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TEST - 6
COURSE NAME : VIKAAS (JA) & VIPUL (JB) COURSE CODE : CLINIC CLASSES
TARGET : JEE (IITs) 2014
Date : 26-02-2013 Duration : 1 Hour Max. Marks : 80
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
14. The question paper consists of 1 parts. The part consists of Two Sections.
15. For each question in SectionI, you will be awarded 3 marks if you darken the bubble(s) corresponding to
the correct choice for the answer and zero mark if no bubbled is darkened. In case of bubbling of incorrect
answer, minus one (1) mark will be awarded.
16. For each question in SectionII, you will be awarded 5 marks if you darken the bubble corresponding to the
correct answer and zero marks if no bubble is darkened. In case of bubbling of incorrect answer, minus
one (1) mark will be awarded.
CHEMISTRY
PART - II : CHEMISTRY
Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]
SECTION - I
Straight Objective Type
This section contains 15 questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of
which ONLY ONE is correct.
2. The correct order of hybridisation of the central atom in the following species NF3, BF3, PF5 and [SiF6]2 is:
(A) sp2, sp3, sp3d2, sp3d (B) sp3, sp2, sp3d, sp3d2
2 3 3 3
(C) sp , sp , sp d, sp d2 (D) sp3, sp2, sp3d2, sp3d3
3. In which of the following sets the central atom of each member involves sp3 hybridisation ?
(A) O4 , Cl4 , F4+ (B) XeO3 , XeO4 , XeF4
(C) SO3, SO32 , SO42 (D) PCl4+ , BF4 , ClO4
4 In which of the following groups all the members have linear shape ?
(A) NO2 , N3, ICl2+ (B) N3 , I3 , NO2+ (C) XeF2, C2H2, SO2 (D) CO2, BeCl2, SnCl2
RESONANCE JA&JBTEST6260213C0-1
CHEMISTRY
5. Which reactions involves a change in the electronpair geometry (i.e. hybridisation) for the under lined
geometry ?
(A) BF3 + F BF4 (B) NH3 + H+ NH4+
(C) 2 SO2 + O2 2 SO3 (D) H2O + H+ H3O+
7. When PCl5(g) is heated, two chlorine atoms are dissociated from two positions which are
(A) one axial and one equitorial (B) Both axial
(C) Both equitorial (D) From any of two positions out of five positions
9. The average charge on each O atom and average bond order of IO bond in IO65 is-
(A) 1 and 1.67 (B) 5/6 and 1.67 (C) 5/6 and 1.33 (D) 5/6 and 1.167
RESONANCE JA&JBTEST6260213C0-2
CHEMISTRY
11. Amongst the following, the total number of species which does/do not exist is :
SF6, BF63, SF4, OF4, AlF63, PH5, PCl5, NCl5, SCl6
(A) 9 (B) 5 (C) 6 (D) 8
13. In NO3 ion number of bond pair and lone pair of electrons on nitrogen atom are
(A) 2,2 (B) 3,1 (C) 1,3 (D) 4,0
14. Which of the following arrangements is correct on the basis of the increasing p-character of the hybrid
orbitals of the central atoms in the following :
(I) ClO2 (II) CS2 (III) SnCl2
(A) I > III > II (B) II > I > III (C) I > II > IIII (D) III > I > II
RESONANCE JA&JBTEST6260213C0-3
CHEMISTRY
SECTION - II
Multiple Correct Answer Type
This section contains 7 questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of
which ONE OR MORE is/are correct.
16. Which of the following species are correctly matched with their geometries according to the VSEPR theory?
(A) BrF6+ octahedral. (B) SnCl5 trigonal bipyramidal.
(C) ClF2 linear.
(D) IF4+ see-saw.
18. Select that pair(s) in which bond angle of first member is less than second one.
(A) BrO3, ClO3 (B) AsI3, SbI3 (C) SbBr3, SbI3 (D) NF3, NH3
RESONANCE JA&JBTEST6260213C0-4
CHEMISTRY
20. Which of the following are not isomorphous to each other
(A) BaSO4 and KMnO4 (B) KNO3 and NaClO4
(C) K2CO3 and K2SO3 (D) Na2CO3 and Mg(NO3)2
22. To which of the following species is the octet rule is not applicable ?
(A) BrF5 (B) SF6 (C) IF7 (D) CO2
RESONANCE JA&JBTEST6260213C0-5