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FIITJEE JEE(Advanced)-2014
ANSWERS, HINTS & SOLUTIONS
FULL TEST –I
(Paper-1)

Q.
PHYSICS CHEMISTRY MATHEMATICS
ALL INDIA TEST SERIES

No.
1. B B B
2. B C A
3. A D A
4. B D A
5. A A C
6. A D B
7. C B A
8. D B C
9. B B A
10. A A A
11. D B C
12. B B D
13. B A C
14. A B A
15. B C C
16. C A C
17. A B A
18. C A B
19. C C C
(A)  (r, s), (B)  (r, s), A → (q, r) B → (q, r) (A)  (s), (B)  (p),
1.
(C)  (q, s), (D)  (p, s) C → (p, s) D → (p, s) (C)  (q), (D)  (r)
(A)  (p, s), (B)  (p, A → (r, s) B → (r, s) (A)  (q), (B)  (s),
2. s), (C)  (p), (D)  (r)
C → (p, r) D → (p, q)
(C)  (q, s), (D)  (p, s)
(A)  (p, q, r, s), A → (q) B → (r) (A)  (q), (B)  (s),
3. (B)  (q, s) (C)  (q, s), (C)  (p), (D)  (r)
C → (s) D → (p)
(D)  (p, q, r, s)

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AITS-FT-I-(Paper-1)-PCM(S)-JEE(Advanced)/14
2

Physics PART – I

1. Now downward force on the right block is T T

more.

mg mg

2. IC = I0 + M(OC)2 = I0 + M(OB2 + BC2) = IB + M(BC)2

3. Potential difference across AC is zero as E1 = 10V

IAC = 0 r1 = 1
5  2I = 0
I = 2.5 A
Let the resistance of part BC be r C
A G B
Applying KVL
10 + 5  2I  Ir  I = 0 E2 = 5V
2.5r = 7.5  r = 3  r2 = 2
As resistance of part AB = 9
 Length AC = 66.7 cm

5. Initial energy of electron = 2eV

Energy after formation of hydrogen atom in the ground state
= 13.6 eV.
Energy released = 2  (13.6) = 15.6 eV
hc
  793 Å
15.6

6. Threshold wavelength = 5000Å

hc
Work function = = 2.48 eV

K.E. = eV = 3 eV
hC
  2258 Å
5.48

V2 V 2 3002
7. P R= 2   900 
R P 100
V 300 1
 current i   = A
R 900 3
Let L be the required inductance, then
500 1 500 1
 or =
z 3 2 2
(900)  x 2 3
XL  1200
1200 1200 1200
L    4H
W 2f 150
2 


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 3 AITS-FT-I-(Paper-1)-PCM(S)-JEE(Advanced)/14

8. In steady state potential difference across each capacitor = E

2
4
E2 4
 6t  dt
9. H= 0 R dt   = 64 J
0 12

14. q1 + q2 = 0 q2
kq kQ kq2 Q
vA = 1   q1 C
R 2R 4R B
kq1 kQ kq2 A
vC =  
4R 4R 4R
vA = vC
 q1 = Q/3 and q2 = Q/3

 Q Q Q  Q
15. vA = k     
 3R 2R 12R  160R

 Q Q Q  5Q
16. vB = k      48 R
 6R 2R 12R  0

di
17-19. When current is maximum 0
dt
 emf across L = 0 and potential difference across the capacitor will be same.
From conservation of charge V
 + + 
V
3CV + CV = 6CV0  CV0
C 3C S
5CV0
 V= L
4
Loss in energy of capacitor = energy stored in inductor
3V0 3C
 Imax =
2 L

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AITS-FT-I-(Paper-1)-PCM(S)-JEE(Advanced)/14
4

Chemistry PART – II

1. Ag  I  AgI  e  Eo  0.152 V

Ag  e   Ag Eo  0.800 V
Ag  I  AgI Ecell = 0. 952 V
2.303RT 1
At eqm, Eo   

 Ag  I  K SP
2.303RT
 0.952  logK SP  0.059 logK SP
F
 logK SP  16.13
2. A 2  t  
on differentiating the equation we get:
dA   1
2AdA  dt or   A
dt 2A 2
Hence order is -1.
rA  1
3.   0.5 . As it lies in the range 0.414 to 0.732. AB has octahedral structure like that of NaCl.
rB 2
 
 a  2 rA   rB  2 1  2   6 pm
Volume = a = (6 pm)3 = 216 pm3
3

4. 

BaF2  s   2 
 Ba  aq   2F aq 
2 K sp
K sp  Ba2   F   F 
Ba2  
2
Again K sp  2  Ba2   F 
K sp
 F  
2 Ba2  
5. Co3  1s2 2s2 2p6 3s2 3p6 3d6
3d6 4s 4p 4d

sp3 hybridisation
6. Bond order of N2 ,N2 ,NO  ,NO,CN and CN are 3, 2.5, 3, 2.5, 3, 2.5 respectively. Higher is bond
order smaller is bond length. Bond order of CO and CO+ are 3 and 3.5.
7. Br C N COOH

Cl2 /h
MgCl Br2 /h KCN 
H3 O
CH4  CH3 Cl 
     
8. O

Br 
CH3 CH2 O

H C6H5

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 5 AITS-FT-I-(Paper-1)-PCM(S)-JEE(Advanced)/14

O O
O CH3
Br  Br 

C6H5 C6H5 C6H5
9.
O H OH
O3 / Zn  H2O
O
KOH

  
Cannizzaro reaction

O +
O O K
H
Y
 1  3 
14. Ho  H CaSO 4 . H2 O  s    H  H2O  g 
 2  2 
1
H CaSO 4 .2H2 O  s    833 kJ mol
= + 484 kJ for 1 kg
15. Ho  Ho  So
= 17920 J mol-1
Go  2.303RTlogK p
3
Go
logK p 
2.303RT

 7.22  10 4 pH2O  2

pH2 O  8.1 10 3 atm

16. pH2O  1, K p  1
Go  0 at eqm.
Ho
Ho  TSo  T   380 K
So
= 107oC

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AITS-FT-I-(Paper-1)-PCM(S)-JEE(Advanced)/14
6

Mathematics PART – III

1. x2 + y2 – 2x – 2y – 1 = 0
x 2 + y2 –1=0
Common chord is –2x – 2y = 0  2x + 2y = 0
y = –x
 1 1 
Points of intersection of circles are   ,  
 2 2

k
k 1 10  2 5
2. P(E)  8
 
C2 8  7 14

3. The line can be written as y = mx and curve as x 2 + y2 = 4

C(h, k)
Let, C(h, k) be a point on the circles and A  3, 1 be B
2
1 (, m)
h2 3
given point then, 
3  
3, 1 A
 (0, 0)
 h  3  2 3
k2
 m
3
 k = 3m – 2 y = mx
Now, this point (h, k) lies on the circle
2
  3  2 3    3m  2   4
2

9 2  12  12 3  9m2  2  4  12m  4
 9 1  m2   2  12  3  m  12  0
3 1  m2   2  4  3  m   4  0
2
16  3  m   4  3 1  m2   4   0
2
 3  m   3 1  m2   0
3  m2  2 3m  3  3m2  0
2 3m  2m2  0
2m2  2 3m  0
m   0, 3

4. Suppose m is an integer root of x4 – ax3 – bx2 – cx – d = 0 as d  0

m0
(I) m > 0
m4 – am3 – bm2 – cm = d
 d = m(m3 – am2 – bm – c)
dm
Also, m4 – am3 = bm2 + cm + d
3 2
m (m – a) = bm + cm + d
 m > a  contradiction
(II) m < 0
m = –n
 n4 + an3 – bn2 + cn – d = 0

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 7 AITS-FT-I-(Paper-1)-PCM(S)-JEE(Advanced)/14

n4 + n2(an – b) + (cn – d) > 0

So, contradiction
Hence, equation has no integral solution
+ – +
1 1 1 1
5. (I) x2  x 
2 1 3 1 3
1 1
2  
 2 2 2 2
x    1
 2 4
1 3 + – +
 x 
2 2 1 2
+ + – – +
+ – – + +
2
(II) x – 3x + 2 1 1 1 1 1 2 1
1 3 1 3
 
2 2 2 2
2

–2x

–1 1
1
(III) x  1  x  1 
2
1 1
 1
 set x can be  ,    
 4
3
4   2x 
2
1
2x 
2
1

3
 x  x
4 4

/2 y
dx
6. Required area, A  4  0
y
dt
dt (0, a)

/2
x 0 x
 a sin t   a cos2 t  dt
= 4
0
 sin t 
/2 (0, –a)
2 2 2
= 4a
 cos
0
t dt  a y

7. Distance from origin, D  x2  y2  z2 where P(x, y, z) is any point on the curve

2 2
D2 = x2 + y2 + z2 = x2 + y2 +  2xy  4
xy xy
 D = 2 and occurs at point(s) 1, 1, 2  and  1,  1, 2  , 1, 1,  2  ,  1, -1,  2 

r2
8. Differentiating w.r.t. ‘r’, 2r dr = 2a cos 2 d, a 
sin 2
r2
 rdr  cos 2 d
sin 2
d
 r  tan2
dr

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AITS-FT-I-(Paper-1)-PCM(S)-JEE(Advanced)/14
8

d
So, differential equation of orthogonal trajectory, r    cot 2
dr
dr
Solving  tan 2 d 
r
 ln(cos 2) = 2 ln r + k  r2 = c cos 2

9. Let f  x   x 3  bx 2  cx  1. f  0   1  0, f  1  b  c  0
So,    1,0  . So, 2 tan1  cosec   tan1 2sin  sec 2   
 1  1  2sin    1  1  
 2 tan1    tan  2   2  tan 
1
  tan  sin   
 sin    1  sin     sin   
 
 2       as sin   0 
 2

1 2
10. is continuous every where except where 1 + z = 0
1  z2
 z = i so when |z| < 1 then above points are excluded so f(z) is continuous

11. Continuity : for any point z, lim f  z   lim x  x 0  f  z0  . Non differentiable : for any point z,
z  z0 z  z0

f  z  z   f  z  x x x
f '  z   lim  lim now lim  0 and lim 1
z  0 z z  0 x  iy x 0 x  iy y 0 x  iy
y 0 x 0

m
12. y1  cos  m sin 1 x  
1  x2
1  x2 y1  mcos msin1 x 
 1  x 2  y 2  xy1  m2 y  0
 n  n  1   
 1  x  yn 2  n  2x  yn1 
2
2 yn    xyn1  n.1.yn   m2 yn  0
2 
Simplifying we get, 1  x y n 2  2n  1 yn1  n2  m2  yn  0
 2  

dy 3at  2  t 3 
13. 
dt 1  t 3 2
1 3
dx  t 
 6a  2 
2
dt 1  t 
3

dy 1/3
Now   at t  (2)
dx
      
14.-16. Here, Pv  P2  PK so Pv will make acute angle with all the vectors from P2 , P3 , ....., Pk
Pm
Pk
Pn–2 P3
Pn–1 P2
Pn P1

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 9 AITS-FT-I-(Paper-1)-PCM(S)-JEE(Advanced)/14

   

So, OPv   OP2  OP3  .....  OPk 1   0
Again, if n is odd  n = 2k – 1
  
OP1  OP2k 1  OPk
   
Now OPk will make acute angle with all the vectors from OP1, OP2 ..... OP2k 1
       
OPk   OP1  OP2  .....  OPk  OPk 1  .....  OP2k 1   OPk  OPk  1
         
Now, OPk   OP1  OP2  .....  OP2k 1   OPk OP1  .....  OP2k 1 = OP1  OP2  .....  OPn
   
Again, V makes acute angle with all the vectors OP1, OP2 , ....... OP7
      
So, V  S  OP1 + OP2 +.......+ OP7  1  V  S  1

17. Eigen values are roots of the equation A – X = 0  (A – I)X = 0

 |A – I| = 0
8   4
 0
2 2
 ( – 4)( – 6) = 0
  = 4, 6

18. When  = 6
8  6 4   x1  2 4   x1  0 
 2    
 2  6   x 2  2 4   x2  0 
 2x1 – 4x2 = 0  x1 = 2x2
 2
 X  C 
 1

19. |A – I| = 0
1  0 1
 1 2 1 0
2 2 3
3 2
  – 6 + 11 – 6 = 0   = 1, 2, 3,
For  = 3
1
X  C  1  which is orthogonal
 2

SECTION – B
2 2 2
1. (A) Assume sphere as, x + y + z + 2ux + 2vy + 2wz = 0
Now P, Q, R are (–2u, 0, 0), (0, –2v, 0), (0, 0, –2w)
x y z
So, equation of plane is   1
2u 2v 2w
1 2 3
Since it passes through (1, 2, 3)   1
2u 2v 2w
If centre is (x, y, z)  (–u, –v, –w)
1 2 3
 locus is    2
x y z
2 2
(B) Assume equation of sphere as, x + y + 2ux + 2vy + 2wz = 0

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It passes through (, 0, 0), (0, , 0), (0, 0 )

  r
 u   , v=  ,   
2 2 2
2 2 2
    
Radius = 1        1
 2  2 2
2 2 2
 +  +  = 4 if (x, y, z) are coordinates of centroid
   4
 x  , y  , z   x 2  y 2  z2 
3 3 3 9
(C) P  (, 0, 0), Q  (0, , 0), OPQ = 15º

 tan 15º = ….. (1)

Now if sphere is made with PQ as diameter (x – )x + (y – )y + z2 = 0
2 2 2
 x + y + z = ax + by ….. (2)
A plane through PQ parallel to z–axis is
x y
 1 ….. (3)
 
 x y
Using (1), (2), (3) we get x 2 + y2 + z2 = (x + y)   
 
z2
 z2 = xy(tan 15º + cot 15º)  2xy  0
2
(D) Using family of planes any plane through line of intersection is x + y – 6 + (x – 2z – 3) = 0
 6  3 1
Now, its distance from centre of sphere is radius  3 ,  = 1, 
2
1     1  4 2 2
 Equation is x + 2y + 2z = 9; 2x + y – 2z = 9


2. (A) Let p = cos x sin y cos z. As,  y  z , sin (y – z)  0
2
1 1
p  cos z sin  x  y   sin  x  y    cos2 z
2 2
As, sin (x – y)  0 and sin (x + y) = cos z
1 1  2 3
p  1  cos 2z    1  cos  
4 4 6 8
8  2 7 8  2 7
(B) The equation can be written as 3u2  8u  3  0  u1   u2 
6 6

Clearly, u1, u2 are negative so  x1, x2  
2
   3 
  < x1 + x2 < 2 as cot x tan x = 1 = cot x cot   x  = cot x  cot   x
2   2 
3 7
 x1  x 2  and another pair, x '1  x '2     x '1, x'2  2
2 2
 x1 + x '1 + x2 + x '2 = 5

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(C) |EF|  |E1F1| = a – [|BF| cos B + |CF| cos C] A

|DE|  C – [|AE| cos A + |BD| cos B]
|FD|  b – [|CD| cos C + |AF| cos A] E
1 F
|DC| + |CE| = |EA| + |AF| = |FB| + |BD| =  a  b  c 
3
 |DE| + |EF| + |FD|
B C
1 1 F1 D E1
 a  b  c    a  b  c  cos A  cosB  cosC     a  b  c 
3 2
1
So, minimum value is
2
2 2 2
(D) sin x1 + sin x2 + ….. + sin x10 = 1
2
cos xi   sin
j 1
xj

 sin x
j i
j
2
For each 1  i  10 we have cos xi   sin
j i
xj 
3
10 10 sin x j 10
sin x i
 
i1
cos xi  
i1 j i
3
 9
i1
3
cos x1  cos x 2  .....  cos x10
 3
sin x1  sin x 2  .....  sin x10

3. (A) Property of ellipse

(B) Normal chord is made between points A  2, 2 2  and B  8,  4 2  so its length is 6 3
(C) Q  (4, 2), S : (x – 4)2 + (y – 2)2 = 16 then required circle is (x – 1)2 + (y – 1)2 + (x – y) = 0
162
Here,  = 9 and radius =
2
2
3y
(D) x 2  c
2
5 5
e (c > 0) and e  (c < 0)
3 2

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