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Xi Neet Iseet Chemistry PDF
Xi Neet Iseet Chemistry PDF
Written according to the New Text book (2012-2013) published by the Maharashtra State
Board of Secondary and Higher Secondary Education, Pune.
Std. XI Sci.
Triumph Chemistry
Salient Features:
9 Exhaustive coverage of MCQs subtopic wise.
9 Each chapter contains three sections.
9 Section 1 contains easy level questions.
9 Section 2 contains competitive level questions.
9 Section 3 contains questions from various competitive exams.
9 Important formulae in each chapter.
9 Hints provided wherever relevant.
9 Useful for NEET and ISEET preparation.
Price : ` 200/-
Printed at:
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Target PUBLICATIONS PVT. LTD.
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Off.Tel: 022 6551 6551
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PREFACE
With the change in educational curriculum its now time for a change in Competitive Examinations.
NEET and ISEET are all poised to take over the decade old MHT-CET. The change is obvious not merely
in the names but also at the competitive levels. The state level entrance examination is ushered aside and the
battleground is ready for a National level platform. However, keeping up with the tradition, Target Publications
is ready for this challenge.
To be at pace with the changing scenario and equip students for a fierce competition, Target Publications
has launched the Triumph series. Triumph Chemistry is entirely based on Std XI (Science) curriculum of the
Maharashtra Board. This book will not only assist students with MCQs of Std. XI but will also help them
prepare for NEET and ISEET.
The content of this book has evolved from the State Board prescribed Text Book and weve made every
effort to include most precise and updated information in it. Multiple Choice Questions form the crux of this
book. We have framed them on every sub topic included in the curriculum. Each chapter is divided into 3
sections:
Section 1 consists of basic questions.
Section 2 consists of questions which can be asked at a competitive level.
Section 3 consists of questions compiled from various competitive examinations.
To end on a candid note, we make a humble request for students: Preserve this book as a Holy Grail even
after your first year in junior college. This book would prove as an absolute weapon in your arsenal for your
combat against Medical and Engineering entrance examinations.
Yours faithfully
Publisher
Contents
No. Topic Name Page No.
2 States of Matter 17
3 Structure of Atom 37
4 Periodic Table 71
5 Redox Reactions 91
9 Hydrogen 211
13 Alkanes 292
14 Alkenes 309
15 Alkynes 326
15. Joseph Priestly found that the gas evolved on 23. In SO2 and SO3, the ratio of the masses of
heating mercury oxide, supported vigorous oxygen which combine with a fixed mass of
burning. He named this gas as sulphur is 2:3. This is an example of the law of
(A) Oxygen (A) Constant proportion.
(B) Dephlogisticated air (B) Multiple proportion.
(C) Phlogisticated air (C) Reciprocal proportion.
(D) Hydrogen (D) Gay Lussac.
16. There are _____ fundamental SI units. 24. Among the following pairs of compounds, the
one that illustrates the law of multiple
(A) 5 (B) 3
proportions is
(C) 12 (D) 7
(A) NH3 and NCl3 (B) H2S and SO2
17. The phlogiston theory was suggested for (C) CuO and Cu2O (D) CS2 and FeSO4
(A) neutralisation reaction. 1.4 Daltons Atomic Theory
(B) oxidation reaction.
(C) reduction reaction. 25. Greek philosopher _____ had suggested that
(D) combustion reaction. matter is composed of extremely small
a-tomio.
18. Which one of the following is not a mixture? (A) Dalton (B) Aristotle
(A) Iodized table salt (C) Ptolemy (D) Democritus
(B) Gasoline
26. Dalton assumed that _____ are the smallest
(C) Liquefied Petroleum Gas (L. P. G.) particles of compound.
(D) Distilled water. (A) Atoms (B) Molecules
1.3 Laws of Chemical Combination (C) Ions (D) Elements
1.5 Concepts of Atoms and Molecules
19. The law of definite composition was proposed
by 27. Atoms have a mass of the order
(A) Lomonosov (A) 1026 kg (B) 1015 kg
(B) Antoine Lavoisier (C) 1026 g (D) 1015 g
(C) Joseph Proust
28. A _____ is an aggregate of two or more atoms
(D) Dalton of definite composition which are held
20. ___________ law of combining volumes together by chemical bonds.
states that Whenever gases combine, they do (A) Ion (B) Molecule
so in simple ratio by volumes. (C) Compound (D) Mixture
(A) Avogadros (B) Gay Lussacs 29. Atoms have a radius of the order
(C) Daltons (D) Thomsons (A) 1026 m (B) 1015 m
15
21. The sum of the masses of reactants and (C) 10 mm (D) 1015 m
products is equal in any physical or chemical 1.6 Atomic and Molecular Masses
reaction. This is in accordance with
30. SI unit of mass is
(A) Law of multiple proportion (A) kg (B) g
(B) Law of definite composition (C) m (D) m1
(C) Law of conservation of mass
31. Mole is the SI unit of________.
(D) Law of reciprocal proportion
(A) Volume
22. Pure water can be obtained from various (B) Pressure
sources, but it always contains hydrogen and (C) Amount of substance
oxygen, combined in a ratio of 1:8 by weight. (D) Density
This is an example of 32. ________ is the sum of the atomic mass of all
(A) Law of conservation of mass the atoms as given in the molecular formula of
(B) Avogadros law the substance.
(C) Law of definite composition (A) Molecular mass (B) Empirical weight
(D) Gay Lussacs law (C) Percentage weight (D) Percentage volume
2 Some Basic Concepts of Chemistry
TARGET Publications Std. XI: Triumph Chemistry
33. The mass percentage of each constituent 43. One _____ is the collection of 6.022 1023
element present in 100 g of compound is atom /molecules/ions.
called its (A) kg (B) g
(A) Molecular composition. (C) mole (D) cm
(B) Atomic composition.
(C) Percentage composition. 44. How many molecules are present in one gram
(D) Mass composition. of hydrogen?
(A) 6.02 1023 (B) 3.01 1023
34. Molar mass is a _____ quantity. (C) 2.5 1023 (D) 1.5 1023
(A) Vector (B) Imaginary
(C) Unitless (D) Useless 45. Avogadros number is
(A) number of atoms in one gram of element.
35. 1 amu is equal to
(B) number of millilitres which one mole of
1 1 a gaseous substance occupies at N.T.P.
(A) of C 12 (B) of O 16
12 14 (C) number of molecules present in one
(C) 1g of H2 (D) 1.66 1023 kg gram molecular mass of a substance.
36. 10 dm3 of N2 gas and 10 dm3 of gas X at the (D) number of elements in one gram of
same temperature contain the same number of compounds.
molecules. The gas X is 46. Which of the following law states that equal
(A) CO (B) CO2 volume of all gases contain equal number of
(C) H2 (D) NO molecules?
37. In the reaction (A) Boyles law
2Na2S2O3 + I2 Na2S4O6 + 2NaI, the (B) Charles law
equivalent weight of Na2S2O3 is equal to (C) Avogadros law
(Molecular mass = M) (D) Gay Lussacs law
(A) M (B) M/2 47. According to Avogadros law
(C) M/3 (D) M/4
1
(A) V (B) V T
38. A molal solution is one that contains 1 mole of P
a solute in (C) V n (D) all of these
(A) 1000 g of the solvent
(B) One litre of the solvent 48. Avogadros law distinguishes between
(C) One litre of the solution (A) Cations and anions
(D) 22.4 litres of the solution (B) Atoms and molecules
(C) Atoms and ions
39. Recently the unit of atomic mass amu is
(D) Molecules and ions
replaced by
(A) u (B) mol 49. One mole of H2O corresponds to
(C) g (D) kg (A) 22.4 litres at 1 atm and 25 C
40. The molecular mass of hydrogen peroxide is (B) 6.02 1023 atoms of hydrogen and
34. What is the unit of molecular mass? 6.02 1023 atoms of oxygen
(A) g (B) mol (C) 18 g
1
(C) g mol (D) mol g1 (D) 1 g
52. What is the mass of 0.5 mole of ozone molecule? 62. The starting material which takes part in
(A) 8g m (B) 16 g chemical reaction is called
(C) 24 g (D) 48 g (A) Product (B) Reactant
53. Which one of the following pairs of gases (C) Catalyst (D) Starter
contains the same number of molecules 63. ________ is the quantitative relationship
(A) 16 g of O2 and 14 g of N2 between the reactants and products in a
(B) 8 g of O2 and 22 g of CO2 balanced chemical equation.
(C) 28 g of N2 and 22 g of CO2 (A) Stoichiometry (B) Complexometry
(D) 32 g of O2 and 32 g of N2 (C) Chemistry (D) Reactions
54. One mole of oxygen weighs______.
64. The _____ coefficients are the coefficients of
(A) 8g (B) 32g
reactants and products in the balanced
(C) 1g (D) 6.023 1023 g
chemical reaction.
55. The number of atoms present in a molecule of (A) balanced
a substance is called ________. (B) chemical
(A) Atomicity (B) Volume (C) stoichiometric
(C) Density (D) Mass (D) molar
1.8 Percentage Composition and Molecular Miscellaneous
Formula
65. Which of the following is correct?
56. The percentage composition of carbon in urea,
[CO(NH2)2] is (A) 1 L = 1 dm3
(A) 40% (B) 50% (B) 1 L = 10 dm3
(C) 20% (D) 80% (C) 10 L = 1 dm3
(D) 1 L = 1 m3
57. _____ of a compound is the chemical formula
indicating the relative number of atoms in the 66. One mole of CO2 contains
simplest ratio. (A) 6.022 1023 atoms of C
(A) Empirical formula (B) 6.022 1023 atoms of O
(B) Molecular formula (C) 18.1 1023 molecules of CO2
(C) Empirical mass
(D) 3 g atoms of CO2
(D) Molecular mass
58. _____ indicates the actual number of 67. Chemical formula cannot be determined by
constituent atoms in a molecule. using
(A) Empirical formula (A) Raman Spectroscopy
(B) Molecular formula (B) Nuclear magnetic resonance
(C) Empirical mass (C) Titration
(D) Molecular mass (D) X-ray diffraction method
59. Empirical formula of glucose is 68. Which of the following reactions has the ratio
(A) C6H12O6 (B) C6H11O6 of volumes of reacting gases and the product
(C) CHO (D) CH2O as 1:2:2?
1.9 Chemical Reactions and Stoichiometry (A) 2CO(g) + O2(g) 2CO2(g)
(B) O2(g) + 2H2(g) 2H2O(g)
60. _____ reactant is the reactant that reacts (C) H2(g) + F2(g) 2HF(g)
completely but limits further progress of the
(D) N2(g) + 3H2(g) 2NH3(g)
reaction.
(A) Oxidizing (B) Reducing 69. Volume occupied by 1 g molecular weight of
(C) Limiting (D) Excess any gas is called
61. _____ reactant is the reactant which is taken in (A) Gram molecular volume
excess than the limiting reactant. (B) Gram atomic volume
(A) Oxidizing (B) Reducing (C) Gram molecular weight
(C) Limiting (D) Excess (D) Gram atomic weight
4 Some Basic Concepts of Chemistry
TARGET Publications Std. XI: Triumph Chemistry
4. _______ cannot be carried out in a lab. 16. Two elements, X (Atomic mass 16) and Y
(A) Photosynthesis (B) Reduction (Atomic mass 14) combine to form
(C) Oxidation (D) Hydration compounds A, B and C. The ratio of different
masses of Y which combine with fixed mass
5. The compound which is added to table salt for of X in A, B and C is 1:3:5. If 32 parts by
maintaining proper health is mass of X combine with 84 parts by mass of Y
(A) KCl (B) KBr in B, then in C, 16 parts by mass of X will
(C) NaI (D) MgBr2 combine with
1.2 Historical Approach to Particulate Nature (A) 14 parts by mass of Y
of Matter (B) 42 parts by mass of Y
(C) 70 parts by mass of Y
6. SI unit of velocity is (D) 82 parts by mass of Y
(A) km s1 (B) km hr1
(C) m s2 (D) m s1 17. The volume of oxygen required for complete
combustion of 0.25 cm3 of CH4 at S.T.P is
7. SI unit of temperature is (A) 0.25 cm3 (B) 0.5 cm3
(A) K (B) C (C) 0.75 cm3 (D) 1 cm3
(C) F (D) D
18. How many litres of ammonia will be formed
8. Electrochemical equivalence has unit ____. when 2 L of N2 and 2 L of H2 are allowed to
(A) kg m s1 (B) kg m2 s1 react?
1
(C) kg C (D) kg m1 s2 (A) 0.665 (B) 1.0
9. Magnitude of pico is _____. (C) 4.00 (D) 1.33
(A) 1012 (B) 1015 19. Two elements, A and B, combine to form a
12
(C) 10 (D) 1015 compound in which a g of A combines with
10. One atmosphere is equal to b1 and b2g of B respectively. According to
(A) 101.325 K pa (B) 1013.25 K pa law of multiple proportion _____.
5
(C) 10 Nm (D) 107 Nm (A) b1 = b2
11. Which of the following elements of matter (B) b1 and b2 bear a simple whole number
would best convey that there is life on earth? ratio
(A) Oxygen (B) Hydrogen (C) a1 and b1 bear a whole number ratio
(C) Carbon (D) Iron (D) No relation exists between b1 and b2
5
Some Basic Concepts of Chemistry
Std. XI: Triumph Chemistry TARGET Publications
20. 1.0 g of an oxide of A contained 0.5 g of A. 28. From the following masses, the one which is
4.0 g of another oxide of A contained 1.6 g of expressed nearest to the milligram is
A. The data indicate the law of (A) 16 g (B) 16.4 g
(A) Reciprocal proportions (C) 16.428 g (D) 1.64284 g
(B) Constant proportions
29. If the equivalent weight of a trivalent metal is
(C) Conservation of energy
32.7, the molecular weight of its chloride will
(D) Multiple proportions
be
21. Hydrogen and oxygen combine to form H2O2 (A) 68.2 (B) 103.7
and H2O containing 5.93% and 11.29% of (C) 204.6 (D) 32.7
hydrogen respectively. The data illustrates
(A) Law of conservation of mass 30. The mass of 1 1022 molecules of
(B) Law of constant proportions CuSO4.5H2O is
(C) Law of reciprocal proportions (A) 41.59 g (B) 415.9 g
(D) Law of multiple proportions (C) 4.159 g (D) 42.2 g
22. One unit volume of N2 reacts with 3 unit 31. The number of atoms in 6 amu of He is
volumes of H2 to form 2 unit volumes of NH3. (A) 18
This is in accordance with (B) 18 6.022 1023
(A) Avogadros law (C) 54
(B) Gay Lussacs law (D) 54 6.023 1023
(C) Law of conservation of mass 1.7 Avogadros Law
(D) Law of chemical combination
32. The number of molecules in 22.4 dm3 of
1.4 Daltons Atomic Theory nitrogen gas at STP is
23. _____ proposed some symbols for some (A) 6.023 1020 (B) 6.023 1023
common atoms and molecules. (C) 22.4 1020 (D) 22.4 1023
(A) Democritus (B) Newton
33. Number of moles of water in 1 L of water with
(C) Thompson (D) Dalton density 1 g/cc are
1.5 Concepts of Atoms and Molecules (A) 55.56 (B) 45.56
(C) 56.55 (D) 56.45
24. Atoms are the smallest particle of the ___.
(A) Compound (B) Substance 34. 27 g of Al (Atomic mass = 27) will react with
(C) Mixture (D) Element oxygen equal to
(A) 24 g (B) 8 g
25. Which one of the following properties of an (C) 40 g (D) 10 g
element is not variable?
(A) Valency 35. The largest number of molecules is present in
(B) Atomic weight (A) 54 g of nitrogen peroxide
(C) Equivalent weight (B) 28 g of carbon dioxide
(D) Molar mass (C) 36 g of water
(D) 46 g of ethyl alcohol
1.6 Atomic and Molecular Masses
36. How many moles of electrons weigh one
26. Which one of the following is not the kilogram?
standard for atomic mass? 1
(A) 11 H (B) 12 (A) 6.023 1023 (B) 1031
6 C 9.108
14 16
(C) C (D) O 6.023 1
1054 108
6 8
(C) (D)
9.108 9.108 6.023
27 Which of the following weighs the least ?
(A) 2.0 gram mole of CO2. 37. Which of the following has maximum number
(B) 0.1 mole of sucrose ( C12 H22 O11). of atoms?
(C) 1 gram atom of calcium. (A) 18 g of H2O (B) 16 g of O2
(D) 1.5 mole of water. (C) 4.4 g of CO2 (D) 16 g of CH4
6 Some Basic Concepts of Chemistry
TARGET Publications Std. XI: Triumph Chemistry
38. Which of the following contains more 47. The molecular mass of an organic compound
molecules? is 78. Its empirical formula is CH. The
(A) 1 g CO2 (B) 1 g N2 molecular formula is
(C) 1 g H2 (D) 1 g CH4 (A) C2H4 (B) C2H2
(C) C6H6 (D) C4H4
39. 1g-atom of nitrogen represents
(A) 6.02 1023 N2 molecules 48. Percentage of nitrogen in urea is about
(A) 46 % (B) 85 %
(B) 22.4 L of N2 at N.T.P.
(C) 18 % (D) 28 %
(C) 11.2 L of N2 at N.T.P.
(D) 28 g of nitrogen 49. Which of the following has same molecular
formula and empirical formula?
40. 1 atom of an element weighs 1.792 1022 g. (A) CO2 (B) C6H12O6
The Atomic mass of the element is (C) C2H2 (D) C2H2O4
(A) 108 (B) 17.92
(C) 1.192 (D) 64 50. The empirical formula of a compound is
CH2O. 0.0835 moles of the compound
41. The number of sulphur atoms present in contains 1.0 g of hydrogen. Molecular formula
0.2 moles of S8 molecules is of the compound is
(A) 4.82 1023 (B) 9.63 1022 (A) C2H12O6 (B) C5H10O5
(C) 9.63 1023 (D) 1.20 1023 (C) C4H8O8 (D) C3H6O3
1.9 Chemical Reactions and Stoichiometry
42. The mass of 1 atom of hydrogen is
(A) 1 g (B) 0.5 g 51. What mass of CaO will be obtained by heating
(C) 1.6 1024 g (D) 3.2 1024 g 3 mole of CaCO3 [Atomic mass of Ca = 40] ?
(A) 150 g (B) 168 g
43. 1 mol of CH4 contains (C) 16.8 g (D) 15 g
(A) 6.02 1023 atoms of H
52. Volume of O2 required to produce 44 g of CO2
(B) 4 g atom of Hydrogen
by combustion of carbon is
(C) 1.81 1023 molecules of CH4 (A) 2.24 L (B) 22400 mL
(D) 3.0 g of carbon (C) 22.4 mL (D) 224 mL
44. Which of the following has smallest number 53. 3 g of H2 reacts with 29 g of O2 to yield water.
of molecules Which is the limiting reactant?
(A) 0.1 mol of CO2 gas (A) H2 (B) O2
(B) 11.21 of CO2 gas at NTP (C) H2O (D) none of there
(C) 22 g of CO2 gas Miscellaneous
(D) 22.4 g 103 mL of CO2 gas
54. The unit J Pa1 is equivalent to
1.8 Percentage Composition and Molecular (A) m3 (B) cm3
Formula (C) dm 3
(D) dm3
45. Which pair of species have same percentage of 55. What volume of ammonia would be formed
carbon? when 0.36 dm3 of nitrogen reacts with
sufficient amount of hydrogen? (all volumes
(A) CH3COOH and C6H12O6
are measured under same conditions of
(B) CH3COOH and C2H5OH temperature and pressure)
(C) HCOOCH3 and C12H22O11 (A) 0.36 dm3 (B) 0.72 dm3
(D) C6H12O6 and C12H22O11 (C) 0.18 dm 3
(D) 0.12 dm3
46. Two elements X (Atomic mass 75) and Y 56. If the law of conservation of mass was to hold
(Atomic mass 16) combine to give a true, then 20.8 g of BaCl2, on reaction with 9.8 g
compound having 75.8% X. The formula of of H2SO4 will produce 7.3 g of HCl and ______
the compound is BaSO4.
(A) XY (B) XY2 (A) 11.65 g (B) 23.3 g
(C) X2Y2 (D) X2Y3 (C) 25.5 g (D) 30.6 g
7
Some Basic Concepts of Chemistry
Std. XI: Triumph Chemistry TARGET Publications
57. Two containers of the same size are filled 4. The law of multiple proportions is illustrated
separately with H2 gas and CO2 gas. Both the by the two compounds [NCERT 1972]
containers under the same T and P will contain (A) Sodium chloride and sodium bromide
the same (B) Ordinary water and heavy water
(A) Number of atoms. (C) Caustic soda and caustic potash
(B) Weight of gas. (D) Sulphur dioxide and sulphur trioxide
(C) Number of molecules.
(D) Number of electrons. 5. After a chemical reaction, the total mass of
reactants and products [MP PMT 1989]
58. A compound made of two elements A and B
(A) Is always increased
are found to contain 25% A (Atomic mass
(B) Is always decreased
12.5) and 75% B (Atomic mass 37.5). The
simplest formula of the compound is (C) Is not changed
(A) AB (B) AB2 (D) Is always less or more
(C) AB3 (D) A3B 6. The law of definite proportions is not
59. Hydrogen reacts with nitrogen to form applicable to nitrogen oxide because
ammonia as: N2(g) + 3H2(g) 2NH3(g) [EAMCET 1981]
The amount of ammonia that would be (A) Nitrogens atomic weight is not constant
produced if 200 g of H2 reacts with N2 is (B) Nitrogens molecular weight is variable
(A) 1032.2 g (B) 11332 g (C) Nitrogens equivalent weight is variable
(C) 1133.3 g (D) 8692.6 g (D) Oxygens atomic weight is variable
7. Which of the following pairs of substances
SECTION - 3
illustrate the law of multiple proportions?
1.2 Historical Approach to Particulate Nature [CPMT 1972, 78]
of Matter (A) CO and CO2
(B) H2O and D2O
1. In known elements, the maximum number is (C) NaCl and NaBr
of [CPMT 1985] (D) MgO and Mg(OH)2
(A) Metals (B) Non-metals
(C) Metalloids (D) None of these 8. Different proportions of oxygen in the various
1.3 Laws of Chemical Combination oxides of nitrogen proves the
[MP PMT 1985]
2. Two samples of lead oxide were separately (A) Equivalent proportion
reduced to metallic lead by heating in a (B) Multiple proportion
current of hydrogen. The weight of lead from (C) Constant proportion
one oxide was half the weight of lead obtained
(D) Conservation of matter
from the other oxide. The data illustrates
[AMU 1983] 9. A sample of pure carbon dioxide, irrespective
(A) Law of reciprocal proportions of its source contains 27.27% carbon and
(B) Law of constant proportions 72.73% oxygen. The data supports
(C) Law of multiple proportions [AIIMS 1992]
(D) Law of equivalent proportions (A) Law of constant composition
3. Which of the following is the best example of (B) Law of conservation of mass
law of conservation of mass? [NCERT 1975] (C) Law of reciprocal proportions
(A) 12 g of carbon combines with 32 g of (D) Law of multiple proportions
oxygen to form 44 g of CO2.
(B) When 12 g of carbon is heated in a 10. Which one of the following pairs of
vacuum there is no change in mass. compounds illustrates the law of multiple
(C) A sample of air increases in volume proportion? [EAMCET 1989]
when heated at constant pressure but its (A) H2O, Na2O
mass remains unaltered. (B) MgO, Na2O
(D) The weight of a piece of platinum is the (C) Na2O, BaO
same before and after heating in air. (D) SnCl2, SnCl4
8 Some Basic Concepts of Chemistry
TARGET Publications Std. XI: Triumph Chemistry
1.4 Daltons Atomic Theory 20. A molar solution is one that contains one mole
of a solute in [IIT 1986]
11. The law of multiple proportions was proposed (A) 1000 g of the solvent
by [IIT 1992] (B) One litre of the solvent
(A) Lavoisier (B) Dalton (C) One litre of the solution
(C) Proust (D) Gay-Lussac (D) 22.4 litres of the solution
1.5 Concepts of Atoms and Molecules 21. 74.5 g of a metallic chloride contains 35.5 g of
chlorine. The equivalent weight of the metal is
12. The number of atoms in 4.25 g of NH3 is
approximately [CBSE PMT 1999] [CPMT 1986]
(A) 19.5 (B) 35.5
(A) 1 1023 (B) 2 1023
(C) 39.0 (D) 78.0
(C) 4 1023 (D) 6 1023
1.7 Avogadros Law
13. Equivalent weight of crystalline oxalic acid is
[MP PMT 1995] 22. The number of water molecules in 1 litre of
(A) 30 (B) 63 water is [EAMCET 1990]
(C) 53 (D) 45 (A) 18 (B) 18 1000
(C) NA (D) 55.55 NA
1.6 Atomic and Molecular Masses
23. The numbers of moles of BaCO3 which
14. Which property of an element is always a contain 1.5 moles of oxygen atoms is
whole number? [MP PMT 1986] [EAMCET 1991]
(A) Atomic weight (A) 0.5 (B) 1
(B) Equivalent weight (C) 3 (D) 6.02 1023
(C) Atomic number
24. The number of moles of sodium oxide in
(D) Atomic volume 620 g is [BHU 1992]
15. The modern atomic weight scale is based on (A) 1 mol (B) 10 moles
[MP PMT 2002] (C) 18 moles (D) 100 moles
(A) C12 (B) O16 25. How many atoms are contained in one mole of
(C) H1 (D) C13 sucrose (C12H22O11) [Pb. PMT 2002]
16. The mass of a molecule of water is (A) 45 6.023 1023 atoms/mole
[Bihar CEE 1995] (B) 5 6.623 1023 atoms/mole
26
(A) 3 10 kg (B) 3 1025kg (C) 5 6.023 1023 atoms/mole
26
(C) 1.5 10 kg (D) 2.5 1026 kg (D) None of these
1.8 Percentage Composition and Molecular
17. Sulphur forms the chlorides S2Cl2 and SCl2.
Formula
The equivalent mass of sulphur in SCl2 is
[EAMCET 1985] 26. The percentage of oxygen in NaOH is
(A) 8 g/mole (B) 16 g/mole [CPMT 1979]
(C) 64.8 g/mole (D) 32 g/mole (A) 40 (B) 60
(C) 8 (D) 10
18. In chemical scale, the relative mass of the
isotopic mixture of oxygen atoms (O16, O17, 27. If two compounds have the same empirical
O18) is assumed to be equal to formula but different molecular formula, they
[Bihar MADT 1981] must have [MP PMT 1986]
(A) 16.002 (B) 16.00 (A) Different percentage composition
(C) 17.00 (D) 11.00 (B) Different molecular weights
(C) Same viscosity
19. The weight of a molecule of the compound (D) Same vapour density
C60H122 is [AIIMS 2000]
28. The empirical formula of an acid is CH2O2,
(A) 1.4 10 g
21
the probable molecular formula of acid may be
(B) 1.09 1021g [AFMC 2000]
(C) 5.025 1023g (A) CH2O (B) CH2O2
(D) 16.023 1023g (C) C2H4O2 (D) C3H6O4
9
Some Basic Concepts of Chemistry
Std. XI: Triumph Chemistry TARGET Publications
Section 1
1. (A) 2. (B) 3. (D) 4. (D) 5. (B) 6. (B) 7. (D) 8. (A) 9. (B) 10. (D)
11. (C) 12. (C) 13. (A) 14. (D) 15. (B) 16. (D) 17. (D) 18. (D) 19. (C) 20. (B)
21. (C) 22. (C) 23. (B) 24. (C) 25. (D) 26. (A) 27. (A) 28. (B) 29. (D) 30. (A)
31. (C) 32. (A) 33. (C) 34. (C) 35. (A) 36. (A) 37. (A) 38. (A) 39. (A) 40. (C)
41. (B) 42. (D) 43. (C) 44. (A) 45. (C) 46. (C) 47. (C) 48. (B) 49. (C) 50. (D)
51. (A) 52. (C) 53. (A) 54. (B) 55. (A) 56. (C) 57. (A) 58. (B) 59. (D) 60. (C)
61. (D) 62. (B) 63. (A) 64. (C) 65. (A) 66. (A) 67. (C) 68. (B) 69. (A)
Section 2
1. (C) 2. (C) 3. (C) 4. (A) 5. (C) 6. (D) 7. (A) 8. (C) 9. (A) 10. (A)
11. (C) 12. (B) 13. (C) 14. (C) 15. (A) 16. (C) 17. (B) 18. (D) 19. (B) 20. (D)
21. (D) 22. (B) 23. (D) 24. (D) 25. (B) 26. (C) 27. (D) 28. (C) 29. (C) 30. (C)
31. (A) 32. (B) 33. (A) 34. (A) 35. (C) 36. (D) 37. (D) 38. (C) 39. (C) 40. (A)
41. (C) 42. (C) 43. (B) 44. (A) 45. (A) 46. (B) 47. (C) 48. (A) 49. (A) 50. (A)
51. (B) 52. (B) 53. (A) 54. (A) 55. (B) 56. (B) 57. (C) 58. (A) 59. (C)
Section 3
1. (A) 2. (C) 3. (A) 4. (D) 5. (C) 6. (C) 7. (A) 8. (B) 9. (A) 10. (D)
11. (B) 12. (D) 13. (B) 14. (C) 15. (A) 16. (A) 17. (D) 18. (B) 19. (A) 20. (C)
21. (C) 22. (D) 23. (A) 24. (B) 25. (A) 26. (A) 27. (B) 28. (B) 29. (D) 30. (C)
31. (A) 32. (C) 33. (C) 34. (C). 35. (C) 36. (B)
Section 1
36. As, Molecular mass of CO = 28 and
Molecular mass of N2 = 28
39. u means unified mass.
41. No. of molecules = n 6.022 1023
mass of oxygen 16
Now, n = = = 0.5
molar mass of oxygen 32
Number of molecules = 0.5 6.022 1023 = 3.011 1023
47. Volume of gas is directly proportional to number of molecules.
50. Molecular formula of benzene is C6H6.
Molecular mass = sum of atomic weight of all the atoms
Molecular mass = 12 6 + 6 1
= 72 + 6
= 78
According to Avogadros number, The gram molecules of benzene is equal to 78g of C6H6
51. Nitrogen (14) : Oxygen (16)
Ratio is 7 : 8
52. 1 mole of ozone(O3) = 48 g
0.5 mole of ozone(O3) = ?
0.5 48
0.5 mole of ozone(O3) = = 24 g.
1
16 1
53. 16g O2 has number of moles = =
32 2
14 1
14g N2 has number of moles = =
28 2
Number of moles are same, so number of molecules are same.
56. Urea [H2N CO NH2]
60 gm of urea contains 12 g of carbon.
12
100 gm of urea contains 100 = 20 %
60
Section 2
16. In compound B, 32 parts of X react with 84 parts of Y.
In compound B, 16 parts of X react with 42 parts of Y.
In compound C, 16 parts of X react with x parts of Y.
The ratio of masses of Y which combine with fixed mass of X in compounds B and C is 3:5.
B 42 3
C x 5
42 5
x= = 70
3
17. CH4 + 2 O2 CO2 + 2H2O
(1 vol.) (2 vol.) (1 vol.) (2 vol.)
1 cm3 of CH4 gives 2 cm3 of O2
0.25 cm3 of CH4 gives 0.5 cm3 of O2
11
Some Basic Concepts of Chemistry
Std. XI: Triumph Chemistry TARGET Publications
55. N2 + 3 H2 2 NH3
(1 vol.) (3 vol.) (2 vol.)
1 : 3 : 2
0.36 : 3 0.36 : x
2 1.08 3
x= = 0.72 dm
3
56. BaCl2 + H2SO4 HCl + BaSO4
20.8 + 9.8 = 7.3 + x
x = 23.3
58.
Elements % Composition Atomic Mass Moles Ratio
25 2
A 25 12.5 =2 =1
12.5 2
75 2
B 75 37.5 =2 =1
37.5 2
Hence the compound will be AB (1 : 1)
59. N2 + 3H2 2NH3
(28 g) (6 g) (34 g)
6 gms of H2 produces 34 gms NH3
34 200
200 gms of H2 produces = 1133.3 gms
6
Section 3
12. 17gm NH3 contains 6 1023 molecules of NH3
6 1023
4.25gm NH3 contains = 4.25
17
6 1023 4.25
Number of atoms = 4 = 6 1023.
17
13. Molecular mass of crystalline Oxalic acid i.e. C2H2O4. 2H2O is 126
Molecular mass 126
Equivalent weight = = = 63
Valency 2
M
22. d= (d = density, M= mass, V =volume)
V
Since d = 1
So, M = V
18 gm = 18 mL
18 ml = NA molecules (NA = Avogadro's number)
N
1000 mL = A 1000 = 55.555 NA.
18
29. C = 24 g, H = 4 g, O = 32 g
So, Molecular formula = C2H4O2
So, Empirical formula = CH2O
(Simplest formula).