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    CSIR Net Notes

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    CSIR Net Notes

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
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    20 views128 pages

    EMT PastProblems 2016 CarerEndavour

    Uploaded by

    Swashy Yadav
    CSIR Net Notes

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
    of 128
    ‘able dare ids 28, The set of eigenfunctions PE (yexsa,n=1,2,3,0) is x oy 8 @X>Z>¥ — @Y>Xoz @Y>u>X Xo Yar 19, The major product P of the following acceptable wave function for bound J bon? P system, because 7 ' ot" off NN, Sores , ” m D 2 Anong ‘emt i. iT on 6 pow oh © LEN oe of 21, Areston flaws snd oder rt a, dependent on path from A lependent of path from AtoB. 29, The triple point for water is (@) wmique b) depends on p but is independent of T spends on T but is independent of p sounsoqi oop Sumpamtsinano om weg xqyeauroy) oyqes s2[are soutanqus-ouynso'Seiouad (p) sdnos3 Ha wows saqysod aun ag 6 pun #0038 9 (@) uospoysd xq soqumu won emp 20049 30 word xn Sop spt UMNFED Co) souop walxa ancany sopiueygu sppeui ae suor apueyyae Jo 921 (2) a ‘sponpop Sarai Burddosp ou NH OME MME OB= TED ed oy ways “V9, 0 ‘svasn pu np sani8 pure ‘apernnaya aun yi0q 0} yodsau ype x9ps0 9844 (P) ‘svozou Sudo ye wononpox oyss0801 van uos09[9 oss sonfuopun ooueeqns Y 9 Jo woyEs;eoouo op Jo wopuodo Jo woresjuan¥09 yBty 9 Jo uoweRuaouon ysiy ye Lops0 8 1 aseamn £q 80mm Jo ssKIoupsq “08 oowmepuet ooo) sepuonbay UNDO 3 _| oma a: sto v0 ding on of nthe ‘tive ‘ame less the cv: CHEMISTRY 40. The incorrect statement for solid sodium chloride is that (a) both sodium and chloride ions adopt Inert gas configuration (6) the conduction band is fall (6) the conduction band is empty (a) the valence band is fall, Q. 41-48 require matching of items of Column 1 with the appropriate items in Column 2. Choose the correct one from the alternatives (), (6), () and (d) 41, Column t P Cytochrome ¢ Q Calmodulin Chlorophyll 8 Aloohol defiydrogenase @ 8 © PIP PY PY qu qm ew ew RM RV RM RI sv sy sl sv 4 Columnt Column 2 P Atomic [ransition absorption time @ Chrono- WCelleonstant potentiometry R Spectrophotometry 1H Coulea 8 Conduetometry IV Mol ab Viimiting current Vi Holtow cathode lamp a) ® o @ PL PM Pi PY qm gt qu qu RV RW RW Ra sv sn sv sw 4, Cofumnt P Wilkinson's catalyst (GATE 2005-5 Column 2 trans- IxCKCOXPPR)), Q Speier'scatalyst I Hydroslylation Water gasshify II] RHCHPPA), 8 Zeolite ZSM-5 IV synthetic catalyst catalyst @ © Pal PA qn av RM RM sy sv 44 Column v Ww CO Py an RL sv gasoline Iydroformy> lation Tine-copper oxide @ Pall qui RIV sa Column 2 P Ostwald process [ Manufacture of nickel @ Solvay process Tl Manufacture? nitrieacid R Mond process I Manufacture of aco, S_ Frasch process IV Manufuctureof ® 6 Pl PH qm Qu RI RI svl SMI 45, Column Compounds silicones V Manufacture of caustic soda VI Miningof o PA qt ‘lomental sulfur RV RY sv su Colwnn 2 Carton stretching fregieney (en) P yelohexanone 11910 Q eyelopentanone 111715 R eyelobutanone 111813 ' yelopropanone IV 1650 v3780 vuMs, ASKYpwe BUETONP eT HIng 4 S-ipam-Z sue PEEAP Bs soe avo NaCl and and and cv : CHeMsTRY 64, Inthe reversible chemical reaction taking place under standard eondition at 298K (ahoqual to AH? —(@) equal to TAS* A) equal to zero (d) equal to AU* 65. The orital y = 15,,~ 1s,0f water simple harmonic ‘indamental frequency vis given by a ranean) for one mole a Vander Waals gas is of oe) RT @ ye © zer0 (68, A gaseous sample on exposure to total radiant energy of 6,626 J at 300 nm results in the photodisociation of 10° mol of this sample. Assuming the sample absorbs all te light, the quantum yield {for this photochemical reaction is @) 6028 ( 0602 fo 230 © 0.060 ‘Gare : 2005-9 68, Ifstandaré emf of the cell, @ 43x10" entropy of erystalline carbon ‘monoxide (in kJ/mol) at 0 Kis around @) 008 260 © wero @ 516 TL. Metals used in automobile catalytic converters are : (a) PtandPd (6) Ptand Rh (© PdandRh— (d) BhandNi Q, 72-77 contain a-Statement with a Reason and an Assertion. For each ‘question, choose the correct answer from the following four choices. (a) Both Reason and Assertion are correct (6) Both Reason and Assertion are wrong (©) Reason is correct but Assertion is wrong bonded (Re,Cl,P is a strong royal blue colour Reason : This is due to ax absorption band the visible region duetoexctation ofan electron from o'x'6ground stateto o'x69" excited state offieligand, ® ooutp @) omy (9) 0 (0) a Tsswonsma ppogesed eons, aE arreusadjque youn (p) mews fous espoyey>0 panoystp fipeuesex39 () PLOSL# Sawer vorysge 620 pasate (9) rig. dine condo omer spe RoE) A918 Shea uondnege twomoy eit poe arausewered (@ {1061s tuo vonsdone awonoy af PUY apoudemeled (9) suatpeinqnp ds ou gy-= deur uaNID AS e-2'f-vif-n4g+0(y) e—n'n'0'g+m () Wedd -Didg to st yams ateguyy oxpnse04 soanyoq yu 2p00KI ‘NDE SHIEH OL £2309 qo9'D 01819) : SNOLLSAND UHASNY GAUNTT 030-() $90 wu ore 3 sugpue ge woongoq soyeao (ouyey) “srowoquue 310 opesundeso aeyjaayo pre a80057 "08 seouuesg pu osoonkD: Hon AO—ey an@aou @) stoquoooai0s sR OBE ‘usanp nq "ye sopuRDONIAS IIA Jo3H0] cy wag 20 PH apatiog ne ‘ayesoudaaes SU 0" "POUND “pre suds ven spor EU Augean pews poydooyd mins gH, anug-9ag rods aah: sampans Pyds=9=T+ p= ay pease set qun Jo 3a oaen uLSWHBHO ko Xe ggg “HHO BING UON Ze=9x r= snp Spgs SSH + ZT +9 = Wane seats en 6I=6 +01 o% mrargeoetc ns peg t sah ayduos yds ey suow 1p stone pamodun ree a ane ‘Gare 7005-15 26, lectron Paramagnetic Resonance (EPR) & Nuclear Magnetic Resonance (NMR) Ou & Fe (both) Calcium 42. Atomicabsorption > Holloweathde lamp Chronopctentometry-» Transition time Spectrophotometry > Molar absorvity Solvay Process ‘Mond Process Frasch Process Cydlobutanone : Anos8 yfuoqzea om 0 ogo Sunsdqpo orp us nou Tap PAR 30H peruoLIO OF st dnosd year OM —— ‘ya dnd ous ap Sune w0 9pm ee way sspuye We “uoRSod-D ap ran ese pry oye geo open ps0 pany 'Bo}uoryppE pojosjueD seOR NEw U-- oxor a1 08 oprrouoer gexy soneng emma 385049 "pnpoad oleae ogre oumpasti jo Atosyuo prepuryg “qy, sv ORAS —ofmy saEND oy SIPING yy a RUE) ANN'O= OSWMPULOLLT: UL "T9 —-# MH pumnod09 ony ‘uops0d euoynbo ye dnoxa SING. g ‘wopovas WORE “BF juonooqe zr w 0 SRR 22n00281~ wont stow UT auBewopanequipy < amyeiodury MOT onary anes JueunEIOP seg - — ONDA KUTA \al ‘Duration: Three Hours = ‘Maximum ark 00 1, The O,, character table (i nt eT TT) - A 7 T 7 7 aaa A 1 1 a E aot 6 a Gay, 19— 99h, 92) 2 Physical constants {e) Bbullioscopic constant for water, K = 051K kg mol-+ ) Acidity constant for car S637, pK y= 1025 (@ Debye constant, D P29 Alais Se=21 Tin22 Cr=24 a=29 Mo-42 Rusat Gi=48 Pr=59 Bus63 Re=75 Hy=80 ‘8, The plot that describes a carnot eye is 1, Amolecule has 2foldaxisand a mirror plane perpendicular to that, The point ws wrt me tortes ‘electronic transitions from the copied Tt v to the unodcupied molecular orbitals do Os ov NOT occur at an OD ? T om am stspunoduios Sarno} ‘orp yo yp 24 Jo 19p50 7001209 HL, “YE ‘woygeutps009 Wy squowun> yous AP) wer no Om) woporeget weingaspcy 0 vopeuORIRAYNA peep ime nN Agena gone, A685) Sgpssedunayozozopenbost ype (2) ‘pur asvazou yj sosvaszop Ay3EsIy (q) ‘qurosvazsur ij seswozaU1 Ay (0) an sod van sures 9 eoppaed() ABx0U9 980] you" ‘sa0p woyss ayy ‘uorstfoo oxy BuLmmp (2) suns wos uopou wapuaoag ® Ur axe sypqued (@) suo ou ng sso ney sped 88 () ean TONS squomaprs Soy tp 0 yoy “soe epi yo roy anauD 99 30d sy “9 ct) 20) 1@ 0) | amp tn sj oqpmyonned eaBoqorg ut e948My> anydyns-uosy OL ay GuyUEo SpuEHamesadu a By *Y sasaH9 49 2-02: avo = (CY : CHEMISTRY GATE : 2006-3 ical 15. Match the following compounds with 18, The most appropriate starting materials for ‘their respective classes ‘one step synthesis ofthe compound (1) are - CoO rof. 7 : c : S we ‘the ) q I . (a) I: Steroid; II: ‘terpenoid; II poe a fe raat 1 (6): terpenoid; 11: Steroid; III: alkaloid; : - C C 10, Identify the major product Pin the eee nen ec me T the . m @ [es Wo, 2 (@) CH,COH @ ()CH,CONEC,H, y 1 © nCHyC=CH of 0 jpooeaqaonyjo how santero Bowe Powe” php EO sn une Bap om OME ey porn epen “Ape a geempos FPuoqerzea oh axe f pav 19 asoym ‘aye Dt gilag <8 onpuny pee ‘dont euopmes on operswaap 15 ‘poo NAT Om KAD TDD ay PEO ‘Aion owoote ony pe s2e=H OSE) OO _e0noea ony 2p eo aH i pee LORRIO MEMES TOPE 7 002 suv ae al a cv seHeMsTRY 29, 85%, ft the flowing reaction, a 298 Ny + SH, > 2NH, ASS, = -1973K", AH’, =-91.8k3 19738 0. (©) 308K! @k, and h., decreases, and hy/k.y St, Arodical tains *N-= with ypertine 82 The set of ions expected to show ‘Jahn-Teller distortion in their complexes increasing dyin thie complexes ia @ 2NOF {is 38 dm* molt at 300K. ‘The order othe reaction is @o or cave 207-8 Q.21-Q. 75 Carry two marks each addin aqueous sation n presence af veerol behaves as a strong acid doe tothe farmation of (o)an anioniemetal-chelate () borate anion (c) glycerate ion (@acharg transfer complex 2 Match the compounds in List with the corresponding structurlproperty given nist Listt tistt A. PhPYROCI (Spina BLiC, Gi Intercalation CPR, i) Oxidisngagent DINGS, Go) Catalyst for alkene ‘hydrogenation c idrupolar nature of iy), the MM bond (0)30and35 (35and8.0 25, A student recorded a polarogramh of 20 ‘mM Ca soution and forgot to add KCL ‘soltion, What type of error do you expect inkis results? Sag> "og > aap) “oa “aa 30 soot Hoomwtol ("oon P) FooMNo] TCO! Soo NNCOI"HO 100K se(OFHDPO] PUP el *HINICOIP) "aFO0X Pur ONIN () final pee ON @) ans] pe ox 0) azayds rouuy sworjoy @ woHees uw ads no sao 1 uoqoeey a) pans omy a BuUMomO) axon +o} lt ovon +-9O)%) sal (OFDIOAD + A OFHPCHNTO] sl @HNDIO0D] + (ODIO) “T ‘woRaea4 of} JOPISUOD “1g ausieHO 49 loana= x. od) = XV) DeOW=1! HSAOW=KO) DGWwOW=1! Hs@UOD=Ko Tosa"Q@=1 1 HSGIEOD=KO NORRIE SRE 1 e000 ae "as's ' ‘a wonvar " ‘aC H%a] Jo wor tpg 991 () aur pagpodsoapanq 0978 a Jo oumqeu oy} pe yuno> wos ‘auaTeA OM, "CfeaN) ID 1681 Pur (Buns) {HD L9q1 8 nde Ovonbay uN ATR OOF to-do oo of Brow orp anna ap peers a Mp eeY w 8K Qh OT) st popesedos 9q [ua sunt omy yp of CHE MSTA 288 The compound which shows LM. charge transfer is (@)NWOO, KC, (Heo a NiO) ‘98, The reaction of PECT,P-with NH, gives se to GPEC ovty, (yeranrGPCLINEE)) (orPIClNH) (Cheis PICHON) 1, Zeise’s salts represented as UPC, oper (©) (an POY? CH 38, The catalyst used inthe conversion of ethylene to acetaldehyde using Wacker process is (@HCACO, @rpacye V0 TROL, in the presence of AKCyH), 88, The temperature of 4 gofwaterisraied ffom 15°C to 75°C at constant pressure ‘The change inthe enthalpy ofthe system (given that Gof water = 75 JK! mot) @asKs (@90Ks 135K @rsoKs BPO" Fes @orey ()-040V @9mRY 040 ‘sare 2007-5 P+Q+R>8, 48, Sucrose is converted to a mixture of lucose and fructose in a pseudo first arder process under alkane conditions, ‘The reaction has a half life of 28.4 min, ‘The time required forthe reduction of 2a amin. +0, (4) 2N0,(8} proceeds via the flowing steps No+No—bow,0, 8,0, S.No +o N,0, +0, “2 4NO, +NO, (0) (2k, INOFLO,M, + h!03) (©) AINOHIO,) (@ksNOYO,) a solution of pi 6.30. the volume ofthe buffer remains unchanged, the pHofthe buffer Bigg = 1,005 10) is @50 (6)500 fo.30 @wa ypu n yoq (p) 1 pu 14909 (2) own 0 poppe st UBIO w UT (2 -ayfiyJo uo ds08qe £q 2968 aquon99p9 yous iayjOUD oO} ayaeapop (88 woyy won sajoat ousosazong J sse0014 94, (2) 101 FBT * SV pu ou 46891 = HIV uous snoouejuods 81g © ¥ WoNDEE 9M “99s AY paved ‘yenba ‘axe opoqous sanzep [eat ‘Brows youoneaqh uy, any Suto) auoutoyeys 3291209 9, “6 xg yo oun ayn yoy fy, way poe comma ena ured ugg ey

    002 ‘Rauazoyie souoy{ eure agp yey lip 248 yon woRmaRGEs eam epoapope spams soma repo Syapoeoy BL 71 waOTFOND 305 ee MONTE, “ar 3 20 bo jut oxen aay ny donc ° ‘wo 8 opATTEPOe we OY LON TE SUT ‘gy Bear uo yoga Produc ou, “yy ‘Yoo 009 upd ox ‘swoqe a proodas oe axe ‘oqo o4oqe ao SWF FONG OY “SL 0 Axyouuss yoUrsTP Jo = wee po ema oop ousyd Anomruuzs ‘syxe fouortenos PI-g en qeape ao 21 OL | ‘BL 22 72 SuOpseNh 20 wyeT WOME RT OPEN AIST NONNCO —‘squewsods9 eqexedos uy ‘eIy-eIV-2Ud SNOLISANO VEVENOWWOD —21y-Aip opndodeund ayo woueay, “9 > | susan: 40 11008: v0 ‘eible ofthe Point ile phic Bein with ides 76 t0 985 Carry two marks each. Liked Answer Questions @. 76 & 77 76. Inthe reaction Cs hm mt Compound Kis ‘71 Oxidation of X with Chromic acid chilly gives coos @| C o co ‘oar : 2007 = 11 76. inthe reaction ‘Compound Xis GrAdenine (Xanthine, (02, 6diemiaopurine (Adenosine 78. Compound X an treatment with cone. HCL ives (@Uricacid (@) Adenine (@/Aypoxanthine (@ Guanine Linked Answer Questions 80 & 81 ()BANSH, ©) BN Hy 81. Which of the following statements) i! are true for X? @ Xis not isoelectroni¢ with benzene. (i Xundergoes addition action with CT ig lectrophilic substitution reaction on Linked Answer Questions 62 & 83 ‘82 Consider a particle of mass m moving in ‘aone-dimensional box under the potential Ve0 for 0

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