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GBH Enterprises Ltd.

Types of Reformer Design

Gerard B. Hawkins
Managing Director
GBH Enterprises Ltd.

 Four main types


• Pre reformers
• Primary reformers
◦ Main different designs
• Secondary reformers
• Compact reformers

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• Need
◦ To contain the catalyst - use tubes
◦ High heat transfer area - lots of narrow ID tubes
◦ To supply heat - combustion of fuel
◦ To distribute feed - headers
◦ To collect effluent - headers
◦ To supply fuel/combustion air - headers & duct
◦ To contain combustion gases - casing
◦ To recover heat - flue gas duct and coils

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• Three main types considered


◦ Top Fired
◦ Foster Wheeler Terrace Wall
◦ Side Fired
• Many other types
◦ Not considered
◦ Not encountered frequently
◦ Same principles still apply

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Side
Bottom Top
Wall

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Tube Support
Pigtail
Burner

Tube

Coffins

Exit Header

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Transfer Line

Risers

Tubes
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 Nearly all heat transfer is by


radiation
 Radiation from the flue gas to

the tubes
 Little direct radiation from

refractory to tube
 Refractory acts as a reflector
 Radiation from flame to tube at
tube top

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Top Fired Temperature Profiles

1600 2800

Fluegas Temperature
Process and Outside

1500 2600
Temperature (°F)

1400 2400 Outside Tube Wall


Tube Wall

1300 Temperature
2200

(°F)
Process Gas
1200
2000 Temperature
1100
Fluegas Temperature
1000 1800

900 1600
800 1400
0 20 40 60
Distance Down Tube (ft)

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• The key advantages of this design are


• Small catalyst volume
• A relative small number of burners
• Combustion air preheat is simple to install
• The key disadvantages of this design are
◦ High heat fluxes at the top of the tubes can lead to carbon
formation and hence to hot bands
• The heat flux down the tube can not be varied
• Burner control is coarse due to the low number of burners
used on top fired reformers
• A temperature pinch between the flue gas and process gas at
the exit of the tubes

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NG Feed MP
Steam

Fuel
HP
Steam

Air

BFW

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Fluegas Fans

Convection Section

Tubes

Upper Firing Level

Lower Firing Level

Cell 1 Cell 2
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• Nearly all heat transfer is by


radiation from flames and
refractory
◦ Major portion is from Convection
refractory
◦ Some from flame
◦ Some from flue gas Radiative
• Heat is transferred from heat flows
flame to the walls
◦ By convection/radiation

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Foster Wheeler Temperature Profiles

2000

Fluegas Temperature
1800
Temperature (°F)

Outside Tube Wall


1600 Temperature

(°F)
Process Gas
1400
Temperature
1200 Fluegas Temperature

1000

800
0 20 40 60
Distance Down Tube (ft)

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• The key advantages of this design are,


◦ Ability to alter the firing between the two levels to either,
 Reduce methane slip,
 Or increase the flue gas temperature and hence raise more
steam,
◦ A low heat flux which means carbon formation should not be
an issue.
• The key disadvantages of this design are,
◦ Relatively high catalyst volume,
◦ The feed and fuel gases must be balanced between the two
cells,
◦ A large number of burners.

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 Convection section is placed


above transfer duct
 Elevated - makes
modifications difficult
 Long tubes in coil
 Multiple fans in some cases
 Can include auxiliary burners

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Pigtail
Fluegas Extraction
Tube

Burner
Burner

Peephole

Burner
Burner

Outlet Collector

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Tubes
Burners

Peephole

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Staggered

Single Lane

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• Nearly all heat transfer is by Convection


radiation from flames and
refractory
◦ Major portion is from
refractory
◦ Some from the flames - less
than for Foster Wheeler
• Some from flue gas
• Heat is transferred from flame Radiative
heat flows
to the walls
◦ By convection/radiation

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Side Fired Temperature Profiles

1700 2200

Fluegas Temperature
Process and Outside

1600 2100
Temperature (°F)

1500 2000 Outside Tube Wall


Tube Wall

1400 Temperature
1900
1300

(°F)
Process Gas
1800
1200 Temperature
1100 1700 Fluegas Temperature
1000 1600
900 1500
800 1400
0 10 20 30 40
Distance Down Tube (ft)

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• The key advantages of this design are,


◦ Ability to alter the firing between the burner levels to either,
 Reduce methane slip,
 Or increase the flue gas temperature and hence raise more
steam,
◦ A low heat flux which means carbon formation should not be
an issue.
• The key disadvantages of this design are,
◦ Relatively high catalyst volume,
◦ The feed and fuel gases must be balanced between the two
cells,
◦ A large number of burners.

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 Issues
• Variation of tube wall temperature
• Tubes are at different distances from burners
• Leads to high methane slip
• Variability of tube life

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• Most of these reformers are


◦ Upfired
◦ Upflow
◦ Therefore same as a top fired
reformer
• Small plant capacities
• Always have uneven heat flux and
therefore un-even temperatures
• One side hotter than the other

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 Offered by
• Howmar
◦ Now designing Top Fired furnaces
• Howe Baker
◦ Now designing Top Fired furnaces
• Chemico

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• Use low grade heat from


flue gas duct to preheat air
• Maximize efficiency as stack
temperature is reduced
• Minimizes fuel used
• No preheating in primary of
the combustion air
• Must ensure symmetry
◦ Prevents mal-distribution

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Burner Tube Feed Header


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Burner Tube
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Burner Tube Fuel Header


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Burner Tube

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 Main types include


• Gas Heated Reformer (GHR)
• Advanced Gas Heat Reformer (AGHR)
• Enhanced Heat Transfer Reformer (EHTR)
• KRES

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 Aim is to
• Minimize plot area
◦ Eliminate large fired box
◦ Eliminate convection section
• Maximise heat integration
• Eliminate HP steam system

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• Developed for ammonia process - LCA


• Early 1980’s - Paper exercise
• Mid 1980's - Sidestream unit at Billingham
• Mid 1980's - LCA design developed
• Late 1980's - ICI Severnside plants start up
• 1991 - BHPP LCM plant designed
• 1994 - BHPP plant start up
• 1998 - AGHR Start Up
• 1998 - MCC Start Up

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Steam Oxygen
Preheater

Purifier

Natural gas

Saturator
Refined GHR Secondary
methanol
Purge Converter

Refining Topping
Column Column

Fusel oil Purge


to fuel

Process
condensate
water
Crude methanol

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Air / Oxygen

Steam + Gas
Secondary
Reformer

GHR
Steam

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2,590 Nm3/Hr
30`C Oxygen
22.0% Methane
43.7 Barg 39.2 Barg
21,000 Nm3/Hr 701`C
425`C
Gas/steam

37.9 Barg
1200`C
515`C

Syngas 0.4% Methane


38.6 Barg
975`C

GHR 742`C
Secondary
40.6 Barg Reformer
16.6% Methane

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• Shellside heat transfer usually poor


• Minimize tube count with expensive alloys
• Tubes are externally finned
• Designed as double tubes
• Sheath tube
• Produces much smaller tube bundle
• Allows scale up to higher capacities

Double tube
Catalyst tube Fins

Hot shellside gas


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Gas &
Steam Hot Reacted
Gas
Scabbard
Tube
Catalyst

Bayonet
Tube

Support
Grid
End
Cap
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Hot Gas/Steam
gas
Twin
tubesheets

Syngas

Refractory

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• GHR operates in extremely corrosive duty


• Metal dusting - catastrophic carburization
• Need for materials research
• Suitable high temperature alloys identified
• Many years of operation in LCA plants
• Also confirmed in Methanol plant

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• Retain
• Series reforming scheme
• Shellside heat transfer enhancement
• Mechanical & process design methods
• Change to
• Non bayonet design
• Hot end tubesheet
• Sliding seal system

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• Novel seal system


• Prevents leakage from tubeside to shellside
• Not sensitive to wear of sliding surfaces
• Allows independent tube expansion
• Proven in full scale pilot plant tests

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• Easier to replace tubes


• Easier to load catalyst
• Capacity of up to 6,500 mtpd in single shell
◦ Would need 2 conventional primaries

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• APCI / KTI
• EHTR
• Kellogg
• KRES
• Uhde
• CAR
• GIAP
• Tandem
• Johnston Matthey
• GHR

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Feed &
Steam In

Cylindrical
Distributor To Heat
Recovery

Catalyst
Tube

Reformer
Effluent
Perforated
Distributor
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