Jawab .

The Compressibility factor is related to the measured quantities by :

PVt MP V t
Z= =
nRT mRT
(A)

By Eq. (3.38)

( Z1 ) M V t
B=(Z-1)V=
m
(B)

(a). By Eq. (A)

dZ dM dP dVt dm dT
= + + - -
Z M P Vt m T
(C)

Thus Max |% Z| | M|+| P|+| V t|+| m|+ T |

Assumsing a Aproxximately equal error in the fiv variable, a 1 Maximum error in

Z requires error in the variable of <0,2%.

dB Z dZ d V t dM dm
(b). By Eq. (B) = + + t +
B Z1 Z V M m

t
By Eq. (C)
dB
=
Z dP dT 2 Z1 d V dM dm
B Z1 P
(T
+ )
Z1 V t
+
M

m( )
Therefor

Max |% B | Z1
Z
|(| P|+| T|)+ 2Z1
Z 1 t
(| V |+| M|+| m|)
For Z 0,9 and for approximately equal error in the five variables, a 1
maximum error in B requaires errors in the variables of less than about 0,02%.This is
because the divisor Z-1 0,1thelimit as Z 1, the error B approaches