Surface Chemistry ERCISE - 05 [A] JEE-[MAIN] : PREVIOUS YEAR QUESTIONS. ‘The disperse’ phase in collldal iron (ll) hydroxide and colloidal gold is positively and negatively charged, respectively. Which of the following statement is NOT correct IAIEEE-2005] (1) Magnesium chloride solution cooguates, the gold sol more readily than the iron (il) hydroxidesot {2) Sodium sulphate solution cause coagulation in both sls (8) Mixing the sols has no effect (4) Coaguiation in both sols can be brought about by electrophoresis The volume of a colloidal particle, Vas compared to the volume ofa solute patil in true soliton V, could be = {AIEEE-2005] Ve Vos ° Ve _ 193 Me 10 Ne 10) Oy aE MY, ‘Which of the following statements is incorrect regarding physisorptions ? [AIEEE-2009] (1) Under high pressure it results Into muiti molecular layer on adsorbent surface (2) Enthalpy of adsorption (AH,cpued) is low and positive 8 4gmn/ (3) It occurs because of Van de? Weal’s forces a. {4) More easly liquefiable gases are adsorbed readily luton ane ‘According to Freundlich adsorption isotherm, which of the folowing is correct ? [AIEEE-2012) lista Xap? nce tt) Rep 2) Sept selmal Kapile = @ oP (4) All the above are correct for different ranges of pressure ‘The coagulating power of electrolytes having ions Na*, AlS* and Ba®* for aresenic sulphide sol increases in the.ordér + (JEE-Main 2013] (1) APY < BaP < Nat (2) Nat < Ba" < AI* (3) Ba? < Not < AP (4) AR < Nat < Ba? The following statements relate to the adsorption of gases on a solid surface. Identify the incorrect statement among them : [JEE-Main (Online) 2015) (1) On adsorption, the residual forces on the surface are increased (2) On adsorption decrease in surface energy appears as heat (3) Entropy of adsorption is negative (@ Enthalpy of adsorption Is negative | Fora linear plot of oglx/m) versus iog p in.a Freundlich adsorption isotherm, which of the folowing statements | is comect ? and n are constants) [JEE-Main 2016] | {1) log (1/n) appears as the intercept (2) Both k and 1/n appear in the slope term | (8) 1/n appears as the intercept (4) Only 1/n appears as the slope | | i= a 37JEE-Chemisiry 8. A particular adsorption process has the following characteristics: (It arises due to van der Weals forces and i) it is reversible. Mntity the correct statement that describes the above adsorption process: [JE Main (Online) 2016] (2) Enthalpy of adsorption is greater than 100 kul mek (2) Energy of activation is low, (2) Adsorption ts monolayer (4) Adsorption ‘increases with increase in temperature 9. Match the items in Coldimn I with its main use ited in Column I; [JEE Main (Online) 2016 Column-t Colunn-t (A)] Sica get | @ [Transistor B)| Siicon (@ |fon-exchanger (©)|Siivone (@ [Drying agent (D)|siteate (i) [Seatane (1) (AMG, (BH, (CH, (DH) (2) (AM), (B)40, (CHE), (DH) (3) (AH, (BH, (CH), (OH) (4) (AME, (BHO, (CH), (OM) 10, The most appropriate method of making egg-albumin so! is : [JEE Main (Online) 2016] (1) Keep the egg in boing water for 10 minutes, After removing the shel transfer the white part ofthe content to 100ml. of 5% w/V saline sclution and homogenize with a mechanical shaker. (2) Break an egg carefully and transfer only the yellow part of the content to 100 mL. of 5% w/V saline solution and stir well (8) Keep the egg in boiling water for 10 minutes. After removing the shal, transfer the yellow part of the content to 100mL of 5% w/V saline solution and homogenize with a mechanical shaker. (4) Break an egg carefully and transfer the transparent part of the content to 100 mi. of 596 w/V saline solution and str wel 11. Gold numbers of some colloids are : Gelatin : 0.005 - 0.01, Gum Arabic : 0.15 ~ 0.25 ; Oleate : 0.04 - 1.0, Starch : 15 ~ 25. Which among these is a better protective.collold ? [JEE Main (Online) 2016] (1) Oleate (2) Gelatin (3) Gum-Arabie (4) Starch, 12, Which one of the following substanceé used in dry cleaning is a better strategy to control environmental pollution ? [JEE Main (Online) 2016] (1) Nitrogen dioxide (2) Sulphur dioxide (3) Carbon dioxide (4) Tetrachloroethslene +) 2016 Surface Chemistry XERCISE - 05 [B] JEE-[ADVANCED] : PREVIOUS YEAR QUESTIONS ‘Among thé following, the surfactant that will from micelles in aqueous solution at the lowest molar concentration at ambient conditions is {JEE 2008} (A) CHJCH,),.NYCH,),Br (8) CHJCH,),,0S0,"Na* (©) CH{CH,},COO"Na* (D) CH,CH,},,N*(CH,),Br° ‘Among the électrolytes Na,SO,, CaCl, Al,{SO,), and NH,CI, the most effective coagulation agent for Sb,S, sol is [JEE 2009] (A) Na,SO, (CaCl, ()AL{SO,), (D) NH,CI ‘The correct statement(s) pertaining to the adsorption of a gas on a solid surface is (are) - (A) Adsorption is always exothermic [JEE 2011] (B} Physisorpticn may transform into chemisonption at high temperature (C) Physisorption increases with increasing temperature but chemisorption decreases with increasing temperature (0) Chemisorption is more exothermic than physisorption, however it is very slow due to higher energy of activation Choose the correct reason(s) for the stablity-of the Iyophobie colloidal particle. [EE 2012} (A) Preferential adsorption of ions on thelr surface from the solution (B) Preferential adsorption of solvent on their surface from the solution (©) Attraction between different particles having opposite charges on their surface (0) Potential difference between the fixed layer and the diffused layer of opposite charges around the colloidal particles ‘The given graphs / data I, I, IM and IV represent general trends observed for different physisorption and chemisorption processes under mild conditions of temperature and pressure, Which of the following choicels) about I, I, HI and IV is (ate) correct ? (JEE 2012] 3 )— Peonstant 3 W — Peonstant 3 3 é & 2 3 = z 2 3 é é T T oe 200K 250K ‘Amount of gas adsorbed Potential eneray P . . (A) Lis physisorption and II is chemisorption _(B) is physisorption and Ill is chemisorption {C)1V ts chemisorption and Hl is chemisorption _(D) IV is chemisorption and Ill is chemisorption. 39JEE-Chemistry 6. Methylene blue, from its aqueous solution, is adsorbed on activated charcoal at 25°C. For this process, the corréct statement is - EE. Adv. 2013) (A) The adsorption requires activation at 25°C (B) The adsorption is accompanied by a decrease in enthalpy (©) The adsorption incréases with increase of temperature (©) The adsorption is irreversible ‘The qualitative sketches I, andl! glven below show the variation of surface tension with molar concentration of three different aqueous solutions of KCI, CH,OH and CH,(CH,},,0SO," Na" at room temperature. The correct assigntient of the sketches is = [JEE, Adv. 2016] I u mt g § § 3 : j B & a & € é a Z Z concentration ‘concentration concentration (a): Kel 1: CHOH Il : CHJCH,,,0S0, Not (BL: CH/CH),OSO, Nats CHO mm: Kel (1: Kel It: CH{CH),,080," Nat MH: CH,OH {0) 1 : CH,OH MW: KCI MM : CHCH,,,0S0,° Nat