TRNG I HC VINH THI TH THPT QUC GIA LN 1

TRNG THPT CHUYN Bi thi: Khoa hc t nhin; Mn: HA HC

Thi gian lm bi: 50 pht, khng k thi gian pht
( thi gm 40 cu)
M : 132

H, tn th sinh:___________________________________________S bo danh:__________________

Cho bit nguyn t khi ca cc nguyn t :

H =1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S =32; Cl = 35,5; K = 39; Ca = 40; Cr = 52;
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.

Cu 1: Thc hin cc th nghim sau:

(1) Cho kim loi Fe nguyn cht vo dung dch CuSO4.
(2) Cho l kim loi Al nguyn cht vo dung dch HNO3 c ngui.
(3) t dy kim loi Mg nguyn cht trong kh Cl2.
(4) Cho l hp kim Fe Cu vo dung dch H2SO4 long.
S th nghim xy ra phn ng n mn l
A. 4.
B. 3.
C. 2.
D. 1.
Cu 2: Hnh v sau y m t th nghim kh X tc dng vi cht rn Y, nung nng v sinh ra kh Z:

Cu + H2O
o
t
A. CuO + H2
B. Fe2O3 + 3H2 2Fe + 3H2O
to
B.
CuO + CO Cu + CO2
o
t
C.
2HCl + CaCO3 CaCl2 + CO2 + H2O
to
D.
Cu 3: Khi thy phn hon ton mt triglixerit X trong mi trng axit thu c hn hp sn phm gm glixerol,
axit panmitic v axit oleic. S cng thc cu to X tha mn tnh cht trn l
A. 8.
B. 4.
C. 2.
D. 6.
Cu 4: Este CH2=CHCOOCH3 khng tc dng vi cht (hoc dung dch) no sau y?
A. Dung dch NaOH, un nng.
B. H2O. (xc tc H2SO4 long, un nng)
C. Kim loi Na.
D. H2. (xc tc Ni, nung nng)
Cu 5: Cho 4,05 gam bt Al tc dng vi V lt kh O2 thu c hn hp rn X. Cho X tc dng vi lng d dung
dch NaOH, sinh ra 1,68 lt H2 (ktc). Bit cc phn ng xy ra hon ton. Gi tr V l
A. 1,68.
B. 3,36.

1
 C. 6,72.
D. 1,26.
Cu 6: Cho mu nc cng c cha cc ion: Ca2+, Mg2+, Cl-, SO42- . Ha cht c dng lm mm mu nc
cng trn l
A. BaCl2.
B. NaCl.
C. AgNO3.
D. Na3PO4.
Cu 7: Pht biu no sau y l sai?
A. Kim loi cesi dng ch to t bo quang in.
B. Cng thc ha hc ca phn chua l (NH4)2SO4.Al2(SO4)3.24H2O.
C. Cc kim loi Na v Ba u c cu to mng tinh th lp phng tm khi.
D. Thch cao sng dng sn xut xi mng.
Cu 8: Pht biu no sau y l sai?
A. Tinh bt l lng thc ca con ngi.
B. Xenluloz v tinh bt c phn t khi bng nhau.
C. Thnh phn chnh ca si bng, g, na l xenluloz.
D. Khi cho gim n (hoc chanh) vo sa b hoc sa u nnh th c kt ta xut hin.
Cu 9: S ng phn cu to l tetrapeptit c cng cng thc phn t C9H16N4O5 l
A. 2.
B. 1.
C. 3.
D. 4.
Cu 10: Phn trm khi lng ca nguyn t cacbon trong phn t anilin (C6H5NH2) l
A. 78,26%.
B. 77,42%.
C. 75,00%.
D. 83,72%.
Cu 11: Metylamin khng phn ng vi
A. Dung dch H2SO4.
B. Dung dch HCl.
C. H2. (nung nng, xc tc Ni)
D. O2. (nung nng)
Cu 12: Cho 9 gam C2H5NH2 tc dng va vi dung dch HCl, khi lng mui thu c l
A. 16,10 gam.
B. 12,63 gam.
C. 12,65 gam.
D. 16,30 gam.
Cu 13: Kim loi no sau y khng phn ng vi dung dch CuSO4?
A. Ag.
B. Al.
C. Fe.
D. Zn.
Cu 14: Cho m gam axit glutamic (HOOC[CH2]2CH(NH2) COOH) tc dng va vi 300 ml dung dch
KOH 1M. Gi tr ca m l
A. 43,80.
B. 21,90.
C. 44,10.
D. 22,05.
Cu 15: Este no sau y khi tc dng vi dung dch NaOH un nng, thu c hn hp sn phm gm
CH3COONa v CH3CHO?

2
 A. CH2=COOCH3.
B. CH3COOCH=CH2.
C. HCOOCH=CH2.
D. CH3COOCH=CHCH3.
Cu 16: Cng thc phn t ca tristearin l
A. C57H104O6.
B. C54H104O6.
C. C54H98O6.
D. C57H110O6.
Cu 17: S ng phn amin c cng cng thc phn t C3H9N l
A. 1.
B. 4.
C. 2.
D. 3.
Cu 18: Thnh phn chnh ca vi l
A. CaCO3.
B. BaCO3.
C. MgCO3.
D. FeCO3.
Cu 19: Cho m gam kim loi Ba vo nc d, sau phn ng thu c 4,48 lt H2 (ktc). Gi tr m l
A. 13,70.
B. 27,40.
C. 54,80.
D. 20,55.
Cu 20: Polime c iu ch bng phn ng trng hp l
A. poliacrilonitrin.
B. poli(etylentetrephtalat).
C. nilon6,6.
D. xenluloz triaxetat.
Cu 21: Kim loi no sau y l kim loi kim th?
A. Na.
B. Ca.
C. Fe.
D. Al.
Cu 22: Cho 0,15 mol bt Fe tc dng vi 0,15 mol Cl2, nung nng. Phn ng xy ra hon ton, thu c m gam
mui. Gi tr m l
A. 16,250.
B. 19,050.
C. 12,700.
D. 8,125.
Cu 23: Cho dy cc kim loi Fe, Cu, Mg, Ag, Al, Na, Ba. S kim loi trong dy phn ng c vi dung dch
HCl l
A. 4.
B. 3.
C. 6.
D. 5.
Cu 24: Phn ng ha hc no sau y l sai?
A. 2NaHCO3 Na2CO3 + CO2 + H2O
to

B. NaHCO3 + NaOH Na2CO3 + H2O

C. 2Li + 2HCl 2LiCl + H2

3
 2MgO
o
t
D. 2Mg + O2

Cu 25: Trong qu trnh in phn dung dch NaCl (in cc tr, c mng ngn), cc m (catot) xy ra
A. s oxi ha cation Na+.
B. s oxi ha phn t H2O.
C. s kh phn t H2O.
D. s kh cation Na+.
Cu 26: Mt hc sinh tin hnh nghin cu dung dch X ng trong l khng dn nhn th thu c kt qu sau:
- X u c phn ng vi dung dch NaOH v dung dch Na2CO3.
- X u khng phn ng vi dung dch HCl v dung dch HNO3.
Vy dung dch X l dung dch no sau y?
A. Dung dch KOH.
B. Dung dch AgNO3.
C. Dung dch Ba(HCO3)2.
D. Dung dch MgCl2.
Cu 27: Cho 0,1 mol bt Fe tc dng vi lng d dung dch H2SO4 c, nng. Sau khi phn ng xy ra hon
ton, thu c dung dch X v V lt kh SO2 (sn phm kh duy nht, ktc). Gi tr ca V l
A. 6,72.
B. 2,24.
C. 3,36.
D. 4,48.
Cu 28: Cho 0,2 mol bt Fe phn ng ht vi dung dch X cha ng thi Cu(NO3)2 v a mol Fe(NO3)3, thu c
dung dch Y c khi lng bng khi lng dung dch X ban u (gi thit nc bay hi khng ng k). Gi tr
ca a l
A. 0,10.
B. 0,15.
C. 0,05.
D. 0,02.
Cu 29: Cho 0,2 mol hn hp X gm phenylamoni clorua (C6H5NH3Cl), anilin (CH3CH(NH2)COOH) v glyxin
(H2NCH2COOH) tc dng vi 300 ml dung dch H2SO4 nng a mol/lt (long), thu c dung dch Y. Dung
dch Y tc dng va vi 500 ml dung dch NaOH 1M. Gi tr ca a l
A. 2,0.
B. 0,5.
C. 1,5.
D. 1,0.
Cu 30: Kt qu th nghim ca cc dung dch X, Y, Z, T vi thuc th c ghi bng sau:

Mu th Thuc th Hin tng

X Qu tm Qu tm chuyn mu xanh
Y Nc brom Kt ta mu trng
Z Dung dch AgNO3 trong NH3 Kt ta Ag trng sng
T Cu(OH)2 Dung dch c mu xanh lam
Cc dung dch X, Y, Z, T ln lt l
A. Natri stearat, anilin, mantoz, saccaroz.
B. Natri stearat, anilin, saccaroz, mantoz.
C. Anilin, natri stearat, saccaroz, mantoz.
D. Anilin, natri stearat, mantoz, saccaroz.
Cu 31: Hn hp M gm amino axit X (no, mch h, phn t ch cha 1 nhm COOH v 1 nhm NH2) v este
Y to bi X v C2H5OH. t chy hon ton m gam M bng mt lng O2 va , thu c N2; 12,32 lt CO2
(ktc) v 11,15 gam H2O. Gi tr m l
A. 11,30.
B. 12,35.
C. 14,75.

4
 D. 12,65.
Cu 32: t chy hon ton hn hp gm CH C-CH=CHCH2NH2 v (CH3)2CHCH(NH2)COOH cn dng x
mol O2 (va ), ch thu c N2, H2O v 4,48 lt CO2 (ktc). Gi tr ca x l
A. 0,270.
B. 1,350.
C. 0,540.
D. 0,108.
Cu 33: Hp cht X c cng thc phn t C10H8O4. T X thc hin cc phn ng (theo ng t l mol):
C10H8O4 + 2NaOH X1 + X2
2 H O,t o

X1 + 2HCl X3 + 2NaCl
nX3 + nX2 Poli(etylen-tetrephtalat) + 2nH2O
to

Pht biu no sau y l sai?

A. S nguyn t H trong X3 bng 8.
B. Dung dch X2 ha tan Cu(OH)2 to dung dch phc cht c mu xanh lam.
C. Dung dch X3 c th lm qu tm chuyn mu hng.
D. Nhit nng chy ca X1 cao hn X3.
Cu 34: Thc hin cc th nghim sau:
(1) Cho kim loi K vo dung dch HCl.
(2) t bt Al trong kh Cl2.
(3) Cho Na2CO3 vo dung dch AlCl3.
(4) Cho NaOH vo dung dch Mg(NO3)2.
(5) in phn nng chy Al2O3, c mt Na3AlF6.
S th nghim c phn ng oxi ha kh xy ra l
A. 2.
B. 1.
C. 3.
D. 4.
Cu 35: Ha tan hon ton m gam hn hp X gm Ba, BaO, Al v Al2O3 vo nc d, thu c dung dch Y v
5,6 lt H2 (ktc). Nh t t n d dung dch HCl 1M vo dung dch Y. th biu din s ph thuc khi lng
kt ta Al(OH)3 theo th tch dung dch HCl 1M nh sau:

Gi tr ca m l
A. 47,15.
B. 56,75.
C. 99,00.
D. 49,55.
Cu 36: Cho dy cc cht: tinh bt, protein, vinyl fomat, anilin v mantoz. Pht biu no sau y ng khi ni v
cc cht trong dy trn?
A. C 3 cht b thy phn trong dung dch H2SO4 long, nng.
B. C 2 cht tham gia phn ng trng bc.
C. C 1 cht lm mt mu nc brom.

5
 D. C 2 cht c tnh lng tnh.
Cu 37: Cho hn hp X gm 0,12 mol CuO; 0,1 mol Mg v 0,05 mol Al2O3 tan hon ton trong dung dch cha
ng thi 0,15 mol H2SO4 (long) v 0,55 mol HCl, thu c dung dch Y v kh H2. Nh t t dung dch hn hp
Ba(OH)2 0,1M v NaOH 0,6M vo dung dch Y n khi thu c khi lng kt ta ln nht, lc kt ta em
nung n khi lng khng i, thu c m gam rn khan. Gi tr ca m gn nht vi gi tr no sau y?
A. 52,52.
B. 48,54.
C. 43,45.
D. 38,72.
Cu 38: Ha ton hon ton 16,4 gam hn hp X gm FeO, Fe3O4 v Cu ( trong FeO chim 1/3 tng s mol
hn hp X) trong dung dch cha NaNO3 v HCl, thu c dung dch Y ch cha cc mui clorua v 0,896 lt NO
(sn phm kh duy nht ca N+5, ktc). Mt khc, ha tan hon ton 16,4 gam hn hp X trn trong dung dch HCl
thu c dung dch Z ch cha 3 mui c tng khi lng 29,6 gam. Trn dung dch Y vi dung dch Z thu c
dung dch T. Cho dung dch AgNO3 ti d vo dung dch T thu c m gam kt ta. Biu cc phn ng u xy ra
hon ton. Gi tr m gn nht gi tr no sau y?
A. 196,35.
B. 111,27.
C. 160,71.
D. 180,15.
Cu 39: Hn hp M gm 4 peptit X, Y, Z, T (u mch h) ch to ra t cc -amino axit c dng
H2NCnH2nCOOH (n 2). t chy hon ton 26,05 gam M, ri cho ton b sn phm chy (ch gm CO2, H2O v
N2) vo bnh ng 800 ml dung dch Ba(OH)2 1M, sau khi cc phn ng xy ra hon ton thy ch c 3,248 lt
(ktc) mt cht kh duy nht thot ra v thu c dung dch E (cha mui axit) c khi lng gim m gam so vi
khi lng dung dch Ba(OH)2 ban u. Gi tr ca m gn vi gi tr no nht sau y?
A. 90.
B. 88.
C. 87.
D. 89.
Cu 40: un nng 21,9 gam este n chc X vi lng d dung dch NaOH th c ti a 12 gam NaOH phn ng.
Mt khc, t chy hon ton m gam X trn cn dng va 42,56 lt O2 (ktc). Gi tr ca m l
A. 26,28.
B. 43,80.
C. 58,40.
D. 29,20.
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