‘Table C.1: Heat Capacities of Gases in the Ideal-Gas State’ Conta in eqution CH Ad Bryer? + pr? ‘Chemical species Tom Chl AW he 0-SD Pan Methane Ch, 150042171702 9081-264 Bihawe Cite 15006369 List 1935 S61 Propane Coie 1500 S01 1213 28785 Rane Butane Catto 1500119281935 36915 11am bro Batne Gitlin 150011501 L677 37.853. 11945 ‘Penne Giiin 1500147812468 45351 “14 rele Cotte 17s 3028 3372 “ier tr Hepane Gitig 1500203613570 GIN? i986 ‘Octane Cog 150023174 ©4108 70567 22308 Alene: Bile City 1500 55258 142k 1404-4382 Propylene Cie 15007992 1687 2706 e915 Bate City 150010520 1967 31650 973 Penene CsHio 150013437691 30753 ~I2aK7 THoxene Geils 1500 16340 3.220 Hee 15157 ERepiene Cots 1500 1853 3.768 S688 17847 LOetene Cattig 150021868 4326 960 “an 21 scetneous orgies ‘Acetlchyse C40 10006508 1.693 17978 ‘eevene Gir 15005253 6m 9m ~1299 Benzene Ceti 1500 10259-0205 38.060, 13sBeatene Cie 1500 10729-2734 25786 Gyetterane Getta 1500121 3.16 208 tana HO 1500 $948 3.518 20.001 Etytenzoe Coto 1500155531124 55380 Eyles ode CHO 10005788 0385 TASS Formadehye Cio 1500 1912264 70m Metal Gyo 1500 S57 221112216 Syren Gotin 1500155342050 s0.s2 Toone Gi 1500 25m 0290 7052 Miscetanous inne: aie 2000 3509 3.355 0016 ‘nionia Nis 18004209 3.578 =a Bromine Bq 300043574493, Tass Cacvonmonosite «2593073376 =aoat Carton dixie co, too 4575457 chs? Carson date cs: iso 332 oat “1905 Choise 3000 za =a3e4 Hiycogen Hy 300034653208 083 Hydiopen nce Hs 200 Alle 3931 0282 Hystopen corde = HCL 20003512356 coll Tash Hydrogen cyanide HON 280043264735 13590 css 0725 Nitogen Nz 200035023280 0593 ass Oa ious oxide Njo 200 Sete 53281214 1908 Niticoride NO 20035503387 Oe oie Niogen dioxide NO; 2000 aa 49821195 sss 0792 Dinivogen ode N30, 2009198 116802287, “a8 Onyeen Op 200035353639 0506 ss Oar Saifrioxide SO 20004756 5699 BOL Ss “15 Sl tonide $0; 200060548060 1.056 Sass 2.08 War Ho 200040383470 1450 ont ‘Selecied ftom H. M. Spence, tnd. Eng. Chem, vol. 40, pp. 2152-2154, 1948; K. K. Kelley, US. Bur Mines Bul. 564, 1960; 1. Pankratz, U.S. Bur Mines Bul. 672, 1982APPENDIX C. Heat Capacities and Property Changes of Formation ‘Table C.2: Heat Capacities of Solids’ Constants forthe equation Cp/R = A+ BT -+ DT~? T (elvis) for 298 Kt0 Tine Chemica species Tax Crigg/R_ A cx0 200 ~—~«S.058 6108 CaCO; 100 (9.48 12572 Ca(OF 112179397 aC 7508 8.254 cach, 872 86 (graphite) m6 7m omTt cu 2989 2677 ais c00 Sox 57800973, Fe@) 300s ON] 6.111 e203 12480 118129697 e304 181389598 27.12 Fes 6573 261213286 b 699 64811302 tier 578 $287 2476 0.193 Nucl wor 5939 6.105 Na 37l 3.386 1.988 4.688, Nec 13 GIL «55261963 NaOH 56600717 O12 16316 1.948 NaHCO 400 10539 5.128 18.148 SGivombic) 3683 3788 44-128 0.783, Sip (quartz) 8475345471 5.365 ‘Selected trom K, K. Kelley, U.S. Bur Mines Bull 584, 1960; LB Panksat, U.S. Bur Mines Bul. 672, 1982. ‘Table C.3: Heat Capacities of Liquidst Constants forthe equation Cp/R = A+ BT + CT? T from 273.15 0 37315 K Chemical species Cryy/R_ AIRC “Ammonia 978 22626 10078 19271 ‘line 20m 15819 2903-1580 Benzene Wis7 077 67963778 13:Butadone “7 Dm -6796 0579 Catbontetachovide 18781 21.185 “4828 TOLI4 Clorbenzene 1324011278 3285-3190 (Cheroform B86 19218 28 BOL CGyeloherane 18737 90% 38 16182 Bihan! 144s 33865 I) SIT ilo oxi 10590 21039 6a T1238 Methanol 998 13431 S128 aL ‘ePropanol W6sot41.6s3 2103242720 Solar oxide soaos 2930 13708 “8473 Toluene We 151336791635 Wate 9069 8712 as 018 ‘Based on conelations presented by J. W. Miler, J, G.R, Schon, and CL. Yaws, Chem. Eng, vol 6123), , 129, 1976.‘Table C.4: Standard Enthalpies and Gibbs Energies of Formation ‘at 298.15 K* Joules per mole ofthe substance formed Suite AH}, Gy, Chemical species (Note 2) (Note 1) (Note 1) Paraffin Methane cH @ — -74520 0.460 Bihane Cols @ — ~83820 —31,855 Propane Cos (=) 104,680 24290 Butane Cilio) =128790 -16,570 mPeatane GHz) =146,760 8,650 n-Hexane Celie) = 166920 130 n-Hleptane Ce @) 187780 8,260 Octane CiHis —)——~208.750 16,260 1 -Alkenes: Bihylene Call @ 52510 68.460 Propylene Cote @ 19710 62,205 1-Butene Cally ® ~540 70340 L-Pentene CsHio = 2428078410 LHexene Colin) 41950 86,830 1-Heptene Cie @) 62,760 Miscellaneous organics: Acetaldchyde CoO —®)_——166,190 —128,860 Acetic acid C240, 484,500 —389,900 ‘Acetylene Cath, () 227.480 209,970 Benzene Cette @ 82930 129.665 Benzene CoH © 49080 124,520 13-Butadiene Cat @ — 108,240 149.795 Cyclohexane Coti2 —(@) 123,140 31,920 Cyclohexane Cohi2 156.230 26,850 1.2-Bthanediol CoH6Or —(——— 454,800. —323,080 Ethanol Hg @)_—=235,100 ~168,450 Ethanol CHO ~277,690 ~174.780 Btnylbenzene Cato @) 29920 130,890 Ethylene oxide GO —@) 52.630 13,010 Formaldehyde Cho @)——108,570 —102,530 Methanol CHO) = 200,660 161,960 Methanol CHO = ~238,660 —166270 Methyleyclohexane Cig), —154,770 27,480 Methyleyelohexane = C7Hig_ 190,160 20,560 Styrene Cols @ 147360213900 ‘Toluene CH ® 50,170 122,050 ‘Toluene CiHs © 12,180 113,630APPENDIX C. Heat Capacities and Property Changes of Formation ‘Table C-4 (Continued) ‘State AH} AGhy Chemical Wote2) ote 1) __ (Note) ‘Miscellaneous Inorganics: ‘Ammonia Hy 46,10 16,450 ‘Ammonia Ni 7 =26'300, Cate carbide cat @ —_-39800 64900 Calcium carbonate CaCO3, ®) 1,206,920 —1,128,790 Calcium chloride Gch “1983300” 748,100 Cale chloride Gch (ea) 310900 Calcium chords Gxchor,0 = -2,607900 Calcium hydroxide Ca(OH) (s) =986,090 898,490. Calcium hydroxide Ca(OF eo =B681070 Calcium oxide Gro (S — -635090 04030 Carbon dioxide co, ® — ~393,509 394359 Carbon monoxide co () 110,525 =137,169 HL @ 92307 957299 HCN @ 1351100 1247700, is @ — 20630 331360 FOO. & — -2100 Iron oxide (hematite) Fey “824200 —742,200 Iron oxide (ng Teo, & 1118400 10151400 Iron sulfide (pyrite) PeS> ® 178200 166,900 Lithium chloride Lich — —A08;s10 ithium chloride TiCL,0 @ — =112580 Lithium chloride Lici2ti,0 1012650, Tici30 Q 3 HNO3 oO 1,100, 80,710 HNO} «oa =111,250 NO. ) 90,250 86,550, Nop o 3318) S110 N20 @) 82,050 104,200, N204, @) 9,160 97,540 Nicos ) — ~1,130/680 1,084,440 NaCOs-10H:0 G)_—_—4081,320 Nac () 4153 —384,138 Nec (on) 393133 Sodium hydroxide NaOH (425,609 Sodium hydroxide Mont ap Sulfr dioxide $02 S 296830 ‘Sulfur teioxide S03 (@) (395,720 Sulfur tionide 503 — —aatoao Sulfuric acid H2S0q oO 813,989 —690,003 ‘Sulfuric acid H2SOq (aq) 744,530 Water #20 @ 21g 225572 Waer H,0 2853830 237129, TBrom TRC Thermodmanic Tables—Hidrocarbons, Themodynamics Research Cen ter, Texas A & M Univ. System, College Station, TX; “The NBS Tables of Chemical ‘Thermodynamic Propottes,” J Phys. and Chem. Reference Data ol 1, supp. 2, 1982. [Notes 1. The standard propery changes of formation AH, and AGY,,, ate the changes ‘ccusting when 1 mol ofthe listed compound is formes from ts elements with cach substance in its standard state at 298.15 K 25°C). 2, Standard states: (@) Gases (g): pure ideal gas at | bar and 25°C. (b) Liquids () ‘and solids (): pure substance at 1 bar and 25°C. (¢ Solute in aqueous solution (aq): Hypothetical ideal {-molal solution of solute in water at bar and 25°C.