FIITJEE JEE Advanced 2014 Paper 1 PCM Full Test IV Answers

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AITS-FT-IV-(Paper-1)-PCM(S)-JEE(Advanced)/14
JEE(Advanced), 2014
ANSWERS, HINTS & SOLUTIONS
FULL TEST IV
(Paper-1)
ALL INDIA TEST SERIES
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Q.
No.
1.
PHYSICS
CHEMISTRY
MATHEMATICS
2.
3.
4.
5.
6.
7.
8.
9.
A, B, C, D
B
A, B
10.
A, C
A, B
A, B, C, D
11.
A, C, D
A, B
12.
A, C
A, D
A, B, C
13.
14.
15.
16.
17.
18.
1.
(A) (q),(B) (p, q, s, t),

(C) (p, q, s, t), (D) (r, s)
A (p, q) B (p,
q) C (q) D (r, t)
(A) (p), (B) (p, r)

(C) (r), (D) (p, r)
(A) (q, r), (B) (s),

(C) (p, s, t), (D) (p, q, r, t)
A (p, q, s, t)
B (p, r, s)
C (q, s)
D (q, s, t)
(A) (q), (B) (p)

(C) (t), (D) (r)
2.
A, C, D
A, B, D
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website: www.fiitjee.com
Physics
1.
PART I
Particle vel =
dx
x
x0 2n cos 2 nt
dt
max particle vel = x02n putting cos term = 1 wave vel =
n
T
for x02n = 4n
x
0
2
2.
4.
1
1
1
mv 2 mg
sin 60 mv 20 mg 1 sin30
2
2
3
v0 = 2 m/s
=
1
LCeq
= 100
T = 1/50 sec
5.
sin C = 2/1

1 cos C = 2
1
2 2
1 n.p
1
2 3
2
3 3
4
1
5 2 = 5
25
1
1
6.
En = 3.4 eV En
1
n2
E1 13.6 eV
n=2
Angular momentum =
7.
nh 2h h
2.11 1034 Js
2 2
2 2
v = (A x ) = 3 a =
= 1 rad/sec
3a
x = 2a sin(t + ), v = 2a cos (t + )
At t = 0, x = a & v = +ve
1
= sin
2
6
= n + (1)n 6 =
5 6
v at = /6 = + ve and v at = 5/6 = ve
So, = /6
x = 2a sin (t + ) = 2a[sin t cos + cost sin]
x = a ( 3 sin t + cos t)
8.
For a polytropic process

R
U
1
1
R
R
1
Q
1
1 1 x
1 x
For polyatomic gas, = 4/3
U
1
1
Q
1
3 1 x
This is max at x = 3/2
9.
Use the concept of capacitor.
10.
Area in (vL-t)graph = LI
1
2(if 0) = 10 2
2
if = 5A
13 -15. For long time capacitor gets full charged and charge on each capacitor must be same.
Q Q
20
2 3
Q = 24 C
1
1
10
50 rad/s

6
2
LC
2 2 10
Q(t) = 24 sin t C
Q(t) = (24 sin t) C
n
500t = 1 n
2
n
n
t=
1
500
1000
Q20 24 103 24 10 6
Emax =
= 144 106 Joule = 0.144 mJ

2C
2 2 106
16.
Q = QAB + QBC + QCA

10U0
Q = 5U0 + 3U0 +
ln 2.5
3
17.
W AB = QAB UAB = 5U0 (3U0) = 2U0
18.
Process AB U = constant
P RT
and U t
M
P = const
Process BC isochoric
Process CA isothermal
SECTION - B
2.
1
2
2
2
6m 36a2 m4a + 2ma = 24a m
for p, q, s & t
12
v
v
2
p v 0 j , 24ma = mv02a k + 2mv0a k = 0 k
9
6a
2
q v 0 , 24ma
= 2mv02a k + 2mv0a k = 0 k
4a
v0
2
sv
j , 24ma = mv02a k + 2mv0a( k ) = 0
3
4v 0
tv
j , 24ma2 = 4mv0a k + 2mv0a( k ) = v 0 k
9
12a

6v
2
2
2
r v 0 , (18 ma + ma +2m4a ) = 4mv0a k + 2mv0a k = 0 k
25a
I=
Chemistry
PART II
SECTION - A
1.
Due to non availability of d-orbitals, boron is unable to expand its octet. Therefore it cannot
extend its covalency more than 4.
3.
BaCO3 + 2HCl BaCl2 + H2O + CO2

ZnS + 2HCl ZnCl2 + H2S
4.
2Ag2CO3
4 Ag + 2CO2 + O2
552 gm Ag2CO3 432 g of Ag

2.76 g Ag2CO3
5.
432
2.76 2.16g
552
NO in iron complex has +1 oxidation number.

Thus, a 5 0 1 1 2 0
a 1
6.
It is called Zinc blend
7.
From left to right in a period acidic character increases due to increase in electronegativity.
8.
H
|
C3H7 C NH2
|
CH3
9.
Roults law for ideal solutions can be represented in the above two given ways.
11.
Hunds rule.
12.
Addition of Br2 in CCl4 is anti addition.
13.
In the original compound

Z atoms form CCP
X atoms present in tetrahedral void.
rX 50
rZ 200 0.25
Y atoms present in octahedral void
rY 100
rZ 200 0.5
Assuming, all voids are occupied, formula of the original compound = X8Y4Z4.
On removing atoms along one body diagonal,
We lose 2Z atoms,
2X atoms, 1Y atom (body centre)
The new formula becomes X6 Y3Z3.75

Simplest formula X8Y4Z5
14.
On removing atoms along another body diagonal, we lose

2Z atoms
2X atoms
The new formula becomes = X4Y3Z3.5
Simplest formula = X8Y6Z7
16.
pH = pKa + log
[Base] =
Base
Salt
0.01 500
0.01
500
Let a milli moles of (NH4)2SO4

[NH4+] =
a2
;
500
[Salt] = [NH4 ]
0.01
pH = 9.26 + log
2a / 500
0.01 500
8.26 = 9.26 + log
2a
a = 25
Moles of (NH4)2SO4 added = 0.025
17.
CH3 COOH NaCl

Solution (I) CH3 COONa HCl
1
1
0
0
0
0
1
1
CH3 COOH
No.of moles
1
1
Volume of solution 1
K
H C C a K a .C K a
C
1
1
i.e. pH1 = log K a pK a
2
2
Solution (II) CH3 COONa CH3 COOH

1
1
It is buffer.
CH3 COONa
pH2 = pKa + log
CH3 COOH
pH2 = pKa + log
1
1
pH2 = pKa
18.
pH1 1
pH2 2
HA BOH
BA H2O
t0
a
12 0.1
0
0
t eq (a 1.2) 0
1.2
1.2
Meq of HA = Meq of BOH at end point

A = 26.6 0.1 = 2.66
Meq of HA left = 2.66 1.2
Now, pH = pKa + log
5 = log Ka + log
Salt
Acidleft
1.2
2.66 1.2
Ka = 8.219106
Mathematics
PART III
SECTION A
1.
2.
We can assume that OP and OR are xaxis and yaxis respectively.

2
Let OP = a, then ar(sq. OPQR) = a
a
a
coordinates of M and N are a, and , a respectively
2
2
a
a
2
1
2 3a
ar OMN
2 a
8
a
2
8 k

3 6
k = 16
y
R
Q
M
Equation of the two circles be (x r)2 + (y r)2 = r2 i.e.

x2 + y2 2rx 2ry + r2 = 0 where r = r1 and r2. Condition of orthogonality gives
2r1r2 2r1r2 r12 r22
4r1r2 r12 r22
Circle passes through (a, b)
a2 + b2 2ra 2rb + r2 = 0 i.e. r2 2r(a + b) + a2 + b2 = 0
r1 + r2 = 2(a + b) and r1r2 = a2 + b2
4(a2 + b2) = 4(a + b)2 2(a2 + b2) i.e. a2 4ab + b2 = 0
3.
f(x) is a decreasing function and for major axis to be xaxis

f(k2 + 2k + 5) > f(k + 11)
k2 + 2k + 5 < k + 11
k (3, 2)
4.
f(x) = 2 sin2 + 4 cos (x + ) sin x sin + cos (2x + 2)

= 2 sin2 + cos (2x + 2) + 2 cos (x + ) cos (x ) 2 cos2 (x + )
= 2 sin2 + 2 cos2 (x + ) 1 + 2 cos2 x 2 sin2 2 cos2 (x + )
= cos 2x
f 2 x f 2 x cos2 2x sin2 2x 1
4
5.
Consider the function f x
a0 xn1 a1xn a2 xn1

a x2
..... n 1 an x
n 1
n
n 1
2
Then f(0) = 0 and f(1) = 0

Hence f(x) = 0 has at least one solution in (0, 1)
6.
fog x e x 1
I
ex 1dx
2t 2
2
dt (where
= 2t 2 tan1 t + C = 2 e x 1 2 tan1
ex 1 t )
e x 1 C 2fog x 2 tan1 fog x C
A + B = 2 + (2) = 0
7.
Area =
n x tan1 x dx xn x 12
1 dx x tan
2
x1
1 x
dx
5
1
n 2 n 5 2 tan1 2 1
2
2
4
8.
Let x + y = v
9.
I f 4 15
n
n
Let g 4 15 , then 0 < g < 1

If
g
C0 4n nC1 4n1 15 n C2 4n215 nC3 4n 3 15 .....

3
C0 4n nC1 4n1 15 nC2 4n215 nC3 4n3 15 .....
I f g 2 n C0 4n n C2 4n215 .....
0<f+g<2
f+g=1
= even integer
1 f = g thus I is an odd integer 1 f = g = 4 15

(I + f)( 1 f) = (I + f) g = 1
10.
1 2 3
(A) P(E1) = 1 P(R R R) = 1
3 4 5
2 1 2 1
(B) P(E2) = 3P(B R R) = 3
3 4 5 5
P R R R
P R R R P B B B
2 3 4
8
0.1
1
But P B B B
P(E3 )
3 4 5 20
0.1 0.4 5
2 3
(D) P(E 4 ) 1 P B B B 1
5 5
(C) P(E2) = P(R R R/R R R B B B) =
11.
12.
|z i Re (z)| = |z lm (z)|
Let z = x + iy, then |x + iy ix| = |x + iy y|
i.e. x2 + (y x)2 = (x y)2 + y2
i.e. x2 = y2
i.e. y = x
1 a1 a2 a2 a3 a3 a4 2a2 a3 a4 o
i.e. 1 a1 1 2 a2 1 a3 a 4 o

Since a1, a2 , a3 , a 4 are linearly independent
= 1 = 0, 1 + 2 = 0, + + 1 = 0, + = 0
i.e. = 1, = 2, + + 1 = 0, + = 0
2
1
1
i.e. = 1, , ,
3
3
3
13.
1 2 e
4
3
13 32
10
13 12 22 32 12 22
2 12 122
14.
Since i is real
is purely imaginary
15.
e 2 i
2
1 i 2 1 i

16.
Equation of the second plane is x + 2y 3z + 5 = 0

2(1) + 3, 2 + (4)(3) > 0
origin lies in obtuse angle (2 1 + 3(2) 4 3 + 7)(1 + 2(2) 3 3 + 5)
= (2 6 12 + 7)(1 4 9 + 5) > 0
P lies in obtuse angle
17.
12+2133<0
Origin lies in acute angle
Also (2 + 2(1) 3(2) + 5)(2 2 1 + 3 2 + 1) = (1)(10) < 0
P lies in obtuse angle
18.
149<0
Origin lies in acute angle
Further (1 + 4 6 + 2)(1 4 + 6 + 7) > 0
The point P lies in acute angle
SECTION B
1.
sinB
b2 c 2 a2
b
, we have
2sinC
2bc
2c
or b2 + c2 a2 = b2 or c2 = a2
Hence c = a and so the ABC is isosceles
(B) cos A (sin B sin C) + (sin 2B sin 2C) = 0
or cos A (sin B sin C) + 2 sin (B C) cos (B + C) = 0
or cos A (sin B sin C) 2 cos A sin (B C) = 0
either cos A = 0 A = 90
or (sin B sin C) 2(sin B cos C cos B sin C) = 0
a2 b2 c 2
c 2 a2 b2
b C 2 b
c
2ab
2ca
or a(b c) 2(b2 c2) = 0

(b c)[a 2(b + c)] = 0
b c = 0 or b = c
Isosceles
(C) Combine first and thiral and put the value of cos B
(A) Since cos A
2
1 c 2 a2 b2 a2 b2
b
ac
b
2ca
abc
2
2
2
2
2
or 4b + c + a b = 2a + 2b2
b2 + c2 + a2
A = 90
11
(D)
2.
sin A B k 2 sin2 A sin2 B
by sine formula
sin A B k 2 sin2 A sin2 B
sin A B sin A B sin A B
or
sinC
sin2 A sin2 B
sinC
1
or sin A B
0
2
2
sinC
sin A sin B
Either sin (A B) = 0
A = B i.e. is isosceles
2
2
2
2
2
2
or sin A + sin B = sin C or a + b = c
is right angled
2
(A) x (3k 1)x + 2k 3k 2 0

[x (k 2)][x (2k + 1)] 0
k2 1
+1
2k+1
+1
f(1) 0
f(1) 0
Hence 2k + 1 1 and k 2 1
i.e. k 0 and k 1
k [0, 1]
+m=1
(B) 1 a 2 a (AM GM)
1 b 2 b
1 c 2 c
1 d 2 d
(1 + a)(1 + b)(1 + c)(1 + d) 16 abcd 16
Minimum value = 16
(C) 5 x 2 5
2
x
2
x
2
x 2x 2
0
x
x 12 1
0
x
x (0, )
3
(D) f(x) = x + 3x + 1 and g(x) is inverse of f(x)
f(1) = 5
g(5) = 1
1
1
g' f x
f' x
3x 3
x2
g' f 1
g' 5
1
33
1
6

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FIITJEE

ALL INDIA TEST SERIES

(A) (q),(B) (p, q, s, t),

(A) (p), (B) (p, r)

(A) (q, r), (B) (s),

(A) (q), (B) (p)

max particle vel = x02n putting cos term = 1 wave vel =

For a polytropic process

Use the concept of capacitor.

= 144 106 Joule = 0.144 mJ

Q = QAB + QBC + QCA

W AB = QAB UAB = 5U0 (3U0) = 2U0

BaCO3 + 2HCl BaCl2 + H2O + CO2

552 gm Ag2CO3 432 g of Ag

NO in iron complex has +1 oxidation number.

It is called Zinc blend

Addition of Br2 in CCl4 is anti addition.

In the original compound

Y atoms present in octahedral void

2X atoms, 1Y atom (body centre)

The new formula becomes X6 Y3Z3.75

On removing atoms along another body diagonal, we lose

Let a milli moles of (NH4)2SO4

CH3 COOH NaCl

Solution (II) CH3 COONa CH3 COOH

pH2 = pKa + log

Meq of HA = Meq of BOH at end point

We can assume that OP and OR are xaxis and yaxis respectively.

Equation of the two circles be (x r)2 + (y r)2 = r2 i.e.

f(x) is a decreasing function and for major axis to be xaxis

f(x) = 2 sin2 + 4 cos (x + ) sin x sin + cos (2x + 2)

Consider the function f x

a0 xn1 a1xn a2 xn1

Then f(0) = 0 and f(1) = 0

e x 1 C 2fog x 2 tan1 fog x C

Let g 4 15 , then 0 < g < 1

C0 4n nC1 4n1 15 n C2 4n215 nC3 4n 3 15 .....

C0 4n nC1 4n1 15 nC2 4n215 nC3 4n3 15 .....

1 f = g thus I is an odd integer 1 f = g = 4 15

(C) P(E2) = P(R R R/R R R B B B) =

Equation of the second plane is x + 2y 3z + 5 = 0

or a(b c) 2(b2 c2) = 0

(A) Since cos A

sin A B k 2 sin2 A sin2 B

(A) x (3k 1)x + 2k 3k 2 0

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