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ANSWER KEY
DPP No. # 35 (JEE-MAIN)
1. (C) 2. (B) 3. (A) 4. (D) 5. (B 6. (C) 7. (D)
8. (B) 9. (C) 10. (D) 11. (A) 12. (D) 13. (D) 14. (A)
15. (A) 16. (D) 17. (B) 18. (D) 19. (D) 20. (A)
2. The two forms of D-Glucopyranose obtained from solution of D-Glucose are known as
(A) Epimers (B*) Anomers (C) Enantiomers (D) Geometrical Isomers
D-Xywdksl ds foy;u ls izkIr D-Xywdkslik;jsukst ds nks :i dgykrs gSa %
(A) ,ihej (B*) ,uksej (C) izfrfcEc:ih (D) T;kfefr; leko;oh
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Sol. -D-Glucopyranose and -D-Glucopyranose are anomers.
gy . -D-Xywdksik;jsuksl vkSj -D-Xywdksik;jsuksl ,uksej gSaA
Sol.(A)
5. In which of the following pairs, both the compounds give positive test with Tollen’s reagent?
(A) Glucose and sucrose (B*) Glucose and fructose
(C) Fructose and sucrose (D) Acetophenone and hexanal
fuEu esa ls dkSu ls ;qXeksa esa] nksuksa ;kSfxd VkWysu vfHkdeZd ds lkFk /kukRed ijh{k.k nsrs gSaA
(A) Xyqdkst rFkk lqØksl (B*) Xyqdksl rFkk QDVªksl
(C) ÝDVksl rFkk lqØksl (D) ,slhVksQhuksu rFkk gSDlsusy
Sol. Aldehydes and -hydroxy ketones give positive Tollen's test. Glucose has an aldehyde group and fructose is
an -hydroxy ketones.
Sol. ,fYMgkbM vkSj -gkbMªkWDlh dhVksu èkukRed VkWysu ijh{k.k nsrs gSaA Xywdksl ,fYMgkbM lewg j[krk gS tcfd ÝDVksl
-gkbMªkWDlh dhVksu gSA
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6. Which of the following is a reducing sugar fuEu eas ls dkSu vipf;r 'kdZjk gS \
(A) (B)
(C*) (D)
Sol.
It has a cyclic hemiacetal structure in one ring which opens in aqueous solution to aldehydic acyclic form
and reduces Tollen's reagent and Fehling solution.
;g ,d oy; ;qDr pfØ; gseh,slhVsy lajpuk j[krh gSA tks tyh; foy;u esa [kqydj ,fYMgkbfMªd ,lkbfyd :i cukrh
gS rFkk VkWysu vfHkdeZd o Qsgfyax foy;u dks vipf;r djrh gSA
H SO
2
4
+
KCN
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8. The open chain structure of the following compound is
Sol.(B)
10. Which of the following is not a tautomer of Fructose fuEu esa ls dkSu ÝDVkst dk pyko;oh ugha gSA
CH2OH
|
CO
| (Fructose) (ÝDVksl)
(CHOH)3
|
CH2OH
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CH2OH
CH OH |
|| C OH
C OH ||
(A) | (B) C OH (C) (D*)
(CHOH)3 |
| (CHOH)2
CH2OH |
CH2OH
Sol. Its molecular formula is C6H10O5. Fructose has molecular formula C6H12O6. So it is not tautomer of Fructose.
bldk v.kqlw=k C6H10O5 gSA ÝsDVªkWl dk v.kqlw=k C6H12O6 gS blfy, ;g ÝsDVªkWl dk pyko;oh ugha gSA
2H 2H
Sol.
Na – Hg / H2O Na – Hg / H2O
12. Which of the following will form same product (osazone) on reaction with PhNHNH 2 (excess).
fuEu esa ls dkSuls PhNHNH2 ¼vkf/kD;½ ds lkFk fØ;k djds leku mRikn ¼vkslktksu½ cuk;sxsaA
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13. When D-Glucose is placed in basic aqueous solution an equilibrium mixture of three compounds is obtained.
Which of the following will not be present in equilibrium mixture.
{kkjh; tyh; foy;u esa tc D-Xywdksl dks j[kk tkrk gS rks rhu ;kSfxdks dk lkE; feJ.k izkIr gksrk gSA fuEu esa ls dkSulk
mRikn lkE; feJ.k esa mifLFkr ugha gksxkA
Sol.(D)
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14. How many moles of acetic anhydride (Ac2O) is needed to react completely with tataric acid, ribose and
glucose respectively.
VkVZfjd vEy] jkbckst vkSj Xywdkst ds lkFk vfHkfØ;k djus ds fy, ,slhfVd ,ugkbMªkbM ds Øe'k% fdrus eks y dh
vko';drk gksrh gSA
(A*) Glucose monomer and - glycosidic linkage (B) Fructose monomer and - glycosidic linkage
(C) Glucose monomer and - glycosidic linkage (D) Fructose monomer and - glycosidic linkage
(A*) Xywdksl eksuksej rFkk -XykbdksflfMd ca/ku (B) ÝDVksl eksuksej rFkk -XykbdksflfMd ca/ku
(C) Xywdksl eksuksej rFkk -XykbdksflfMd ca/ku (D) ÝDVksl eksuksej rFkk -XykbdksflfMd ca/ku
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17. The true/false statements about the following compounds are :
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20.
The above process in which and form remain in equilibrium with acyclic form and a change in optical
rotation is observed which is called as -
(A*) Mutarotation (B) Epimerisation (C) Condensation (D) Inversion
mijksDr izfØ;k ftlesa vkSj :i vpfØ; :i ds lkFk lkE; voLFkk esa jgrs gSa vkSj izdkf'kd ?kw.kZu esa ifjorZu ns[kk tkrk
gSA bls dgrs gS &
(A*) E;wVkjksVs'ku (B) ,ihejhdj.k (C) la?kuu (D) izrhiu
Ans. The above phenomenon is called as mutarotation.
mijksDr ?kVuk dks E;wVkjksVs'ku dgrs gSA
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