009 12
11 38.66 37.75 0.0130 1.2109 76.92 0.8258 9.5 80.2 89.7 0.0218 0.2008 11
10 39.49 38.57 0.0130 1.1864 76.81 0.8429 9.8 80.0 89.9 0.0225 0.2008 10
9 40.34 39.40 0.0130 1.1624 76.70 0.8603 10.1 79.9 90.0 0.0232 0.2007 9
8 41.20 40.25 0.0131 1.1390 76.59 0.8780 10.4 79.7 90.2 0.0239 0.2006 8
7 42.07 41.11 0.0131 1.1161 76.47 0.8960 10.8 79.5 90.3 0.0246 0.2006 7
6 42.95 41.98 0.0131 1.0937 76.36 0.9143 11.1 79.4 90.5 0.0252 0.2005 6
5 43.85 42.87 0.0131 1.0719 76.25 0.9329 11.4 79.2 90.6 0.0259 0.2004 5
4 44.77 43.78 0.0131 1.0506 76.14 0.9518 11.7 79.1 90.7 0.0266 0.2004 4
3 45.70 44.69 0.0132 1.0299 76.02 0.9710 12.0 78.9 90.9 0.0273 0.2003 3
2 46.64 45.63 0.0132 1.0096 75.91 0.9905 12.3 78.7 91.0 0.0280 0.2002 2
1 47.60 46.57 0.0132 0.9898 75.80 1.0103 12.6 78.6 91.2 0.0286 0.2002 1
0 48.57 47.54 0.0132 0.9705 75.68 1.0304 12.9 78.4 91.3 0.0293 0.2001 0
1 49.56 48.51 0.0132 0.9516 75.57 1.0509 13.3 78.2 91.5 0.0300 0.2000 1
2 50.57 49.51 0.0133 0.9332 75.46 1.0716 13.6 78.0 91.6 0.0307 0.2000 2
3 51.59 50.51 0.0133 0.9152 75.34 1.0927 13.9 77.9 91.8 0.0314 0.1999 3
4 52.62 51.54 0.0133 0.8975 75.23 1.1142 14.2 77.7 91.9 0.0320 0.1999 4
5 53.67 52.58 0.0133 0.8803 75.11 1.1360 14.5 77.5 92.1 0.0327 0.1998 5
6 54.74 53.63 0.0133 0.8635 75.00 1.1581 14.9 77.4 92.2 0.0334 0.1998 6
7 55.82 54.70 0.0134 0.8470 74.88 1.1806 15.2 77.2 92.3 0.0341 0.1997 7
8 56.92 55.79 0.0134 0.8310 74.76 1.2034 15.5 77.0 92.5 0.0348 0.1996 8
9 58.04 56.90 0.0134 0.8153 74.65 1.2266 15.8 76.8 92.6 0.0354 0.1996 9
10 59.17 58.02 0.0134 0.7999 74.53 1.2501 16.1 76.6 92.8 0.0361 0.1995 10
11 60.32 59.16 0.0134 0.7849 74.42 1.2740 16.5 76.5 92.9 0.0368 0.1995 11
12 61.49 60.31 0.0135 0.7702 74.30 1.2983 16.8 76.3 93.1 0.0375 0.1994 12
13 62.67 61.48 0.0135 0.7559 74.18 1.3230 17.1 76.1 93.2 0.0382 0.1994 13
14 63.87 62.67 0.0135 0.7418 74.06 1.3480 17.4 75.9 93.3 0.0388 0.1993 14
15 65.09 63.88 0.0135 0.7281 73.95 1.3734 17.8 75.7 93.5 0.0395 0.1993 15
16 66.33 65.10 0.0135 0.7146 73.83 1.3993 18.1 75.6 93.6 0.0402 0.1992 16
17 67.58 66.34 0.0136 0.7015 73.71 1.4255 18.4 75.4 93.8 0.0409 0.1992 17
18 68.85 67.60 0.0136 0.6887 73.59 1.4521 18.7 75.2 93.9 0.0416 0.1991 18
19 70.14 68.88 0.0136 0.6761 73.47 1.4791 19.1 75.0 94.0 0.0422 0.1991 19
20 71.45 70.18 0.0136 0.6637 73.35 1.5066 19.4 74.8 94.2 0.0429 0.1990 20
21 72.78 71.49 0.0137 0.6517 73.23 1.5344 19.7 74.6 94.3 0.0436 0.1990 21
22 74.12 72.82 0.0137 0.6399 73.11 1.5627 20.1 74.4 94.5 0.0443 0.1990 22
23 75.49 74.18 0.0137 0.6284 72.99 1.5914 20.4 74.2 94.6 0.0450 0.1989 23
24 76.87 75.55 0.0137 0.6171 72.87 1.6206 20.7 74.0 94.7 0.0456 0.1989 24
25 78.27 76.94 0.0137 0.6060 72.75 1.6502 21.0 73.8 94.9 0.0463 0.1988 25
26 79.69 78.35 0.0138 0.5952 72.63 1.6802 21.4 73.6 95.0 0.0470 0.1988 26
27 81.13 79.78 0.0138 0.5845 72.50 1.7108 21.7 73.4 95.1 0.0477 0.1987 27
28 82.60 81.22 0.0138 0.5742 72.38 1.7417 22.1 73.2 95.3 0.0484 0.1987 28
29 84.08 82.69 0.0138 0.5640 72.26 1.7732 22.4 73.0 95.4 0.0490 0.1987 29
6
Table 1 (continued)
Suva 404A (HP62) Saturation PropertiesTemperature Table
7
Table 1 (continued)
Suva 404A (HP62) Saturation PropertiesTemperature Table
8
Table 2
Suva 404A (HP62) Superheated VaporConstant Pressure Tables
V = Volume in ft3/lb H = Enthalpy in Btu/lb S = Entropy in Btu/(lb) (R) (Saturation Properties in parentheses)
9
Table 2 (continued)
Suva 404A (HP62) Superheated VaporConstant Pressure Tables
V = Volume in ft3/lb H = Enthalpy in Btu/lb S = Entropy in Btu/(lb) (R) (Saturation Properties in parentheses)
10
Table 2 (continued)
Suva 404A (HP62) Superheated VaporConstant Pressure Tables
V = Volume in ft3/lb H = Enthalpy in Btu/lb S = Entropy in Btu/(lb) (R) (Saturation Properties in parentheses)
11
Table 2 (continued)
Suva 404A (HP62) Superheated VaporConstant Pressure Tables
V = Volume in ft3/lb H = Enthalpy in Btu/lb S = Entropy in Btu/(lb) (R) (Saturation Properties in parentheses)
12
Table 2 (continued)
Suva 404A (HP62) Superheated VaporConstant Pressure Tables
V = Volume in ft3/lb H = Enthalpy in Btu/lb S = Entropy in Btu/(lb) (R) (Saturation Properties in parentheses)
13
Table 2 (continued)
Suva 404A (HP62) Superheated VaporConstant Pressure Tables
V = Volume in ft3/lb H = Enthalpy in Btu/lb S = Entropy in Btu/(lb) (R) (Saturation Properties in parentheses)
14
Table 2 (continued)
Suva 404A (HP62) Superheated VaporConstant Pressure Tables
V = Volume in ft3/lb H = Enthalpy in Btu/lb S = Entropy in Btu/(lb) (R) (Saturation Properties in parentheses)
15
Table 2 (continued)
Suva 404A (HP62) Superheated VaporConstant Pressure Tables
V = Volume in ft3/lb H = Enthalpy in Btu/lb S = Entropy in Btu/(lb) (R) (Saturation Properties in parentheses)
16
Table 2 (continued)
Suva 404A (HP62) Superheated VaporConstant Pressure Tables
V = Volume in ft3/lb H = Enthalpy in Btu/lb S = Entropy in Btu/(lb) (R) (Saturation Properties in parentheses)
17
Table 2 (continued)
Suva 404A (HP62) Superheated VaporConstant Pressure Tables
V = Volume in ft3/lb H = Enthalpy in Btu/lb S = Entropy in Btu/(lb) (R) (Saturation Properties in parentheses)
18
Table 2 (continued)
Suva 404A (HP62) Superheated VaporConstant Pressure Tables
V = Volume in ft3/lb H = Enthalpy in Btu/lb S = Entropy in Btu/(lb) (R) (Saturation Properties in parentheses)
19
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