Nama siswa : Lucky Arif D

1.Convert these IUPAC names into their skeletal structures.

1. trans-2,5-dimethyl-3-heptene
2. 3-ethyl-5-propyloctane
3. cis-2-methyl-1-ethylcyclopentane
4. 4-ethyl-1-hexyne
5. trans-4,5,6,7-tetramethyl-2-nonene

2.Give the IUPAC name for the following alkenes and alkynes.

3. A 0.5865-g sample of lactic acid (HC3H5O3) is burned in a calorimeter whose heat capacity is
4.812 kJ/C. The temperature increases from 23.10 C to 24.95 C. Calculate the heat of
combustion of lactic acid (a) per gram and (b) per mole.

Answers: (a) 15.2 kJ/g, (b) 1370 kJ/mol.

4. Calculate H for the reaction

2 C(s) + H2 (g) C2H2 (g)

given the following chemical equations and their respective enthalpy changes

6. The standard enthalpy of combustion of cyclopropane is 2091 kJ mol1 at 25C.

Additionally, the enthalpy of formation of its isomer propene is +20.42 kJ mol1 .
 In terms of given variables, this is written mol1 propene enthalpy of formation :
rH = 2091 kJ mol1 cyclopropane combustion fH = +20.42 kJ .Calculate the
enthalpy of formation of cyclopropane?
7. What is the name of the alkane shown?
a.

b.

8. Draw structural formulas for each of the following.

a. 4-ethyloctane
b. 2-methylnonane
c. 3,3-dimethylpentane
d. 3-ethylpentane
e. 3-ethyl-2-methylheptane