3.28.

Derive an equation for the work of a mechanically reversible, isothermal

compression of 1 mole of a gas from an initial pressure p1 to a final pressure p2
when the equation of state is the virial expansion truncated to:

Z=1+B'P

How does the result compare with the corresponding equation for an ideal gas?

Diketahui : 1 mol dengan tekanan awal P1 dan tekanan akhir P2

Ditanya : persamaan yang membandingkan dengan gas ideal

Penyelesaian:

Dari mechanically reversible kita tahu bahwa:

2
W= (eq 3.25 hal.74)

Z=1+B'P ( di soal)

Z= ( gas ideal)

= 1+B'P

V= (1 + B'P)

1
V=RT( + B')

perbandingan keduanya terhadap tekanan :

1
= RT ( + 0)
2

dV= dP
2

2
W=
 2
W= PdV
2

2 1
= RT

2
=RT Ln |1

= RT (Ln P2 Ln P1)

2
W= RT Ln
1