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J
J
B
B
I

G
GGSIPU chemistry 2012 I

G
D
1. Which of the following compound is found most abundantly in nature? D
E
E
A
a Fructose b Glucose
A
L
c Starch d Cellulose L

J
2. Gabriel synthesis is used for synthesis of J

B B

I
a primary amines b secondary amines
I

G
c aldehydes d acids G

D D

E
3. Glycerol is
E

A
a 1,3 -dihydroxy propane A

L L
b 2,3 -digydroxy propanone
J J
c 2,3 -dihydroxy propane B
B

I
I d 1,2,3 -propane triol
G G
4. Propanal on reaction with dilute sodium hydroxide forms D
D

E a CH 3CH2CH2CH2CH2CHO E

A A
b CH 3CH2CHOH) CH2CH2CHO
L L

J c CH 3CH2CH2CH(OH)CH2CHO J

B
B
d CH 3CH2CH(OH)CH(CH3CHO
I
I

G 5. Complete combustion of 0.858 g of compound X gives 2.63 g of CO2 and 1.28 g of H2O.The lowest G

D
molecular weight which X can have, is D

E
E a 43 g b 86 g
A
A
c 129 g d 172 g L
L

J
J 6. What structural feature distinguishes glycine form other natural a-aminoacids?
B
B
a It is optically inactive I
I
G
G b it contains aromatic group
D
D
c It is a dicarboxylic acid E
E
A
A
L
L

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J
B
B
I d It has a secondary amine I
G
G
7. Soft drink and baby feeding bottles are generally made up of
D
D
E a polyester b polyurethane E
A
A
c polyurea d polystyrene
L
L
8. The product formed in the following reaction is CH3CH(CH3CH = CH2+HBr
J J

B product B

I I
a CH 3 2CHCH(BrCH 3
G G
b CH 3 2CHCH2CH2Br
D
c CH 3 2CBrCH 2CH3 D

E
d CH3CH(CH3CHBrCH 2CH3 E

A A

L
9. How many isomers can C5H12 have?
L

a 3 b 2 J
J

B
B c 4 d 5
I I
10. Which amino acid is achiral? G
G

D a Alanine b valine D

E E
c Proline d Glycine
A A

L 11. When propyne is treated with dilute sulphuric acid in presence of mercury II sulphate, the major L

J
product is J

B
B
a acetone b propene
I
I

G
c propanol d propanal G

D
D 12. Reduction of carbonyl compounds with hydrazine in presence of strong base is called
E
E
a Cannizaros reaction A
A
L
L b Clemmensens reduction
J
J
c Wolf f-Kishner reduction B
B
I
I d Meerwein -Pondorf reduction
G
G
13. Which of the following is the most stable form of cyclohexane? D
D
E
E
a Boat b Planar
A
A
L
L

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J
J
B
B
I c twist boat d Chair I
G
G
14. What kind of bonding is responsible for the secondary structure of proteins
D
D
E a Covalent bonding E
A
A
b Hydrogen bonding
L
L
c Ionic bonding
J J

B d van der Waals forces B

I I
15. The beta and alpha glucose have different specific rotations. When either is dissolved in water,
G G
their rotation changes until the same fixed value results. This is called
D D

E a epimerization b racemization E

A
c anomerization d mutarotation A

L L
1. BH3/THF
16. The product of following reaction is
J J
2. H2O2/OH-

B B

I I
a pentanol b 2 -pentanol
G G

D
c pentane d 1,2 -pentan-di-ol D

E E
17. Streptomycin is used as :
A A

L
a antipyretic b mordant L

J
J c antibiotic d a ntihistamine
B
B
18. Which one of the following will be most basic ? I
I
G
G a Aniline b p -methoxyaniline
D
D
c p -nitroaniline d Benzylamine E
E

A 19. Which of the following will exhibit highest boiling point? A

L
L
a CH 3CH2OCH2CH3
J
J
b CH 3CH2CH2CH2CH2OH B
B
I
I c CH 3CH2CH2CH(CH3OH
G
G
d CH 3CH2CCH 3 2OH D
D
E
E 20. Geomatrical isomerism is possible in case of
A
A
L
L

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J
J
B
B
I a 2 -butyne b 1 -butene I
G
G
c propene d 2 -butene
D
D
E 21. n-butyl benzene on oxidation will give E
A
A
a benzoic acid b butanoic acid
L
L
c benzyl alcohol d benzaldehyde
J J
2 2 6 2 6 10 1
B 22. The element with electronic configuration of its atom 1s ,2s ,2p ,3s ,3p ,3d ,4s is B

I I
a fe b Co c Ni d Cu
G G

D 23. According to Bohrs theory the energy required for the transition of H atom from n = 6 to n=8 D

E state is E

A
a equal to the energy required for the transition from n=5 to n=7 state A

L L
b larger than in A
J J

B c less than in A B

I I
d equal to the energy required for the transition from n=7 to n=9 state
G G

D
24. The dimensions of viscosity coefficient are D

E -1 -1 -1 E
a ML T b MLT
A A
-1
L
c ML T d MLT L

J
J 25. In the chemical reaction 2SO2+O2 2SO3 increasing the total pressure leads to
B
B
a increase in amount of SO3 I
I
G
G b increase in partial pressure of O 2
D
D
c increase in the partial pressure of SO 2
E
E

A d change in equilibrium constent A

L
L
26. A 4p-orbital has
J
J
a one node b two nodes B
B
I
I c three nodes d four nodes
G
G
27. At the triple point of water the number of phases in equilibrium are D
D
E
E a zero b one
A
A
L
L

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B
B
I c two d three I
G
G
28. The emf of a daniell cell at 298 K is E1 Zn/ZnSO4 0.01 || CuSO4 1.0 M | Cu When the
D
concentration of ZnSO4 is 1.0 M and that of CuSO4 is 0.01 M.The emf changed to E2. Whatv is the D
E
relation between E1 and E2? E
A
A
L a E 1=E2 b E 2=0 E1
L

J c E1>E2 d E 1<E2 J

B B
29. The correct order of ionization is
I I

G a Zn<Cd< Hg G

D D
b Na<Rb<Cs
E E

A c Rb<Cs<Na A

L
d Cs<Rb<Na L

J J
30. The structure of CH2 = CH2 is
B B

I
a linear I

G G
b planar
D D

E
c non -planar E

A A
d has resonance structure
L L
31. The hybridization of xenon in XeF2 is J
J
3 2 B
B a sp b sp
I
I
c sp 3d d sp2d G
G

D 32. The reagent commonly used to determine hardness of water titrimetrically is D

E
E
a oxalic acid
A
A

L b sodium citrate L

J
J c disodium salt of EDTA
B
B
d sodium carbonate I
I
G
G 33. 0.01 N solution of KCL and BaCL2 are prepared in water. The freezing points of KCL is found to be -
D
D 2 0C. What is the freezing point of BaCL2 solution assuming both KCL and BaCL2 to be completely
E
E ionized?
A
A
L
L

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J
B
B
I a -3 0C b +3 0
C I
G
G
c -2 0C d -4 0C
D
D
E 34. 45 g of ethylene glycol is mixed with 600 g of water. What is the freezing point of the solution? k f E
A = 1.86 K kg mol-1
A
L
a - 270.90 K L

J J
b 270.90 K
B B

I c 273 K I

G G
d 274.15 K
D D

E 35. Which of the following used as a preservative for biological specimens E

A
a Acetic acid A

L L
b Chloroform
J J

B c Formalin B

I I
d Formic acid
G G

D
36. The charge required to deposit 9 g of AL from an AL 3+ solution is D

E E
a 32166.3 C b 96500 C
A A

L
c 3216.33 C d 9650 C L

J
J 37. A compound formed by elements A and B crystallizes in the cubic arrangement in which A atoms
B are at the corners of a cube and B atoms are at the face centers. What is the formula of compound? B

I
I
a AB 3 b B 3A
G
G

D c A 2B2 d AB 2
D

E
E
38. What is the pH value of M H2SO4?
A
A

L a zero b One L

J
J c 2 d -0.3010
B
B
39. F2C = CF2 is a monomer of I
I
G
G a glyptal b Teflon
D
D
c orlon d buna -S E
E
A
A
L
L

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B
B
I 40. To an Ag2CrO4 solution over its own precipitate,CrO42- ions are added. This results in I
G
+ G
a increase in Ag concentration
D
D
E b decrease in concentration E
A
A
c increase in the solubility product
L
L
d decrease in the solubility product
J J

B 41. For a first order reaction, to obtain a positive slope,we need to plot {[A] is the concentration of B

I reactant A} I

G G
a log 10[A] vs t
D D

E b -loge[A] vs t E

A
c log 10 [A] vs log t A

L L
d [A] vs t
J J

B 42. The species A in the reaction is B

I 236 I
92U 54Xe144 + 38Sr90 + A
G G
1 1
D
a 1H b 0n D

E 1 1 E
c 0n d 2 0n
A A

L
43. In Brownian movement or motion, the paths of the particle are L

J
J a linear b zig -zag
B
B
c uncertain d curved I
I
G
G 44. The heats of adsorption in physisorption or physical adsorption lie in the range of in kj/mol
D
D
a 40 -400 b 40 -100 E
E

A c 10 -40 d 200 -400 A

L
L
45. The reaction 2H2O2 2H2O+O2 is
J
J
a a redox reaction B
B
I
I b a hydrolysis reaction
G
G
c a solvolysis reaction D
D
E
E d disproportionation
A
A
L
L

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J
J
B
B
I 46. The most abundant element in the earths crust by weight is I
G
G
a Si b AL c O d Fe
D
D
E 47. The most electropositive metals are isolated from their ores by E
A
A
a high temperature reduction with carbon
L
L
b self -reduction
J J

B c thermal decomposition B

I I
d electrolysis of fused ionicsalts
G G

D 48. The reaction of slaked lime with CL2 gas gives D

E E
a only CaOCL 2
A A

L b only CaCL2 L

J c a mixture of CaOCL 2,CaOH 2,CaCL2 and H2O J

B B
d quick lime
I I

G 49. The nitride saltr of Ca when treated with H2O gives G

D D
a N 2 b CaO
E E

A c CaH 2 d NH 3 A

L L
50. Correct formula of the comp[lex formed in the brown ring test for nitrates is
J
J
a FeSO 4NO B
B
2+ I
I b [FeH 2O 5NO]
G
G
+
c [FeH 2O 5NO] D
D
3 E
E d [FeH 2O 5NO]
A
A
L
L

J
J
B
B
I
I
G
G
D
D
E
E
A
A
L
L

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