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An International Journal of
PERIOD!CO di MINERALOGIA
MINERALOGY, CRYSTALLOGRAPHY, GEOCHEMISTRY,
established in1930
ORE DEPOSITS, PETROLOGY, VOLCANOLOGY
and applied topics on Environment, Archaeometry and Cultural Heritage
1 Dipartimento di Scienza della Terra, Universita di Roma La Sapienza, P .le Aldo Moro 5, 1-00185 Roma, Italy
2 Concordia University, 7 14 1, Sherbrooke Street W, Montreal, H4B 1R6, Canada
ABSTRACT. - Over the past fifteen years many cratoni c m a s s e s , b u t a l s o in adjacent reg i ons ,
scientific papers have been published on the nature particularly in the associated mobile belts. Even if
and o r i g i n of d i a m on d s . M o d ern anal y t i c a l the kimberl itic and l ampro i t i c rocks b e l ong t o
techniques show that diamonds' solid inclusions are intrusive phases o f different ages, they can still crop
sometimes as small as 1 50-200 microns. They have out in the same geological sectors ; therefore some
also shown that diamonds invariably derive from diamantiferous diatremes may contain diamonds of
peridotitic and eclogitic rock s ; kimberli tes and different ages. As the majority of kimberlitic and
l ampro i t e s are genera l l y more recent than the lamproitic rocks belong to relatively recent intrusive
diamonds themselves indicating that kimberlites and phases (the last 200 million years), some significant
lamproites are not necessarily and directly linked to intrusions reveal ages of about 1 . 6 b i llion years
the origin of these precious crystals, but constitute (Low Proterozoic) as well as ages preceding 2 . 6
instead the means by which diamonds reach the billion years.
surface of our planet. It has also been shown that
diamonds associated with peridotitic rocks are about RIA S SUNTO. - I numero s i l av ori s c i en t i f i c i
3.3 billion years old, whereas those associated with p u b b l i c at i n e g l i u l ti m i q u i n d i c i anni h anno
eclogitic rocks v ary in age between 1 . 6 and 1 . 0 contribuito a chiarire molti concetti riguardanti la
bill i on years . In light of their considerabl e age natura e l a genesi dei diamanti . In particolare il
difference we can safely surmise that, as diamonds notevole c ontri b u t o di cono s c enze maturato in
generally precede their including volcanic rocks, questo periodo e derivato dall' avanzamento degli
t h e i r g e n e t i c c onne c t i o n s t o k i m b erl i t e s and s t u d i g e o c h i m i c i s u l l e i nc l u s i oni s o l i d e - d i
l ampro i t e s are rare ; that they h a v e b e e n dimensioni limitatissime, non piu grandi d i 1 50-200
intermittently generated over long periods of the micron - resi pos sibili dalle moderne tecniche e
planet's geological history, and that kimberlites and tecnologie analitiche.
lamproites are mixed volcanic rocks derived from I recenti ri sul tati tratti dalle inc l u s ioni hanno
d e e p e r m a g m a t i c s ou r c e s than pre v i o u s l y d i m o s trato che questi minerali deri v an o , senza
hypothesized. Although kimberlitic rocks are present alcuna eccezione, da rocce peridotitiche e da quelle
in a l l c ontinen t s , i m p or t ant d i am o n d - b e aring eclogitiche. Le rocce kimberlitiche e le lamproitiche,
deposits can be located not only in the continental a c u i di r e g o l a s ono i n t i m am e n t e a s s o c i at i i
diamanti, risultano pero generalmente piu recenti di
questi . Da tale fatto si deduce chiaramente che le
*Corresponding author, E-mail: ferrini@uniroma l.it kimberliti e le lamproiti non sono necessariamente e
110 V. FERRINI and G. SASSANO
direttamente legate alla genesi dei preziosi cristalli accumulation, the type of including rock, and
ma costituiscono piuttosto il mezzo attraverso cui si the geology commonly associated with their
realizza il trasferimento d e i d i amanti v e r s o l a
presence, are themes which have always
superficie del nostro pianeta, ove s i ritrovano in
interested scientists: both on account of their
giacitura alloctona. E stato anche dimostrato che i
diamanti associati alle rocce peridotitiche hanno economic and industrial importance, and their
un'eta di circa 3 , 3 miliardi di anni, mentre quelli intrinsic beauty. Only in the last ten years,
associati alle rocce eclogitiche ne accusano una however, has any considerable progress been
variabile tra i 1,6 ed 1,0 miliardi di anni. made towards an understanding of the
Alla luce di questa notevole differenza di eta si puo geochemical phenomena associated with the
affermare che, poiche i diamanti sono generalmente
genesis of diamonds. New concepts and
ant e c e d enti a l l e r o c c e inc a s s anti (kimberliti e
lamproiti), raramente sono legati geneticamente ad theories - thanks mainly to the use of highly
e s s e e c h e il minerale si e formato in m o d o specialized equipment- have enabled scientists
intermittente durante lunghi perio di d e l l a s toria to shed light on many aspects concerning the
geologica della Te1ra. Le altre considerazioni emerse formation of the carbon crystals.
inducono a puntualizzare che le kimberliti e le In the present paper the authors propose to
lamproiti sono rocce vulcaniche particolari derivate
present an up-to-date synthesis of the most
da sorgenti magmatiche piu profonde di quanta fino a
pochi anni fa fosse stato ipotizzato, che le kimberliti
advanced theories in the field of the origin of
sono presenti in tutti i continenti, ma che i depositi these minerals, basing their discussion on both
diamantiferi molto importanti, economicamente e their own personal experience matured over
scientificamente, sono localizzati non solo nelle years of teaching at their respective universities
masse cratoniche continentali ma anche nei settori (i.e. La Sapienza in Rome, Italy, and Concordia
adiacenti, specialmente nelle cinture mobili ad esse
in Montreal, Canada), and consultation of an
associate. Le rocce kimberlitiche e lamproitiche, pur
extensive bibliography.
connesse a fasi magmatiche di eta diversa, possono
affiorare negli stessi settori geologici; pertanto alcuni Among the works cited, a special mention is
diatremi diamantiferi possono contenere diamanti di due to the authoritative papers by Mitchell and
eta completamente differente. Infine c'e da notare che Bergman (1991 ), Ross et al. (1989), Nix on
sebbene la maggior parte delle kimberliti e lamproiti (1987), Mitchell (1986; 1991; 1995), Glover
siano correlate a fasi piuttosto recenti (ultimi 200 and Harris (1984), Dawson (1980; 1989), and
milioni di anni) alcuni carpi di notevole importanza
the articles published by Gurney (1989), Meyer
rivelano eta di circa 1,6 miliardi di anni (Basso
Proterozoico) e oltre, antecendenti a 2,6 miliardi di (1985) and Slodkevich (1983). Other authors,
anni. such as Anderson, O . L. ( l 979), Brummer
(1984), Smith et al. (1985), Richardson (1986),
KEY WoRDS: Diamonds o rigin, solid inclusions, and Richardson et al. (1984; 1990), as well as
kimberlites, lamproites. the recent papers by Eggler (1989), Wyllie
(1989), Kirkley et al. (1991a; 1992), have been
widely cited in this synthesis in recognition of
INTRODUCTION
their notable contribution to the understanding
Recent discoveries of diamonds in the of the subject.
Canadian territories of the North West, the
Provinces of Quebec and Saskatchewan, and PREVIOUS STUDIES
other regions of Canada, together with the
finding of extensive placer deposits along the One of the biggest problems left unresolved
banks of the tributaries of the Gumani and to date in the study of the genesis of diamonds
Icabaru rivers in Venezuela, have renewed the consisted of the indisputable genetic association
interest of the mining industry in the genesis of existing between diamonds and their including
this mineral. rocks, kimberlites and lamproites. Two
The nature of these precious stones, the fundamental hypotheses reflected the lack of
means of transport, the mechanism of precise knowledge in this field:
Nature, origin and age of diamonds: a state-of-the-art report 111
ea
. ""'
.. .
. \ \
.
I " J'l -..
.. .
:.-\ )' . 8\
Garnets in
diamonds from
lamproite
Fig. 1 -Relative abundances between calcium (Ca), magnesium (Mg) and iron (Fe) in garnet inclusions contained in peri
dotitic and eclogitic diamonds (modified after Meyer, 1987).
112 V. FERRINI and G. SASSANO
The data presented in fig. suggest in fact compositions can be supposed also for their
that: respective original magmatic fluids. However,
(a) The diamonds were generated lamproitic rocks contain a certain number of
intermittently during the geological history of accessory minerals - leucite, sanidine, wadeite
the planet, particularly between 3. 3 and 0.99 and priderite - which clearly distinguish them
billion years ago; from kimberlites. They are also discriminated
(b) These crystals were accumulated at great by their substantial difference in magmatic
depths (i.e. the mantle) prior to being composition. A comparative table of the
transported to the surface by the kimberlites or pmagenetic association of both rocks is given
lamproites. in Table 2.
Consequently, it is logical to presume that TABLE 2
diamonds characterized by very different ages
can coexist in the same diamantiferous deposits Minerals found in kilnberlitic and lamproitic
and in the same including rocks, even if they rocks (modified qfter Kirkley et al., 1992).
originate from different sources situated in the Kimberlite Lamproite
mantle of our planet.
A. Minerals which crystallize directly from kimberlite and
lamproite magmas
Major minerals
Olivine X X
THE ORIGIN OF KIMBERLITES AND LAMPROITES
Diopside X X
Phlogopite X X
It has been established that diamonds are Calcite X
Serpentine X
brought to the surface by the ascent of Monticellite X
particular vulcanic rocks - mainly kimberlites Leucite X
and lamproites - during eruptive phases and in Amphibole X
Enstatite X
important geological ages. Sanidine X
As diamonds seem to come from depths
exceeding 150-200 km (see below), it can be Minor minerals
Apatite X X
assumed that these rocks originated from these Perovskite X X
depths, and hence that they intersect mantle llmenite X X
regions capable of producing the diamonds Spinel X X
Priderite X
prior to reaching the earth's crust. From this Nepheline X
point of view, then, kimberlites and lamproites Wadeite X
appear to constitute volcanic facies derived
B. Xenocryst minerals derived from the upper mantle
from much deeper magmatic sources than Olivine X X
originally supposed only a few decades ago Gam X X
(Eggler, 1989; Wyllie, 1989). Clinopyroxene X X
Orthopyroxene X X
From a genetic point of view, it can be Chromite X X
affirmed that kimberlites and lamproites are
mixed rocks, as they consist both of Both rocks seem to have originated from the
xenoliths and xenocrystals derived from the partial melting of very similar but nonetheless
upper part of the mantle, and of magmatic distinct peridotitic materials, in environments
compounds closely linked to the crystallization characterized by p ress ures with values
products of the magmas themselves formed at determined by depths varying from about 150
these depths. The principal mineral to 250 km, whereas the formation temperatures
components particularly olivine, are approximately 1100-1500C. Within this
clinopyroxene, phlogopite, apatite, perovskite, scale of values, kimberlites formed preferably
ilmenite and spinel - are common to both at lower temperatures, while lamproites seemed
rocks, so that rather similar chemical to favour higher temperatures.
Nature, origin and age of diamonds: a state-of-the-art report 113
compatibility, and the speed of transport. The pyrrhotite. Four additional minerals (i.e. rutile,
last factor, in particular, can generate pressure kyanite, corundum and cohesite) form the
and temperature variations in the ascending lesser constituents typical of the eclogitic
magmas, giving rise to important phenomena i nclusions. As a result, these take o n an
of digestion and recrystallization. exceptional importance for the interpretation of
Studies on the solid inclusions in diamonds the data and the differentiation of the primary
make it possible to state that the diamonds genetic sources (Mitchell, 1986).
present in xenolithic fragments are generally The 11 remaining accessory minerals, which
older than the including kimberlitic and are much rarer, do not offer any statistically
lamproitic rocks (Kirkley et al., 19 92). It can significant elements. On the basis of the
also be affirmed that the conditions of chemical composition, then, it is possible to
formation deduced from the studies on these classify 98% of diamonds as peridotitic (i.e.
rocks make it feasible to infer with greater P-type diamonds) and eclogitic (i.e. E-type
precision the physical-chemical conditions of diamonds) (Kirkley et al., 1992). Garnets are
the genetic environment in which the carbon particularly useful, especially if it is considered
crystals formed. that the peridotitic garnets contain higher
percentages of Mg and lower percentages of Fe
and Ca than those associated with the eclogitic
MINERAL INCLUSIONS IN DIAMONDS rocks (fig. 1). Considering that both types of
diamonds (i.e. P-type and E-type) can be
Study of the solid inclusions contained in found in the same diamantiferous deposit, it
diamonds was performed with the help of follows that the volcanic rocks which constitute
particular techniques which allowed the the ore deposit must necessarily have sampled
identification and dating of the minerals rocky masses originating from two different
contained in the diamonds (Moore and Gurney, areas of the mantle containing diamonds prior
1985; Meyer, 1987; Gurney, 1989). As to reaching the surface.
mentioned previously, the analytical data are As previously mentioned, the diamantiferous
interpreted on the basis of the fundamental xenoliths originating from eclogitic rocks seem
concept of co-geneticity of the solid phases to be much more abundant than those from
contained in the diamonds themselves. In order peridotitic rocks. However, if solely the solid
to obtain mineral inclusions (i.e. garnets) in the inclusions contained in diamonds are
including minerals (i.e. diamonds), it has of considered, it must be acknowledged that the
course to be presumed that the solid phase reverse is true: the P-type inclusions are
bearing the inclusion must have been generated much more frequent than the E-types. This
at the same time and in the same environmental observation seems to demonstrate an essential
locality as the included phase. If the solid fact: as soon as the solid inclusions are
inclusions contained in the diamonds belong to included, they are automatically protected from
the peridotitic assemblage, it follows that the any chemical reactions taking place in the
diamonds themselves formed in peridotitic including magmas during the solidification
embedding rocks. This simple rule applies also process. Consequently, they are not subject to
to diamonds found in eclogitic rocks. the disintegrations which appear to modify
A total of 22 accessory minerals (see Table peridotitic xenoliths during ascent. Hence it
2) were found as original solid inclusions in the should not be illogical to accept the relative
diamonds examined by Gurney (1989). Only abundance of the solid inclusions in diamonds
six minerals, however, appear in both the as a basic indicator efficaciously representing
peridotitic and eclogitic assemblages: olivine, their respective percentages, and therefore -
orthopyroxene, clinopyroxene, garnet, analogously - the relative importance of the
chromite, and some sulphides such as rock types constituting the source of the
Nature, origin and age of diamonds: a state-olthe-art report 115
It should also be noted that eclogites have a Wyoming State Line District. Quite a
chemical composition almost identical to that significant number have been discovered
of basaltic rocks. The minerals which make up recently in the Prince Albert district and in the
basalts - mainly feldspar and clinopyroxene - region of Fort a la Come, in Saskatchewan
can recrystallize, in environments characterized (Lehnert-Thiel et al., 1992), in the Lac de Gras
by high pressures and temperatures, in the form zone, in the N. W. T., and in Quebec, Canada.
of garnets and omphacites. During a Further occurrences are c urrently being
continental collision, the basaltic rocks- which explored in the regions of the Icabaru and
cons titute one of the most important rock Guarani rivers, in Venezuela and in Russia.
components of ocean floor- are transported to If all the kimberlitic occurrences present in the
considerable depths below the continental earth's crust are considered, it has to be
masses, in areas characterized by high acknowledged that only about a thousand are
pressures and temperatures. These rocks are characterized by the presence of diamonds,
gradually transformed into eclogitic rocks. while only sixty or so can be considered
Huge quantities of carbon, in the form of economically viable, according to the present
carbonates belonging to oceanic plates under market requirements. Moreover, it is calculated
subduction (i.e. calcite or dolomite) or in the that only 12 deposits are currently exploited for
form of hydrocarbons (i. e. organic matter), diamond production as such. It should be
could therefore represent the original source of remembered that the core-like masses best
carbon necessary for the formation of eclogitic known for their production have a circular area
diamonds at great depths (Kirkley et al., 1992). which varies from 5 to 30 hectares. In South
Peridotitic diamonds, on the other hand, Africa these deposits contain an average of 20
appear to possess a more homogeneous source carats per 100 tons of extracted kimberlitic rock.
of carbon, perhaps associated with convection The core-like deposits of this rock are
zones existing in the upper parts of the mantle. grouped in well identified clusters, generally
Peridotitic carbon could be primordial (i.e. containing a certain number of diamantiferous
primary carbon), accumulated in the mantle masses which varies from 6 to 40, as is
about 4.5 billion years ago. acknowledged in certain areas of South Africa,
Siberia and Tanzania. Recent data show that
the five main deposits outcropping in the
OCCURRENCE AND GEOGRAPHIC DISTRIBUTION Kimberley area, South Africa, cover a circular
OF DIAMANTIFEROUS ROCKS area of about 10 km in diameter, while the
main cluster - which contains the most
Two fundamental factors characterize the important deposits and all the dikes
outcrops of kimberlitic and lamproitic rocks: outcropping in the sector - covers an area of
one geographic, and the other geological. The about 40 km in diameter. J an se (1984)
role of these two factors in the emplacement of suggested that the average distance between
diamond-bearing rocks was evaluated by various South African and Siberian
Clifford (1970), J an se (1984) and Dawson diamantiferous clusters is around 400 km. This
(1989). Unfortunately a greater emphasis was author has also produced some interesting
placed on the genesis of kimberlitic rocks, reports on the economically viable and non
because knowledge of these is more complete. viable masses contained in the various
It has been demonstrated that kimberlitic kimberlitic clusters, noting values varying from
rocks are widespread throughout the earth's 5 (out of 15) for the productive deposits of
crust. Appr oximately 3000 kimberlitic Kimberley, from 3 (out of 29) for those of
occurrences have been described in South Orapa in Botswana, and 1 (out of 30) for Alakit
Africa, and about 350 in North America: in Siberia. Many clusters are of course barren,
around sixty of these in the Colorado- and therefore not economically viable.
Nature, origin and age of diamonds: a state-of-the-art report 117
-------
Unfortunately, the specialized literature does cratonic zones deeply exposed to erosion. This
not provide similar data for those fact has of course led specialists to the hurried
diamantiferous deposits characterized by generalization that the sectors most favourable
lamproitic rocks. Even the discovery of the to the location of diamond-bearing kimberlites
Argyle deposit in Western Australia in 1979 has are situated in the same cratonic masses,
only partially attracted the experts' attention. considering that the barren zones are
Numerous outcrops which were previously apparently located in more remote zones
mapped as being characterized by lamproitic or distant from these. Such a theory seems in
similar rocks, such as alnojites, monchiquites fact to have been contradicted by the discovery
and lamprophyres, are currently being of diamantiferous lamproites in Argyle,
reassessed and reclassified. These studies have Australia. This deposit - which today
however led to the discovery of the Prairie represents the most productive diamond
Creek deposit (Murfreesboro) in Arkansas, bearing deposit in the world - is situated in a
U SA. In this case, the rock which was mobile belt integrated with a cratonic mass
originally recognized as a simple kimberlite has of about 1.8 billion years old.
instead proved to be a lamproite with olivine. This seems to be the demonstration that
The geographical distribution of diamantiferous deposits of great importance can
diamantiferous kimberlites is not accidental, be found not only in the commonly accepted
but in fact coincides with the oldest cratonic continental cratonic masses, but also in the
areas. Furthermore, it has been found that adjoining regions, particularly in the mobile
diamond-bearing kimberlites are not found in belts sometimes associated with these.
oceanic environments or along the more recent
mountain ranges (Clifford, 1970). It must be AGE OF INTRUSIVE PHENOMENA
remembered that the continental cratonic areas AND SPEED OF ASCENT
constitute those portions of the earth's crust
and of the upper zones of the mantle which Kimberlitic rocks have intruded the Earth's
have reached a high stability as a result of the crust from the very beginning of the geological
complete absence of deformative tectonic history of our planet. This fact is demonstrated
processes over considerably long periods of by the age of the diamantiferous conglomerates
time, particularly in the last 1.5 billion years. in Witwatersrand, South Africa, which are
In terms of production, certain cratonic
masses seem to be more productive than others. TABLE 3
The South African craton of Kaapvaal
(Kalahari), in particular, contains 7 of the 11 Geological age of some intrusions found in
most productive clusters in the world. Detailed kimberlitic provinces (modified after
studies regarding the outcropping of Dawson, 1989).
kimberlites in the main cratonic masses have Geologic age Time (My) Localities
revealed that the presence of core-like
kimberlitic masses are very common in the Eocene 50-55 Namibia, Tanzania
most recent sedimentary platforms which Upper Cretaceous 65-80 Southern Cap (south Africa)
Middle Cretaceous 80-100 Kimberley (south Africa)
almost horizontally overlie the cratonic masses
Lower Cretaceous 115-135 Angloa, west Africa, Siberia
characterized by Archean rocks more than 2.5
Upper Jurassic 145-160 Eastern north America, Siberia
billion years old. Indeed, kimberlitic provinces Devonian 340-360 Colorado-Wyoming, Siberia
located in the most deeply eroded zones of the Ordovician 440-450 Siberia
continental shields are extremely rare. The Upper Proterozoic 810 Northwest Australia
most important examples concern the cratonic Middle Proterozoic 1100-1250 Premier (south Africa), India,
about 2. 6 billion years old. The presence of The conclusions reported above do not
diamonds in these placer deposits points to the contradict the fundamental concepts commonly
existence of kimberlitic (or lamproitic) rocks accepted by the specialists. The currently
even older than the age reported. It should be accepted hypothesis is that kimberlitic and
noted that the oldest kimberlitic rocks found so lamproitic magmas are the result of the partial
far correspond to the intrusions of about 1. 6 melting of peridotitic materials whose
billion years old, in the centre of Kuruman, compositions are similar and at the same time
Cape Province, South Africa. These intrusions, distinct. These magmas appear t o have
situated in the Kaapvaal Craton, are barren. originated from deep mantle zones varying
Other kimberlitic rocks belonging to a long from 125 km to 400 km of depth. It is
intrusive phase of about 1.2 billion years have acknowledged that the magmas themselves
been found in South Africa in the Premier intruded old cratons of the earth's crust, and
Mine sector, in the state of Mali, and in India that the process of intrusion was in fact able to
(Table. 3). Further important kimberlitic operate from at least 2.6 billion years ago; what
episodes are listed in Table 3. has still to be discovered is the mechanism of
Lamproitic intrusions, on the other hand, the intrusion itself.
appear to cover a much shorter geological The fact that carbon crystals reach the
period, ranging from an age of about 1.2 billion surface in an excellent state of conservation,
years (in the Argyle Pipe) to one of about 20 and that they have not been converted into
million years (Lower Miocene) in the lamproites graphite or carbon dioxide or reabsorbed by
of Ellendale, Western Australia, situated at kimberlitic magmas during the intrusive phase,
approximately 400 kiloineters from the Argyle means that the speed of ascent was without
deposit. In the Ellendale group about 50 doubt extremely rapid. A slow ascent - or one
podiform masses were found, only a few of which entailed frequent slowing down- would
which are considered to have economic most probably lead to the complete destruction
potential. These lamproitic rocks are intmded in of diamond crystals. A classic example of
platform sediments of the Devonian and Permian diamonds reconverted to graphite is found in
ages. Some lamproites in Wyoming, the the outcrops of Beni Bouchre, in Morocco
Antarctic and other localities seem to correspond (Slodkevich, 198 3). In this case, the
to much more recent intmsive phases (about 1.0 diamond/graphite transformation has been
million years). Very little is known about the mainly attributed to the slow cooling of the
diamantiferous deposits discovered recently in magmatic masses and the slow pressure
the heart of the Canadian shield. reduction.
Taking into account also the most recent age Although it is generally accepted that
datings published within the last fifteen years kimberlitic magmas reach the earth's surface
(Smith et al., 1985), the following conclusions very rapidly, the exact speed of ascent is not
can therefore be reached: yet known; it is thought to vary between 10 and
a- Kimberlitic and lamproitic rocks can crop 30 km/hr (Eggler, 1989). These values appear
out in the same geological sectors, even if they to be fairly accurate, and it is thus possible to
belong to intmsive phases of different ages; calculate that magmas with diamond crystals
b - The majority of kimberlitic and could reach the surface iri 5 to 15 hours. This
lamproitic rocks belong to fairly recent time interval would correspond to the
intmsive phases (the last 200 million years). It minimum time necessary to transport the
should be noted, however, that certain diamonds to the surface from the zones of
intrusions of considerable importance have production, situated at the depths mentioned at
revealed ages of about 1.6 billion years (Low the base of the continental cratonic blocks. It is
Proterozoic), and possibly older than 2.6 billion evident that the speed of ascent could change
years. considerably in the last 3 or 4 km (see below).
Nature, origin and age of diamonds: a state-of-the-art report 119
In any case, the sole factor indispensable for been generated at depths exceeding those
the mechanism of ascent seems to be the considered for peridotitic diamonds.
availability of zones of crustal weakness or The diagrams proposed by Kirkley et al.
deep fractures able to extend beyond the base (1992) may also indicate that the eclogitic
of the cratonic blocks, at depths exceeding 150 rocks originated from oceanic basalts have
km. These fractures are naturally present only been transported below the continental masses
in areas which have been geologically very by subduction processes. This eclogitic
stable for long periods of time. However, the material is probably distributed throughout all
mechanism responsible for the creation of these the peridotitic lithospheric masses, given that
zones of crustal weakness and their tendency to an active subduction must have pushed
recur is still unclear: indeed, repeated portions of basaltic crust below the continents
kimberlitic intrusions can take place over long for millions of years. The most significant zone
geological periods in the same geological is that situated between the 900 and 1200
sectors, and even within the same isotherms. This zone is further restricted by the
diamantiferous deposits. Eggler ( 1989), graphite-diamond equilibrium curve (i . e .
Dawson (1989) and Mitchell (1986) have central zone), which represents an area i n
proposed some solutions to the problem, which physical-chemical conditions are
suggesting that there migth have been crack favourable to the preservation of diamonds. A
propagation (Anderson, 1979) caused by the kimberlitic diatreme, like that denoted as K1, is
intrusions themselves during the ascent of ideally situated in the thickest part of the
magmas, as well as rapid lithospheric craton; it should therefore contain diamonds,
deformation mainly due to movement of the provided that the speed of ascent was
crustal plates. favourable. Analogously, the kimberlitic
diatreme K2 would be rich in diamonds only if
the geothermal gradient - found at the base of
SAMPLING OF THE MANTLE
the cratonic block- did not exceed 1200C, at
AND TRANSPORT TO SURFACE
a depth of 175-250 km.
In a discussion of the sampling of diamonds On the contrary, the diatreme K3 should be
and their transport from the upper part of the barren, as it is situated in zones marginal to the
mantle to the earth's crust, the genetic models cratonic mass. An exception to the rule would
published in the specialized literature must be be represented by the lamproitic deposits of
taken into account. Particular reference shall be Argyle and Ellendale, situated in zones which
made to those originally proposed by Haggerty are marginal to the cratonic masses, but
(1986), Eggler (1989), Wyllie (1989), and nevertheless belonging to the mobile belts. In
Kirkley et al. (1992) an attempt to explain the presence of diamonds
These authors have pointed out that in all in these deposits, Haggerty (1986) suggested
cratonic areas the geothermal gradients are sampling in appropriate zones of the mantle
relatively low in comparison with the oceanic mainly characterized by a complex system of
zones of the planet. For this reason, the deep fractures, probably interconnected each
isothermal lines tend to show a curvilinear other (i.e. lamproitic diatreme L l ).
configuration, concave towards the bottom
(Kirkley et al., 1992). On the other hand, MORPHOLOGICAL CONFIGURATION OF DIATREMES
according to Kirkley et al. (1992), when the
equilibrium curve between graphite and The term diatreme is generally attributed
diamond is compared with a cratonic section, a to sub-volcanic cuneiform pipes filled with
curve is obtained with a convex tendency brecciated material and emplaced by violent
towards the top. Hence a debatable hypothesis gaseous explosions. As it has such a general
may suggest that eclogitic diamonds must have meaning, this term can be attributed to rocky
120 V. FERRINI and G. SASSANO
U.S.S.R.
ZIMBABWE
ZARNITSA
ZAIRE 2229 B2/K2
MASSIF LETHLAKANE ......
ft K9
V._ LESOTHO
SWAZILAND UDATCHNAYA
WEST END
FINSCH
_ .
KIMBERLEY
.... PREMIER U.S.A. ..
..
MlR
(BIG HOLE) '33 HA. I
BATTY CLAIM "'6 HA.
JAGERSFONTEIN PRAIRIE CREEK DALNAYA
masses of various types, in different geological diatremes, especially those concerning the
situations (i.e. basalt diatreme). However, the kimberlite masses in South Africa, show a
set of geological characteristics which make up fairly regular mass, with core-like or cuneiform
the diamantiferous diatremes seem to be morphology, with the acute tip terminating
attributable exclusively to kimberlitic or very rapidly towards the bottom. The advent of
lamproitic diatremes, both for the incredible new mining techniques and the need to increase
depth at which these formations originate, and production in depth have led to the discovery
for the considerable quantity of gas they of geological features which are extremely
contain and/or emit. important for an understanding of the
The main geological characteristics of mechanism of intrusion in the including rocks.
kimberlitic or lamproitic diatremes In particular, it has been observed that the
(Hawthorne, 1975), although some are possibly central part (the so-called Principal
common to all types, are as follows: Diatreme) is c haracterized by strongly
(a) the specific morphology of the brecciated kimberlitic rocks which do not
mineralized masses (fig. 3), appear to have metamorphosed the including
(b) the subdivision into three distinct zones rocks of the volcanic chimneys or the
(roots, main diatreme and crater) which xenolithic masses contained in the kimberlites.
constitute the main body of the deposit (fig. 4). Lastly, certain surface characteristics appear
The classic representations of diamantiferous to be essential in the description of a
Nature, origin and age of diamonds: a state-of-the-art report 121
This violent degassing phenomenon can be Bellsbank), all cretaceous in age, present
compared to a sudden subterranean explosion. greatly differing levels of erosion.
This results in a typical kimberlitic mass Consequently, the Bellsbank mine has very
characterized by a high speed of ascent limited economic potential, as almost all of the
(probably about 100 km per hour) and a highly mineralized part belonging to the crater and
fluid mixture composed of solidified blocks, main diatreme has already been removed by
magmatic liquids and gases of various nature, surface erosion. The Orapa mine, on the other
which is able to perforate the final 2 or 3 km of hand, has preserved intact nearly all of the
the earth's crust. This fluidized mass is further main diatreme to a depth of about 2,000 m, so
able to crush any crystallized kimberlitic that production can be guaranteed for at least
masses present in the typical cuneiform or another hundred years.
core-like eruption vent. Finally, the kimberlitic
magma rapidly crystallizing as a result of the
THE DISCOVERY OF DIAMONDS IN CANADA
lowered temperature and pressure - cannot
produce thermic reactions of contact with the Several exploration attempts have been made
including rocks or the xenoliths contained in the last thirty years to discover diamonds in
inside them. Canada. Brummel (1984) has, for instance,
Any diamonds present in the eruptive mass reconsidered the question of the presence of
are therefore not converted into graphite, since diamonds in the glacial moraines of Ontario
the temperature at this stage is low enough to and in the regions of the Great Lakes in the
allow their survival . USA. The author has again examined all the
The crater zone occupies the highest part of available data on known occurrences of
the deposit. It generally extends to about 300 m diamonds in Canada, concentrating his
in depth, and is characterized by a mixture of attention on the outcroppings in Ile Bizard
rock fragments, tuffs, lapilli and pyroclastic (Montreal, Quebec) and those of Somerset
material. On the surface this zone takes on Island (N.W.T., Canada). Both these deposits
circular morphological features as a result of contain microscopical diamonds, but are not
the presence of the tuffaceous ring; in many economically viable. Since 1988 further
cases a lake or maar is present. It is to be noted kimberlitic deposits have been found near
that only a few rare examples of kimberlitic Prince Albert and at Fort a la Corne,
volcanoes are known to exist: in Tanzania, Saskatchewan (Lehnert-Thiel et al., 1992). The
Mali and Botswana. In certain cases kimberlitic two most interesting discovery - perhaps the
volcanoes consist of low-relief craters. most promising from an economic point of
Fig. 4 shows that the distance between the view - are the BHP Koala Camp, owned by
highest part of the crater and the base of the Dia Met Minerals (i.e. Lac de Gras, 350 km
main diatreme is about 2,300 m. Considering northeast of Yellowknife, N. W.T.) and the
the local geomorphological and topographical Snap Lake property (same district) owned by
characteristics and an average speed of erosion Winspeare Resources Ltd. Oif Vancouver. The
equivalent to one metre every 30,000 years, it Koala Camp discovery was made thanks to the
can be easily foreseen that the majority of prospector Chuck Fipke and John Gurney, and
known kimberlitic diatremes are eroded as far it is probably destined for economic production
as the root level in about 70 million years. in the near future, considering that around 30%
During this period of time, the diamonds of diamonds found in surveys have proved to
contained in the including rock will be freed be of gemological value.
and deposited in ore bodies of fluvial gravels or This discovery, which is now a producing
sandy littoral deposits (i.e. placers). It is mine, was made possible mainly as a result of
noteworthy that some mines in South Africa geochemical sampling techniques (fig. 5)
(i.e. Orapa, Jagerfontein, Kimberley and which utilize marker minerals such as garnet
Nature, origin and age of diamonds: a state-of-the-art report 1 23
MgO
10
12
7 9
11
.a
FeO cao
Fig. 5 - Average chemical composition of pyrope-type garnets, based on the classification method proposed by Dawson
and Stephens ( 1975, 1976).
G10, poor in Ca (ea. 4%) and rich in Cr and Ontario, and secondly, it would indicate for the
Mg, and chromite, which is exceptionally rich first time the presence of diamonds in lamproitic
in Cr, generally exceeding 62.5% (Dawson and rocks in territories of the Canadian shield.
Stephens, 1975, 1976 Griffin et al., 1991 Finally, the most exciting discovery to date,
Gent, 1992). Another geochemical marker is has been made in the Snap Lake area, Camsel
represented by ilmenite, which - although not Lake district, N. W. T. , owned by Winspear
always present in the stability field typical of Resources Ltd. of Vancouver, B.C. The results
diamonds - seems nevertheless to play an of the recently completed drilling program
important genetic role. Indeed, it has been have indicated the extend of a potentially
observed that, when the iron in ilmenite is mineable hypoabyssal kimberlite dike system
highly oxidized, the diamantiferous diatremes hosted in precambrian granitic material.
are barren (Gurney, 1984, 1989). This fact Notably, su- b stantial amounts of kimberlite
appears to be directly proportional to the carrying abundant macro and micro diamonds,
temperature conditions and the quantity of underlie the north shore of Snap Lake ( J.A.
oxygen present in the kimberlitic magma. The McDonald, personal communication, 1998).
oxidization of iron in ilmenite thus appears to Considering the gentle dip of the structure,
be a good criteri0n for assessing the persistence the easy acces to eventual open pit operations,
of diamonds in the kimberlitic magma. Indeed, the exceptional grades, beauty and weight of
it seems certain that the fugacity of oxygen in the stones found during bulk sampling, the
the ascending magma induces vaporization Snap Lake property seems to shape up as the
of the carbon minerals, transforming them true diamond mine in Canada.
automatically into C02 or CO. The interest shown by various mining
Another group of diamantiferous companies is therefore justified: the majority of
outcroppings has recently come to light in an Canadian territories consist of areas belonging
area situated on the border between Ontario and to the immense North American craton which,
Quebec, almost below the southernmost tip of i n certain zones ( Superior and Slave
Hudson Bay. This is a significant finding for provinces), is ideally characterized by very
two reasons: firstly, it would constitute at last a ancient rocks (i.e. Arch eo zoic), and hence
logical explanation for the discovery of theoretically suited to containing economically
diamonds in the glacial moraines of southern viable quantities of diamonds.
1 24 V. FERRINI and G. SASSANO
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