JEE-Chemistry ALLE EXERCISE - 05 [A] JEE-[MAIN] : PREVIOUS YEAR QUESTIONS 1. The solubility of MofOH\}, is x mole/lit. then its solubility product is [AIEEE-2002) (x3 (2) 5x? {3} 4x3 {@) 2x? 2. The solubility in water of a sparingly soluble salt AB, is 1.0 x 10°5 mol L- 1. Its solubility product will be {AIEEE-2003] (1 xt aan 13) 4 x10 5 4x10 3. ‘The molar solubility in mal L-! of a sparingly soluble salt MX, is’s’. The corresponding solubility product is Kg. “es given in terms of Kgp by relation : IAIEEE-2004] (Ys = Kop / 12804 (2) s = (128K p14 {Shs = (256K) (A) s = Kep/256)" 4. Hydrogen ion concentration in mol/L in a solution of pH = 5.4 will be - [AIEEE-2005} {1} 3.88 x 10° (2) 3.98 «108 (3) 3.98 x10°® {4) 3.68 x 10° 5. The solubility product of a salt having general formula MX,, in water is : 4 x10" 1, The concenirat ions in the aqueaus solution ofthe salt is : (au (1) 1.0 x10°*M (2) 2.0 x10 © M {34.0 x10 4M (4) 1.6 x10 OM 6. _ Ina saturated solution of the sparingly soluble strong electrolyte AglO, fmolecular mass = 283) th which sats in is (Au AMO, SEB Agiigy + ica) the solubility product constant K,, of AglO, at a aiven temperature fs 1.0 x 10°, shat is the mass of AIO, contained in 100 ml of its saturated solution ? (1) 28.3 x10-2g (2) 2.83 «10-39 8) 1.0 x10-7 4 10x10 4g 7. The pk, of a weak acid, HA, is 4.80, The pk, of a weak base, BOH, i 4.78. The pH of an aqueous sohtion of the corresponding salt. BA, will be ~ {AIEEE-2008] (9.58, (214.79 3) 7.01 (4) 9.22 8, Solld BONO), is gral dissolved in a 1.0 x 10-4 M Na,CO; soktion Ai what concentration of Ba? ila precipitate begin to form? {Kgp for Ba COs = 5.1 x 109] [AIEEE-2009) (1) 8.1 x105M {2)8.1 x10-7M (14.1 x 105M (4)5.1 x10 9M 9. Al 25°C. the solubility producet of MglOH)y is 1.0 x10", At which pH, will Mg? ions start precinitating the form of Mg{OH), from a solution of 0.001 M Mg? iors ? {AIEEE-2010} 5 as i219 (3) 10 ytd 10. In aqueous solution the ionization constants for carbonic acid are Ky = 4.29107 and Ky = 4.8 x10"! Select the correct statement for a saiuraied 0.034 M solution of the carbonic ac {Ale (4) The concentration of His double that af CO,” (2) The concentration of CO,? is 0.034 M 3) The concentration of CO,* is greater than that af HCO, (4) The concentrations of H* and HCO, ave anproximately equal 13411. 12. 13. 4. 15. 16, 17, 18. i lonic Equilibrium, Acid Base Solubility product of silver bromide is 5.0 x10", The quantity of potassium bromide (molar mass taken as 120 9 mot” to be added to 1 litre of 0.05 M solution of silver nitrate to start the precipitation of Ag IATEEE-2010] (5.0 x10%g (12x10 g (3)1.2x10%g 6.210% ‘An acid HA ionises as HAS Hee a ‘The pH of 1.0 M solution is 6. tts dissoctation constant would be [AIEEE-2011) (1) 1 1049 5 (3)5 x10 (4) 1108 The Ky, for CHOH); is 1.6 x 10°, The molar solubility ofthis compound in water is = (AIEEE-2011] () ¥6x10" 6x10" (3) {16x10 727 41.6 x10-0/27 ‘The pH of 2 0.1 molar solution of the acid HQ is 3. The value of the ionisation constant, Ka of this acid is [AIEEE-2012} (yi x10? 23x10? 1 x10 (1x10 How many lites of water must be added fo 1 live of an aqueous solution of HICH with a pH of T to create ar aqueous solution with pHi of 2? (AIERE-2013] quoi (20.91. B20L 9.08 Two Faraday of electricity is passed through a solution of CuSQ,, The mass of copper deposited atthe cathode is fat, mass of Cu = 63.5 amu) [JEE-Main-2015} (1) 2g 21275 G09 A variable, opposite external potential.) appli [JEE-Main (Online)-2015} (1} anode to cathode in both cases (2) anode to cathode and cathode (3) cathode to anode in both cases (@) cathode to anode and anode to cathod At 298K, the standard reduction potentials are 1.51 V for MnO; Mn2, 1.36 V jor Chil 1.07 V for Bry Br and 0.64 V forty. At pH = 3, permanganate’is expected to oxidize ( 0.050V [JEE-Main (Online)-2015) (1) Ch and Br (2) Ch, Br and F (3) Brand | (4h only The volume of 0.1N dibasic acid sufficient to neutralize 1g of a base that furnishes 0.04 mole of Olt in aqueous solution is [JEE-Main (Online}-2016} (1) 400 mt (2) 200 mt. 8) 600 mL. (4) 800 mtne 2E-Chemistry ALLER IXERCISE - 05 [B] JEE-[ADVANCED] : PREVIOUS YEAR QUESTIONS ‘What will be the resultant pH when 200 mi of an aqueous solution of HCI {pl = 2.0) is mixed wilh 300 ml of an aqueous solution of NaOH (pH = 12.0)? [SEE 1998), ‘The pH of 0.1 M solution of the following salts increases in the order [SEE 1999] (A) NaCl < NH,CI< NaCN < HCL (B) HCL < NH,Cl < NaCl < NaCN (C)NaCN < NH,C! < NaCl < HEI (DVHCI < NaCl < NaCN < NH,Cl _ Abulfer solution can be prepared from a mixture of (JEE 1999] 13. {A) sodium acetate and acetic acid in water {B) sodium acetate and hydrochloric acid in water (C) ammonia and ammonium chloride in water (D) ammenia and sodium hydroxide in water ‘The solubility of PL(OH), in water is 6.7 %10-6M. Calculate the sokibiiy of PbO! in a b pH» 8. oS concentvation of SO, in the atmosphere over a city on a certain day is 10 ppm, when t temperatire is 298 K. Given that the solubility of SO, in water af 298 K is 1.2653 mioles lire"? and the pK, of H,S0, is 1.92. estimate the pH of rain on that day, [SEE 2000} For sparingly soluble salt ApBa, the relationship ofits solubility product(s} with its solubility (8) is [MEE 2001) (A)Ls= Spr g® BLS = SP, pig? (CVs =S™\ phi (DI Ls = S#,fpcle9 ‘An aqueous solution of 6.3 g oxalic acid diaydrate is made up to 250 ml. The volume of 0.1 N NaOH required to completely neutralise 10 ml. of this solution is [SEE 2001] 10) 40 mi. {8} 20 mL. (C)10 mh. (0)4 ml 500 mi of O.2 M aqueous solutlon of acetic acid is mixed with 500 ml. of 0.2 M HCl at G@] Calculate the degree of dissociation of acetic acid in the resulting solution and pH of the solution, fb) {16 gof NaOH is added ta the above solution, determine final pH. Assume there is no change in volume ‘on mixing. K, of acetic acid is 1,75 x10" M. ISEE 2002] A solotion which is 10-8 M each in Mn?*, Fe’, Zn® and Hg? ist jon. HK... MoS. S, ZnS and HgS are 10°*, 10-23, 10-2 ancl 10- respectively, whieh one will precipitate ved with 10°10M [JEE 2003] (Fes (aM (OHys 10) 2 ind 258C ? Explain. [EE 2003] Will the pH of water be seme at 4°C a 0.1 Mof HA is tivated with 8.1 DH, caleulate the pH ai end point. Given Ka(htA} = 5: [SEE 2004] HX is a weak acid (K, = 105}. It forms a salt NaX (0.1 M) on reacting with caustic soda, The degree hydrolysis of NaX is (ay0.01% (8) 0.001% (oo. 10) 05 [aE 2004) CHgNH, (0.1 mole, K,, ~ 5 x 10+) is added to 0.08 moles of HICI and the slation is diluled 1p one Bre, § resulting hydrogen ion concentration is, (ay 1.6 x10" (a)Sx10% (5 «10% (D2 %10% — fJEE 20055 ° Eine onic Equilibrium, Aci Base 14. The species present in solution when CO, is dissolved in water (A) CO,, H,CO,, HCO; , CO,” ()H,CO,, CO,* [JE 2006} (1C0,?, HCO, ©)CO,, HCO, 2 2 15. 2.5 ml. of 3 Mweak monoacidic base {K, = 1 5107 at 25°C] is titrated with 7g MHC in water at 25°C he concentration of He x10" at 250) (3.7 x10" (B)3.2«107M (32x10%™ )2.7 x10°M 16. Solubility product constants (Kap) of salts of iypes MX, MX, and M,X at temperature “T” are 4.0 10%, 3.2 10 and 2.7 x07, respectively. Sclubiltie (mol din} ofthe sats a temperature Tare in equivalence point is (SEE 2008] the order (A) MX > MX, > MAX (B)M,X > MX, > MX [SEE 2008) (OMX, > MX > MX (O1MX > MX > MX, 17. The dissociation constant ofa substituted benzoic acd at 25°C is 1.0 104, The pH of a 0.01 M soktion of its sodium salt i [JEE 2009] KOH, CH,COOH and CH,COONa of identical concentrations are provided, The pair(s) of solutions which form @ buffer upon mixing isfare {AJ HNO, and CH,COOH {8} KOH and CH,COONa () HINO, and CH,COONe (D) CH,COOH and CH,COONa 19. in 1, saturated solution of AgCI IK (AgCH = 1.6 x10", 0.1 mol of acl HKA{CuCH = 1.0 x 10° is added. The resultant concentration of Ag! in the solution is 1.6 x10, The value of ‘x’ is, [SEE 2011) 20. The ints rate of hydrolysis of methy| acetate (IM) by a weok acc HA, 1M) is L/100" of that of a strong acid (HX, IM) at 25°C. The K, of HA is (SEE 2013] iE x104 (B) 1 x10" (11 x10* (D) 1x10 2A. The K, of Ag,Cr0, is 1.1 x10" at 298 K. The sokbly fm mol/L} of Ag, CxO, in 20.1 M AGNO, soluslon is [SEE 2013) ix (B) 1.1 «107° (11x10 (it x10” 22. “The molar conductivity ofa solution ofa weak acid HX (0,01 M)is 10 times smaller thon the moter conductivity of solution ofa weak acid HY (0.1 M128. w 2°, the diference in thelr pK, values PR HX) ~ pk), is (consider degree of ionization of bath acids to be <<}. [SEE Advanced 2015} ee i ESaa aia eee pes pH = 11.3010 2. {Bi 3. BL) 4. = 1.203 5. 6. tA) ine (Ab 3. {a} 0.0175% , (b) 4.757 io (c) 10. No it will be > 7 ll pH=9 22. (A) 13. B) 14, (A) 15. (DD) 16. (Dp 17, (8) 18. (©), (D} 19, (7) |20. tA) 21. (BP 22. E) 7