m molar d

m amostra= 30
m agua= m1 18.008 0.9974
m etanol= m2 46.07 0.78

x fm1 fm2 m1 m2 V1 V2 x m Vpic

0 1.0000 0.0000 30.0000 0.0000 30.0782 0.0000 0 0.0000
0.02 0.9504 0.0496 28.5114 1.4886 28.5857 1.9084 0.02
0.04 0.9037 0.0963 27.1102 2.8898 27.1808 3.7049 0.04
0.06 0.8596 0.1404 25.7888 4.2112 25.8560 5.3990 0.06
0.08 0.8180 0.1820 24.5406 5.4594 24.6046 6.9992 0.08
0.1 0.7787 0.2213 23.3598 6.6402 23.4207 8.5130 0.1
0.12 0.7414 0.2586 22.2410 7.7590 22.2990 9.9474 0.12
0.14 0.7060 0.2940 21.1794 8.8206 21.2346 11.3084 0.14
0.16 0.6724 0.3276 20.1708 9.8292 20.2234 12.6015 0.16
0.18 0.6404 0.3596 19.2113 10.7887 19.2614 13.8316 0.18
0.2 0.6099 0.3901 18.2974 11.7026 18.3451 15.0033 0.2
0.3 0.4770 0.5230 14.3101 15.6899 14.3474 20.1152 0.3
0.4 0.3696 0.6304 11.0884 18.9116 11.1173 24.2457 0.4
0.5 0.2810 0.7190 8.4310 21.5690 8.4530 27.6526 0.5
0.6 0.2067 0.7933 6.2016 23.7984 6.2178 30.5108 0.6
0.7 0.1435 0.8565 4.3045 25.6955 4.3158 32.9429 0.7
0.8 0.0890 0.9110 2.6706 27.3294 2.6776 35.0376 0.8
0.9 0.0416 0.9584 1.2487 28.7513 1.2520 36.8606 0.9
1 0.0000 1.0000 0.0000 30.0000 0.0000 38.4615 1
 Volum e m olar da m istura / m L/m ol
Sistema gua-etanol
70

d / g/mL M / g/mol Vmol

60
0.9974 18.008 18.054943
f(x) =
f(x)
f(x) == 40.1826017442x
3.8990081569x^2 ++17.619033448
-- 0.1508896183x^4
1.2796033992x^3 36.5677339719x + 18.0062433803
+ 5.761972805x^2
- 0.9882333069x^3 + 35.8886028229x
+ 5.5889913682x^2 + 18.0484862369
+ 35.9209938127x + 18.04725
0.9884 18.56920 18.787131 R =
R = 0.9994263639
0.9999797343
0.9999842715
0.9999842672
0.9808 19.13050 19.504996 50
0.9744 19.69170 20.209052 f(x) = 48.0335099153 x^0.3135196648
0.9675 20.25300 20.933333 R = 0.8896437529

0.9597 20.81420 21.688236 40

0.9523 21.37540 22.446078
0.9463 21.93660 23.181444
30
0.9437 22.49790 23.840097
0.9321 23.05920 24.738977
0.9273 23.62040 25.472231 20
0.9028 26.42660 29.271821
0.8771 29.23280 33.328925
0.8592 32.03900 37.289339 10
0.8442 34.84500 41.275764
0.8257 37.65100 45.598886
0
0.8135 40.45800 49.733251 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0
0.7986 43.26380 54.174555 x etanol
0.7891 46.07000 58.382968
+209938127x
18.0484862369
+ 18.0472591719

0.7 0.8 0.9 1

 grau 3 2 1 0
ajuste -1.2796 5.762 35.889 18.048
derivada 0 -3.8388 11.524 35.889 Volume molar da m
70

Vm/ mL/mol
60
x Vmol alpha Vag Vet
f(x) = - 1.2796033992x^3 + 5.761972805x^2 + 35.
0 18.054943 35.889 18.054943 53.943943 R = 0.9999842672
50
0.02 18.787131 36.117944 18.064772 54.182716 f(x) = 48.0335099153 x^0.3135196648
40 R = 0.8896437529
0.04 19.504996 36.343818 18.051243 54.395061
0.06 20.209052 36.56662 18.015055 54.581675 30
0.08 20.933333 36.786352 17.990425 54.776777
20
0.1 21.688236 37.003012 17.987935 54.990947
0.12 22.446078 37.216601 17.980086 55.196687 10
0.14 23.181444 37.42712 17.941647 55.368766
0
0.16 23.840097 37.634567 17.818567 55.453134 0 0.1 0.2 0.3 0.4 0.5
0.18 24.738977 37.838943 17.927967 55.76691
0.2 25.472231 38.040248 17.864182 55.90443 x etanol

0.3 29.271821 39.000708 17.571609 56.572317

0.4 33.328925 39.884392 17.375168 57.25956
0.5 37.289339 40.6913 16.943689 57.634989 Volume molar da
0.6 41.275764 41.421432 16.422905 57.844337

Va / mL/mol
18.5
0.7 45.598886 42.074788 16.146534 58.221322
18
0.8 49.733251 42.651368 15.612157 58.263525
17.5
0.9 54.174555 43.151172 15.338501 58.489673
17
1 58.382968 43.5742 14.808768 58.382968 16.5
16
15.5
15
14.5
14
0 0.1 0.2 0.3 0.4 0.5

x etanol
Volume molar da mistura

x^3 + 5.761972805x^2 + 35.8886028229x + 18.0484862369

35099153 x^0.3135196648
437529

0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

x etanol

Volume molar da gua Volume molar do etanol

Ve / mL/mol

59
58
57
56
55
54
53
52
51
0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8

x etanol x etanol
nol

6 0.7 0.8 0.9 1