Series SMA/2 we 4. 56/2/1 Code No. waa Wari as oO Fax-gReaT FE-TS Roll No. % sree fers | Candidates must write the Code on the title page of the answer-book. ° wa oa a a fe we eee Ff ar ye 2 7 oom § afet aa at sik fag ae ats aa at on sayfa & ya-ye u fee | ° ga ca a Gf ow F 30 we BT ww aT sat fra YS SO a wes, we a ais saya fe © We a ie & fae 5 fee Ha fee 2 lee a fa ie 10.15 7 feet SET | 10.15 TF 10.30 TI TH Be Baa eT aT UE aK wa safe & chr 3 sacyferar we ate amt ae feat | Please check that this question paper contains 12 printed pages. © Code number given on the right hand side of the question paper should be written on the title page of the answer-book by the candidate. * Please check that this question paper contains 30 questions. * Please write down the Serial Number of the question before attempting it. © 15 minutes time has been allotted to read this question paper. The question paper will be distributed at 10.15 a.m. From 10.15 a.m. to 10.30 am., the students will read the question paper only and will not write any answer on the answer-book during this period. Taree fas (agi) CHEMISTRY (Theory) Profits war: 3 qe RIBIT SH: 70 Time allowed : 3 hours Maximum Marks : 70 56/2/1 1 PIDwart fier @ Gi) (iii) (iv) (wy) (vi) (vii) aot x07 siftart & | wets wer & art oie wale me eI TETACN 13 8 oe sie ag-arda Tete | aes res & fee 1 wa 2 1 FRAG 9 18 aH vase eT S| ete TET H fee 2 as BI TeA-G@T 19 3 27 we Ht ay-aada sede | wee eT & fee 3 ais F 1 Wei 28 3 30 ae-saiia wea & | woke eT fore 5 aie FI sreraeagaR aT sacl ar walt at | aegeed & svatr at spate wer é: General Instructions : @ 3) (iii) (iv) (w) (vi) (vii) All questions are compulsory. Marks for each question are indicated against it. Questions number 1 to 8 are very short-answer questions and carry 1 mark each. Questions number 9 to 18 are short-answer questions and carry 2 marks each. Questions number 19 to 27 are also short-answer questions and carry 8 marks each. Questions number 28 to 80 are long-answer questions and carry 5 marks each. Use Log Tables, if necessary. Use of calculators is not allowed. 1. dat % ave fears & ded 8 ug ‘fafa aa a wer eet 2? What is meant by the term ‘forbidden zone’ in reference to band theory of solids ? 2. saferetar feat wer semen sat ect 2 ? Why is the adsorption phenomenon always exothermic ? 3. NaCN & oa faer aaen & fared } veaq fae % few & fee ot fate at ont @, 8 fafac 1 Write the reaction involved in the extraction of silver after the silver ore has been leached with NaCN. 56/2/16. waft oa at ater ager wines ¥ He afie yaa % fi ft oe aT Waris VESh VES Ht ater aa afte aa eo? 1 Although the H-bonding in hydrogen fluoride is much stronger than that in water, yet water has a much higher boiling point than hydrogen fluoride. Why ? frafefiad aif ar ones. art fear : 1 H,C - CH = CH - CH - CH, - CH, | OH Write the IUPAC name of the following compound : H,C - CH = CH - CH - CH, - CH, | OH aif, 4Afrete-3-$4-2.8 af onftas dem aitfad atfac 1 Draw the molecular _— structure = of ~~ the _~— compound, 4-methylpent-3-en-2-one. DNA 3it RNA & pol wit af fear 1 1 Write the full forms of DNA and RNA. ‘dat tees Ufcariifzry’ en ea z ? 1 What is meant by ‘narrow spectrum antibiotics’ ? (a) Prefefan vet FS ate at vitae aifsc : G@ ave am (van't Hoff) Fis Gi) Ara #7 (Mole fraction) Gi) taferaeaiies aerta saa) feria (b) see ar fram fear | Get aaa feed ter % ort a wat 1.25 g (mL) @ ak ve WH 1.0 kg # Nat aet at 92 g amt Wed @ | Nat ard at gia % wet F steer eT ert 2 CRAM] TA Na = 23-00 u) 2 56/2/1 3 POCae:10. 11, 12. 13. (a) Define any two of the following terms : @ _ van’t Hoff factor (i) Mole fraction (ii) Ebullioscopic constant (b) State Raoult’s law. OR The density of water of a lake is 1-25 g (mL)? and one kg of this water contains 92 g of Na* ions, What is the molarity of Na* ions in the water of the lake ? (Atomic mass of Na = 23-00 u) frrfatad vet at ofentad aifse : @ — afafrar at atte Gi) afafrar at afer sat Define the following terms : (i) Order of a reaction (ii) Activation energy of a reaction ain sik tality & wus yer ret 3 am fafar | gr Ooi ses & aio & fee sqm fat ar am afer | Name one chief ore each of copper and aluminium, Name the method used for the concentration of these two ores. frefefad at ere sir : @ wea & ater age at verre ofnaar aed wr at 21 (i) SF afrear (kinetically) fafera @ | Explain the following : (i) The chemical reactivity of nitrogen is much less than that of phosphorus. (i) SF, is kinetically inert. frafefad Sivis a snftas deat ontfed afer : @ — HjPO; Gi) BrF, Draw the molecular structures of the following species : @ — HyPO, Gi) BrF, 56/2/1 414. 15. 16. 17. 18. saaeait aise (ambident nucleophiles) #1 @a @ ? UH Se Ba AE afar | 2 What are ambident nucleophiles ? Explain giving an example. arm 2a et We aif fe ai @ Yeaa tags gta aA wot wa Fafa F Gi) fare afters af fricte feafedt ¥ a errr afer | 2 Explain as to why (i) Alkyl halides, though polar, are immiscible with water. (i) Grignard’s reagents should be prepared under anhydrous conditions. sete attire & fre wari atten ea ee frafatad a avi aif: 2 @ what attic Gi) aa i aS after Describe the following giving the chemical equation in each case : (i) Carbylamine reaction (i) Hofmann’s bromamide reaction frafetar after eect a pt ifs: 2 () CgH,N,Cl + HPO, + H,0 > (i) CgHsNH, + Br (aq) > Complete the following reaction equations : @ — CgH;N2Cl + H3PO, + H,0 > (i) CgH;NH, + Brg (aq) > frefefad 7 8 yels sat st aT Ba ae ae aif: 2 G) adh ve H aT wart ae ar 2 Gi) Tyee Tes (aspartame) H ST 3s ee sik TA at yet we ifr eat @ | State a reason for each of the following statements : @ Soaps do not work in hard water. . Gi) The use of the sweetner aspartame is limited to cold foods and drinks. 56/2/1 5 P.T.O.19. 20. 21. 286-65 pm aa frat & ae arena sar Aaa sa (bee) wa Ba are 2 | SUPRA FH WA 7-874 gem 2 | ge BA H SR H Cats den a oes Sift | (Fe # WAM] RAM = 55-845 u) ae facet heh Sac SARE (fee) Uae Se H factors aot @ 1 ale fee Ge at fT 145 pm @, Tt Uae Aa} weds feat st cas em ehh 7 Iron has a body centred cubic (bec) unit cell with a cell dimension of 286-65 pm. The density of iron is 7-874 g cm’. Use this information to calculate Avogadro's number. (Atomic mass of Fe = 55-845 u) oR Silver crystallises in face centred cubic (fcc) unit cell. If the radius of silver atom is 145 pm, what is the length of each side of the unit cell ? 25°C R a H Aga aT TA 3-165 kPa (23-75 mm Hg) @ | St THR aT (artaRS) % 5% Tea fart at agai aT aa wa aia | (afer a te RAAF = 60-05 g mol) At 25°C the saturated vapour pressure of water is 3-165 kPa (23-75 mm Hg). Find the saturated vapour pressure of a 5% aqueous solution of urea (carbamide) at the same temperature. (Molar mass of urea = 60-05 g mol”) afi 2A+Bo C+D % fran aifae | attire at & a ser at ET faq 7g sari # frafafien oftors Te Ae : <4 safer wiz (mol Lt) [artis Frater at = [A] [B] [D] (M/min) 1 0-10 0-10 15x 10 2 0-20 0-20 3-0 x 10 3 0.20 0-40 6-0x 10 (a) sfaimer % fare ex frat a fear | (>) safer & fare ez feria & ae ar afters aif | (:) frefefiad # @ staat aera cfiinat Grate (a) F fem me a fae age @ ? L A+B3C+E (am) A+E>D (tm) I. BoC+E (th) A+E>F (@m) A+F>D (a) 56/2/1 622. Consider the reaction 2A+B>C+D Following results were obtained in experiments designed to study the rate of reaction : Initial concentration | Initial rate of Exp. No. (mol L) formation [Al [B] [D] (M/min) 1 0-10 0-10 15x10 2 0-20 0-20 3-0x 10° 3 0:20 0-40 60x 10° (a) Write the rate law for the reaction. (b) . Calculate the value of rate constant for the reaction. (c) | Which of the following possible reaction mechanisms is consistent with the rate law found in (a) ? L A+B—>C+E (slow) A+E-D (fast) I. BC+ E (slow) A+E > F (fast) A+F—D (fast) wets % fore Ua Say saewT At gy frafafad vel a vfenfia aif : 3 @ aga a Gaew (Electrophoresis) (i) fr8ea (Micelles) Gii) 424 (Peptization) Define the following terms giving one suitable example for each : (i) Electrophoresis (i) Micelles < (iii) Peptization 56/2/1 7 P.T.O.23, frafafad caaie stew st wt sfc ; 24, 25. (@) — NH,Cl(aq) + NaNO, (aq) > (i) Py +NaOH + H,0 > Gi) = Xe@ + F,@ SBR, 1B. (onfier 3 sf) “ Complete the following chemical equations : () — NH,Cl(aq) + NaNO, (aq) > (i) P4 + NaOH + H,0 > 673 K iii Xe(g) + Fy(g) “SS, ee ‘(Xenon in excess) 2 1 Bar frefatisn at caret afar : @ eaiedes dae dan ae & fee a aA aa eI Gi) fad) fer far aeGasts sides ae sat 2 | (iii) [Fe(CN)gI*~ sik [FeCH,0),2* ay farerrtt F areata oS aE 1 Explain the following : (i) The x-complexes are known for transition elements only. Gi) Nickel(D) does not form low spin octahedral complexes. (iii) [Fe(CN)g]*~ and [Fe(H,0),]** are of different colours in dilute solutions. frefefad afitraret # sere ai fear : @ CH, -CH, ~ CH, ~ 0 ~ CH, + HBr — 0C,H; (ii) Cc + HBr — Gi) (CH,),C-0c,H, HES State thé products of the following reactions : @ CH, —CH, - CH, -0-CH, + HBr —> OC.H, Gi) cr + HBr — Gi) (CH),C-00c,H, EL 566/2/1 826. TARGA (glycogen) I @ ? We wr a Sa fiw 2 2 KM des wT a 27. 28. aque 3 aa fie 2? 3 What is glycogen ? How is it different from starch ? How is starch structurally different from cellulose ? frafafad seta ages & uae a dea fafa : 3 @ — arreia-6 Gi) aaa Gi) Asi Write the structure of the monomer of each of the following polymers : (i) ~~ Nylon-6 Gi) Teflon (iii) Neoprene (a) dat das ded fea von at ded 2? faga ara ae & der dares act 2 a act te ak date afiteat sik cept afr, wi at fafax | (be) we ada fa fre aed & aa asc & Be fe oT? : Ag* (0-001 M)|Ag 3i% Cu”* (0-10 M)| Cu. gaat Gat fave faa dar afee ? (Ey, = 0-46 V, Log 10° = 5) 23 waar (a) Set seed ve Ft vftafia aif sik orem aie fe ag sik waa Frgrearmmeat & fee tee eres Reverie are BA oahae ada # (b) fae ag at TH wt Ni(NO,), % 1teR faces 4 wat ort 2 sik fae amg at we vet AgNO, & 1-ttex facay 4 eet ort @ | oa Set faear a ae fa wa Ser am @ sik cht vedi a ot B steer & aig fear aia @, va us agnueets Ya aa ar 2 | @ Fate act apt afar & far ws dgiea whew fafa sik fa fava ar ufc aif | (i) -Af& Ni(NO,), a1 Stet HF sfEHH siz 0-100 He SK AgNO, aT aief aeioes. MM LOO. Mer w, At Ser Tee 25 CSCI EH, E vfteferd aifrg | [E. =-0-25 V; E. = 0-80 V: oe ‘ag’ Ag = 0°80 V3 Log 10-4 = — 1] Niet Ni 56/2/1 9 P.T.O.(a) What type of battery is the lead storage battery ? Write the anode and cathode reactions and the overall reaction occurring in a lead storage battery sending out an electric current. (b) A voltaic cell is set up at 25°C with the half-cells Ag* (0-001 M)|Ag and Cu’* (0-10 M)| Cu. What should be its cell potential ? (Ez. = 0-46 V, Log 10° = 5) OR (a) Define the term molar conductivity and explain how molar conductivity changes with solution concentration for weak and strong electrolytes. (b) A strip of nickel metal is placed in a 1-molar solution of Ni(NOs). and a strip of silver metal is placed in a 1-molar solution of AgNO. An electrochemical cell is created when the two solutions are connected by a salt bridge and the two strips are connected by wires to a voltameter. (Write the balanced equation for the overall reaction occurring in the cell and calculate the cell potential. (ii) Calculate the cell potential, E, at 25°C for the cell if the initial concentration of Ni(NO5), is 0-100 molar and the initial concentration of AgNO, is 1-00 molar. . 1, ee aa . 4 [Ev 2 yi = — 0-25 V; Bact ag = 0-80 V; Log 10° = vy 29. (a) frafefad wate aiewil 4) yf sik dgfera aif: @) Cn0?7 +17 + Ht (ii) MnO; + SOf +H* > (>) frafefad sacterdi st erent sifse : @ | aan ce ak sae afte ses oad at Gi) Sar ost a Ge aot Fate & eee ao SG sea siete saeat wefita at sit 2 1 Gi) aang sree fects Sk acta Sot S dar oe A fae woo oe aa @ 1 2,8 agat 56/2/1 10(b) (a) (b) (a) (b) 56/2/1 fe ie seer are Fo agina agi sf dent oa uieer wife: Mn™, Cr**, v°* ait Fe?* wa @ sche fae F aha wae afte wag 2 7 (4. 3. V = 23, Cr = 24, Mn = 25, Fe = 26) frafafiad saci at carer aif : @) dam ang area acta aoe A are eR aa eI Gi) Cu) sete reer ¥ wart ae 2 1 Gil) GH SHAT ag St Teas ST sae Ee atleaES aT FESS efits eet t 1 Complete and balance the following chemical equations : @) CRO +I +Ht Gi) MnO; + SO? + Ht > Explain the following observations : () Transition elements and their compounds are known to act as catalysts. (ii) The higher oxidation states are usually exhibited by the members in the middle of a series of transition elements. (iii) The metal-metal bonding is more frequently found with the second and third series of transition elements. OR Calculate the number of unpaired electrons in the following gaseous state ions : Mn2*, Cr°*, V3* and Fe?*. Which one of these is the most stable in aqueous solutions ? (At. nos. V = 23, Cr = 24, Mn = 25, Fe = 26) Explain the following observations : (@ The transition metal ions are usually coloured in aqueous solutions. . Gi) | Cu(I) is not stable in an aqueous solution. Gii) The highest oxidation state of a transition metal is exhibited in its oxide or fluoride. 11 PTO30. (a) 3a frafafe ar aia aifae frat we aie % anit agg a fre afters Ysa @ sik we AA (adduct) Te-sTIeT BMI UH Uestelet Sa 21 (>) refed aifiet at dorm aitfas sits : @ — 3-Afraaetat (i) t4-1,6-sRsige art Gi) p-aRghiaisia 28 aaa (a) wae fae ws srqe wari wiew ta qe Prafefad sftieasit at sega aise : @ Sftsrt at atitear Gi) taareré-sirei afatrar (b) farafafad einer ora aa att 2 ste & fam yh ater feed | @ wha # 3-aggieiegaa # Gi) sigs are at maga tester F Gi) Fiteers F Aste F (a) Describe the mechanism of the addition of Grignard reagent to the carbonyl group of a compound to form an adduct which on hydrolysis yields an alcohol. (b) Draw the structures of the following compounds : @ — 8-Methylbutanal (ii) Hexane-1,6-dioie acid (iii) p-Nitropropiophenone OR (a) Iilustrate the following reactions giving a suitable chemical equation for each : @ — Cannizzaro reaction (i) Hell-Volhard-Zelinsky reaction (b) How would you bring about the following conversions ? Write the complete equation in each case. (@ — Ethanal to 3-hydroxybutanal (i) Benzoie acid to m-nitrobenzyl alcohol (iii) Benzaldehyde to benzophenone 56/2/1 12 2,150