I.

Flow chart
1. Preparation isomer Trans potassium bisoxalato diaquo chromate (III)

3 grams of oxalic acid dehydrate

- Dissolved with 1 drop of boiling distilled

water into beaker glass
- Added drop by drop 1 gram of potassium
dichromate that dissolved with 1 drop of
hot distilled water
- Closed the beaker glass with petri dish
- Evaporated it in water bath until the
volume is a half
- Allowed evaporated by itself at room
temperature until 1/3 volume
- Filtered it

Residue (Crystal) Filtrate

- Washed with 5 mL of distillate

water than 5 mL of ethanol
- Dried it in oven (40℃)

Result

- Calculated the rendemen

- Observed the color
- Determined the melting point
- Analyzed with UV-VIS

Result

Reaction:
7H2C2O4.2H2O(aq) + K2Cr2O7(aq) → 2K[Cr(C2O4)2(H2O)2] (s) +
6CO2 (g) + 7H2O(ℓ)
2. Preparation isomer Cis potassium dioxalato diaquo chromate (III)

1 gram of potassium dichromate + 3 grams of oxalic

acid dehydrate

- Inserted into beaker glass

- Added 1 drop of hot distilled water

Produce H2O and CO2 gas

- Keep it (don’t become solution)

Mixture of pasta

- Added 5 mL of ethanol
- Stir until produce precipitate
- Decanted it
- Added 5 mL of ethanol again
- Filtered it

Residue Filtrate

- Washed with 5 mL of distillate

water than 5 mL of ethanol
- Dried it in oven (40℃)

Result

- Calculated the rendemen

- Observed the color
- Determined the melting point
- Analyzed with UV-VIS

Result

Reaction:
7H2C2O4.2H2O(aq) + K2Cr2O7(aq) → 2K[Cr(C2O4)2(H2O)2] (s) +
6CO2 (g) + 7H2O(ℓ)
3. Isomer purity test

Crystal Isomer Cis and Trans

- Placed on filter paper

- Dropped with ammonium hydroxide solution

A dark green color rapidly A light brown solid which is

spreading on the filter insoluble (Trans)
paper (Cis)

Reaction:
2K[Cr(C2O4)2(H2O)2](s)+ 2NH4OH(aq) → 2K[Cr(NH3)2(H2O)2](s) +
H2C2O4(aq) + H2O(ℓ)
VII. Observation Result
1. Preparation isomer Trans potassium bisoxalato diaquo chromate (III)
No. Perlakuan pengamatan Reasksi Kesimpulan
1. Oxalic acid dehydrate White crystal H2C2O4.2H2O  The preparation trans-potassium
2. Oxalic acid dehydrate + White lump H2C2O4.2H2O(s) + H2O(ℓ) → bisoxalato diaquo chromate (III)
can be prepared by Oxalic acid
distillate water H2C2O4.2H2O(aq)
dehydrate is reacted with
3. Potassium dichromate Orange crystal K2Cr2O7 Potassium dichromate
4. Potassium dichromate + Orange lump K2Cr2O7 + H2O(ℓ) → K2Cr2O7(aq)  The percent yield of crystal
trans-potassium bisoxalato
distillate water
diaquo chromate (III)
5. Oxalic acid dehydrate - Blackish brown solution 7H2C2O4.2H2O(aq) + K2Cr2O7(aq) K[Cr(C2O4)2(H2O)2] is 25% , but
solution + Potassium - Bubbles appear → 2K[Cr(C2O4)2(H2O)2] (s) + in this experiment the trans
isomer is impurities, it’s proven
dichromate solution - There are condense in beaker 6CO2 (g) + 7H2O(ℓ)
that its crystal color is brown
glass wall color and there is dark green
- Exothermic reaction, because color
releasing heat
6. After the mixture of 2 Dark green lump 2K[Cr(C2O4)2(H2O)2] (s)
solutions are evaporated
7. After crystal is filtrated - Residu : dark green
- Filtrate : blackish green
solution
8. After washing with - Residu : dark green
 distillate water
9. After washing with
ethanol
10. After drying (T= 40oC)
constant weight
11. Isomer purity test : filter
paper + crystal +
ammonia solution
- Filtrate : green solution
Dark green
- Weight 1 = 0.5577 gr
- Weight 2 = 0.5461 gr 0.5173 𝑔𝑟𝑎𝑚
% yield = x 100%
2.0604 𝑔𝑟𝑎𝑚
- Weight 3 = 0.5432 gr
= 25 %
- Weight 4 = 0.4625 gr
- Average weight = 0.5173 gr
Brown color + dark green color 2K[Cr(C2O4)2(H2O)2](s)+
2NH4OH(aq) →
2K[Cr(NH3)2(H2O)2](s) +
H2C2O4(aq) + H2O(ℓ)
 2. Preparation isomer Cis potassium dioxalato diaquo chromate (III)

No. Perlakuan pengamatan Reasksi Kesimpulan

1. Oxalic acid dehydrate White crystal H2C2O4.2H2O  The preparation Cis potassium
2. Potassium dichromate Orange crystal K2Cr2O7 dioxalato diaquo chromate (III)
can be prepared by Oxalic acid
3. Oxalic acid dehydrate + White orange crystal 7H2C2O4.2H2O(s) + K2Cr2O7(s) ↛ dehydrate is reacted with
Potassium dichromate Potassium dichromate
4. Oxalic acid dehydrate + - Blackish brown solution 7H2C2O4.2H2O(aq) + K2Cr2O7(aq)  The percent yield of crystal
trans-potassium bisoxalato
Potassium dichromate + - Bubbles appear → 2K[Cr(C2O4)2(H2O)2] (s) +
diaquo chromate (III)
1 drop of distillate water - There are condense in beaker 6CO2 (g) + 7H2O(ℓ) K[Cr(C2O4)2(H2O)3] is 86.34 % ,
glass wall which the crystal color is dark
green
- Exothermic reaction, because
releasing heat
5. After the mixture of Duration of stirring until
solutions + ethanol + formed precipitate = 1 minute
stirred 28 second
6. After decanted + ethanol - Residu : black 2K[Cr(C2O4)2(H2O)2] (s)
again - Filtrate : blackish purple
solution
7. After crystal is filtrated - Residu : black
- Filtrate : blackish purple
solution
8. After drying (T= 40oC)
constant weight
9. Isomer purity test : filter
paper + crystal +
ammonia solution
- Weight 1 = 1.9275 gr
- Weight 2 = 1.8607 gr
- Weight 3 = 1.8236 gr
- Weight 4 = 1.6523 gr
- Average weight = 1.7789 gr
Dark green color
1.7789 𝑔𝑟𝑎𝑚
% yield = 2.0604 𝑔𝑟𝑎𝑚 x 100%
= 86.34 %
2K[Cr(C2O4)2(H2O)2](s)+
2NH4OH(aq) →
2K[Cr(NH3)2(H2O)2](s) +
H2C2O4(aq) + H2O(ℓ)
 Calculation Attachment

Known: - Mass of H2C2O4.2H2O = 3 grams

- Mr of H2C2O4.2H2O = 126 grams/mole
- Mass of K2Cr2O4 = 1 grams
- Mr of K2Cr2O4 = 294 grams/mole
The data that obtain are:
- Weight 1 = 0.5577 gr
- Weight 2 = 0.5461 gr
- Weight 3 = 0.5432 gr
- Weight 4 = 0.4625 gr
- Average weight = 0.5173 grams
Asked: % yield= …….. %
Answered :
3,000 𝑔𝑟𝑎𝑚
- Mass of Initial mole H2C2O4.2H2O = 126 𝑔𝑟𝑎𝑚/𝑚𝑜𝑙 = 0,0238 mol
1,000 𝑔𝑟𝑎𝑚
- Initial mole K2Cr2O4 = 294 𝑔𝑟𝑎𝑚/𝑚𝑜𝑙 = 0,0034 mol

7H2C2O4.2H2O + K2Cr2O7 → 2K[Cr(C2O4)2(H2O)2] + 6CO2 + 7H2O

Initial = 0.0238 mole 0.0034 mole - - -
React = 0.0238 mole 0.0034 mole 0.0068 mole 0.0204 mole 0.0238 mole
Residue= 0 mole 0 mole 0.0068 mole 0.0204 mole 0.0238 mole

- Theoritical mass of K[Cr(C2O4)2(H2O)2]

grams
= 0.0068 mole x 303 = 2.0604 grams
mole
Experimental mass
% yield = × 100%
Theoritical mass
0.5173 grams
% yield = × 100%
2.0604 𝑔𝑟𝑎𝑚𝑠
% 𝐲𝐢𝐞𝐥𝐝 = 𝟐𝟓 %
 Known: - Mass of H2C2O4.2H2O = 3 grams
- Mr of H2C2O4.2H2O = 126 grams/mole
- Mass of K2Cr2O4 = 1 grams
- Mr of K2Cr2O4 = 294 grams/mole
The data that obtain are:
- Weight 1 = 1.9275 gr
- Weight 2 = 1.8607 gr
- Weight 3 = 1.8236 gr
- Weight 4 = 1.6523 gr
- Average weight = 1.7789 gr
Asked: % yield= …….. %
Answered :
3,000 𝑔𝑟𝑎𝑚
- Mass of Initial mole H2C2O4.2H2O = 126 𝑔𝑟𝑎𝑚/𝑚𝑜𝑙 = 0,0238 mol
1,000 𝑔𝑟𝑎𝑚
- Initial mole K2Cr2O4 = 294 𝑔𝑟𝑎𝑚/𝑚𝑜𝑙 = 0,0034 mol

7H2C2O4.2H2O + K2Cr2O7 → 2K[Cr(C2O4)2(H2O)2] + 6CO2 + 7H2O

Initial = 0.0238 mole 0.0034 mole - - -
React = 0.0238 mole 0.0034 mole 0.0068 mole 0.0204 mole 0.0238 mole
Residue= 0 mole 0 mole 0.0068 mole 0.0204 mole 0.0238 mole

- Theoritical mass of K[Cr(C2O4)2(H2O)2]

grams
= 0.0068 mole x 303 = 2.0604 grams
mole
Experimental mass
% yield = × 100%
Theoritical mass
1.7789 grams
% yield = × 100%
2.0604 𝑔𝑟𝑎𝑚𝑠
% 𝐲𝐢𝐞𝐥𝐝 = 𝟖𝟔. 𝟑𝟒 %