Satellite Beach PFOS-PFOA Sampling Report

August 2, 2018
Mr. Nicholas Frank Sanzone

Environmental Programs Coordinator
565 Cassia Boulevard
Satellite Beach, FL 32937
nsanzone@satellitebeach.org
Subject: City of Satellite Beach Per– and Polyfluoroalkyl Substances (PFAS) Water
Sampling
Satellite Beach, Florida
Dear Mr. Sanzone:
Tetra Tech, Inc. (Tetra Tech) is pleased to provide the City of Satellite Beach this report
summarizing the recent Per– and Polyfluoroalkyl Substances (PFAS) groundwater sampling
services for the City of Satellite Beach.
BACKGROUND
PFAS are a group of manufactured compounds widely used to make products resistant to stains,
grease, and water. These compounds are found in everyday products, such as nonstick pans, post
it notes, and food packaging. PFAS are also widely used in fire suppression foams. Some PFAS
compounds can biotransform to perfluoroalkyl acids like perfluorooctane sulfonate (PFOS) and
perfluorooctanoic acid (PFOA), which do not readily degrade. These compounds are emerging
contaminants, and the science of the health risks, fate and transport, and detection methods is
developing but still in the initial stages.
The most likely route of exposure to these chemicals is through contaminated food or water. The
United States Environmental Protection Agency (USEPA) has not established maximum
contaminant levels (MCLs) for drinking water for PFAS, and the Florida Department of
Environmental Protection (DEP) has not established Groundwater Cleanup Target Levels for
PFAS. However, the USEPA has established a Health Advisory for PFOA and PFOS of 0.07
ug/L, and the DEP is expected to release its health advisory levels in the coming days.
The City of Satellite Beach requested that Tetra Tech install and sample three monitoring wells.
The City selected two City owned properties and one Brevard County owned property for the
installation and sampling of monitoring wells with analysis for PFAS compounds, including
PFOA and PFOS.
Tetra Tech, Inc.

11 Riverside Drive, Suite 204, Cocoa, FL 32922
Tel 321.636.6470 Fax 321.636.6473 www.tetratech.com
Mr. Nick Sanzone
August 2, 2018
Page 2 of 10
PHYSICAL SETTING
According to the Geologic Map of Florida (Florida Geologic Survey 2001) the City of Satellite
Beach is located in the Pleistocene/Holocene aged Beach Ridge and Dune Formation. The
formation includes siliciclastics of light gray, tan, brown to black, unconsolidated to poorly
consolidated, clean to clayey, silty, unfossiliferous, variably organic-bearing sands to blue green
to olive green, poorly to moderately consolidated, sandy, silty clays. The sandy marine deposits
are underlain by limestone, which may be exposed along much of the shoreline of Satellite
Beach.
FIELD INVESTIGATION ACTIVITIES
Tetra Tech initiated field activities on July 17, 2018. The investigation included the installation
and sampling of three monitoring wells at the following locations, as shown on Figure 1:
• Satellite Beach City Hall (SB1)

• Satellite Beach near Jackson Avenue and Delaura Court (SB2)
• Brevard County Parks - Sea Park (SB3)
The field investigation activities conducted are described below.
Well Drilling Activities
Prior to drilling, Sunshine One Call underground utility clearance hotline was contacted by Tetra
Tech’s Licensed Well Drilling subcontractor, Preferred Drilling Solutions, Inc., to mark publicly
accessible utilities. Well Construction Permits were obtained from the Brevard County Health
Department prior to drilling, and permits are provided in Attachment A.
All borings were hand cleared with a 4-inch diameter hand auger to identify and minimize the
likelihood of damage to shallow subgrade utilities. Three groundwater monitoring wells were
installed. Each well was constructed with a 1-inch diameter, Schedule 40, polyvinyl chloride
(PVC), 0.010-inch slotted well screen, and 20-30 size sand filter pack. The well screens at each
well location were 10 feet long. Drilling activities encountered refusal at a depth of 12.5 feet below
ground surface (bgs) at location SB1, likely due to the presence of limestone, and well screens were
installed from 2.2 to 12.2 feet bgs. Monitoring wells SB2 and SB3 were installed to a depth of 19.5
feet bgs, with well screen installed between 9.5 and 19.5 feet bgs. Sand filter pack was installed to
one foot above the well screen. A minimum of 6-inches of bentonite was placed above the sand
pack, and neat portland cement was used to seal the well to the surface. After installation and
development, each temporary monitoring well was allowed to stabilize for a minimum of 24 hours
TETRA TECH
Mr. Nick Sanzone
August 2, 2018
Page 3 of 10
before purging and sampling was initiated. The Well Construction and Development Logs are
provided in Attachment A.
Groundwater Sampling and Analysis
Each of the three monitoring wells were purged and sampled with a peristaltic pump using the low
flow sampling techniques. Purging and groundwater sample collection was conducted in general
accordance with FDEP-SOP-001/01 FS 2200: Groundwater Sampling, with additional
precautions for PFAS cross contamination using Tetra Tech Standard Operating Procedure SA-
1.8 for Sample Acquisition for Perfluoroalkyl and Perfluoroalkyl Substances (PFAS) Analysis.
New High-Density Poly Ethylene (HDPE) tubing was used to purge and collect groundwater
samples at each monitoring well. Samples were obtained by pumping water from the aquifer
until the water quality parameters stabilize. Field parameters (pH, specific conductance,
dissolved oxygen, temperature, and turbidity) were measured at regular intervals using a water
meter equipped with a flow through cell until three consecutive measurements met the following
thresholds:
• Temperature: ± 0.2° C
• pH: ± 0.2 Standard Units
• Specific Conductance: ± 5.0% of reading
• Dissolved Oxygen: ≤20% Saturation
• Turbidity: ≤20 NTU
In addition to the monitoring well samples, one Field Reagent Blank was also collected prior to
sampling SB3. Samples were placed in laboratory-provided containers, sealed, labeled, packed
in ice, and shipped under chain-of-custody protocol to SGS Laboratories for analysis of PFAS,
including PFOA, PFOS and 22 additional compounds via USEPA Method 537M.
Copies of the groundwater sampling sheets are provided in Attachment B.
GROUNDWATER ANALYTICAL RESULTS
Tetra Tech compared the analytical results of the groundwater samples to the 0.070 ug/L USEPA
Health Advisory, as outlined in the USEPA documents Drinking Water Health Advisory for
Perfluorooctanoic Acid (PFOA) (USEPA May 2016) and Drinking Water Health Advisory for
Perfluorooctane Sulfonate (PFOS) (USEPA May 2016). In the USEPA Memorandum dated
November 15, 2016, USEPA provided clarification that the purpose of the Health Advisories
was to “identify the concentration of PFOA and PFOS in drinking water at which adverse health
effects are not anticipated to occur over a lifetime.” The health advisories are not intended to be
TETRA TECH
Mr. Nick Sanzone
August 2, 2018
Page 4 of 10
used for other exposure scenarios. The State of Florida DEP does not currently have a
Groundwater Cleanup Target Level for PFOA and PFOS; however, DEP has stated that they will
be issuing a Health Advisory Level for PFOA and PFOS in the coming days.
PFOA and PFOS were detected in each of the three monitoring wells, with PFOA concentrations
ranging from 0.00733 ug/L I (I qualified, meaning that the detected concentration was below the
practical quantitation limit) in SB3 to 0.0119 ug/L in SB1. PFOS concentrations ranged from
0.0188 ug/L in SB2 to 0.0296 ug/L in SB1. USEPA recommends adding PFOA and PFOS
numbers together if both compounds are present and applying the sum of both compounds to the
0.070 ug/L Health Advisory Level. Combined PFOS and PFOA concentrations ranged from
0.02285 ug/L in SB2 to 0.0415 ug/L in SB1. All the PFOA and PFOS (including combined)
results were less than the 0.070 ug/L USEPA Health Advisory Level.
In addition to PFOA and PFOS, other PFAS were detected; however, there are no USEPA
Health Advisory Levels available for PFAS except for PFOA and PFOS. The following
additional PFAS compounds were detected:
• SB1: Perfluorobutanoic acid, perfluoropentanoic acid, perfluorohexanoic acid,

perfluoroheptanoic acid, perfluorobutanesulfonic acid, perfluoropentanesulfonic acid,
and perfluorohexanesulfonic acid, with a maximum concentration of 0.0146 ug/L.
• SB2: Perfluoropentanoic acid at a concentration of 0.00295 I.
• SB3: Perfluorobutanoic acid, perfluoropentanoic acid, perfluorohexanoic acid,

perfluoroheptanoic acid, perfluorobutanesulfonic acid, and perfluorohexanesulfonic
acid, at a maximum concentration of 0.0129 ug/L.
No PFAS analytes were detected in the Field Reagent Blank.
An analytical data summary and comparison to the USEPA Health Advisories is provided in
Table 1, a summary of the PFOA and PFOS results are provided on Figure 1, and the laboratory
analytical report is provided in Attachment C.
CONCLUSIONS
Based on the results of the groundwater sampling and analytical results, PFAS analytes were
detected in each of the three monitoring wells, and PFOA and PFOS were both detected in each
of the three wells. The individual PFOA and PFOS concentrations and the sum of the PFOA and
PFOS concentrations were less than the USEPA Health Advisory level of 0.070 ug/L for each
TETRA TECH
Figures
TETRA TECH
Tables
TETRA TECH
Table 1 - Monitroing Well PFAS Analytical Results
City of Satellite Beach
SB1-20180718 SB2-20180718 SB3-20180718 FRB-20180718 USEPA

Analyte
7/18/2018 7/18/2018 7/18/2018 7/18/2018 HA
Perfluorobutanoic acid 0.0101 I 0.0038 U 0.00631 I 0.0038 U NA
Perfluoropentanoic acid 0.00721 I 0.00295 I 0.0129 0.0029 U NA
Perfluorohexanoic acid 0.00614 I 0.0019 U 0.00625 I 0.0019 U NA
Perfluoroheptanoic acid 0.00402 I 0.0019 U 0.00288 I 0.0019 U NA
Perfluorooctanoic acid (PFOA) 0.0119 0.00405 I 0.00733 I 0.0019 U 0.07
Perfluorononanoic acid 0.0019 U 0.0019 U 0.0019 U 0.0019 U NA
Perfluorodecanoic acid 0.0019 U 0.0019 U 0.0019 U 0.0019 U NA
Perfluoroundecanoic acid 0.0019 U 0.0019 U 0.0019 U 0.0019 U NA
Perfluorododecanoic acid 0.0029 U 0.0029 U 0.0029 U 0.0029 U NA
Perfluorotridecanoic acid 0.0019 U 0.0019 U 0.0019 U 0.0019 U NA
Perfluorotetradecanoic acid 0.0019 U 0.0019 U 0.0019 U 0.0019 U NA
Perfluorobutanesulfonic acid 0.0108 0.0019 U 0.00615 I 0.0019 U NA
Perfluoropentanesulfonic acid 0.00552 I 0.0019 U 0.0019 U 0.0019 U NA
Perfluorohexanesulfonic acid 0.0146 0.0019 U 0.00207 I 0.0019 U NA
Perfluoroheptanesulfonic acid 0.0019 U 0.0019 U 0.0019 U 0.0019 U NA
Perfluorooctanesulfonic acid (PFOS) 0.0296 0.0188 0.0228 0.0029 U 0.07
Perfluorononanesulfonic acid 0.0019 U 0.0019 U 0.0019 U 0.0019 U NA
Perfluorodecanesulfonic acid 0.0019 U 0.0019 U 0.0019 U 0.0019 U NA
PFOSA 0.0019 U 0.0019 U 0.0019 U 0.0019 U NA
MeFOSAA 0.0077 U 0.0077 U a 0.0077 U 0.0077 U a NA
EtFOSAA 0.0077 U 0.0077 U 0.0077 U 0.0077 U NA
4:2 Fluorotelomer sulfonate 0.0038 U 0.0038 U 0.0038 U 0.0038 U NA
Notes:
All results are reported in ug/L.
USEPA HA - United States Environmental Protection Agency Health Advisory Level.
a - Associated CCV outside of control limits high, sample was ND.
U - Not detcted above the referenced method detection limit.
I - Result concentration is greater than or equal to the method detection limit but less than the practical quantitation limit.
NA - Not available.
Attachment A
Monitoring Well Construction
TETRA TECH
Attachment B
Monitoring Well Sampling Forms
TETRA TECH
Attachment C
Groundwater Analytical Results
TETRA TECH
07/31/18
Orlando, FL 07/31/18
The results set forth herein are provided by SGS North America Inc.
e-Hardcopy 2.0
Automated Report
Technical Report for
Tetra Tech
Satellite Beach PFC
100-1WM-T38598
SGS Job Number: FA55955
Sampling Date: 07/18/18
Report to:
Tetra Tech
11 Riverside Dr Suite 204
Cocoa, FL 32922
matt.shelton@tetratech.com
ATTN: Matt Shelton
Total number of pages in report: 26
Test results contained within this data package meet the requirements Caitlin Brice, M.S.
of the National Environmental Laboratory Accreditation Program General Manager
and/or state specific certification programs as applicable.
Client Service contact: Ariel Hartney 407-425-6700

Certifications: FL(E83510), LA(03051), KS(E-10327), IL(200063), NC(573), NJ(FL002), NY(12022), SC(96038001)
DoD ELAP(ANAB L2229), AZ(AZ0806), CA(2937), TX(T104704404), PA(68-03573), VA(460177),
AK, AR, IA, KY, MA, MS, ND, NH, NV, OK, OR, UT, WA, WV
This report shall not be reproduced, except in its entirety, without the written approval of SGS.
Test results relate only to samples analyzed.
SGS North America Inc. • 4405 Vineland Road • Suite C-15 • Orlando, FL 32811 • tel: 407-425-6700 • fax: 407-425-0707
SGS is the sole authority for authorizing edits or modifications to this document. Please share your ideas about 1 of 26
Unauthorized modification of this report is strictly prohibited. how we can serve you better at:
Review standard terms at: http://www.sgs.com/en/terms-and-conditions EHS.US.CustomerCare@sgs.com FA55955
Sections:
Table of Contents
1
-1-
2
Section 1: Sample Summary ................................................................................................... 3
Section 2: Case Narrative/Conformance Summary .............................................................. 4
3
Section 3: Summary of Hits .................................................................................................... 5
Section 4: Sample Results ........................................................................................................ 6
4
4.1: FA55955-1: SB1-20180718 .......................................................................................... 7
4.2: FA55955-2: SB2-20180718 .......................................................................................... 9
5
4.3: FA55955-3: FRB-20180718 ......................................................................................... 11
4.4: FA55955-4: SB3-20180718 .......................................................................................... 13
6
Section 5: Misc. Forms ............................................................................................................ 15
5.1: Chain of Custody ........................................................................................................... 16
Section 6: MS Semi-volatiles - QC Data Summaries ............................................................ 18
6.1: Method Blank Summary ................................................................................................ 19
6.2: Blank Spike Summary ................................................................................................... 21
6.3: Matrix Spike Summary .................................................................................................. 23
6.4: Duplicate Summary ....................................................................................................... 25
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FA55955
1
SGS North America Inc.
Sample Summary
Tetra Tech
Job No: FA55955
Satellite Beach PFC
Project No: 100-1WM-T38598
Sample Collected Matrix Client

Number Date Time By Received Code Type Sample ID
FA55955-1 07/18/18 10:05 EM 07/19/18 AQ Ground Water SB1-20180718
FA55955-3 07/18/18 13:20 EM 07/19/18 AQ Ground Water FRB-20180718
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FA55955
SAMPLE DELIVERY GROUP CASE NARRATIVE
2
Client: Tetra Tech Job No: FA55955
Site: Satellite Beach PFC Report Date: 7/31/2018 9:45:30

4 Sample(s) were collected on 07/18/2018 and were received at SGS North America Inc - Orlando on 07/19/2018 properly preserved, at 1.5
Deg. C and intact. These Samples received an SGS Orlando job number of FA55955. A listing of the Laboratory Sample ID, Client Sample
ID and dates of collection are presented in the Results Summary Section.
Except as noted below, all method specified calibrations and quality control performance criteria were met for this job. For
more information, please refer to QC summary pages.
MS Semi-volatiles By Method EPA 537M BY ID

Matrix: AQ Batch ID: OP70986
All samples were extracted within the recommended method holding time.
All samples were analyzed within the recommended method holding time.
All method blanks for this batch meet method specific criteria.
Sample(s) FA55955-3MS, FA55955-4DUP were used as the QC samples indicated.
Sample(s) OP70986-MS, OP70986-DUP have surrogates outside control limits.
OP70986-DUP for 13C8-PFOA: Outside control limits.
FA55955-2 for MeFOSAA: Associated CCV outside of control limits high, sample was ND.
FA55955-3 for MeFOSAA: Associated CCV outside of control limits high, sample was ND.
SGS Orlando certifies that this report meets the project requirements for analytical data produced for the samples as received at
SGS Orlando and as stated on the COC. SGS Orlando certifies that the data meets the Data Quality Objectives for precision, accuracy and
completeness as specified in the SGS Orlando Quality Manual except as noted above. This report is to be used in its entirety. SGS Orlando
is not responsible for any assumptions of data quality if partial data packages are used.
Narrative prepared by:
______________________________________
Kim Benham, Client Services (signature on file)
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FA55955
Summary of Hits Page 1 of 1
Job Number: FA55955
Account: Tetra Tech
Project: Satellite Beach PFC
Collected: 07/18/18
3
Lab Sample ID Client Sample ID Result/
Analyte Qual PQL MDL Units Method
FA55955-1 SB1-20180718
Perfluorobutanoic acid 0.0101 I 0.015 0.0038 ug/l EPA 537M BY ID

Perfluoropentanoic acid 0.00721 I 0.0077 0.0029 ug/l EPA 537M BY ID
Perfluorohexanoic acid 0.00614 I 0.0077 0.0019 ug/l EPA 537M BY ID
Perfluoroheptanoic acid 0.00402 I 0.0077 0.0019 ug/l EPA 537M BY ID
Perfluorooctanoic acid 0.0119 0.0077 0.0019 ug/l EPA 537M BY ID
Perfluorobutanesulfonic acid 0.0108 0.0077 0.0019 ug/l EPA 537M BY ID
Perfluoropentanesulfonic acid 0.00552 I 0.0077 0.0019 ug/l EPA 537M BY ID
Perfluorohexanesulfonic acid 0.0146 0.0077 0.0019 ug/l EPA 537M BY ID
Perfluorooctanesulfonic acid 0.0296 0.0077 0.0029 ug/l EPA 537M BY ID
FA55955-2 SB2-20180718
Perfluoropentanoic acid 0.00295 I 0.0077 0.0029 ug/l EPA 537M BY ID

Perfluorooctanoic acid 0.00405 I 0.0077 0.0019 ug/l EPA 537M BY ID
FA55955-3 FRB-20180718
No hits reported in this sample.
FA55955-4 SB3-20180718
Perfluorobutanoic acid 0.00631 I 0.015 0.0038 ug/l EPA 537M BY ID

Perfluoropentanoic acid 0.0129 0.0077 0.0029 ug/l EPA 537M BY ID
Perfluorohexanoic acid 0.00625 I 0.0077 0.0019 ug/l EPA 537M BY ID
Perfluoroheptanoic acid 0.00288 I 0.0077 0.0019 ug/l EPA 537M BY ID
Perfluorooctanoic acid 0.00733 I 0.0077 0.0019 ug/l EPA 537M BY ID
Perfluorobutanesulfonic acid 0.00615 I 0.0077 0.0019 ug/l EPA 537M BY ID
Perfluorohexanesulfonic acid 0.00207 I 0.0077 0.0019 ug/l EPA 537M BY ID
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FA55955
Orlando, FL
Section 4
4
Sample Results
Report of Analysis
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FA55955
Report of Analysis Page 1 of 2
Client Sample ID: SB1-20180718
4.1
Lab Sample ID: FA55955-1 Date Sampled: 07/18/18
Matrix: AQ - Ground Water Date Received: 07/19/18
Method: EPA 537M BY ID EPA 537 MOD Percent Solids: n/a
4
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch

Run #1 2Q17576.D 1 07/24/18 16:32 NG 07/20/18 09:30 OP70986 S2Q300
Run #2
Initial Volume Final Volume

Run #1 130 ml 1.0 ml
Run #2
PFAS List
CAS No. Compound Result PQL MDL Units Q
PERFLUOROALKYLCARBOXYLIC ACIDS
375-22-4 Perfluorobutanoic acid 0.0101 0.015 0.0038 ug/l I
2706-90-3 Perfluoropentanoic acid 0.00721 0.0077 0.0029 ug/l I
307-24-4 Perfluorohexanoic acid 0.00614 0.0077 0.0019 ug/l I
375-85-9 Perfluoroheptanoic acid 0.00402 0.0077 0.0019 ug/l I
335-67-1 Perfluorooctanoic acid 0.0119 0.0077 0.0019 ug/l
375-95-1 Perfluorononanoic acid 0.0019 U 0.0077 0.0019 ug/l
335-76-2 Perfluorodecanoic acid 0.0019 U 0.0077 0.0019 ug/l
2058-94-8 Perfluoroundecanoic acid 0.0019 U 0.0077 0.0019 ug/l
307-55-1 Perfluorododecanoic acid 0.0029 U 0.0077 0.0029 ug/l
72629-94-8 Perfluorotridecanoic acid 0.0019 U 0.0077 0.0019 ug/l
376-06-7 Perfluorotetradecanoic acid 0.0019 U 0.0077 0.0019 ug/l
PERFLUOROALKYLSULFONATES
375-73-5 Perfluorobutanesulfonic acid 0.0108 0.0077 0.0019 ug/l
2706-91-4 Perfluoropentanesulfonic acid 0.00552 0.0077 0.0019 ug/l I
355-46-4 Perfluorohexanesulfonic acid 0.0146 0.0077 0.0019 ug/l
375-92-8 Perfluoroheptanesulfonic acid 0.0019 U 0.0077 0.0019 ug/l
1763-23-1 Perfluorooctanesulfonic acid 0.0296 0.0077 0.0029 ug/l
68259-12-1 Perfluorononanesulfonic acid 0.0019 U 0.0077 0.0019 ug/l
335-77-3 Perfluorodecanesulfonic acid 0.0019 U 0.0077 0.0019 ug/l
PERFLUOROOCTANESULFONAMIDES
754-91-6 PFOSA 0.0019 U 0.0077 0.0019 ug/l
PERFLUOROOCTANESULFONAMIDOACETIC ACIDS
2355-31-9 MeFOSAA 0.0077 U 0.038 0.0077 ug/l
2991-50-6 EtFOSAA 0.0077 U 0.038 0.0077 ug/l
FLUOROTELOMER SULFONATES
757124-72-4 4:2 Fluorotelomer sulfonate 0.0038 U 0.015 0.0038 ug/l
U = Not detected MDL = Method Detection Limit I = Result >= MDL but < PQL J = Estimated value
PQL = Practical Quantitation Limit V = Indicates analyte found in associated method blank
L = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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4.1
4
PFAS List
CAS No. ID Standard Recoveries Run# 1 Run# 2 Limits
13C4-PFBA 105% 30-140%

13C5-PFPeA 105% 40-140%
13C5-PFHxA 111% 50-150%
13C4-PFHpA 121% 50-150%
13C8-PFOA 130% 50-150%
13C9-PFNA 136% 50-150%
13C6-PFDA 138% 50-150%
13C7-PFUnDA 79% 50-150%
13C2-PFDoDA 72% 50-150%
13C2-PFTeDA 42% 40-150%
13C3-PFBS 98% 50-150%
13C3-PFHxS 99% 50-150%
13C8-PFOS 109% 50-150%
13C8-FOSA 102% 30-140%
d3-MeFOSAA 78% 50-150%
13C2-4:2FTS 105% 50-150%
13C2-6:2FTS 115% 50-150%
13C2-8:2FTS 112% 50-150%
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4.2
4

Run #1 2Q17748.D 1 07/28/18 01:23 NG 07/20/18 09:30 OP70986 S2Q302
Run #2

Run #1 130 ml 1.0 ml
Run #2
PFAS List
375-22-4 Perfluorobutanoic acid 0.0038 U 0.015 0.0038 ug/l
2706-90-3 Perfluoropentanoic acid 0.00295 0.0077 0.0029 ug/l I
307-24-4 Perfluorohexanoic acid 0.0019 U 0.0077 0.0019 ug/l
375-85-9 Perfluoroheptanoic acid 0.0019 U 0.0077 0.0019 ug/l
335-67-1 Perfluorooctanoic acid 0.00405 0.0077 0.0019 ug/l I
375-73-5 Perfluorobutanesulfonic acid 0.0019 U 0.0077 0.0019 ug/l
2706-91-4 Perfluoropentanesulfonic acid 0.0019 U 0.0077 0.0019 ug/l
355-46-4 Perfluorohexanesulfonic acid 0.0019 U 0.0077 0.0019 ug/l
754-91-6 PFOSA 0.0019 U 0.0077 0.0019 ug/l
2355-31-9 MeFOSAA a 0.0077 U 0.038 0.0077 ug/l
2991-50-6 EtFOSAA 0.0077 U 0.038 0.0077 ug/l
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4.2
4
PFAS List
13C4-PFBA 105% 30-140%

13C5-PFPeA 105% 40-140%
13C5-PFHxA 104% 50-150%
13C4-PFHpA 116% 50-150%
13C8-PFOA 116% 50-150%
13C9-PFNA 112% 50-150%
13C6-PFDA 119% 50-150%
13C7-PFUnDA 104% 50-150%
13C2-PFDoDA 124% 50-150%
13C2-PFTeDA 92% 40-150%
13C3-PFBS 108% 50-150%
13C3-PFHxS 97% 50-150%
13C8-PFOS 102% 50-150%
13C8-FOSA 136% 30-140%
d3-MeFOSAA 104% 50-150%
13C2-4:2FTS 70% 50-150%
13C2-6:2FTS 115% 50-150%
13C2-8:2FTS 99% 50-150%
(a) Associated CCV outside of control limits high, sample was ND.
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FA55955
Client Sample ID: FRB-20180718
4.3
4

Run #1 2Q17749.D 1 07/28/18 01:39 NG 07/20/18 09:30 OP70986 S2Q302
Run #2

Run #1 130 ml 1.0 ml
Run #2
PFAS List
375-22-4 Perfluorobutanoic acid 0.0038 U 0.015 0.0038 ug/l
2706-90-3 Perfluoropentanoic acid 0.0029 U 0.0077 0.0029 ug/l
307-24-4 Perfluorohexanoic acid 0.0019 U 0.0077 0.0019 ug/l
375-85-9 Perfluoroheptanoic acid 0.0019 U 0.0077 0.0019 ug/l
335-67-1 Perfluorooctanoic acid 0.0019 U 0.0077 0.0019 ug/l
375-73-5 Perfluorobutanesulfonic acid 0.0019 U 0.0077 0.0019 ug/l
355-46-4 Perfluorohexanesulfonic acid 0.0019 U 0.0077 0.0019 ug/l
1763-23-1 Perfluorooctanesulfonic acid 0.0029 U 0.0077 0.0029 ug/l
754-91-6 PFOSA 0.0019 U 0.0077 0.0019 ug/l
2355-31-9 MeFOSAA a 0.0077 U 0.038 0.0077 ug/l
2991-50-6 EtFOSAA 0.0077 U 0.038 0.0077 ug/l
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Client Sample ID: FRB-20180718
4.3
4
PFAS List
13C4-PFBA 117% 30-140%

13C5-PFPeA 116% 40-140%
13C5-PFHxA 122% 50-150%
13C4-PFHpA 131% 50-150%
13C8-PFOA 126% 50-150%
13C9-PFNA 134% 50-150%
13C6-PFDA 129% 50-150%
13C7-PFUnDA 108% 50-150%
13C2-PFDoDA 125% 50-150%
13C2-PFTeDA 106% 40-150%
13C3-PFBS 121% 50-150%
13C3-PFHxS 107% 50-150%
13C8-PFOS 109% 50-150%
13C8-FOSA 131% 30-140%
d3-MeFOSAA 112% 50-150%
13C2-4:2FTS 122% 50-150%
13C2-6:2FTS 121% 50-150%
13C2-8:2FTS 100% 50-150%
(a) Associated CCV outside of control limits high, sample was ND.
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FA55955
4.4
4

Run #1 2Q17580.D 1 07/24/18 18:03 NG 07/20/18 09:30 OP70986 S2Q300
Run #2

Run #1 130 ml 1.0 ml
Run #2
PFAS List
375-22-4 Perfluorobutanoic acid 0.00631 0.015 0.0038 ug/l I
2706-90-3 Perfluoropentanoic acid 0.0129 0.0077 0.0029 ug/l
307-24-4 Perfluorohexanoic acid 0.00625 0.0077 0.0019 ug/l I
375-85-9 Perfluoroheptanoic acid 0.00288 0.0077 0.0019 ug/l I
335-67-1 Perfluorooctanoic acid 0.00733 0.0077 0.0019 ug/l I
375-73-5 Perfluorobutanesulfonic acid 0.00615 0.0077 0.0019 ug/l I
355-46-4 Perfluorohexanesulfonic acid 0.00207 0.0077 0.0019 ug/l I
754-91-6 PFOSA 0.0019 U 0.0077 0.0019 ug/l
2355-31-9 MeFOSAA 0.0077 U 0.038 0.0077 ug/l
2991-50-6 EtFOSAA 0.0077 U 0.038 0.0077 ug/l
13 of 26
FA55955
4.4
4
PFAS List
13C4-PFBA 100% 30-140%

13C5-PFPeA 99% 40-140%
13C5-PFHxA 107% 50-150%
13C4-PFHpA 117% 50-150%
13C8-PFOA 141% 50-150%
13C9-PFNA 136% 50-150%
13C6-PFDA 132% 50-150%
13C7-PFUnDA 79% 50-150%
13C2-PFDoDA 73% 50-150%
13C2-PFTeDA 50% 40-150%
13C3-PFBS 99% 50-150%
13C3-PFHxS 99% 50-150%
13C8-PFOS 105% 50-150%
13C8-FOSA 112% 30-140%
d3-MeFOSAA 77% 50-150%
13C2-4:2FTS 100% 50-150%
13C2-6:2FTS 119% 50-150%
13C2-8:2FTS 106% 50-150%
14 of 26
FA55955
Orlando, FL
Section 5
Misc. Forms
5
Custody Documents and Other Forms
Includes the following where applicable:

• Chain of Custody
15 of 26
FA55955
55.1
FA55955: Chain of Custody
Page 1 of 2
16 of 26
FA55955
SGS Sample Receipt Summary
Job Number: FA55955 Client: TERATECH Project: SATELLITE BEACH PFC
Date / Time Received: 7/19/2018 3:05:00 PM Delivery Method: ALSE Airbill #'s:
Therm ID: IR 1; Therm CF: 0.1; # of Coolers: 1
Cooler Temps (Raw Measured) °C: Cooler 1: (1.4);
Cooler Temps (Corrected) °C: Cooler 1: (1.5);
Cooler Information Y or N Sample Information Y or N N/A

1. Custody Seals Present 1. Sample labels present on bottles
5.1
2. Custody Seals Intact 2. Samples preserved properly
3. Temp criteria achieved 3. Sufficient volume/containers recvd for analysis:
4. Cooler temp verification IR Gun 4. Condition of sample Intact
5
5. Cooler media Ice (Bag) 5. Sample recvd within HT
6. Dates/Times/IDs on COC match Sample Label
Trip Blank Information Y or N N/A 7. VOCs have headspace
1. Trip Blank present / cooler 8. Bottles received for unspecified tests
2. Trip Blank listed on COC 9. Compositing instructions clear
10. Voa Soil Kits/Jars received past 48hrs?
W or S N/A
11. % Solids Jar received?
3. Type Of TB Received
12. Residual Chlorine Present?
Misc. Information
Number of Encores: 25-Gram 5-Gram Number of 5035 Field Kits: Number of Lab Filtered Metals:
Test Strip Lot #s: pH 0-3 230315 pH 10-12 219813A Other: (Specify)
Residual Chlorine Test Strip Lot #:
Comments
SM001
Rev. Date 05/24/17 Technician: PETERH Date: 7/19/2018 3:05:00 PM Reviewer: Date:
FA55955: Chain of Custody

Page 2 of 2
17 of 26
FA55955
Orlando, FL
Section 6
MS Semi-volatiles
6
QC Data Summaries
Includes the following where applicable:

• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
18 of 26
FA55955
Method Blank Summary Page 1 of 2
Job Number: FA55955
Account: TETRFLC Tetra Tech
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch

OP70986-MB 2Q17575.D 1 07/24/18 NG 07/20/18 OP70986 S2Q300
6.1.1
The QC reported here applies to the following samples: Method: EPA 537M BY ID
6
FA55955-1, FA55955-2, FA55955-3, FA55955-4
CAS No. Compound Result RL MDL Units Q
375-22-4 Perfluorobutanoic acid ND 0.015 0.0038 ug/l

2706-90-3 Perfluoropentanoic acid ND 0.0077 0.0029 ug/l
307-24-4 Perfluorohexanoic acid ND 0.0077 0.0019 ug/l
375-85-9 Perfluoroheptanoic acid ND 0.0077 0.0019 ug/l
335-67-1 Perfluorooctanoic acid ND 0.0077 0.0019 ug/l
375-95-1 Perfluorononanoic acid ND 0.0077 0.0019 ug/l
335-76-2 Perfluorodecanoic acid ND 0.0077 0.0019 ug/l
2058-94-8 Perfluoroundecanoic acid ND 0.0077 0.0019 ug/l
307-55-1 Perfluorododecanoic acid ND 0.0077 0.0029 ug/l
72629-94-8 Perfluorotridecanoic acid ND 0.0077 0.0019 ug/l
376-06-7 Perfluorotetradecanoic acid ND 0.0077 0.0019 ug/l
375-73-5 Perfluorobutanesulfonic acid ND 0.0077 0.0019 ug/l
2706-91-4 Perfluoropentanesulfonic acid ND 0.0077 0.0019 ug/l
355-46-4 Perfluorohexanesulfonic acid ND 0.0077 0.0019 ug/l
375-92-8 Perfluoroheptanesulfonic acid ND 0.0077 0.0019 ug/l
1763-23-1 Perfluorooctanesulfonic acid ND 0.0077 0.0029 ug/l
68259-12-1 Perfluorononanesulfonic acid ND 0.0077 0.0019 ug/l
335-77-3 Perfluorodecanesulfonic acid ND 0.0077 0.0019 ug/l
754-91-6 PFOSA ND 0.0077 0.0019 ug/l
2355-31-9 MeFOSAA ND 0.038 0.0077 ug/l
2991-50-6 EtFOSAA ND 0.038 0.0077 ug/l
757124-72-44:2 Fluorotelomer sulfonate ND 0.015 0.0038 ug/l
27619-97-2 6:2 Fluorotelomer sulfonate ND 0.015 0.0038 ug/l
39108-34-4 8:2 Fluorotelomer sulfonate ND 0.015 0.0038 ug/l
CAS No. ID Standard Recoveries Limits
13C4-PFBA 109% 30-140%

13C5-PFPeA 108% 40-140%
13C5-PFHxA 108% 50-150%
13C4-PFHpA 114% 50-150%
13C8-PFOA 137% 50-150%
13C9-PFNA 131% 50-150%
13C6-PFDA 106% 50-150%
13C7-PFUnDA 93% 50-150%
19 of 26
FA55955
Method Blank Summary Page 2 of 2
Job Number: FA55955

OP70986-MB 2Q17575.D 1 07/24/18 NG 07/20/18 OP70986 S2Q300
6.1.1
6
FA55955-1, FA55955-2, FA55955-3, FA55955-4
CAS No. ID Standard Recoveries Limits
13C2-PFDoDA 88% 50-150%

13C2-PFTeDA 93% 40-150%
13C3-PFBS 104% 50-150%
13C3-PFHxS 114% 50-150%
13C8-PFOS 112% 50-150%
13C8-FOSA 116% 30-140%
d3-MeFOSAA 88% 50-150%
13C2-4:2FTS 102% 50-150%
13C2-6:2FTS 117% 50-150%
13C2-8:2FTS 98% 50-150%
20 of 26
FA55955
Blank Spike Summary Page 1 of 2
Job Number: FA55955

OP70986-BS 2Q17574.D 1 07/24/18 NG 07/20/18 OP70986 S2Q300
6.2.1
6
FA55955-1, FA55955-2, FA55955-3, FA55955-4
Spike BSP BSP

CAS No. Compound ug/l ug/l % Limits
375-22-4 Perfluorobutanoic acid 0.154 0.162 105 70-130

2706-90-3 Perfluoropentanoic acid 0.154 0.156 101 70-130
307-24-4 Perfluorohexanoic acid 0.154 0.142 92 70-130
375-85-9 Perfluoroheptanoic acid 0.154 0.155 101 71-130
335-67-1 Perfluorooctanoic acid 0.154 0.146 95 74-130
375-95-1 Perfluorononanoic acid 0.154 0.151 98 76-130
335-76-2 Perfluorodecanoic acid 0.154 0.149 97 70-130
2058-94-8 Perfluoroundecanoic acid 0.154 0.160 104 70-130
307-55-1 Perfluorododecanoic acid 0.154 0.176 114 70-130
72629-94-8 Perfluorotridecanoic acid 0.154 0.172 112 70-139
376-06-7 Perfluorotetradecanoic acid 0.154 0.156 101 70-130
375-73-5 Perfluorobutanesulfonic acid 0.136 0.134 98 73-130
2706-91-4 Perfluoropentanesulfonic acid 0.145 0.149 103 70-130
355-46-4 Perfluorohexanesulfonic acid 0.14 0.133 95 74-130
375-92-8 Perfluoroheptanesulfonic acid 0.146 0.158 108 74-130
1763-23-1 Perfluorooctanesulfonic acid 0.142 0.158 111 70-130
68259-12-1 Perfluorononanesulfonic acid 0.148 0.144 97 70-130
335-77-3 Perfluorodecanesulfonic acid 0.148 0.164 110 70-130
754-91-6 PFOSA 0.154 0.159 103 70-131
2355-31-9 MeFOSAA 0.154 0.163 106 70-130
2991-50-6 EtFOSAA 0.154 0.154 100 70-130
757124-72-44:2 Fluorotelomer sulfonate 0.144 0.172 120 70-130
27619-97-2 6:2 Fluorotelomer sulfonate 0.146 0.172 118 70-133
39108-34-4 8:2 Fluorotelomer sulfonate 0.148 0.149 101 70-130
CAS No. ID Standard Recoveries BSP Limits
13C4-PFBA 108% 30-140%

13C5-PFPeA 109% 40-140%
13C5-PFHxA 108% 50-150%
13C4-PFHpA 111% 50-150%
13C8-PFOA 138% 50-150%
13C9-PFNA 133% 50-150%
13C6-PFDA 109% 50-150%
13C7-PFUnDA 98% 50-150%
* = Outside of Control Limits.
21 of 26
FA55955
Blank Spike Summary Page 2 of 2
Job Number: FA55955

OP70986-BS 2Q17574.D 1 07/24/18 NG 07/20/18 OP70986 S2Q300
6.2.1
6
FA55955-1, FA55955-2, FA55955-3, FA55955-4
CAS No. ID Standard Recoveries BSP Limits
13C2-PFDoDA 94% 50-150%

13C2-PFTeDA 101% 40-150%
13C3-PFBS 104% 50-150%
13C3-PFHxS 114% 50-150%
13C8-PFOS 116% 50-150%
13C8-FOSA 124% 30-140%
d3-MeFOSAA 90% 50-150%
13C2-4:2FTS 104% 50-150%
13C2-6:2FTS 123% 50-150%
13C2-8:2FTS 105% 50-150%
22 of 26
FA55955
Matrix Spike Summary Page 1 of 2
Job Number: FA55955

OP70986-MS 2Q17579.D 1 07/24/18 NG 07/20/18 OP70986 S2Q300
FA55955-3 2Q17749.D 1 07/28/18 NG 07/20/18 OP70986 S2Q302
6.3.1
6
FA55955-1, FA55955-2, FA55955-3, FA55955-4
FA55955-3 Spike MS MS
CAS No. Compound ug/l Q ug/l ug/l % Limits
375-22-4 Perfluorobutanoic acid 0.015 U 0.154 0.150 97 70-130

2706-90-3 Perfluoropentanoic acid 0.0077 U 0.154 0.146 95 70-130
307-24-4 Perfluorohexanoic acid 0.0077 U 0.154 0.129 84 70-130
375-85-9 Perfluoroheptanoic acid 0.0077 U 0.154 0.146 95 71-130
335-67-1 Perfluorooctanoic acid 0.0077 U 0.154 0.147 96 74-130
375-95-1 Perfluorononanoic acid 0.0077 U 0.154 0.146 95 76-130
335-76-2 Perfluorodecanoic acid 0.0077 U 0.154 0.136 88 70-130
2058-94-8 Perfluoroundecanoic acid 0.0077 U 0.154 0.149 97 70-130
307-55-1 Perfluorododecanoic acid 0.0077 U 0.154 0.160 104 70-130
72629-94-8 Perfluorotridecanoic acid 0.0077 U 0.154 0.160 104 70-139
376-06-7 Perfluorotetradecanoic acid 0.0077 U 0.154 0.145 94 70-130
375-73-5 Perfluorobutanesulfonic acid 0.0077 U 0.136 0.124 91 73-130
2706-91-4 Perfluoropentanesulfonic acid 0.0077 U 0.145 0.137 95 70-130
355-46-4 Perfluorohexanesulfonic acid 0.0077 U 0.14 0.125 89 74-130
375-92-8 Perfluoroheptanesulfonic acid 0.0077 U 0.146 0.145 99 74-130
1763-23-1 Perfluorooctanesulfonic acid 0.0077 U 0.142 0.151 106 70-130
68259-12-1 Perfluorononanesulfonic acid 0.0077 U 0.148 0.129 87 70-130
335-77-3 Perfluorodecanesulfonic acid 0.0077 U 0.148 0.160 108 70-130
754-91-6 PFOSA 0.0077 U 0.154 0.151 98 70-131
2355-31-9 MeFOSAA 0.038 U 0.154 0.155 101 70-130
2991-50-6 EtFOSAA 0.038 U 0.154 0.146 95 70-130
757124-72-44:2 Fluorotelomer sulfonate 0.015 U 0.144 0.155 108 70-130
27619-97-2 6:2 Fluorotelomer sulfonate 0.015 U 0.146 0.163 112 70-133
39108-34-4 8:2 Fluorotelomer sulfonate 0.015 U 0.148 0.140 95 70-130
CAS No. ID Standard Recoveries MS FA55955-3 Limits
13C4-PFBA 130% 117% 30-140%

13C5-PFPeA 126% 116% 40-140%
13C5-PFHxA 130% 122% 50-150%
13C4-PFHpA 132% 131% 50-150%
13C8-PFOA 162%* 126% 50-150%
13C9-PFNA 156%* 134% 50-150%
13C6-PFDA 120% 129% 50-150%
13C7-PFUnDA 107% 108% 50-150%
23 of 26
FA55955
Matrix Spike Summary Page 2 of 2
Job Number: FA55955

OP70986-MS 2Q17579.D 1 07/24/18 NG 07/20/18 OP70986 S2Q300
FA55955-3 2Q17749.D 1 07/28/18 NG 07/20/18 OP70986 S2Q302
6.3.1
6
FA55955-1, FA55955-2, FA55955-3, FA55955-4
CAS No. ID Standard Recoveries MS FA55955-3 Limits
13C2-PFDoDA 107% 125% 50-150%

13C2-PFTeDA 116% 106% 40-150%
13C3-PFBS 129% 121% 50-150%
13C3-PFHxS 143% 107% 50-150%
13C8-PFOS 132% 109% 50-150%
13C8-FOSA 131% 131% 30-140%
d3-MeFOSAA 100% 112% 50-150%
13C2-4:2FTS 133% 122% 50-150%
13C2-6:2FTS 152%* 121% 50-150%
13C2-8:2FTS 113% 100% 50-150%
24 of 26
FA55955
Duplicate Summary Page 1 of 2
Job Number: FA55955

OP70986-DUP 2Q17581.D 1 07/24/18 NG 07/20/18 OP70986 S2Q300
FA55955-4 2Q17580.D 1 07/24/18 NG 07/20/18 OP70986 S2Q300
6.4.1
6
FA55955-1, FA55955-2, FA55955-3, FA55955-4
FA55955-4 DUP
CAS No. Compound ug/l Q ug/l Q RPD Limits
375-22-4 Perfluorobutanoic acid 0.00631 I 0.00628 J 0 30

2706-90-3 Perfluoropentanoic acid 0.0129 0.0125 3 30
307-24-4 Perfluorohexanoic acid 0.00625 I 0.00638 J 2 30
375-85-9 Perfluoroheptanoic acid 0.00288 I 0.00295 J 2 30
335-67-1 Perfluorooctanoic acid 0.00733 I 0.00773 5 30
375-95-1 Perfluorononanoic acid 0.0077 U ND nc 30
335-76-2 Perfluorodecanoic acid 0.0077 U ND nc 30
2058-94-8 Perfluoroundecanoic acid 0.0077 U ND nc 30
307-55-1 Perfluorododecanoic acid 0.0077 U ND nc 30
72629-94-8 Perfluorotridecanoic acid 0.0077 U ND nc 30
376-06-7 Perfluorotetradecanoic acid 0.0077 U ND nc 30
375-73-5 Perfluorobutanesulfonic acid 0.00615 I 0.00606 J 1 30
2706-91-4 Perfluoropentanesulfonic acid 0.0077 U ND nc 30
355-46-4 Perfluorohexanesulfonic acid 0.00207 I 0.00224 J 8 30
375-92-8 Perfluoroheptanesulfonic acid 0.0077 U ND nc 30
1763-23-1 Perfluorooctanesulfonic acid 0.0228 0.0228 0 30
68259-12-1 Perfluorononanesulfonic acid 0.0077 U ND nc 30
335-77-3 Perfluorodecanesulfonic acid 0.0077 U ND nc 30
754-91-6 PFOSA 0.0077 U ND nc 30
2355-31-9 MeFOSAA 0.038 U ND nc 30
2991-50-6 EtFOSAA 0.038 U ND nc 30
757124-72-44:2 Fluorotelomer sulfonate 0.015 U ND nc 30
27619-97-2 6:2 Fluorotelomer sulfonate 0.015 U ND nc 30
39108-34-4 8:2 Fluorotelomer sulfonate 0.015 U ND nc 30
CAS No. ID Standard Recoveries DUP FA55955-4 Limits
13C4-PFBA 110% 100% 30-140%

13C5-PFPeA 109% 99% 40-140%
13C5-PFHxA 113% 107% 50-150%
13C4-PFHpA 129% 117% 50-150%
13C8-PFOA 152%* a 141% 50-150%
13C9-PFNA 147% 136% 50-150%
13C6-PFDA 138% 132% 50-150%
13C7-PFUnDA 82% 79% 50-150%
25 of 26
FA55955
Duplicate Summary Page 2 of 2
Job Number: FA55955

OP70986-DUP 2Q17581.D 1 07/24/18 NG 07/20/18 OP70986 S2Q300
FA55955-4 2Q17580.D 1 07/24/18 NG 07/20/18 OP70986 S2Q300
6.4.1
6
FA55955-1, FA55955-2, FA55955-3, FA55955-4
CAS No. ID Standard Recoveries DUP FA55955-4 Limits
13C2-PFDoDA 74% 73% 50-150%

13C2-PFTeDA 42% 50% 40-150%
13C3-PFBS 103% 99% 50-150%
13C3-PFHxS 103% 99% 50-150%
13C8-PFOS 107% 105% 50-150%
13C8-FOSA 107% 112% 30-140%
d3-MeFOSAA 76% 77% 50-150%
13C2-4:2FTS 106% 100% 50-150%
13C2-6:2FTS 126% 119% 50-150%
13C2-8:2FTS 108% 106% 50-150%
(a) Outside control limits.
26 of 26
FA55955

Satellite Beach PFOS-PFOA Sampling Report

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Satellite Beach PFOS-PFOA Sampling Report

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August 2, 2018

Mr. Nicholas Frank Sanzone

Dear Mr. Sanzone:

Tetra Tech, Inc.

FIELD INVESTIGATION ACTIVITIES

• Satellite Beach City Hall (SB1)

The field investigation activities conducted are described below.

Well Drilling Activities

Groundwater Sampling and Analysis

Copies of the groundwater sampling sheets are provided in Attachment B.

GROUNDWATER ANALYTICAL RESULTS

• SB1: Perfluorobutanoic acid, perfluoropentanoic acid, perfluorohexanoic acid,

• SB2: Perfluoropentanoic acid at a concentration of 0.00295 I.

• SB3: Perfluorobutanoic acid, perfluoropentanoic acid, perfluorohexanoic acid,

No PFAS analytes were detected in the Field Reagent Blank.

SB1-20180718 SB2-20180718 SB3-20180718 FRB-20180718 USEPA

Monitoring Well Construction

Monitoring Well Sampling Forms

Groundwater Analytical Results

Technical Report for

Sampling Date: 07/18/18

Total number of pages in report: 26

Client Service contact: Ariel Hartney 407-425-6700

Sample Collected Matrix Client

FA55955-1 07/18/18 10:05 EM 07/19/18 AQ Ground Water SB1-20180718

FA55955-2 07/18/18 12:30 EM 07/19/18 AQ Ground Water SB2-20180718

FA55955-3 07/18/18 13:20 EM 07/19/18 AQ Ground Water FRB-20180718

FA55955-4 07/18/18 14:00 EM 07/19/18 AQ Ground Water SB3-20180718

Site: Satellite Beach PFC Report Date: 7/31/2018 9:45:30

MS Semi-volatiles By Method EPA 537M BY ID

Narrative prepared by:

Perfluorobutanoic acid 0.0101 I 0.015 0.0038 ug/l EPA 537M BY ID

Perfluoropentanoic acid 0.00295 I 0.0077 0.0029 ug/l EPA 537M BY ID

No hits reported in this sample.

Perfluorobutanoic acid 0.00631 I 0.015 0.0038 ug/l EPA 537M BY ID

Report of Analysis Page 1 of 2

Client Sample ID: SB1-20180718

File ID DF Analyzed By Prep Date Prep Batch Analytical Batch

Initial Volume Final Volume

CAS No. Compound Result PQL MDL Units Q

Report of Analysis Page 2 of 2

Client Sample ID: SB1-20180718

CAS No. Compound Result PQL MDL Units Q

39108-34-4 8:2 Fluorotelomer sulfonate 0.0038 U 0.015 0.0038 ug/l

CAS No. ID Standard Recoveries Run# 1 Run# 2 Limits

13C4-PFBA 105% 30-140%

Report of Analysis Page 1 of 2

Client Sample ID: SB2-20180718

File ID DF Analyzed By Prep Date Prep Batch Analytical Batch

Initial Volume Final Volume

CAS No. Compound Result PQL MDL Units Q

Report of Analysis Page 2 of 2

Client Sample ID: SB2-20180718

CAS No. Compound Result PQL MDL Units Q

39108-34-4 8:2 Fluorotelomer sulfonate 0.0038 U 0.015 0.0038 ug/l

CAS No. ID Standard Recoveries Run# 1 Run# 2 Limits

13C4-PFBA 105% 30-140%

Report of Analysis Page 1 of 2

Client Sample ID: FRB-20180718

File ID DF Analyzed By Prep Date Prep Batch Analytical Batch

Initial Volume Final Volume

CAS No. Compound Result PQL MDL Units Q

Report of Analysis Page 2 of 2

Client Sample ID: FRB-20180718