P(kpa) T(K) Pc(kpa) Tc(K) R A B a b W f(Z) Z MW kg/m3 V=ZRT/P

25000 300.00 4487.4 248.7569 8.3145 1.5933911 0.3594005 396.54928 0.0358588 0.062815 0.00000 0.7246252 27.5618 381.222 0.0722988

Calculate Z follow Peng Robinson Equation

Z^3-(1-B)Z^2+(A-2B-3B^2)Z-(AB-B^2-B^3)=0
A=a*P/(R^2T^2)
B=bP/R/T
a=0,45724R^2Tc^2/Pc* ^0,5=1+m(1-Tr^0,5)
b=0,0778RTc/Pc m=0,37464+1,54226W-0,26992W^2
Note: Z is true if F(Z)=0 Tr=T/Tc

Tci(k) Pci(kpa) yi MWi Mwi*yi Mw Pci*yi Tci*yi Pc(kpa) Tc(K) wi yi*wi W

27.5618 4487.4 248.7569 0.062815
C1 190.56 4599 0.7 16.043 11.2301 3219.3 133.392 0.0104 0.00728
C2 305.41 4800 0.1 30.07 3.007 480 30.541 0.0979 0.00979
C3 369.77 4240 0.05 44.097 2.20485 212 18.4885 0.1522 0.00761
iC4 407.82 3640 0.03 58.123 1.74369 109.2 12.2346 0.1852 0.005556
nC4 425.1 3784 0.02 58.123 1.16246 75.68 8.502 0.1995 0.00399
iC5 460.35 3381 0.01 72.15 0.7215 33.81 4.6035 0.228 0.00228
nC5 469.65 3365 0.01 72.15 0.7215 33.65 4.6965 0.2514 0.002514
nC6 506.4 3030 0.01 86.117 0.86117 30.3 5.064 0.2994 0.002994
nC7 539.2 2740 0.01 100.204 1.00204 27.4 5.392 0.3494 0.003494
nC8 568.4 2490 0.01 114.132 1.14132 24.9 5.684 0.3977 0.003977
nC9 594.7 2280 0.01 128.258 1.28258 22.8 5.947 0.4445 0.004445
nC10 617.7 2100 0.01 142.258 1.42258 21 6.177 0.4898 0.004898
CO2 304.11 7374 0.01 44.01 0.4401 73.74 3.0411 0.2667 0.002667
H2S 373.37 8963 0.01 34.082 0.34082 89.63 3.7337 0.0948 0.000948
N2 126 3399 0.01 28.0134 0.280134 33.99 1.26 0.0372 0.000372
H2O 647 22118 0 18 0 0 0 0.3443 0
Total 1 27.5618 4487.4 248.7569 0.062815

Solution is obtained by Goal Seek(see under Tools dropdown menu) by setting the value of the cell K2 at zero while changing cell L2

363035672.xls