Answer Key and Solution Jee Advanced

om
JEE ADVANCED
.c
ANSWER KEY AND SOLUTION
on
u ti
www.ezyEXAMS.com / www.ezyEXAMSolution.com
Q. No. PHYSICS CHEMISTRY MATHEMATICS
sol
1. C D B
2. C D C
xam
3. B A D
4. B C A
5. B C D
ye
6. C .ez C A
7. B A C
8. C A, B, C A, B, D
ww
9. A, B, C, D B A, B, C
10. A, B, C B, C B, C
/ w
11. A, B, C A, C A, B
12. A C C
13. B B D
m
14. C A D
.co
15. D A B
16. A D A
ms
(A)  s, (B)  pt, (A)  r, (B)  pt, (A)  prt, (B)  q,

1.
(C)  q, (D)  pr (C)  qs, (D)  qs (C)  t, (D)  s
(A)  pqt, (B)  prt, (A)  pqs, (B)  q, (A)  qt, (B)  q,
2.
exa
(C)  s, (D)  qr (C)  rt, (D)  q (C)  prs, (D)  t

1. 3 4 1
2. 5 7 2
ezy
3. 9 3 1
4. 9 3 5
w.
5. 2 2 7
6. 4 3 2
ww
Physics PART – I
om
SECTION – A
1. C
.c
1 
tan1  tan  
on
e 
vertical component after collision  eucos 
& Horizontal component  u sin 
u ti
u sin  1 
 tan      tan1  tan  
eucos  e 
sol
2. C
Zero Ring T
xam
 T  f  2a
TR  fR  2R  2
a
a  R f
 f  0.
3. B
ye
.ez
V  t /RC1 V
 I1  e & I2  e t /RC2
R R
t 1 1 
I1
ww
   
  eR  C1 C2 
I2
t
I1
  e RC1
/ w
I2
4. B
1 1
f  , f  50 
m
2 LC 2 LC / K
2
 f  50   50   100 
K    K  1  2    1 
.co

 f   f   10 4 
 K  1.01
ms
5. B B
 r1  2R sin30o , r2  2R sin 60o  R 3  R
A
exa
 i i 
BD  B AC  BCB   0 sin 60o  0 sin30 o 
 4 r1 4 r2  i i r2 r1
0 i o
30 30o
 BD 
ezy
30 o 30o
4 R 3
C R R D
6. C
w.
V V V
Beats   
4 4      4     
ww
V

4 2
7. B
3
sin60o   sin90o
2
om
3 3
 ,
2 2
3 3
.c

4
on
8. C
  13.6  10.2  3.4eV 
 1st collision
u ti
&  3.4  15  11.6eV  2nd collision.
sol
9. A, B, C, D
1
V
n
xam
1
P.E.    
r
T  r 3/ 2
1
ye
T.E.    
r .ez
10. A, B, C
2 2
 Vs2   3    8  4   25  Vs  5 volt
ww
Vs
Z  5
I
VR  3  1 R  R  3
R 3
/ w
P.F.    0.6
Z 5
 VL  VC  I lags V.
11. A, B, C
m
1 1 1 v  v
     1  
f v u f  u
.co
since m is positive in the graph,

v v
m    
ms
u u
v  v
 m    1    
f  u
exa
1
 int ercept on m  axis  1 & tan  
f
ezy
12. A
V
  , OP  x 2  y 2
R
origin is ins tan taneous centre of rotation
w.
V 2
 VP  r    OP   x  y2
R
ww
13. B  a  R   2a
 a  R 
2 ac
V V2
om
ac  2R    R 
R R anet
  2a 
.c
ac
tan   1
2a
on
  45o
u ti
14. C
Q 300
Thermal heat capacity, C    15J / o C
T 20
sol
15. D
Q 300
xam
Specific heat capacity, S    600J / kg o C
m T 0.025  20
16. A
Molar heat capacity

Q

300
ye
.ez
nT  25 
   20 
 50 
ww
 30J / mol o C
SECTION – B
1. (A  s) (B  p, t) (C  q) (D  p, r)
/ w
In wrist watch spring force is not dependent on gravity.

m
T  2
K
m
2. (A  p, q, t) (B  p, r, t) (C  s) (D  q, r)
In nuclear reactions energy, charge, mass and momentum remain conserved.
.co
SECTION – C
1. 3
ms
for Rmax ,   45o  Hmax 

 20  
sin2 45o   10m
2  10
 Hmax allowed  5m,
exa
2
 20  sin2 
5    30o
2  10
2
ezy
 20  sin60o
 Rmax  m  20 3m.
10
2. 5
w.
1

 Mcylinder  R2  3R . Icylinder   2
3R3  R2  
ww
2 22 
Msphere  R3 , Isphere   R3   R2
3 53 
29 5
Iremaining portion  Icylinder  2 Isphere  R .
30
3. 9 18 m/s
18 sin 30o
 18 sin30o  r    1
om
18cos 30o
   9 m / s.
.c
on
1m
60o
u ti
0.5m
sol
4. 9
1 1 1
  
F f1 f2
xam
    
1  1  1 1   2  1 1 
    1     1   
24  4   20 20   4   20 20  

 3   3  
ye
5
  1  2     .
9 .ez
5. 2
2
V 200 V 2  200 
I  
ww
 2.5A & P    500 watt

R 80 R 80
When the wire is divided into two equal parts and connected in parallel we get maximum power.
 Re sis tance of each part  40
/ w
 Imax  5A
2
V2  200 
 Pmax    2000W  2kw.
Req  20 
m
6. 4
.co
Q Q
 VAP  , VPB 
3 6
ms
Q Q
 12    Q  24C
3 6
24
 VAP  8
exa
3
 VA  VP  8  VP  4volt.
ezy
w.
ww
Chemistry PART – II
om
SECTION – A
.c
1. D
on
H
H H
B B
u ti
H
H H
H CH3 CH3
sol
B 2 H6 B B
methylation
CH3
CH3
xam
H
2. D
H
ye
+
OH OH +
CH2 H
H+ ring. exp
+
.ez
-H2 O
HO HO
HO HO
OH HO
ww
OH OH
/ w
+
H /excess
similar repetation
HO
m
HO
.co
3. A
At nodal surface,  = 0
ms
2 2
r  Å = 1Å
z z
exa
4. C
+2
Co – ordination no of Fe in D is 6
ezy
-
+
- Na +2
Fe (a sandwhich compound)
C
w.
-
ww
5. C
O
O
om
Zn(Hg) SOCl2
AlCl3 HCl
+ O
HO HO Cl O
.c
O
A B O
O C
on
AlCl3
Br
u ti
NaBH4
NBS/CCl4 H2SO4

F E D
sol
G OH O
ONa
OH
heat
xam
H
ye
6. C
O O O
.ez
H -
OH H OH
(a) -
+ OH
-
ww
O-D D - OD D - OD
O O DO- O O
H
H -
- D D
(b)
/ w
-
DO
-
m
O O O
D O D D
D D H D - OD
D
.co
D
D D
D
D H
ms
H
DO- DO - D -
OD
exa
O O
O D D
D D D D
O-D D
D D
ezy
H
-
- D - OD
D D D D
D
DO - D
w.
O O
ww
D D
D D
D Repeat last two step
D
D D
D D D D D
D
O O O
H
-
om
(d) H OH
OH -
OH
H HO - H
.c
7. A
on
Synergic bonding.
u ti
8. A, B, C
K2 Ho  T2  T1 
sol
log    K1 & K 2 are eq. cons tan t
K1 2.303R  T1T2 
K2 Ea  T2  T1 
log    K1 & K 2 are rate cons tan t
xam
K1 2.303R  T1T2 
9. B
ye
H3C Me CH3
+ 
H3C N -
OH H2C
.ez
CH3
H3C Me CH3
(Major product)
ww
Due to greater probability of losing -H (9 : 3 ratio).

10. B, C
/ w
(b) conjugate base of H2PO4 is HPO24 
1
(c) pH of 0.1 M NaCl (aqueous solution) = pK w
2
m
11. A, C
.co
A 3  3e  Al
4.5
ms
Number of moles of Al produced   0.166

27
Number of moles of electrons used  3  0.166
exa
1
H  e   H2
2
ezy
1
Number of moles of H2 produced   3  0.166
2
Volume of H2 produced  1.5  0.166  22.4  5.57  5.6
w.
12. C
2nd step is r.d.s. in sulphonation reaction.
ww
13. B
2nd step is fast step in nitration.
14. A
 a
 P    V  b   RT
om
 V
on converting into virial equation from, we get
.c
  a  
 b  2  2 3 
PV  RT  RT   b  b  ....... to higher power of n
on
2 4
…(i)
 V V V 
 
 
u ti
For Boyle’s temperature, 2nd virial co-efficient becomes zero

a
sol
b 
RT 2
a
xam
TB 
Rb
a
 TB2 
RB
2a
ye
 Ti   Ti  2TB2
Rb .ez
15. A
ww
Let Boyle’s temperature, TB'
a
/ w
 TB 
Rb
8a a
TB'  2  2TB
R  2b Rb
m
.co
16. D
ms
2
b = 0.04
b = 0.2 lit/mol
exa
Vreal = 4  22.4 + 4  0.2 = 90.4 lit

SECTION – B
1.  A  r  ,B  p,t  , C  q,s D  q,s  .
ezy
(A) Sic covalent carbide (Not hydrolysed)

(B) Al4 C3  12H2O  4Al  OH3  3CH4
w.
(C) Cal2  2H2 O  Ca  OH2  H  C  C  H

ww
(D) Mg2 C3  4H2 O  2Mg  OH 2  CH3  C  CH
2.  A  p,q,s  , B  q , C  r,t D  q .
Al2  SO4 3  2Al3  3SO 4
om
0.2M 0.3M
3 3
AlPO 4  Al  PO 4
.c
0.1M 0.1M
on
Urea 
 Urea
0.1M
u ti
MgCl2  Mg2  2Cl
0.1M 0.2M
sol
SECTION – C
1. 4
xam
Based on fact
2. 7
OH
ye
.ez
-
B
O O
+
HO B O
ww
2Na B OH 8H2O
O -
O
B
/ w
OH
3. 3
m
OHC CHO CHO

.co
ms
, ,
Cl NO2 C
exa
N
ezy
4. 3
OCH3 NH2
OCH3
w.
ww
, ,
H3CO OCH3 OCH3
H3CO
5. 2
1 1 100
t 99  n100; t 90  n
om
K K 10
t 99 n100 2
  2
t 90 n10 1
.c
hence x  2
on
6. 3
u ti
H H
S O
Cl
sol
H
C C C
, , Cl
H
xam
0
O
S
H
H
0 0
ye
.ez
ww
/ w
m
.co
ms
exa
ezy
w.
ww
Mathematics PART – III
om
SECTION – A
1. B Q

.c

PQ  r 2  1  2r cos  r 2  1  r
3
on

& AT  r 2  1  2r cos 
Where 'Q ' is the angle between
u ti

  P
3
OA and OT.
 2  2 A
now, PQ  4 AT 
sol
 2
 
 1  r  r  4 r  1  2r cos  2

2 2
3r  r  3 3r  r  3
xam
cos    1   1; r  0
8r 8r
 7  13 7  13  T
r , .
 6 6 
2. C
ye
.ez
Here two balls are drawn and the result is known that the two balls are white, therefore Bayes’s
theorem should be used.
1
ww
.1
Required probability = 4 1

1 1 6 1 3 1 1 2
.1  .  .  .
4 4 10 4 10 4 10
/ w
3. D
Let Q  x   f  x   g  x  in  x0 x 
By LMVT,
m
Q  x   Q  x 0   Q'  x   Q'  x 0  for some C   x 0 ,x 

 Q  x 0   0, Q'  C   f '  C   g'  C   0
.co
 Q  x   Q  x0   Q  x 
 F'  C   g'  C   x  x0   0
ms
 Q  x   0  f  x   g  x .
exa
4. A
A AP = 23
ezy
(-3, 4)
5
w. 5
13
ww
5. D
5 2n  5
Sn  
4 2 n  1 n  2 
om
5
K 
4
.c
6. A
on
Equation of tan gent at 'P ' is
Y  y  m X  x
u ti
y  mx
Now, x
1  m2
y 2  x 2 dy
sol
  putting y  vx
2xy dx
Solving Differential equation
xam
x 2  y 2  Cx
It passes through 1,2   C  5
Equation of curve  x 2  y 2  5x  0
ye
7. C
x cos  y sin 
T  1
.ez
3 2
x  0, y  2cos ec,
chord A 'P;
ww
2 sin 
y x  3
3  cos   1
2 sin 
/ w
x  0, OM 
   1
cos
2
Now, OQ2  MQ2  OQ2   OQ  OM
 2  OM  OQ   OM2
m
 OM 2OQ  OM
.co
2 sin   4 2 sin  
 
 cos   1  sin  1  cos  
2sin   4  4 cos   2 sin 2  
ms
 2
1  cos   sin 
4 sin  2  2cos   1  cos2  
exa
 2
1  cos   sin 
4
ezy
8. A, B, D
f  x   0  x 3  x 2  x  1   x 2  x  1  2  0
w.
2
 x 3  1 
x2  x  1
ww
-1 1
-2 
2
x3
9. A, B, C
Take f  x    x  and g  x   x and proceed.
om
10. B, C
 cos 2x  1   
I   tan1   dx   tan tan   x  dx
.c
 1  sin 2x    4  
 
on
    x  dx
4 
 x2  x2
I x  C  gx  x  .
u ti
4 2 4 2
11. A, B
sol
 

2  4  4 a2  1 
,    1  a, 1  a
2 y 
xam
 f 1  a   0 & f 1  a   0
 1 
 a    ,1
 4 
ye
.ez
12. C
The value of K1 & K2 decide the opening of parabola
 A max  Area  OBCO 
ww
 A min  Area  OACO 
13. D
/ w
Y 1
c K1 
4
1
m
A K1 
B
8
.co
X' o (1,0) (2, 0) X

ms
exa
Y' 1 K2 = -1
K2  
4
ezy
14. D
Area  BFEC   Area  ABC  AFE  A
 or  AOB  BOC  COA  AFE 
sA
co
w.
2R
1 2   2A
 R sin 2C  sin 2A  sin 2B  sin    2A   F E
2 
ww
1 H O
 R2  sin2B  sin 2C 
2
B C
15. B
AE  R, AF  2Rcos A
 EF  R
om
16. A

.c
AFE 
3
on
 AFE is equilateral
2
R 3  9
 sum of square of altitudes  3   R2 .
 2 
u ti
  4
SECTION – B
sol
1. (A   p, r, t) (B  q) (C  t) (D   s)
xam
    
 A  tan  1 2 3 4   0  1  2  3  4  2n
 2 
B  x 2  4  t 2  2, TR is diameter  6
ye
 2
Area of circle   TR   9
4
.ez
C 6
2
D  y A  yB  yC 
2
  3 3
ww
2. (A 
 q, t) (B 
 q) (C 
 p, r, s) (D 
 t)
/ w
SECTION – C
1. 1
D.C' s of OP are, Z
m
 1 1 1  C (o, o, a)
 , ,  M(a, o, a)
 3 3 3
.co
 1 1 1 
 D.C' s of AL    , , 
 3 3 3 L
(o, a, a)  P (a, a, a)
 1 1 1 
ms
D.C's of BM   , , 
 3 3 3 A (a, o, o)
O X
 1 1 1 
D.C' s of CN   , , 
3 3 3 B
exa

(o, a, o) N (a, a, o)
Let D.C' s of required line be  ,m,n 
 mn  m n
Y
 cos   ,cos  
3 3
ezy
 mn  mn
cosy  ,cos  
3 3
4 2 4
Hence, cos   cos   cos y  cos2  
2 2 2

  m2  n 2  
w.
3 3
2 2 2 2 4 
  cos   cos   cos y  cos       1.
3 
ww
2. 2
The gives equation is  x  1 y  2   4  4
A P  t1 t 
om
XY  4
Equationof tan gent is,
Q B
4 4
Y   2  x  t
.c
t t
 8
 A   0,  & B   2t1 0 
on
 t
1 8
Area    2t  8
u ti
2 t
4K  8  k  2.
sol
3. 1
2 2
CE  a  b   2  3  25
  
DE C2 16 16
xam
 CE 
  1
 DE 
4. 5
ye
10 1 1 1 1
  f K  1  x  dx   f  x  dx   f  x  1 dx.......... f  x  9 
K 1 0
.ez
0 0 0
 putting x  1  t,  x  2   t............  x  9   t
1 2 3 10
ww
  f  x  dx   f  x  dx   f  x  dx..........  f  x  dx
0 1 2 9
10
  f  x  dx  5.
/ w
5. 7
Every ball have two options
 4 balls can be put in 24 ways.
m
Arrangement among themselves in 2!

1
.co
  24  23
2!
But, above count also includes the one case in which all the balls are put in one box,
ms
 Required number of ways = 23 – 1 = 7.

6. 2
exa
3 3 3
K  1 K  2 K  3 
K  1 K  2  K  3  0
1 1 1
ezy
 K  2  K 2
w.
ww

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Q. No. PHYSICS CHEMISTRY MATHEMATICS

(A)  s, (B)  pt, (A)  r, (B)  pt, (A)  prt, (B)  q,

(C)  s, (D)  qr (C)  rt, (D)  q (C)  prs, (D)  t

&  3.4  15  11.6eV  2nd collision.

since m is positive in the graph,

In wrist watch spring force is not dependent on gravity.

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Number of moles of Al produced   0.166

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For Boyle’s temperature, 2nd virial co-efficient becomes zero

Let Boyle’s temperature, TB'

Vreal = 4  22.4 + 4  0.2 = 90.4 lit

(A) Sic covalent carbide (Not hydrolysed)

(C) Cal2  2H2 O  Ca  OH2  H  C  C  H

(D) Mg2 C3  4H2 O  2Mg  OH 2  CH3  C  CH

OHC CHO CHO

Q  x   Q  x 0   Q'  x   Q'  x 0  for some C   x 0 ,x 

 A min  Area  OACO 

X' o (1,0) (2, 0) X

Arrangement among themselves in 2!

 Required number of ways = 23 – 1 = 7.

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