C2H2,acetylene

OPTIONS: joules

TEMPERATURE SCHEDULE

200.000 298.150 300.000 400.000 500.000 600.000

700.000 800.000 900.000 1000.000 1100.000 1200.000
1300.000 1400.000 1500.000 1600.000 1700.000 1800.000
1900.000 2000.000 2100.000 2200.000 2300.000 2400.000
2500.000 2600.000 2700.000 2800.000 2900.000 3000.000
3100.000 3200.000 3300.000 3400.000 3500.000 3600.000
3700.000 3800.000 3900.000 4000.000 4100.000 4200.000
4300.000 4400.000 4500.000 4600.000 4700.000 4800.000
4900.000 5000.000

NOTE: Thermodynamic properties calculated for temperatures outside the range of

the fitted data may have large errors. This program allows calculations only
for temperatures within 20% above or below the fitted temperature range.

COEFFICIENTS FOR FITTED THERMODYNAMIC FUNCTIONS

C2H2,acetylene Hf:TRC(10/93) w-3040. Gurvich,1991 pt1 p47 pt2 p39.

2 g 1/91 C 2.00H 2.00 0.00 0.00 0.00 0 26.03728 228200.000
200.000 1000.000 7 -2.0 -1.0 0.0 1.0 2.0 3.0 4.0 0.0 10005.839
1.598112089E+05-2.216644118E+03 1.265707813E+01-7.979651080E-03 8.054992750E-06
-2.433307673E-09-7.529233180E-14 0.000000000E+00 3.712619060E+04-5.244338900E+01
1000.000 6000.000 7 -2.0 -1.0 0.0 1.0 2.0 3.0 4.0 0.0 10005.839
1.713847410E+06-5.929106660E+03 1.236127943E+01 1.314186993E-04-1.362764431E-07
2.712655786E-11-1.302066204E-15 0.000000000E+00 6.266578970E+04-5.818960590E+01
THERMODYNAMIC FUNCTIONS CALCULATED FROM COEFFICIENTS FOR C2H2,acetylene

T Cp H-H298 S -(G-H298)/T H delta Hf log K

deg-K J/mol-K kJ/mol J/mol-K J/mol-K kJ/mol kJ/mol

0 0. -10.006 0. INFINITE 218.194 228.769 INFINITE

200 35.551 -3.916 185.098 204.680 224.284 228.390 -56.5378
298.15 44.001 0.000 200.916 200.916 228.200 228.200 -36.9091
300 44.139 0.082 201.189 200.917 228.282 228.196 -36.6625
400 50.332 4.825 214.792 202.730 233.025 227.985 -26.7336
500 54.694 10.087 226.517 206.342 238.287 227.672 -20.7829

600 58.062 15.731 236.797 210.579 243.931 227.233 -16.8223

700 60.904 21.682 245.966 214.991 249.882 226.702 -13.9994
800 63.446 27.902 254.267 219.389 256.102 226.127 -11.8874
900 65.776 34.365 261.876 223.693 262.565 225.545 -10.2489
1000 67.904 41.051 268.918 227.868 269.251 224.981 -8.9415

1100 69.854 47.940 275.483 231.901 276.140 224.445 -7.8745

1200 71.639 55.016 281.639 235.792 283.216 223.942 -6.9873
1300 73.259 62.262 287.438 239.544 290.462 223.470 -6.2382
1400 74.722 69.662 292.922 243.163 297.862 223.028 -5.5975
1500 76.042 77.202 298.123 246.655 305.402 222.612 -5.0433

1600 77.234 84.866 303.069 250.028 313.066 222.216 -4.5592

1700 78.311 92.645 307.784 253.287 320.845 221.837 -4.1328
1800 79.286 100.525 312.288 256.441 328.725 221.471 -3.7545
1900 80.171 108.499 316.599 259.495 336.699 221.114 -3.4165
2000 80.976 116.557 320.732 262.454 344.757 220.764 -3.1128

2100 81.710 124.692 324.701 265.324 352.892 220.418 -2.8385

2200 82.382 132.897 328.518 268.110 361.097 220.072 -2.5895
2300 82.998 141.166 332.194 270.817 369.366 219.725 -2.3625
2400 83.566 149.495 335.738 273.449 377.695 219.374 -2.1547
2500 84.090 157.878 339.160 276.009 386.078 219.018 -1.9639
2600 84.576 166.312 342.468 278.502 394.512 218.656 -1.7880
2700 85.029 174.792 345.669 280.931 402.992 218.285 -1.6255
2800 85.451 183.316 348.769 283.299 411.516 217.905 -1.4748
2900 85.848 191.881 351.774 285.608 420.081 217.514 -1.3347
3000 86.222 200.485 354.691 287.863 428.685 217.113 -1.2043

3100 86.576 209.125 357.524 290.064 437.325 216.699 -1.0824

3200 86.913 217.800 360.278 292.216 446.000 216.273 -0.9684
3300 87.236 226.507 362.958 294.319 454.707 215.834 -0.8616
3400 87.546 235.247 365.566 296.376 463.447 215.382 -0.7612
3500 87.846 244.016 368.109 298.390 472.216 214.916 -0.6668

3600 88.137 252.815 370.587 300.361 481.015 214.436 -0.5778

3700 88.422 261.643 373.006 302.292 489.843 213.942 -0.4938
3800 88.701 270.500 375.368 304.184 498.700 213.434 -0.4144
3900 88.976 279.384 377.675 306.039 507.584 212.912 -0.3392
4000 89.249 288.295 379.932 307.858 516.495 212.377 -0.2680

4100 89.520 297.233 382.139 309.643 525.433 211.827 -0.2005

4200 89.792 306.199 384.299 311.395 534.399 211.265 -0.1363
4300 90.063 315.192 386.415 313.115 543.392 210.689 -0.0753
4400 90.337 324.212 388.489 314.804 552.412 210.101 -0.0172
4500 90.612 333.259 390.522 316.465 561.459 209.501 0.0381

4600 90.891 342.334 392.517 318.096 570.534 208.890 0.0909

4700 91.174 351.437 394.474 319.701 579.637 208.268 0.1413
4800 91.461 360.569 396.397 321.278 588.769 207.637 0.1895
4900 91.754 369.730 398.286 322.831 597.930 206.996 0.2355
5000 92.052 378.920 400.143 324.358 607.120 206.348 0.2796