SECTION : I

OBJECTIVE QUESTIONS HAVING ONLY ONE CORRECT OPTION

1. What is product of the reaction

dil . Na CO
3CH2O + CH3CHO  o  ?
2 3

40 C

CH2OH
(a) CH2OH — CH2 – CHO (b)
CH2OH— CH — CHO
CH2OH

(c) CH2 CH — CHO (d*) CH2OH— C — CHO

CH2OH

2. Which of the following is incorrect match –

(a)  C2 H 5O  3 Al CH COOC H – Tischenko reaction
2CH3CHO   3 2 5

NaOH
(b) 2C6H5CHO   C6H5CH2OH + C6H5COOH – Cannizaro reaction
K 2CO3
(c*) 2HCHO  HOH2C – CHO – Aldol condensation
(d) None of these

3. In HSO5– which of the following observation is correct ?

(a) all S–O bonds are of same bond length
(b) 2 S–O bonds are shorter & 2 S–O bonds are longer
(c*) 3 shorter S–O distances & 1 longer S–O distance which is in —O—O—H group
(d) All S–O bond lengths are different

4. Which of the following statement is incorrect

(a) t-BuF is solvolyzed only in very acidic medium
(b) t-BuCl is solvolyzed more slowly in 90% D2O – 10% H2O dioxane than in
90% H2O – 10% dioxane
(c) t-BuCl is solvolyzed much faster than 2-chloro -1, 1, 1 – trifluoro – 2 – methyl propane
(d*) cyclopentyl chloride will hydrolyse much faster than cyclopropyl chloride

5. A halogen compound decolourizes bromine in CCl4, absorb hydrogen in the presence of a catalyst and
gives a white precipitate with Tollen’s reagent. The probable structure that matches with these
properties is
(a) H2C = CH – CH2Cl (b*) HC  C – CH2Cl
(c) H3C – C  C – CH2Cl (d) H2C = CH – Cl
6. Which of the following option is not correct ?
When 2 chloro butane undergo monochlorination total X no.of product formed which are allowed to
undergo fractional cyrstallisation, Y no.of fractions are obtained.
(a*) 6 products are obtained out of which 4 are optically active, 2 are optically inactive
(b) 8 products are obtained out of which 6 are in the form of racemic mixture ; 1 is achiral product
& another is meso compound
(c) 5 fractions are obtained
(d) None of these
 NH2
NO2

7. Correct order of basicity N N N

H H
(A) (B) (C) (D)
(a*) A > B > C > D (b) A>B>D>C (c) A > C > B > D (d) A > D > C > B

8. Sodium sulphide react with sodium nitroprusside to form a purple coloured compound. During the
reaction, the oxidation state of iron
(a) change from +2 to +3 (b) changes from +3 to +2
(c) change from +2 to +4 (d*) remain unchanged
9. A pale yellow substance A when heated with conc. HNO 3 evolves a brown coloured gas B. The
substance A also dissolved in sodium sulphite solution on heating. A clear solution (C) is formed
which on acidification gives a turbid solution and a pungent smelled gas (D) which is formed by the
substance (A) in air. The solution (C) decolourises iodide solution. Which of the following is
incorrect reaction ?

(a) S  HNO3 
 H 2SO 4  N O 2  H 2 O
A  B

(b) S Na 2SO3 
 Na 2S2 O3
A (C)

(c) Na 2S2 O3  H 2SO 4  Na 2SO 4  SO 2  S  H 2O

(d*) Na 2S2 O3  I2  Na 2SO4  I2  SO2
Br
Ph
Ph
10. The reaction of AgBF4 with produce the product which is
Ph
Ph
Br
(*a) aromatic (b) non aromatic
(c) antiaromatic (d) open chain structure

11. Which of the following is correct for the tin that exhibits enantiotropy among its three allotropic
forms ?

Grey tin         white tin  

500K 434K
(a)  brittle tin    
(b)
286.5K
 white tin    200K
Brittle tin       grey tin   
 

(c*) Grey tin         white tin      

286.5K 434K
 brittle tin
White tin      
400K 286.5K
(d)  grey tin     
 brittle tin

12. Which of the following statement is incorrect ?

(a) lead salts are slow poisonous
(b) PbO2 and PbO both are amphoteric in nature but PbO is more basic than PbO2
(c*) Pb(IV) salt is more stable than Pb(II) salt
(d) lead does not show allotropy

SECTION – II
ASSERTION – REASON
Q. 10 to Q. 13 consist of two statements each printed as assertion and reason. Examine both the
statement carefully and mark the correct choice according to instruction given below:-
(A) If both assertion and reason are true and reason is correct explanation of assertion
(B) If both assertion and reason are true and reason is not correct explanation of assertion
(C) If assertion is true but reason is false
(D) If assertion is false but reason is true
15. Assertion : Double bond of alkene undergoes homolytic cleavage when it reacts with triplet carbene
where as it undergoes heterolytic cleavage when it reacts with singlet carbene.
Reason : Singlet carbene acts as electrophile and triplet carbene acts as diradical.
(a*) A (b) B (c) C (d) D
15 –
16. Assertion : H3C – C – NHBr + Et – C – NHBr + OH gives 4 products which are
O O
15 15
CH 3  CN  C  O; Et – N = C = O ; CH3 – N = C = O ; Et N = C = O ;
Reason : The reaction involves intramolecular rearrangement of alkyl group.
(a) A (b) B (c) C (d*) D

15. Assertion : PbBr4 does not exist.

Reason :  Large size of four Br groups makes it unstable .
(a) A (b*) B (c) C (d) D

16. Assertion : NaIO3 is converted to I2 by using SO2 rather than H2O2 or Sn2+.
Reason : SO2 is very cheap
(a*) A (b) B (c) C (d) D
SECTION : III
COMPREHENSION BASED QUESTIONS HAVING ONLY ONE CORRECT OPTION.

COMPREHENSION – I :
Carbonyl compound gives addition reaction with alcohols. The reaction is catalysed by acid as
well as base. Alcohol gives two types of product. Hemiacetal or hemiketal formation takes place
the basic medium. Acetal and ketal formation takes place in acidic medium. These reactions
are reversible reactions.

7. Hemiketal is
(a) , – dialkoxy alkane (b) ,  – dihydroxy alkane
(c*) – Alkoxy alcohol (d) –alkoxy alcohol

8. Which one of the following statements is correct ?

(a) Formation of hemiacetal is catalysed only by base
(b*) Formation of ketal is catalysed only by acid
(c) Formation of ketal is catalysed only by base
(d) Formation of ketal is catalysed by acid as well as base

9. In the given reaction

O 

COOCH3 CH2OH – CH2OH/ H (i) CH3MgBr(excess)

(A) [X]
(ii) NH4Cl/HOH

[X] is
OH CH3OH O OH HO CH3 HO CH3
(a) C – CH3 (b*) C – CH3 (c) COOCH3 (d) COOH
C
CH CH3
3

COMPREHENSION – II :
 The conversion of an amide to a primary amine with one carbon atom less by action of NaOBr
is known as Hoffmann rearrangement. The rearrangement is intramolecular. Hoffmann
rearrangement is accelerated if the migrating group has electron donating group/s.

7. Following is not the reaction intermediate of the Hoffmann rearrangement is


(a) RCO NHBr (b) RCO N Br


(c) R–N=C=O (d*) R – C – N

O

8. Which one of the following is most reactive for Hoffman rearrangement ?

(a) (b) C6H5 – CONH2
H3C CONH2

(c*) (d)
CH3O CONH2 NC CONH2

CH3

H CONH2 
NaOBr
 Product
9. Consider the given reaction
C6H5
(S)
Product of the reaction has :
(a) S – Configuration (b) R – Configuration
(*c) 1 : 1 mixture of R and S (d) 2 : 1 mixture of R and S
SECTION : IV
CONSISTS OF MATCH THE COLUMN MAY HAVE MORE THAN ONE MATCH.
Ex : If the answers is A  P, Q ; B  R, S ; C  P ; D  S, T than mark as
A: P Q R S T
B: P Q R S T
C: P Q R S T
D: P Q R S T

15. Match the following columns.

Column – I Column - II
(A) H2O < H2S < H2Se < H2Te (P) Bond angle
(B) H2O > H2S > H2Se > H2Te (Q) Melting and boiling point
(C) H2O > H2S < H2Se < H2Te (R) Acidic strength
(D) NH3 > PH3 (S) Basic strength

Ans : A  R ; B  P, S ; C  Q ; D  P, Q, S
39. Match the following
Column – I Column – II
(Information) (Gas)
(A) Colourless gas with odour (P) CO2
(B) Brown (Q) Br2
(C) Gas turns lime water milky (R) NO2
(D) Excess of passage of gas through (S) NH3
lime water disappear milkyness (T) SO2
Ans : A  T, S ; B  Q, R ; C  P, T ; D  P, T
28. Match the following columns
Column – I Column – II
(A) Me3C  CH  CH 2  HCl  (P) Mixture of isomeric products is formed
(B) R 2 CH  Cl  KCN  (Q) Attacking nucleophile acts as ambidentate
nucleophile
O

(C) R – C – NH – O – S – CH3   (R) Rearrangement take place
O O
Br2
(D) Cis but2ene 
 CCl4   (S) Leaving group is good leaving group.
A  P, R ; B  PQS ; C  RS ;DP

28. Match the following columns

Column – I (Reaction) Column – II (Mechanism involved)
(A) PhCH2 – CH2 – OTS 
NaN3
 P1 (P) N.G.P

(B) PhCH2 – CH2 – OTS 

NaOEt
 P1 (Q) E2

CH – CH3 Alcoholic
  (R) E1CB
AgNO
(C) Cl
3

NaOEt
(D) Cl 2 HC  CFCl2   (S) E1
Ans : A  P ; B  Q ; C  S ; D  R