You are on page 1of 21

WHITE PAPER

Equations and Example Benchmark Calculations within


the aspenONE® Engineering Safety Analysis Environment
V8.8: Two-phase Orifice Sizing, Vapor Noise and Reaction Forces
Craig Powers, Principal Software Developer, Aspen Technology, Inc.
Introduction
Introduced in Aspen HYSYS® V8.3, the Safety Analysis Environment provides a tool for adding pressure relief devices
and calculating relief loads inside Aspen HYSYS. Leveraging this tool within the rigorous Aspen HYSYS simulator, and in
combination with Aspen Flare System Analyzer, provides an integrated solution for pressure relief analysis (PRA) work.

This white paper contains hand calculations for two-phase orifice sizing and vapor noise and reaction forces inside the
Safety Analysis Environment, helping you to validate the calculations of this tool within Aspen HYSYS.

Leung Omega Method


There are two forms of the Leung Omega Method that are implemented in the Safety Analysis Environment. One form
is for cases that are saturated or two-phase at relief conditions, upstream of the relief valve. The other form is for cases
that are subcooled liquid upstream of the relief valve, with flashing occurring across the valve that produces a two-
phase stream at the valve outlet.

Non-Subcooled Omega Method


Equations
The governing equations for the application of the Omega Method are obtained from Appendix C of API Standard 520
Part I.1 It is a two-point method, meaning that physical properties are required at two thermodynamic state points. For
the non-subcooled method, the first state point is relief conditions. The second state point is obtained by an isentropic
flash to 90% of the relief pressure. Aspen HYSYS® uses an isenthalpic flash to 90% of the relief pressure in place of an
isentropic flash. With this information, the required orifice area may be obtained using the following equations below.

𝑣𝑣! 𝜌𝜌!
Eq. 1 𝜔𝜔 = 9× − 1 = 9× − 1  
𝑣𝑣! 𝜌𝜌!
In the equation above, ω is the Omega parameter, v0 and v9 are specific volumes at upstream and 90% conditions,
respectively, and ρ0 and ρ9 are density at upstream and 90% conditions, respectively.
 
𝑃𝑃! !!.!"#$%!!.!"#$%& !" !
Eq. 2 𝜂𝜂! = ≅ 1 + 1.0446 − 0.0093431 𝜔𝜔 ×𝜔𝜔 !!.!"#"$  
𝑃𝑃!
 
Eq. 3 𝜂𝜂! = 𝑃𝑃! 𝑃𝑃!  

In the equation above, ηc is the critical pressure ratio, Pc is the pressure corresponding to critical flow
at the nozzle throat in the relief valve in absolute units, Pa is the total back pressure at the outlet of
the valve in absolute units, and P0 is the upstream relief pressure in absolute units.

If ηc exceeds ηa, then the flow through the relief valve is critical, and the following equation should be
used to calculate the maximum mass flux, where G is the maximum mass flux through the valve in
lb/s-ft² or kg/s-m², P0 is in psia or Pa, v0 is in ft³/lb or m³/kg, and ρ0 is in lb/ft³ or kg/m³. C1 = 68.09
in U.S. customary units, or 1.0 in SI units.

Equations and Example Benchmark Calculations within the


2 aspenONE® Engineering Safety Analysis Environment
©2015 Aspen Technology Inc. 11-8231-1215
 
𝑃𝑃! 𝑃𝑃!  𝜌𝜌!
Eq. 4 𝐺𝐺 = 𝐶𝐶!   𝜂𝜂! = 𝜂𝜂!  
𝑣𝑣!  𝜔𝜔 𝜔𝜔

If ηc does not exceed ηa, then the flow through the relief valve is subcritical, and the following
equation should be used to calculate the maximum mass flux, where units are as in (Eq. 4).
 
𝑃𝑃! 𝜌𝜌!
Eq. 5 𝐺𝐺 = 𝐶𝐶! −2 𝜔𝜔 ln 𝜂𝜂! + 𝜔𝜔 − 1 1 − 𝜂𝜂!  
1
𝜔𝜔 −1 +1
𝜂𝜂!

Once the maximum mass flux has been obtained, the required effective discharge area may be
calculated by using Equation 6, where A is the required effective discharge area in mm², w is the
required relief load in kg/h, Kd is the discharge coefficient of the valve, Kb is the backpressure
correction factor (applicable to balanced bellows valves only), Kc is the combination capacity factor,
and Kv is the viscosity correction factor. C2 = 0.04 for U.S. customary units, 277.8 for SI units.

 
𝐶𝐶!  𝑤𝑤
Eq. 6 𝐴𝐴 =  
𝐾𝐾! 𝐾𝐾! 𝐾𝐾! 𝐾𝐾! 𝐺𝐺

When an orifice area has been selected, Equation 6 may be rearranged to find the rated capacity of
the valve, shown in Equation 7:

 
Eq. 7 𝑤𝑤!"# = 𝐴𝐴  𝐾𝐾! 𝐾𝐾! 𝐾𝐾! 𝐾𝐾! 𝐺𝐺 277.8  

Example with Critical Flow


The example is based on the following conditions:

15% propane, 25% n-butane, 30% n-pentane,


Composition 30% n-heptane using the Aspen HYSYS PR
package for physical properties
Relief conditions 8.03 barg / 101.2 C
Required relief load 63,000 kg/h 63,000 kg/h

Based on the relief pressure of 8.03 barg, the 90% intermediate flash pressure is at 7.227 barg.
Setting up a stream in Aspen HYSYS at the relief conditions and running it through an isenthalpic
flash will yield the following properties:
ρ0 = 112.0 kg/m³
ρ9 = 90.73 kg/m³

Equations and Example Benchmark Calculations within the


3 aspenONE® Engineering Safety Analysis Environment
©2015 Aspen Technology Inc. 11-8231-1215
 
The Omega parameter may be calculated using (Eq. 1):
 
112.0
𝜔𝜔 = 9× − 1 = 2.110  
90.73

The critical pressure ratio and backpressure ratio may be calculated using (Eq. 2) and (Eq. 3):
 
𝜂𝜂! = 0.6989  
 
1.01325
𝜂𝜂! = = 0.1120  
8.03 + 1.01325

Figure 1: Two-phase critical flow case calculated in Aspen HYSYS

Because ηc is larger than ηa, flow across the relief valve is choked; therefore, the maximum mass flux
is calculated using (Eq. 4).
 
112 9.043 ×100,000  𝑃𝑃𝑃𝑃/𝑏𝑏𝑏𝑏𝑏𝑏
𝐺𝐺 = 0.6989 = 4,844  kg/s-­‐m²  
2.110

Assuming that all capacity coefficients are 1.0, aside from the discharge coefficient which is 0.85 in
accordance with guidance from API, the required area is calculated using (Eq. 6):
 
277.8 63,000
𝐴𝐴 = = 4,250  mm²  
0.85 4,844  

Equations and Example Benchmark Calculations within the


4 aspenONE® Engineering Safety Analysis Environment
©2015 Aspen Technology Inc. 11-8231-1215
For a selected Q orifice with an effective area of 7129 mm², the rated capacity is calculated using
(Eq. 7):  
0.85 4,844   7,129
𝑤𝑤!"# = = 105,700  kg/h  
277.8

The results calculated above are compared to results obtained in Aspen HYSYS in Table 1.

Variable Units Example Calculation Aspen HYSYS


Required Relief Load (w) kg/h 63,000 63,000
Relief Pressure (P0) barg 8.03 8.03
90% Pressure (P9) barg 7.227
Mass Density at Relief (ρ0) kg/m 3
112.0 112.0
Mass Density at 90% (ρ9) kg/m 3
90.73 88.34
Omega Parameter (ω) 2.110
Critical Flow Ratio (ηc) 0.6989
Flow Type Critical Critical
Maximum Mass Flux (G) kg/s-m 2
4,844
Required Area (A) mm 2
4,250 4,448
Rated Capacity (wmax) kg/h 105,700 101,000
Blue = Calculation input Gray = Calculated value

Table 1: Comparison of example calculation and Aspen HYSYS calculation for critical two-phase flow

Example with Subcritical Flow


The example is based on the following conditions:

15% propane, 25% n-butane, 30% n-pentane,


Composition 30% n-heptane using the Aspen HYSYS PR
package for physical properties
Relief conditions 154 kPag / 85 C
Required relief load 20,000 kg/h
Back pressure 60 kPa superimposed

Based on the relief pressure of 1.54 barg, the 90% intermediate flash pressure is at 1.28 barg. Setting
up a stream in Aspen HYSYS at the relief conditions and running it through an isenthalpic flash will
yield the following properties:
ρ0 = 8.264 kg/m³
ρ9 = 7.335 kg/m³

Equations and Example Benchmark Calculations within the


5 aspenONE® Engineering Safety Analysis Environment
©2015 Aspen Technology Inc. 11-8231-1215
The Omega parameter may be calculated using (Eq. 1):
 
8.264
𝜔𝜔 = 9× − 1 = 1.140  
7.335

The critical pressure ratio and backpressure ratio may be calculated using (Eq. 2) and (Eq. 3):
 
𝜂𝜂! = 0.6234  
 
1.01325 + 0.6
𝜂𝜂! = = 0.6318  
1.54 + 1.01325

Figure 2: Two-phase subcritical flow case calculated in Aspen HYSYS

Because ηc is smaller than ηa, flow across the relief valve is unchoked, and the maximum mass flux is
calculated using (Eq. 5), yielding a maximum mass flux G = 830 kg/m²-s.

Assuming that all capacity coefficients are 1.0, aside from the discharge coefficient which is 0.85 in
accordance with guidance from API, the required area is calculated using (Eq. 6):
 
277.8 20,000
𝐴𝐴 = = 7,870  mm²  
0.85 830

For a selected R orifice with an effective area of 10322.5 mm², the rated capacity is calculated using
(Eq. 7):  
0.85 830 10322.5
𝑤𝑤!"# = = 26,230  kg/h  
277.8

The results calculated above are compared to results obtained in Aspen HYSYS in Table 2.

Equations and Example Benchmark Calculations within the


6 aspenONE® Engineering Safety Analysis Environment
©2015 Aspen Technology Inc. 11-8231-1215
Variable Units Example Calculation Aspen HYSYS
Required Relief Load (w) kg/h 20,000 20,000
Relief Pressure (P0) barg 1.54 1.54
90% Pressure (P9) barg 1.28
Mass Density at Relief (ρ0) kg/m 3
8.264 8.264
Mass Density at 90% (ρ9) kg/m3 7.335 7.337
Omega Parameter (ω) 1.140
Critical Flow Ratio (ηc) 0.6234
Flow Type Subcritical Subcritical
Maximum Mass Flux (G) kg/s-m 2
830
Required Area (A) mm 2
7,870 7,710
Rated Capacity (wmax) kg/h 26,230 26,780
Blue = Calculation input Gray = Calculated value

Table 2: Comparison of example calculation and Aspen HYSYS calculation for subcritical two-phase flow

Subcooled Omega Method


Equations
As with the non-subcooled Omega Method, the subcooled Omega Method is a two-point method.
The first point remains the same with the conditions at the PRV inlet. For the second point, the relief
stream is flashed isentropically to 90% of its saturation pressure corresponding to the PRV inlet
temperature T0. As with the non-subcooled method, flow may be critical or subcritical; however,
the subcooled Omega Method also requires a determination as to whether the relief conditions
correspond to “high” or “low” subcooling; that is, whether the fluid will begin to flash in the inlet line,
or whether it will flash at the valve throat.

The omega parameter is calculated using a similar equation to (Eq. 1), where ρℓ0 is the liquid density
at the PRV inlet in kg/m³.

 
𝜌𝜌ℓ𝓁𝓁"
Eq. 8 𝜔𝜔! = 9× − 1  
𝜌𝜌!

“High” or “low” subcooling is determined via the transition saturation pressure ratio, which is
calculated below in Equation 9 and 10, where ηst is the transition saturation pressure ratio, ηs is
the saturation pressure ratio, Ps is the saturation pressure in absolute units, and P0 is the upstream
pressure in absolute units.
 
2𝜔𝜔!
Eq. 9 𝜂𝜂!" =  
1 + 2𝜔𝜔!
 
𝑃𝑃!
Eq. 10 𝜂𝜂! =  
𝑃𝑃!

Equations and Example Benchmark Calculations within the


7 aspenONE® Engineering Safety Analysis Environment
©2015 Aspen Technology Inc. 11-8231-1215
If ηst exceeds ηs, then relief is considered to lie in the “high” subcooling region, and flow will
necessarily be critical unless the total back pressure exceeds the saturation pressure (but in this
case, the fluid is liquid across the valve, and the API liquid sizing will be sufficient to calculate the
orifice size). Otherwise, relief is considered to lie in the “low” subcooling region, and a check must be
made to determine if the flow across the PRV is critical or subcritical. The critical pressure ratio may
be estimated as shown below in Equation 11.
 
2𝜔𝜔! 1 2𝜔𝜔! − 1
Eq. 11 𝜂𝜂! ≅ 𝜂𝜂! 1− 1−  
2𝜔𝜔! − 1 𝜂𝜂! 2𝜔𝜔!

The back pressure ratio ηa is calculated using (Eq. 3) as with the non-subcooled method.

For “low” subcooling, the maximum mass flux is calculated using Equation 12 below.
 
𝑃𝑃! 𝜌𝜌ℓ𝓁𝓁" 𝜂𝜂!
Eq. 12 𝐺𝐺 = 𝐶𝐶! 𝜂𝜂! 2 1 − 𝜂𝜂! + 2 𝜔𝜔! 𝜂𝜂! ln − 𝜔𝜔! − 1 𝜂𝜂! − 𝜂𝜂  
𝜔𝜔! −1 +1 𝜂𝜂
𝜂𝜂

For critical flow, η=ηc; for subcritical flow, η=ηa. Pressure is in psia or Paa. C1 = 68.09 for U.S.
customary units, 1.0 for SI units.

For “high” subcooling, the maximum mass flux is calculated using Equation 13 below.
 
Eq. 13 𝐺𝐺 = 𝐶𝐶! 2  𝜌𝜌ℓ𝓁𝓁" 𝑃𝑃! − 𝑃𝑃!  

The pressure is measured in psia or Paa.

Given a required relief load in lb/h or kg/h, the required area and rated capacity may be calculated
using (Eq. 6) and (Eq. 7).

Example with Low Subcooling, Critical Flow


The example is based on the following conditions:

15% propane, 30% isobutane, 30% n-butane,


Composition 25% isopentane using the Aspen HYSYS PRSV
package for physical properties
Relief conditions 242 psig, 205 F
Required relief load 92,590 lb/h

Setting up a stream in Aspen HYSYS at the relief conditions and flashing appropriately, yields the
following properties:
ρℓ0 = 29.23 lb/ft³
Ps = 241.4 psia
P9 = 217.3 psia
ρ9 = 17.53 lb/ft³

Equations and Example Benchmark Calculations within the


8 aspenONE® Engineering Safety Analysis Environment
©2015 Aspen Technology Inc. 11-8231-1215
The omega parameter is calculated using (Eq. 8):
 
29.23
𝜔𝜔! = 9× − 1 = 6.011  
17.53

Figure 3: Low subcooled critical flow case calculated in Aspen HYSYS

The transition saturation pressure ratio is calculated using (Eq. 9):


 
2 6.011
𝜂𝜂!" = = 0.923  
1 + 2 6.011
The saturation pressure ratio is 0.956. Because this is greater than the transition ratio, this case
involves “low” subcooling, and the critical pressure ratio is calculated using (Eq. 11):
 
2 6.011 1 2 6.011 − 1
𝜂𝜂! ≅ 0.923 1− 1− = 0.8633  
2 6.011 − 1 0.923 2 6.011

The back pressure ratio of 0.0573 is much lower than the critical pressure ratio, so the flow is critical.
The maximum mass flux is calculated using (Eq. 12) with η=ηc. The result shows that G = 2,150
lb/s-ft².

Assuming that all capacity coefficients are 1.0, aside from the discharge coefficient which is 0.65 in
accordance with guidance from API, the required area is calculated using (Eq. 6):
 
0.04 92,590
𝐴𝐴 = = 2.651  in²  
0.65 2,150

Equations and Example Benchmark Calculations within the


9 aspenONE® Engineering Safety Analysis Environment
©2015 Aspen Technology Inc. 11-8231-1215
For a selected L orifice with an effective area of 2.853 in², the rated capacity is calculated using
(Eq. 7):  
0.65 2,150 2.853
𝑤𝑤!"# = = 99,640  lb/h  
0.04

The results calculated above are compared to results obtained in Aspen HYSYS in Table 3.

Variable Units Example Calculation Aspen HYSYS


Required Relief Load (w) lb/h 92,590 92,590
Relief Pressure (P0) psig 242 242.0
Saturation Pressure (Ps) 226.7 psig 241.4 psia
90% Pressure (P9) psig 202.6
Mass Density at Relief (ρℓ0) lb/ft3 29.23
Mass Density at 90% (ρ9) lb/ft 3
17.53 17.51
Omega Parameter (ω) 6.011
Transition Subcool Ratio (ηst) 0.923
Critical Flow Ratio (ηc) 0.8633
Flow Type Low Subcool, Critical Critical
Maximum Mass Flux (G) lb/s-ft 2
2,150
Required Area (A) in 2
2.651 2.663
Rated Capacity (wmax) lb/h 99,640 99,180
Blue = Calculation input Gray = Calculated value

Table 3: Comparison of example calculation and Aspen HYSYS calculation for low subcooled critical flow

Example with Low Subcooling, Subcritical Flow


The example is based on the following conditions:

15% propane, 30% isobutane, 30% n-butane,


Composition 25% isopentane using the Aspen HYSYS PRSV
package for physical properties
Relief conditions 44 psig, 87.5 F
Required relief load 92,590 lb/h
Back pressure 40 psi superimposed

Setting up a stream in Aspen HYSYS at the relief conditions and flashing appropriately yields the
following properties:
ρℓ0 = 35.17 lb/ft³
Ps = 57.13 psia
P9 = 51.4 psia
ρ9 = 13.72 lb/ft³

Equations and Example Benchmark Calculations within the


10 aspenONE® Engineering Safety Analysis Environment ©2015 Aspen Technology Inc. 11-8231-1215
Figure 4: Low subcooled subcritical flow case calculated in Aspen HYSYS

The omega parameter is calculated


  using (Eq. 8):
35.17
𝜔𝜔! = 9× − 1 = 14.07  
13.72
The transition saturation pressure ratio is calculated using (Eq. 9):
 
2 14.07
𝜂𝜂!! = = 0.9657  
1 + 2 14.07

The saturation pressure ratio is 0.9733. Because this is greater than the transition ratio, this case
involves “low” subcooling. The critical pressure ratio is calculated using (Eq. 11):
 
2 14.07 1 2 14.07 − 1
𝜂𝜂! ≅ 0.9733 1− 1− = 0.9130  
2 14.07 − 1 0.9733 2 14.07

The back pressure ratio of 0.9319 is higher than the critical pressure ratio, so the flow is subcritical.
The maximum mass flux is calculated using (Eq. 12) with η=ηa=0.9319. The result is that G = 765.4
lb/s-ft².

Assuming that all capacity coefficients are 1.0, aside from the discharge coefficient which is 0.65 in
accordance with guidance from API, the required area is calculated using (Eq. 6):
 
0.04 92,590
𝐴𝐴 = = 7.444  in²  
0.65 765.4

Equations and Example Benchmark Calculations within the


11 aspenONE® Engineering Safety Analysis Environment
©2015 Aspen Technology Inc. 11-8231-1215
For a selected Q orifice with an effective area of 11.05 in², the rated capacity is calculated using
(Eq. 7):  
0.65 765.4 11.05
𝑤𝑤!"# = = 137,400  lb/h  
0.04

The results calculated above are compared to results obtained in Aspen HYSYS in Table 4.

Variable Units Example Calculation Aspen HYSYS


Required Relief Load (w) lb/h 92,590 92,590
Relief Pressure (P0) psig 44 44.00
Saturation Pressure (Ps) 42.43 psig 57.13 psia
90% Pressure (P9) psig 36.7
Mass Density at Relief (ρℓ0) lb/ft3 35.17
Mass Density at 90% (ρ9) lb/ft3 13.72 13.75
Omega Parameter (ω) 14.07
Transition Subcool Ratio (ηst) 0.9657
Critical Flow Ratio (ηc) 0.9130
Flow Type Low Subcool, Critical Critical
Maximum Mass Flux (G) lb/s-ft 2
765.4
Required Area (A) in 2
7.444 7.450
Rated Capacity (wmax) lb/h 137,400 137,300
Blue = Calculation input Gray = Calculated value

Table 4: Comparison of example calculation and Aspen HYSYS calculation for low subcooled, subcritical
flow

Example with High Subcooling


The example is based on the following conditions:

15% propane, 30% isobutane, 30% n-butane,


Composition 25% isopentane using the Aspen HYSYS PRSV
package for physical properties
Relief conditions 242 psig, 188.3 F
Required relief load 92,590 lb/h

Setting up a stream in Aspen HYSYS at the relief conditions and flashing appropriately, yields the
following properties:
ρℓ0 = 30.34 lb/ft³
Ps = 203.1 psia
P9 = 182.8 psia
ρ9 = 17.40 lb/ft³

Equations and Example Benchmark Calculations within the


12 aspenONE® Engineering Safety Analysis Environment ©2015 Aspen Technology Inc. 11-8231-1215
Figure 5: High subcooled critical flow case calculated in Aspen HYSYS

The omega parameter is calculated using (Eq. 8):


 
30.34
𝜔𝜔! = 9× − 1 = 6.693  
17.4
The transition saturation pressure   ratio is calculated using (Eq. 9):
2 6.693
𝜂𝜂!" = = 0.9305  
1 + 2 6.693
The saturation pressure ratio is 0.7912. Because this is less than the transition ratio, this case
involves “high” subcooling. The critical pressure ratio is equal to the saturation pressure ratio. The
maximum mass flux is calculated using (Eq. 13):
 
𝐺𝐺 = 68.09 2 30.34 256.7 − 203.1 = 3,883  lb/s-­‐ft²  

Assuming that all capacity coefficients are 1.0, aside from the discharge coefficient which is 0.65 in
accordance with guidance from API, the required area is calculated using (Eq. 6):
 
0.04 92,590
𝐴𝐴 = = 1.467  in²  
0.65 3,883
For a selected K orifice with an effective area of 1.838 in², the rated capacity is calculated using
(Eq. 7):  
0.65 3,883 1.838
𝑤𝑤!"# = = 116,000  lb/h  
0.04

The results calculated above are compared to results obtained in Aspen HYSYS in Table 5.

Equations and Example Benchmark Calculations within the


13 aspenONE® Engineering Safety Analysis Environment ©2015 Aspen Technology Inc. 11-8231-1215
Variable Units Example Calculation Aspen HYSYS
Required Relief Load (w) lb/h 92,590 92,590
Relief Pressure (P0) psig 242 242.0
Saturation Pressure (Ps) 188.4 psig 203.1 psia
90% Pressure (P9) psig 168.1
Mass Density at Relief (ρℓ0) lb/ft3 30.34
Mass Density at 90% (ρ9) lb/ft3 17.40 17.38
Omega Parameter (ω) 6.693
Transition Subcool Ratio (ηst) 0.9305
Flow Type High Subcool, Critical Critical
Maximum Mass Flux (G) lb/s-ft 2
3,883
Required Area (A) in 2
1.467 1.473
Rated Capacity (wmax) lb/h 116,000 115,600
Blue = Calculation input Gray = Calculated value

Table 5: Comparison of example calculation and Aspen HYSYS calculation for high subcooled, critical flow

Direct Integration Method


The direct integration method involves evaluating thermodynamic properties of the relieving stream
at a number of state points and then numerically integrating the nozzle equation to determine the
maximum mass flux. This equation is the theoretical basis for every orifice method, so the direct
integration method is applicable to any type of flow, single or multi-phase.

Equations
The nozzle equation is shown below, where G is the mass flux in lb/ft²-s or kg/m²-s, v is the specific
volume in ft³/lb or m³/kg, and dp is the differential pressure increment in lbf/ft² or Pa.

 
−2𝑔𝑔!
Eq. 14 𝐺𝐺 ! = 𝑣𝑣  𝑑𝑑𝑑𝑑  
𝑣𝑣 !
This is approximated as shown below, where v̅ is the average specific volume over the pressure
increment Δp.
 
−2𝑔𝑔!
Eq. 15 𝐺𝐺 ! ≅ 𝑣𝑣 ∆𝑝𝑝  
𝑣𝑣 !
The sum is performed from the relief pressure until either a maximum value of G is reached or the
back pressure Pa is reached. If the maximum in G occurs above Pa, then the flow is choked.

Equations and Example Benchmark Calculations within the


14 aspenONE® Engineering Safety Analysis Environment ©2015 Aspen Technology Inc. 11-8231-1215
Example
The example is based on the following conditions:

25% n-octane, 35% n-decane, 30% n-C11, 10%


Composition nitrogen using the Aspen HYSYS SRK package
for physical properties
Relief conditions 176 psig, 122 F
Required relief load 138,900 lb/h

A property table may be used to obtain the mass density along an isentropic path for numerical
integration, as shown below.

Pressure Mass Density Specific Volume gcv̅ ∆P Mass Flux


psia lb/ft3 ft3/lb ft²/s² lb/ft2-s
190.7 23.21 0.0431 0.0 0.0
180.7 22.48 0.0445 2028 1432
170.7 21.71 0.0461 2098 1972
160.7 20.90 0.0478 2175 2347
150.7 20.06 0.0499 2263 2625
140.7 19.18 0.0521 2363 2835
130.7 18.25 0.0548 2477 2988
120.7 17.28 0.0579 2610 3092
110.7 16.25 0.0615 2766 3150
100.7 15.17 0.0659 2952 3164
90.7 14.04 0.0712 3177 3133

Note that the mass flux reaches a maximum at a pressure of 100.7 psia, indicating that flow is
choked and the relief mass flux is 3164 lb/ft²-s.

Equations and Example Benchmark Calculations within the


15 aspenONE® Engineering Safety Analysis Environment ©2015 Aspen Technology Inc. 11-8231-1215
Figure 6: Direct integration case calculated in Aspen HYSYS

Assuming that all capacity coefficients are 1.0, aside from the discharge coefficient which is 0.85
in accordance with guidance from API for two-phase flow at relief conditions, the required area is
calculated using (Eq. 6):
 
0.04 138,900
𝐴𝐴 = = 2.066  in²  
0.85 3,164

For a selected L orifice with an effective area of 2.853 in², the rated capacity is calculated using
(Eq. 7):  
0.85 3,164 2.853
𝑤𝑤!"# = = 191,800  lb/h  
0.04
The results calculated above are compared to results obtained in Aspen HYSYS in Table 6.

Variable Units Example Calculation Aspen HYSYS


Required Relief Load (w) lb/h 138,900 138,900
Relief Pressure (P0) psig 176 176.0
Relief Temperature (T0) F 122 122.0
Maximum Mass Flux (G) lb/s-ft 2
3,164 3,114
Required Area (A) in 2
2.066 2.099
Rated Capacity (wmax) lb/h 191,800 188,800
Blue = Calculation input Gray = Calculated value

Table 6: Comparison of example calculation and Aspen HYSYS calculation for direct integration

Equations and Example Benchmark Calculations within the


16 aspenONE® Engineering Safety Analysis Environment ©2015 Aspen Technology Inc. 11-8231-1215
Noise
Equations
The equations for computing noise level for atmospheric relief valves are given in section 5.8.10.3
of API Standard 521.2 The noise level at 30 m from the point of discharge is calculated using the
following equation below, where w is the mass flow through the valve in kg/h, c is the speed of
sound in the gas at the valve in m/s, and L is the sound level in decibels.
 
1
Eq. 16 𝐿𝐿!" = 𝐿𝐿 + 10   log!"  𝑤𝑤  𝑐𝑐 !  
7200

The speed of sound may be computed as shown below, where k is the ideal specific heat ratio in the
gas, T is the temperature
  in K, and M is the molecular weight of the gas.

𝑘𝑘  𝑇𝑇
Eq. 17 𝑐𝑐 = 91.2  
𝑀𝑀

The value of L in (Eq. 16) is read from a figure in the text. It may be approximated using two semilog
curve fits shown below, where X is the pressure ratio across the pressure relief valve.
 
39.461 ln 𝑋𝑋 + 12.648     ∶ 𝑋𝑋   ≤ 2.866
Eq. 18 𝐿𝐿 =  
2.1716 ln 𝑋𝑋 + 51.914     ∶ 𝑋𝑋   > 2.866

Example
The example is based on the following conditions:

100% air using the Aspen HYSYS PR package


Composition
for physical properties
Relief conditions 330 kPaa, 311 K
Required relief load 52,560 kg/h

Setting up a stream in Aspen HYSYS at the relief conditions will yield the following properties:
M = 28.95
k = 1.404

Equations and Example Benchmark Calculations within the


17 aspenONE® Engineering Safety Analysis Environment ©2015 Aspen Technology Inc. 11-8231-1215
Figure 7: Noise example calculated
in Aspen HYSYS

The speed of sound may be calculated


  using (Eq. 17) as:

1.404 311
𝑐𝑐 = 91.2 = 354.2  m/s  
28.95

Based on a pressure ratio of 330⁄101.325=3.26, the contribution due to pressure ratio may be
estimated by (Eq.
  18) to be 54.5 dB. Then, the total noise level is calculated using (Eq. 16):
1 !
𝐿𝐿!" = 54.5 + 10   log!"  52,560   354.2 = 114.1  dB  
7200
The results calculated above are compared to results obtained in Aspen HYSYS in Table 7.

Variable Units Example Calculation Aspen HYSYS


Required Relief Load (w) kg/h 52,560 52,560
Relief Pressure (P0) 330 kPaa 2.287 barg
Relief Temperature (T0) 311 K 37.85 C
Sound Level (L30) dB 114.1 114.1
Blue = Calculation input Gray = Calculated value

Table 7: Comparison of example calculation and Aspen HYSYS calculation for noise

Figure 8: Reaction force example


calculated in Aspen HYSYS

Equations and Example Benchmark Calculations within the


18 aspenONE® Engineering Safety Analysis Environment ©2015 Aspen Technology Inc. 11-8231-1215
Reaction Forces
Equations
The equations for computing reaction forces on the outlet piping of atmospheric relief valves are
given in section 4.4.1 of API Recommended Practice 520 Part II.3 The reaction force due to vapor
discharge is calculated using the following equation below, where F is the reaction force in N, w is the
required relief load in kg/h, k is the ideal specific heat ratio of the gas, T is the discharge temperature
in K, M is the molecular weight of the gas, A is the area of the pipe at the point of discharge in mm²,
and p3 is the static pressure at the outlet in barg (that is, 0 for flow that is unchoked at the outlet, or
the choke pressure for flow that is choked at the outlet).
 
1 𝑘𝑘  𝑇𝑇
Eq. 19 𝐹𝐹 = 𝑤𝑤 + 0.1  𝐴𝐴  𝑝𝑝!  
27.9 𝑘𝑘 + 1  𝑀𝑀

Example
The example is based on the following conditions:

30% propane, 70% n-butane using the Aspen


Composition
HYSYS SRK package for physical properties
Relief conditions 4.4 barg, 92.15 C
Required relief load 36,970 kg/h

Fluid properties at relief may be observed to be:


M = 53.92
k = 1.081
P* = 0.8201 bara

The reaction force may be calculated using (Eq. 19), as shown below. Because the choke pressure is
less than atmospheric pressure, the second term may be neglected.
 
1 1.081 92.15 + 273.15
𝐹𝐹 = 37,150 = 2,498  N  
27.9 2.081 53.92

The results calculated above are compared to results obtained in Aspen HYSYS in Table 8.

Variable Units Example Calculation Aspen HYSYS


Required Relief Load (w) kg/h 37,150 37,150
Relief Temperature (T) C 92.15 92.15
Reaction Force (F) N 2,498 2,497
Blue = Calculation input Gray = Calculated value

Table 8: Comparison of example calculation and Aspen HYSYS calculation for reaction force

Equations and Example Benchmark Calculations within the


19 aspenONE® Engineering Safety Analysis Environment ©2015 Aspen Technology Inc. 11-8231-1215
Conclusion
Safety is of the highest priority to every process, and ensuring accurate, validated calculations is a
key component of this work. To view additional validation papers, access tutorial documents and
videos, and learn more information about the tools AspenTech provides to address process safety
work, please visit the safety page on our company website, today!

References
1. American Petroleum Institute, API Standard 520 Part I 9th Ed.: Sizing, Selection, and Installation
of Pressure-relieving Devices, Washington, DC: API Publishing Services, 2014.

2. American Petroleum Institute, API Standard 521 6th Ed.: Pressure-relieving and Depressuring
Systems, Washington, DC: API Publishing Services, 2014.

3. American Petroleum Institute, API Recommended Practice 520 Part II 5th Ed., Reaffirmed,
Washington: API Publishing Services, 2011.

Equations and Example Benchmark Calculations within the


20 aspenONE® Engineering Safety Analysis Environment ©2015 Aspen Technology Inc. 11-8231-1215
AspenTech is a leading supplier of software that optimizes process manufacturing—for energy, chemicals, engineering and
construction, and other industries that manufacture and produce products from a chemical process. With integrated aspenONE®
solutions, process manufacturers can implement best practices for optimizing their engineering, manufacturing, and supply chain
operations. As a result, AspenTech customers are better able to increase capacity, improve margins, reduce costs, and become
more energy efficient. To see how the world’s leading process manufacturers rely on AspenTech to achieve their operational
excellence goals, visit www.aspentech.com.

Worldwide Headquarters
Aspen Technology, Inc.
20 Crosby Drive | Bedford, MA 01730 | United States
phone: +1-781-221-6400 | fax: +1-781-221-6410 | info@aspentech.com

Regional Headquarters
Houston, TX | United States
phone: +1-281-584-1000
São Paulo | Brazil
phone: +55-11-3443-6261
Reading | United Kingdom
phone: +44-(0)-1189-226400
Singapore | Republic of Singapore
phone: +65-6395-3900
Manama | Bahrain
phone: +973-13606-400

For a complete list of offices, please visit www.aspentech.com/locations

Equations and Example Benchmark Calculations within the


21 aspenONE® Engineering Safety Analysis Environment ©2015 Aspen Technology Inc. 11-7852-0915

You might also like