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IDENTIFY: If the given wave function is a solution to the Schrödinger equation, we will get an
identity when we substitute that wave function into the Schrödinger equation.
SET UP: The given function is ( x) Aeikx , and the one-dimensional Schrödinger equation is
d 2 ( x)
U ( x) ( x) E ( x).
2m dx 2
EXECUTE: Start with the given function and take the indicated derivatives: ( x) Aeikx .
d ( x) d 2 ( x) d 2 ( x)
Aikeikx . Ai 2 2 ikx
k e Ak 2 ikx
e . k 2 ( x).
dx dx 2 dx 2
d 2 ( x) 2
k 2 ( x). Substituting these results into the one-dimensional Schrödinger
2m dx 2 2m
2
k2
equation gives ( x) U 0 ( x) E ( x).
2m
d I d II
I ( x) Aeik x Beik x and II ( x) Ceik x . Set I (0) II (0) and
1 1 2
at x 0.
dx dx
d ikx
SET UP: (e ) ikeikx .
dx
d I d II
EXECUTE: I (0) II (0) gives A B C. at x 0 gives ik1 A ik1B ik2C.
dx dx
k k 2k 2
Solving this pair of equations for B and C gives B 1 2 A and C A.
k1 k2 k1 k2
B 2 (k1 k2 ) 2
EVALUATE: The probability of reflection is R . The probability of transmission
A2 (k1 k2 ) 2
C2 4k12
is T . Note that R T 1.
A2
(k1 k2 )2
(n 1) 2 n 2 2n 1 2 1
40.36. (a) Rn 2 . This is never larger than it is for n 1, and R1 3.
n2 n2 n n
(b) R approaches zero; in the classical limit, there is no quantization, and the spacing of successive
levels is vanishingly small compared to the energy levels.
L 4
2 L/4 πx 2 L/ 4 1 2πx 1 L 2πx 1 1
L 0
40.38. (a) sin 2 dx 1 cos dx x sin , which is about
L L 0 2 L L 2 L 0 4 2π
0.0908.
L2
1 L 2πx 1 1
(b) Repeating with limits of L 4 and L 2 gives x sin ,
L 2π L L 4 4 2
about 0.409.
(c) The particle is much likely to be nearer the middle of the box than the edge.
(d) The results sum to exactly 1/2, which means that the particle is as likely to be between
x 0 and L 2 as it is to be between x L 2 and x L.
(e) These results are represented in Figure 40.5b in the textbook.
40.45. (a) We set the solutions for inside and outside the well equal to each other at the well boundaries,
x 0 and L.
x 0 : A sin(0) B C B C, since we must have D 0 for x 0.
2mEL 2mEL
x L: A sin B cos De L since C 0 for x L.
2mE
This gives A sin kL B cos kL De L , where k .
dψ
x 0: kA cos(k 0) kB sin(k 0) kA Cek 0 kA C
dx