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Microelectronics Reliability 48 (2008) 6882


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A strategy for damage assessment of thermally stressed copper vias


in microelectronic printed circuit boards
K. Weinberg *, W.H. Muller
Technische Universitat Berlin, Institut fur Mechanik, Einsteinufer 5, 10587 Berlin, Germany

Received 11 January 2006; received in revised form 23 February 2007


Available online 9 May 2007

Abstract

The thermal fatigue of plated-through vias remains a subject of concern, particularly when exposed to the high operating tempera-
tures associated with automotive applications. In this paper the performance of dierent types of copper vias in dierent positions of a
printed circuit board is analyzed. To this end a two-scale nite element analysis under the loading conditions of thermal cycling is
employed. A new material model for the electrolytically deposited copper accounts for large elastic and plastic deformations and, addi-
tionally, for the growth of pores within the material.
It is common practice to extrapolate the plastic straining computed within few steps of thermal cycling by means of a ConManson-
Equation. We critical examine this strategy and point out, that a certain number of about 20 cycling steps is necessary to obtain mean-
ingful extrapolations. Furthermore, an extrapolation of the computed porosity up to critical values allows similar conclusions.
The presented strategy can serve as a predictive tool for plated through holes and vias and can reduce the need of repetitive exper-
imental failure tests.
 2007 Elsevier Ltd. All rights reserved.

1. Introduction associated with cracks and pores which eventually results


in the electro-mechanical destruction of the connector.
Plated-through holes and vias form conductive paths In this paper we will present a numerical study of such
between the dierent copper layers of circuit boards, see copper vias subjected to thermal cycling between 40 C
Fig. 1. Failure of these connectors due to thermomechani- and +150 C (automotive standard, see Fig. 2). After intro-
cal stresses is a well established cause of failure of circuit ducing a general technique of how to analyze the stress
boards. Therefore, life expectation of plated through vias state in small chip components we focus on a new material
is of great interest for the microelectronic industry. model accounting for both, plastic straining and the
Vias are commonly made of (electrolytically deposited) growth of pores and voids within the copper via. We esti-
copper whereas the surrounding material is typical a non- mate the damage for vias with dierent llings and in dif-
isotropic resin, e.g., the glass bre reinforced resin FR4 ferent positions in an FR4 board onto which a ip chip
(ame-retardant 4 material substrate), [12]. To ensure the component has been mounted (FCOB = Flip Chip On
required life expectation of circuit units standarized ther- Board) and we suggest a technique for improved life time
mal cycle tests are performed. Due to the dierent thermal estimation.
expansion coecients of the copper and the anisotropic
board the copper vias are highly stressed and strained. This
leads to an accumulation of permanent irreversible strains 2. Finite-element modelling of the circuit board and the
plated-through vias

*
Corresponding author. Tel.: +49 30 314 24214; fax: +49 30 314 24499. High density interconnect (HDI) technology is an
E-mail address: weinberg@mech2.pi.tu-berlin.de (K. Weinberg). advanced packaging technology enabling more and more

0026-2714/$ - see front matter  2007 Elsevier Ltd. All rights reserved.
doi:10.1016/j.microrel.2007.03.003
K. Weinberg, W.H. Muller / Microelectronics Reliability 48 (2008) 6882 69

Fig. 1. Board and SMT components in the cross section of a microchip: (a) HDI components, cf. [11]; (b) schematics of plated-through via and microvia.

functions to be utilized in a smaller area for, e.g., the next presented case the global model consists of the chip (more
generation of small portable electronic communication precisely: the FCOB unit) and of the PC board, for dimen-
devices. HDI technology is based on various types of build sions see Fig. 3. Note that delicate substructures, such as
up methods for the manufacture of multi-layer Printed-Cir- the vias, are not included. Moreover, by symmetry the
cuit boards (PC boards). Fig. 1 illustrates the principle nite-element mesh is reduced to one quarter of chip and
setup of a PC board with plated-through holes, vias and board. A nite-element analysis is then performed with this
microvias, where the main physical dierence between the model, i.e., temperature cycles between 40 C and 150 C
rst two is the diameter of the hole. A plated-through-hole are imposed (233/423 K), see Fig. 2, where the rst step
is usually made to have a wire or a lead of a component sol- describes the cooling down from the melting temperature
dered into it. After plating the inner diameter of the hole is of SnPb solder of 183 C. From the global structure the
sized such as to receive a wire with sucient clearance. A locally resulting stresses, strains, and deformations are
via is a special kind of plated through holes that is not calculated.
intended to contain a wire but simply to provide a conduc- In a second step nite-element submodels of the struc-
tive path from one copper layer to another. Thus, its hole tures of interest, namely the plated-through vias, are created
diameter is usually much smaller. A microvia is an even in a way that the geometry of the real objects is reected in a
smaller connection to attach solder balls to the copper suciently accurate manner. The deformations at selected
layer structure on the PC board (right hand side of positions that result from the nite-element calculation of
Fig. 1b). Microvias can be studied in a manner completely the global model are now extrapolated and imposed onto
analogous to the one presented here for vias. the periphery of the local models. Thus, the mechanical
Note that the issue of lling the plated-through vias with response within the substructures can be calculated. Note
solder or epoxy and, if possible, to increase its life expecta- that here the reaction of the submodel to the global struc-
tion as opposed to leaving it unlled has been open to con- ture is considered to be negligible small. If the inuence of
siderable debate, see, e.g., [3]. the plated-through vias on the global structure is of interest,
Compared to a PC board and the microelectronic com- homogenization techniques are required, as, e.g., suggested
ponents mounted thereon the plated-through vias and in [6]. Clearly, it is desirable that during the nite-element
microvias are much smaller. If modelled directly this would analysis (FEA) the stresses and strains are as accurately cal-
lead to a nite-element mesh with an unnecessarily high culated as possible. Therefore, special attention must be
amount of degrees of freedom. For that reason we make paid to the generation of the submodel meshes so that all
use of a submodelling technique. This is a two-step proce- regions of interest, in the present case the copper, are su-
dure during which a global model is created rst. In the ciently far away from the boundary of the submodel.
The global model essentially consist of an chip mounted
upon a PC board. The board is made of FR4, a special
resin with high glass-transition temperature and with
orthotropic (transversal isotropic) material properties, see
Table 4 in the Appendix. In order to avoid the aforemen-
tioned numerical inaccuracy problems in context with the
submodels, i.e., in order not to use submodels that show
copper structures upon their surfaces a quarter of the
whole structure was modelled. Symmetry conditions were
imposed along the diagonal surfaces. Moreover, it was
made sure that the front surface of the compound consist-
ing of solder stop mask and PC-board did not tilt but
rather moved in a straight manner in order to mimic the
embodiment of the package within the whole assembly.
A submodel for the straight-through via is shown in
Fig. 2. Temperature cycling between 40 C and 150 C. Fig. 4. Note that the copper part is also completely
70 K. Weinberg, W.H. Muller / Microelectronics Reliability 48 (2008) 6882

Fig. 3. Finite-element model of a FCOB circuit unit.

Fig. 4. Positions of the vias within the global structure.

Table 1 the out-of plane direction being the z-axis. However, all
Positions of the vias submodels, also those along the horizontal line, i.e., the
Via 1 2 3 4 5 6 y-axis, are completely embedded in the global model.
x (mm) 1.5 0.0 0.0 2.91 0.0 0.0 The dimensions of the plated-through vias are as fol-
y (mm) 2.5 2.35 1.0 4.0 4.0 4.8 lows: width of the basal plane of the whole submodel
1.0 mm, wall thickness of the copper cylinder 0.022 mm,
inner diameter 0.256 mm, outer diameter 0.65 mm, height
of the submodel 1.5 mm. At the upper and the lower sur-
surrounded by underll, solder stop mask and PC board face the copper via is covered by a thin layer of solder stop
material. The submodels were positioned at various points mask with material parameters of Table 5; the copper
of the board, see Table 1. For reasons of conciseness only structure is surrounded by the orthotropic FR4 resin (cf.
one eighth of the whole structure is shown in Fig. 4 with Fig. 4).
K. Weinberg, W.H. Muller / Microelectronics Reliability 48 (2008) 6882 71

Fig. 5. Stressstrain curves for electrodeposited copper provided by [5].

During the manufacturing of plated-through vias and structure of the electrodeposited copper. Atomic-scale
other electrical connectors in high-density-substrates the numerical simulations of nano-crystalline copper in [18]
copper is electrolytically deposited, hence, the mechanical even yield, depending on temperature and grain size, to ini-
properties may dier signicantly from those of bulk cop- tial yield stresses of 0.81.5 GPa. Unfortunately, none of
per. Stressstrain curves for electrolytically deposited cop- the other sources provide such detailed information about
per are rarely provided in the literature with data the temperature dependency of material data as [5].
depending on temperature. The presented nite-element In Fig. 6 the von Mises stress in the deformed board after
simulations make use of the material data shown in cooling to a minimum temperature is shown, with the red
Fig. 5. These bilinear stressstrain diagrams were published and grey colored regions referring to the maxima (of
by DiTomaso [5], obtained from data provided by IBM 150. . .460 MPa) and blue marking the nearly unstressed
electronics division at Endicott, NY, based upon in-house regions. The warpage of the global structure is magnied
testing of electrodeposited copper. The corresponding by a factor of 50. It can clearly be seen that the highest
thermal expansion coecient is a = 17.6 ppm/K. At all deformations is along the diagonal surfaces, whereas in
the temperatures shown in Fig. 5 an initial yield stress is the vicinity of via position 4 the highest stresses occur.
marked at the end of a linear-elastic branch. This is then Depending on the position within the board the warpage
followed by hardening up to strains of e = 0.025. Here will directly inuence the deformations of the submodels.
we use the measured data of [5] but model the stressstrain Anticipated from the global model in the via positions 1,
curves with a smoother elasticplastic transition applying a 2, 4 and 5 shearing deformation appears to be dominant
power law of the form whereas in positions 3 and 6 the via will essentially be
 1=n stretched. Note that the viscous properties of the materials
ep are not modelled, therefore, the computed deformation can
ry ry 0 T 1 p : 1
e0 T considered to be an upper bound of the actual deformation.

The functions of the initial yield stress ry(T) and of the ref- 3. Material model for the electrolytically deposited copper
erence plastic strain ep0 T account for the temperature
dependency of plasticity, the hardening exponent is as- Most metals and alloys contain a certain amount of cav-
sumed constant with n = 25, cf. Table 5. ities. These can be defects in the crystal lattice, along grain
The material data of [5] describe a very soft material boundaries or simply vacancies arising during manufactur-
behavior, with an elastic modulus in the range of ing. Typically the size of the cavities is small compared to
40,000 MPa and an initial yield stress of 150 MPa and the size of the structure. Their amount is measured by pore
lower, see Fig. 5. Dierent but only qualitative observa- volume fraction or porosity
tions are reported in [8,13] stating that electrodeposited
volume of pores
copper has a higher tensile strength than bulk copper. Read fV : 2
et al. [17] observe in electrodeposited copper lms material total volume
properties of the same range as typical bulk copper, i.e., For typical engineering materials the pore volume fraction
E  120 GPa and initial yield stresses of 250 MPa, is initially in the range of 102 to 104. By the technique of
whereas Lu et al. [9] measure initial yield stresses from of electrolytically depositing copper the initial porosity is
250500 MPa up to 1000 MPa depending on the micro- expected to be higher (cf. [14]), but exact data are not
72 K. Weinberg, W.H. Muller / Microelectronics Reliability 48 (2008) 6882

Fig. 6. Von Mises stress in the deformed PC board model. (For interpretation of the references in color in this gure legend, the reader is referred to the
web version of this article.)

available. The growth and nally coalescence of these pores Formulations based on logarithmic elastic strains eec-
in the highly strained material is the basic failure mecha- tively reduce nite-deformation computations to small-
nism in ductile fracture, see, e.g., [19] for a review on this strain updates and pre- and post-processing steps which
subject. are purely kinematic and, therefore, material-independent,
To account for both damaging mechanisms, shear [10,16].
induced plastic straining and growing porosity in the cop- In general the material response is time-dependent. Here
per material, we employ here a material model that com- the speed of loading is slow (in the range of several min-
bines classical von Mises plasticity with plastic volumetric utes) and therefore strain rate eects are of minor inuence.
expansion as induced by the growth of pores. To this end On the other hand, creep eects might play a role. The
we postulate the thermo-mechanical response of the mate- proper criterium to apply in that case is the so-called
rial class considered here to be characterized by a free- homologous temperature, i.e., the current temperature
energy density per unit reference volume of the form divided by the melting temperature of the material (in
K). Creep shall dominate at homologous temperatures
A AT ; F; F p ; ep ; #p ; 3
above 0.5 but with a melting temperature of about
where T is the absolute temperature, F denotes the defor- 1300 K copper has for the temperature range of interest
mation gradient whereas F p (and F e) denote the plastic in this paper a homologous temperature 60.3. Therefore,
(and elastic) part of the deformation gradient. Both com- for the calculation of the irreversible deformation in copper
ponents are related as follows: creep will be neglected and we proceed to establish a time-
independent material model.
F F eF p: 4
We assume that the free-energy density (3) has the addi-
Moreover, the internal variable ep describes the eective tive structure
plastic straining whereas #p measures the eective volumet- AF; F p ; ep ; #p ; T W e F e ; T W p ep ; #p ; T ; 8
ric plastic expansion. e e p p p
Note that we account in this material model for the full where W (F , T) and W (e , # , T) are the elastic and
kinematics of large deformations. By the use of logarithmic stored plastic (i.e., dissipated) energy densities per unit
and exponential mappings the subsequent equations can in undeformed volume, respectively. The elastic strain-energy
part be written in the more familiar terms of strain tensor  density may alternatively be expressed in terms of the log-
with elastic and plastic components e and p, respectively. arithmic elastic strains (5),
To this end we dene W e  W e e ; T W e;vol tre ; T W e;dev dev ; T ; 9
1 where we split the energy density into a volumetric compo-
 lnF > F 5
2 nent and a shear deformation controlled deviatoric compo-
and nent. The corresponding deviatoric part of the strains
results from the decomposition
1 1
e lnF e> F e and p lnF p> F p 6 1
2 2 dev    I tr with tr 11 22 33 : 10
3
to obtain with (4) the additive decomposition
The volumetric energy component We,vol implies the equa-
 e p : 7 tion of state of the material, i.e, p = K tre  3a(T  T0),
K. Weinberg, W.H. Muller / Microelectronics Reliability 48 (2008) 6882 73

where K = E/(3(1  2m)) is the elastic bulk modulus of the The deviatoric part of the plastic energy density is con-
material, and a is the thermal expansion coecient. The structed to prescribe power-law hardening of the yield
deviatoric component We,dev is related to the shear modu- stress ry according to Eq. (1). This gives
lus l = 2E/(1 + m). Then, with mass density .0 and specic  n1
heat per unit mass cv the elastic energy density reads p;dev p;dev p nry T ep0 T ep n
W W e ; T 1 p : 19
  n1 e0
e 1 e 2 T
W Ktr  3aT  T 0 .0 cv T 1  ln The volumetric component Wp,vol = Wp,vol (#p, T) will be
2 T0
specied in detailed below. Then, the deviatoric yield stress
2
ljdev e j2 : 11 reduces to
3
oW p
Following the classical thermo-mechanical approach the ry T ; ep ; #p ; 20
oep
stresses can be computed from the derivative of the energy
density with respect to the conjugate deformation variable. and, likewise, the critical cavitation pressure is
In particular, the von Mises (or eective deviatoric) stress oW p
rv is determined by the relation py T ; ep ; #p : 21
o#p
oW e e Summarizing the thermo-mechanical framework we dene
rv   ; T 12
oep the thermodynamic force Y conjugate to the internal vari-
able ep as
whereas the pressure is recovered as
oA
oW e Y  rv  ry ; 22
p  p e ; T : 13 oep
o#
where the eective deviatoric stress and the yield stress are
The dependence of the elastic energy density W e on the given by (12) and (20), respectively. With pressure (13) and
plastic variables ep and #p is a consequence of the (prior (21) the thermodynamic force Z conjugate to the internal
solution unknown) decomposition (7). variable #p takes the form
The rate of plastic deformation is assumed to obey a
ow rule of the form oA
Z p  py : 23
o#p
F_ p F p1 e_ p M #_ p N; 14
Up to here the components of the free-energy density func-
where the tensors M and N set the direction of the devia- tion coincide with established theories of elasto-plasticity
toric and volumetric plastic deformation rates, respectively. extended to the nite range. The goal of the remaining par-
The tensor M is assumed to be trace-free and normed, i.e., agraph is to relate the continuum measures of volumetric
deformation to the materials porosity. Through this con-
2 3 nection we deduce the stored plastic energy function from
trM 0 and jMj ; 15
2 the analysis of an ensemble of voids. For simplicity, we as-
sume a dilute distribution of spherical voids each sur-
whereas the tensor N is allowed to take one of two values,
rounded by a spherical shell of material. This is, of
1 course, a very simplied approach but it enables us to de-
N  I; 16
3 duce the properties of the void ensemble from the behavior
of a single void. For shear-dominated loading conditions
with the plus sign corresponding to plastic volumetric the actual void shape may signicantly deviate from a
expansion (pore growth), and the minus sign to plastic spherical symmetry, cf. [7]. For a detailed discussion of this
compression (pore collapse). The tensors M and N are model and a comparison with other approaches we refer to
otherwise unknown and are to be determined as part of [20].
the solution. The constraints (15) and (16) may be regarded Consider a representative volume of material of unde-
as dening the assumed kinematics of plastic deformation. formed volume V0 and deformed volume V, where here
The rates of the internal variables e_ p and #_ p describe plas- and subsequently the subindex 0 designates elds dened
ticity due to deviatoric straining and volumetric expansion. on the undeformed conguration. The volumes V0 and V
They are subject to the irreversibility constraints are related by V = JV0, where
e_ p P 0 and #_ p P 0: 17 J  det F detF e F p J e J p 24
The stored plastic energy density per unit volume follows is the local Jacobian of the deformation and J e and J p are
from the rate of plastic straining by (cf. [15]) the corresponding elastic and plastic parts. We recall that
Z t Z ep Jp is the ratio of the volumes of innitesimal material
p
ry e_ dt ry dep : 18 neighborhoods in plastically-deformed setting reference
0 0 setting. In standard theory of plasticity the solid is not
74 K. Weinberg, W.H. Muller / Microelectronics Reliability 48 (2008) 6882

rial sphere surrounding a void and undergoing with the


solid plastic deformation holds
d 4pr3  a3
0: 28
dt 3
This uniquely determines the velocity over the current con-
guration (cf. [15])
a2
r_ a_ ; 29
Fig. 7. Stressed vias, studied experimentally in [2]. r2
and the corresponding rate of the eective von Mises strain
is
 
o_r 2a2 t
e_ r; t   3
p
ja_ tj: 30
or r t
With the incompressibility constraint (28) we can express
the current radius r by r3 r30  a30 a3 . Integrating (30)
in time yields to the plastic strain
 
2 a3  a30
ep ln 1 3
3 r  a3  a30
 
Fig. 8. Spherical shell model of pore growth. 2 a3  a30
ln 1 : 31
3 r30
assumed to expand (or compress) plastically, i.e., Jp  1. The stored energy function W p(ep, #p, T) is formulated by
Alternatively we formulate here assuming an additive decomposition into deviatoric and
V volumetric components and the rst part given by (19)
Jp e 25 models a conventional power law of hardening for the ma-
J V0
trix material surrounding the voids. The stored energy for a
to explicitly allow for plastic volumetric expansion of the spherical void in a power-law hardening material equals
material. the plastic work of deformation attendant to the expansion
For further analysis we assume a spherical shell model, of the void, and, in the dilute limit, the total energy stored
i.e., the material is modelled as a conglomerate of (initially by the void ensemble is the sum of the energy stored by
very small) spherical voids each surrounded by a sphere of each individual void. These considerations applied to a
matrix material, see Fig. 8. The voids may grow but retain spherical shell model lead by direct calculation from (18)
shape whereas the matrix material follows classical metal to the stored energy of volumetric plastic work
elasto-plasticity, i.e., it is incompressible during plastic Z b  n1
straining. The volume of undeformed matrix material is p;vol nr0 T ep0 ep n
W a; T N 1 p 4pr2 dr: 32
(1  fV0)V0. Let us now dene the current mean void radius a n1 e0
a  at. Then, neglecting the elastic volume change of the

voids we can write for the plastic Jacobian (25) of a body Imagine now for a moment a purely volumetric deforma-
with N voids per volume tion of the body, i.e., the deformation gradient is of the
spherical form F = J1/3I. Then the ow rule (14) reduces
a3
4p to ln(Jp)I = #pN which is evaluated to
J p 1  fV 0 N ; 26
3 d
lnJ p trN #_ p #_ p ; 33
or, equivalently, in terms of the current void volume dt
fraction where the plus sign corresponds to void expansion and the
fV 0 J p  1 minus sign to void collapse. From (33) we nd
fV : 27   Z t
Jp d 
_ p  p p p
#  ln J  and # t # 0 #_ p n dn; 34
a and Jp in one-
These relations place the mean void radius  dt 0
to-one correspondence. In all subsequent expressions, we i.e., the variable #p is a measure of the accumulated volu-
conventionally take Jp to be the primary independent var- metric plastic deformation. Evidently, #p and ln Jp coincide
iable and regard a, and its functions, as functions of Jp up to a constant for monotonic expansion. In this case we
through (26). put
From the plastic incompressibility constraint (for the
matrix material) we know that for any radius r of a mate- #p ln J p 35
K. Weinberg, W.H. Muller / Microelectronics Reliability 48 (2008) 6882 75

and with (25) the logarithmic plastic volumetric expansion until fatigue failure is anticipated. Following the tradi-
#p can be expressed as a simple function of mean radius tional approach of, e.g. [13,12,22], we apply a temperature
at
 history as follows: 456233423233423233 K, where
  456 K refers to the melting temperature of eutectic SnPb
p p 4p  3 3

#  # at ln 1 N  a t  a0 : 36 which was assumed to be the stress free state of reference.
3
Note that we apply two forms of loading on the via sub-
Then the stored energy of volumetric plastic work can be model, the temperature dependent material behavior and
formulated as the deformation resulting from the global model. More-
over, in order to account for the maximal possible growth
nr0 T ep0 4p
a3 of pores within the copper material the irreversibility con-
W p;vol #p ; T N g#p ; n; 37
n1 3 straint (17) is applied. Physically speaking this means that
with we allow the voids to open but not to close irreversibly.
!n1 Three (limit) cases are considered.
Z 1 n
fV 2 x
g#p ; n 1 p ln fV 0
dx: 38 (1) Unlled: The plated-through vias are empty copper
1 3e0 x  1 f exp #p 1
V0
vias embedded in the board as described in Section 2.
Note that these relations hold for arbitrary plastic defor- (2) Soft lled: The copper vias are lled with solder stop
mation of the matrix material. In an analogous manner mask with material data as outlined in Section 2.
additional energy contributions, e.g., the kinetic energy of (3) Hard lled: The vias are lled with a material harder
the body attributed to pore expansion, can be computed than copper. We choose here the material parameter
[21]. of mild steel.
For an arbitrary loading combining alternating phases
of pore expansion and collapse the distinction between All via positions are analyzed with these three llings.
the two variables Jp and #p becomes important. The simple Summarizing the results after the temperature changes
one-to-one relations (35) and (36) do not hold anymore. have been applied we observe that in the cases of no lling
For instance, suppose now that the pore radius history and soft lling the vias are to a dierent extend strained
at grows monotonically from a0 to 
 a1 , then decreases mostly in the middle of the copper cylinder. The typical
montonically from  a1 to a2 , and so on. Then the integration strain distribution is displayed for an unlled and a soft-
of (30) with respect to time gives lled via of position 4 in Figs. 9 and 10, respectively. In
 3   3  the unlled via the values of both, plastic strain and volu-
p 2 a1 r30  a30
 2 a1 r30  a30
 metric plastic dilatation, i.e., maximal porosity, are smaller
e r0 ; t ln ln 3
3 r30 3 a2 r30  a30
 than in the lled via. Depending on the position of the
 3 
2 a r30  a30
 unlled via the maxima of plastic strain and of plastic dila-
ln 33  39 tation occur in the outer region (position 1, 2, 4, 5) as well
3 a2 r30  a30

as in the inner regions (position 3, 6) of the thin copper cyl-
For the formulation of the stored energy of volumetric inder, whereas in case of a soft lling the maximum values
plastic work (37) relation (31) then needs to be replaced are all found on the inner side. In that context the wall
by (39). thickness of the copper cylinder may be of considerable
Note that for an arbitrary history of the plastic volumet- inuence and needs to be further investigated.
ric expansion the value of #p(t) rises even when the pores For hard llings the location of the maximum straining
shrink. That means by constraint (17) the internal variable shifts as one may expect away from the copper tube to
#p(t) basically measures the ups and downs of pore growth the attached upper and lower layers, see Fig. 11. Note that
and, therefore, cannot anymore be compared to the mono- because our FEA does not consider debonding of the cop-
tonic loading. The information about current pore size is in per material from the lling the straining that was com-
general solely in Jp(t) via relation (26). The corresponding puted here is not necessarily realistic. The values may
physical constraint is now dier in particular in case of a loose tting of a sti ller,
J p P 1; 40 e.g., a wire. This may also prevent bending of the copper
tube but it allows for pressure and tension, the main mech-
i.e., the pores are not allowed to be smaller than the initial anisms that cause pores to grow.
pore size with Jp = 1. In Table 2 the results are given in detail. Because FEA of
the vias at position 1 and 4, and, 2 and 5, respectively, leads
4. Comparison of numerical results after 5 temperature steps to very similar results, we list here only the latter. More-
over, for clarity all values are referred to an average strain
The presented material model was employed to study and an average dilatation with value 0.03. Note that we
the response of the plated-through vias during thermal compare maximum values and that the position of the
cycling. It is common practise to simulate only a few steps maxima may dier. In particular we emphasize that in
of the temperature cycling test and extrapolate the results case of a hard lling the maximum value is on the upper
76 K. Weinberg, W.H. Muller / Microelectronics Reliability 48 (2008) 6882

Fig. 9. Distribution of accumulated plastic strain and porosity (as indicated by ep and #p) in an unlled via at position 4 after 5 temperature steps
(maxima: red, minima: blue): (a) plastic strain ep; (b) pore growth #p. (For interpretation of the references in color in this gure legend, the reader is
referred to the web version of this article.)

Fig. 10. Distribution of accumulated plastic strain and porosity in a soft-lled via at position 4 after 5 temperature steps (maxima: red, minima: blue): (a)
plastic strain ep; (b) pore growth #p. (For interpretation of the references in color in this gure legend, the reader is referred to the web version of this
article.)

Fig. 11. Typical distribution of accumulated plastic strain and porosity in a hard-lled via after 5 steps (maxima: red, minima: blue): (a) plastic strain ep;
(b) pore growth #p. (For interpretation of the references in color in this gure legend, the reader is referred to the web version of this article.)

boundaries of the via, see Fig. 11. Nonetheless we can sum- structure. After ve temperature changes the unlled
marize as follows: vias show lower plastic strain and lower porosity.
A hard lling supports the via, i.e, it prevents bending.
The lling of the vias with solder stop mask does not The maximum of straining is shifted from the center
improve necessarily the mechanical properties of the to the boundary of the structure instead.
K. Weinberg, W.H. Muller / Microelectronics Reliability 48 (2008) 6882 77

Table 2 absolute value in strain also shows the highest increments


Maxima of plastic strain and pore growth in the dierent via positions in strain after ve steps. The analog holds for the plastic
after 5 temperature steps
dilatation, but the locations of maxima do not coincide.
Via Relative strain Relative dilation A similar behavior was observed for the (not displayed)
position maximum maximum
unlled vias, but here the rising temperature also causes a
3 No lling 0.8588 0.2905 (comparatively small) growth in plastic strain. Cases where
4 0.9123 0.4183
5 0.8012 0.2859
in unlled vias the element with the highest plastic strain
6 0.8478 0.3095 shows saturation already after rst cooling, as reported
in [2], were not found here. However, in case of the hard-
3 Solder stop mask 1.1223 0.7630
4 lled 1.2328 0.8547 lled vias the temporal development shows these saturation
5 1.0567 0.7880 after the rst step of cooling for both, plastic strain and
6 1.1088 0.7507 pore growth.
3 Hard lling 1.1687 0.6353
4 1.1757 0.6380 5. Long term response
5 1.0737 0.6637
6 1.1128 0.6340 In experiments the number of temperature cycles that a
circuit board can tolerate is generally considered to be a
measure of the circuit coppers resistance to fatigue dam-
The via at position 3 (in the middle of the chip) as well age. It depends in a large part on an inverse relationship
as the via at position 4 (on the diagonal) are the most with strain amplitude De within one cycle. The fatigue fail-
strained ones, and, moreover, show dierent regimes ure of a metal, as here the electrodeposited copper, is com-
of loading (stretching, bending). We therefore proceed monly estimated using a ConManson relationship of the
analyzing only these two positions. form [4]
The diagrams in Fig. 12 allow to gain an overview of the De rf b c
2N f ef 2N f ; 41
development of maximum plastic strain and plastic dilata- 2 E
tion in time for the soft-lled vias located at positions 36. where (2Nf) is the number of strain reversals (cycles), E
The response in all positions of the via is similar. The initial is Youngs modulus, rf is the tensile strength, and ef is
cooling 456233 K causes a formidable plastic strain but the related ductility. The exponents b, c are empirical
no plastic dilatation. The reason for that may be a pressure constants.
dominated stress state; because of the dierent thermal Fatigue of copper is characterized by elastic and plastic
expansion coecients the copper is bended but under pres- strain components. During a high-strain/low-cycle testing
sure. On the opposite, rising temperature causes tension as considered here the dominant component is the plastic
and voids to grow but at least in the rst steps observed deformation. Elastic deformations play a role mainly dur-
here no plastic straining. The process repeats with smaller ing low-strain/high-cycle testing, therefore, the region of
amplitude. elastic deformation is also considered as the dynamic
The vias along the diagonals are the most severely region. In that case the rst term of Eq. (41) dominates
strained, all other vias show approximately the same level and fatigue performance is mainly a function of the tensile
of strain. In all cases the nite element with the highest strength.

a 0.04 0.03

0.035 via @ 3 via @ 3


via @ 4 0.025 via @ 4
via @ 5 via @ 5
accumulated plastic strain p

0.03
via @ 6
accumulated porosity p

via @ 6
0.02
0.025

0.02 0.015

0.015
0.01

0.01

0.005
0.005

0 0
0 1 2 3 4 5 0 1 2 3 4 5
steps steps

Fig. 12. Temporal development of the maxima of plastic strain and pore growth in the soft-lled via: (a) plastic strain; (b) pore growth.
78 K. Weinberg, W.H. Muller / Microelectronics Reliability 48 (2008) 6882

Conversely, in the high-strain/low-cycle regime, the sec- Depave 0:002876. Applying Eq. (42) gives a live expecta-
ond term of (41) dominates and fatigue is a function of tion of Nf = 591 and Nf = 1867 for the unlled and lled
ductility. The account in terms of stress is less useful and via, respectively. The same procedure applied to the vias
the rst term in Eq. (41) does not apply. The strain ampli- at position 3 results in Nf = 1084 for the unlled and
tude within one cycle is replaced by the plastic strain incre- Nf = 525 for the lled via.
ment to give The calculated numbers of cycles are low with respect
to the required life expectation of at least 4000 cycles,
Dep
ef 2N f c ; 42 i.e., Nf = 8000. Moreover, this approach does not account
2
for the fact that the absolute value of ep is higher in case
where c is known as the fatigue ductility exponent, com- of a lling in the vias. Also, additional information about
monly ranging from 0.5 to 0.7 for metals. Dierent crack or pore growth are not consulted for life time
sources report that the ductility of electrodeposited copper estimation.
is smaller than the ductility of bulk copper, [3,13,17,8]. To answer the question of how reliable this simple tradi-
Thus, we assume here a maximal ductility of 20%. tional approach is, we study in the following the mechani-
We now apply relation (42) to the results of Section 4. cal response of the vias over a longer period of time and
The plastic strain increment is found by averaging the plas- analyze the plastic strain as well as the expected pore
tic strain from step 2 to step 5. The rst step is skipped growth. To this end, 20 steps of temperature cycling after
because the strain induced by the initial cooling gives no the initial cooling are computed. Because of the signicant
information about a typical strain increment. computational eort we analyze here only the maximal
The region with maximum straining of the via is marked loaded vias at position 3 and 4, the conclusion for the
in Figs. 13 and 14 by a circle. Here we get (averaged over remaining via positions are analogous. In case of the
the integration points of the element) for the unlled via hard-lled vias we do not observe additional straining after
at position 4 Depave 0:005737 and for the soft-lled via the rst cool down. Therefore, and because hard lling is of

Fig. 13. Distribution of accumulated plastic strain and porosity in an unlled via at position 3 (maxima: red, minima: blue): (a) plastic strain; (b)
volumetric plastic dilatation. (For interpretation of the references in color in this gure legend, the reader is referred to the web version of this article.)

Fig. 14. Distribution of accumulated plastic strain and porosity in an unlled via at position 4 (maxima: red, minima: blue): (a) plastic strain; (b)
volumetric plastic dilatation. (For interpretation of the references in color in this gure legend, the reader is referred to the web version of this article.)
K. Weinberg, W.H. Muller / Microelectronics Reliability 48 (2008) 6882 79

somewhat articial nature, we investigate in the following tiate such an eect experimentally, for a rst indication see
only the unlled and soft-lled vias. Fig. 7.
The distribution of plastic variables after 21 temperature The strain values at inner and outer side of the via wall
steps is shown in Figs. 13 and 14 for vias at position 3 and become similar. Moreover, starting after about 8 steps the
4, respectively. During continued temperature cycling the rising of temperature starts to cause a small increase in
location of the maximal values of plastic strain and plastic plastic strain also for the soft-lled vias. Pore growth as
pore growth changes. The displayed distribution nicely modelled here can only happen in a tension dominated
reects the loading of the via. In position 4 bending dom- state, i.e., during heating.
inates and the accumulated plastic strain and, in particular, To account for both plastic straining and increasing
the plastic volumetric dilatation show a localization on the porosity the temporal development of the plastic variables
corresponding sides of the via. In position 3 (direct under- is plotted in the Figs. 1518 for the position marked in
neath the chip) the via is mainly stretched along its axis and Fig. 14. The values computed at this locus are close to
the distribution of plasticity in circumferential direction is the absolute maxima of ep, #p for all analyzed vias. In order
basically homogeneous. The highest plastic straining is to additionally avoid numerical artifacts all plotted values
accumulated in the upper half of the copper tube, whereas are averaged within the nite elements.
the pores and voids grow increasingly towards the lower For all studied vias the cooling from manufacturing
half. If we consider superposition of both defects there temperature of 456 K down to 233 K initiates an formida-
seems to be a higher probability of failure within the mid- ble amount of plastic strain with amplitudes higher in the
dle parts of the vias. Clearly, here is some need to substan- lled than in the unlled vias. Within the next temperature

0.04 0.08

via @ 3, filled
0.035 0.07
via @ 4, filled
via @ 3, unfilled
p

0.03 0.06
accumulated plastic strain

via @ 4, unfilled
accumulated porosity p

0.025 0.05

0.02 0.04

0.015 0.03
via @ 3, filled
0.01 via @ 4, filled 0.02
via @ 3, unfilled
via @ 4, unfilled
0.005 0.01

0 0
0 5 10 15 20 0 5 10 15 20
steps steps

Fig. 15. Temporal development of plastic straining within 21 temperature Fig. 17. Temporal development of monotonically assumed void growth
steps for unlled and soft-lled vias. within 21 temperature steps for unlled and soft-lled vias.

0.02 0.02
via @ 3, filled via @ 4, filled
0.018 via @ 3, unfilled 0.018 via @ 4, unfilled

0.016 0.016
increment of plastic strain p

increment of plastic strain p

0.014 0.014

0.012 0.012

0.01 0.01

0.008 0.008

0.006 0.006

0.004 0.004

0.002 0.002

0 0
0 5 10 15 20 0 5 10 15 20
steps steps

Fig. 16. Increments of plastic strain Dep within the temperature steps for unlled and soft-lled vias: (a) vias at position 3; (b) vias at position 4.
80 K. Weinberg, W.H. Muller / Microelectronics Reliability 48 (2008) 6882

0.04 Table 3
Life expectation in the dierent via positions
via @ 3, filled
0.035
via @ 4, filled Via position Nf(ep) Nf(sp)
via @ 3, unfilled
0.03 via @ 4, unfilled 3 No lling 4529 1293
remaining porosity log(Jp)

3 Soft-lling 4942 1864


0.025 4 No lling 15,818 6172
4 Soft-lling 21,490 14,125
0.02

0.015 ing but now without its physical meaning of pore growth.
To ensure that the pores must not get smaller than their ini-
0.01 tial size within the virgin material we constrain sp P 0.
Fig. 18 monitors the volumetric growth (and shrinkage)
0.005
in the vias during 21 temperature steps. In all vias the rst
0 heating steps cause a signicant growth in porosity. Then,
0 5 10 15 20
steps similar to the plastic straining, a certain saturation is
reached after approximately six steps. Thenceforward
Fig. 18. Temporal development of pore opening and closure within 21 pores in the copper material open and close with every tem-
temperature steps for unlled and soft-lled vias.
perature cycle. The resulting porosity shows a slight
increase in every cycle.
steps the increments of plastic strain are still large but To estimate the life time of a materials from its porosity
around step 6 the plastic straining shows saturation. Then an empirical equation like (41) is not known. Therefore we
it depends on the position of the via how much the strain apply the following strategy to calculate the number of
increments reduces. To illustrate this, Fig. 16 shows the cycles when the resulting porosity reaches a critical value.
strain increments within the steps. We clearly see that the First we determine the porosity after the rst few cycles,
increment of plastic strain computed from a FEA of 5 tem- here we choose step 6. For the unlled via at position 3
perature steps is not representative for the rest of the life we get spini 1:187  104 , for the lled via spini
cycle. The increment Dep is in the rst steps signicantly 2:003  104 . Now we compute the average increase of
higher than the average between step 6 and 21. In particu- porosity within every temperature cycle from step 6 to 21
lar, the inuence of the llings in the vias is inverse. In case (Dsp = 1.499 104/Dsp = 2.2135 104) and extrapolate
of no lling we get in position 4 an average strain of that increase in a linear manner until the resulting porosity
Depave 0:000798 (with lling Depave 0:000664), resulting reaches the critical value.
in Nf = 15,818 and Nf = 21,490, respectively. The corre-  
Dsp spcrit  spini N 1
f : 43
sponding numbers of the unlled and lled via at position
3 are Nf = 4529 and Nf = 4942. Note that the computed The number of cycles (2Nf) corresponds to the life expecta-
live expectations are by an order of magnitude larger than tion. Table 3 summarizes the results for both, plastic strain-
above. ing and resulting porosity computed with 21 temperature
Fig. 17 displays the temporal development of the maxi- steps. Both criteria yield qualitatively equal results and
mal possible void growth, i.e., the volumetric plastic dilata- show the unlled via at position 3 being the most likely
tion #p. Nearly constant increments D#p are observed after to fail. The lower numbers for the porosity criterion is
each heating step. Because the volumetric plastic dilatation likely to be caused by the linear way of extrapolation
as a function of time (or steps) shows an almost linear slope (Eq. (43) vs. Eq. (42)). Fillings support the vias, in partic-
it may reach a critical value after a certain number of steps. ular, in a tension-compression dominated state. An exper-
Ductile metals are known to fail by fracture when the imental verication of the observed correlations (as well as
porosity reaches a volume fraction of at most 0.3, [19]. of the relatively high fatigue ductility) was not available to
Extrapolating the function in Fig. 17, this critical porosity us and is left for future research.
would be reached after 150. . .300 temperature steps. This
number is a not necessarily realistic because by Eq. (17) 6. Conclusions
we allow the pores to open in tension but not to shrink
in compression. Consequently, #p can be considered an The presented analysis of plated trough vias shows that
auxiliary value which at best gives an upper limit for the both mechanisms, plastic straining and the growth of pores
realistic porosity. within the copper via have an essential inuence on the life
Henceforth, lets follow the constitutive model outlined time expectation of the vias and, consequently, the whole
in Section 3 which allows also for pore closure. To this circuit unit. The actual accumulated damage is determined
end, we introduce the variable sp = ln(Jp) to measure plas- by the position of the via on the PC board and by its lling.
tic volume change, i.e., to account for the growth and To estimate the life expectation not only the plastic strain-
shrinkage of voids and keep #p to be an internal variable ing but also the growth of voids should be investigated. For
accounting for volumetric plasticity and for work harden- the latter we presented a simple engineering model of dilute
K. Weinberg, W.H. Muller / Microelectronics Reliability 48 (2008) 6882 81

void growth which captures the growing porosity in the Table 6


copper via in a qualitatively correct manner. This porous Elastic parameter of solder stop mask and soft lling
plastic model presents a workable set of constitutive equa- T (K) E (MPa) m
tions and is open to further (micromechanically motivated) 218 6000 0.34
improvements. 295 5000 0.38
The extrapolated number of cycles until failure of the 343 3400 0.40
373 2500 0.42
units depends on the number of temperature cycles consid- 423 1000 0.45
ered in the numerical analysis. In particular, a realistic life
time estimate needs to base on a nite element analysis of
at least 20 temperature steps. Considering less steps gives
Table 7
rather accidental results inuenced, e.g., by the initial refer- Thermal expansion coecients
ence state. Furthermore, after few temperature cycles it is
ax = ay (ppm/K) az (ppm/K)
not yet possible to estimate whether the lling of a copper
5
via supports plastic straining or prevents it. FR4 board 1.7 10 6 105
Copper 1.76 105 1.76 105
Presumed that the input to the nite element analysis, in Solder stop mask 6 105 6 105
particular the material properties of the electrolytically Filling 6 105 6 105
deposited copper and the failure criteria, reect the actual
situation, the introduced FEA-based strategy can serve as
a predictive tool for the plated through holes and vias. This References
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