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∂Ψ ~2 2
i~ =− ∇ Ψ,
∂t 2m
is manifestly not Lorentz constant since time and space derivatives are of different order.
This implies that it changes its structure under a transformation from one inertial system
to another.
Dirac (P.A.M. Dirac, Proc. Roy. Soc. (London) A117, 610 (1928)) published in 1928
the Dirac equation, which is a relativistic equation for spin-1/2 particles. This equation
has, like the Klein-Gordon equation, solutions with negative energy. In order to avoid
transitions of an electron to states of negative energy, Dirac postulated in 1930 that the
states of negative energy should all be occupied and the particles that are missing in these
occupied states represent particles of opposite charge (antiparticles). Pauli and Weisskopf,
using this concept, also interpreted the Klein-Gordon equation as such that could be used
to describe f.i. mesons with spin zero (π-mesons).
139
140 CHAPTER 6. RELATIVISTIC QUANTUM MECHANICS
as
∂
energy E → i~ ∂t
~
momentum p~ → −i~∇
and obtain from the non-relativistic energy of a free particle
p~ 2
E= ,
2m
its time-dependent Schrödinger equation:
∂ ~2 ∇2
i~ Ψ=− Ψ
∂t 2m
which is not Lorentz invariant.
In order to introduce the relativistic formulation, we first define our notation according
to the special theory of relativity:
3 - we use Einstein’s summation convention: Greek or Latin indices that appear twice,
one contravariant and one covariant, are summed over;
(i) The contravariant and covariant components of the position vector are
xµ : x0 = ct x1 = x x2 = y x3 = z (contravariant)
xµ : x0 = ct x1 = −x x2 = −y x3 = −z (covariant)
xµ = gµν xν , xµ = g µν xν .
and
1 0 0 0
0 1 0 0
gνµ = δνµ =
.
0 0 1 0
0 0 0 1
For instance, the d’Alembert operator is defined in terms of gµν as
3
1 ∂2 X ∂2
= 2 2 − i )2
= ∂µ ∂ µ = gµν ∂ µ ∂ ν ,
c ∂t i=1
∂(x
(v) In relativity, proper time is the time between events occuring at the same
place as where the single clock that measures it is located. The proper time
depends on the events and on the motion of the clock between the events. An
accelerating clock will measure a shorter proper time between two events than
a non-accelerating (inertial) clock would do for the same events.
dx dx dt v/c
ẋµ (s) = = · =p .
ds dt ds 1 − (v/c)2
Therefore, according to the special theory of relativity, the energy E and the mo-
mentum (px , py , pz ) transform as the components of a contravariant four-vector :
µ 0 1 2 3 E
p = (p , p , p , p ) = , px , py , p z .
c
7 - with the metric tensor gµν , we obtain the covariant components of the four-momentum:
ν E
pµ = gµν p = , −~p .
c
E2
pµ pµ = − p~ 2 = m2 c2 ,
c2
where m is the rest mass and c is the speed of light. By using special relativity, we
obtain the energy-momentum relation for a free particle:
p
E= p~ 2 c2 + m2 c4 . (6.3)
6.1. THE KLEIN-GORDON EQUATION 143
We apply now the correspondence principle to eq. (6.3) and obtain the wave equation
∂ √
i~ Ψ = −~2 c2 ∇2 + m2 c4 Ψ ,
∂t
in which time and space do not occur symmetrically because a Taylor expansion of the
square root leads to infinitely high derivatives in space. But if, instead of eq. (6.3), we
start from the squared equation,
E 2 = p~ 2 c2 + m2 c4 ,
we arrive at
∂2
2 2~ 2
−~2 Ψ = −~ c ∇ + m 2 4
c Ψ,
∂t2
which can be written in the following Lorentz covariant form:
mc 2
µ
∂µ ∂ + Ψ=0, (6.4)
~
Eq. (6.4) is the Klein-Gordon equation. Let us now consider its properties.
~
We multiply now (6.6) by 2mi
and obtain (writing explicitly)
∂Ψ∗
∂ i~ ∗ ∂Ψ ~ · ~
Ψ −Ψ +∇ [Ψ∗ ∇Ψ − Ψ∇Ψ∗ ] = 0,
∂t 2mc2 ∂t ∂t 2mi
~ · ~j = 0 ,
ρ̇ + ∇
~j = ~ Ψ∗ ∇Ψ
~ − Ψ∇Ψ
~ ∗ .
2mi
Note:
Ψ(~x, t) = ei(Et−~p·~x)/~ ,
with
p
E=± p~ 2 c2 + m2 c4 .
Both solutions with positive and negative energies are possible, and the energy is not
bounded from below, which does not make sense for a free particle. Moreover, this is
a scalar theory, which doesn’t contain spin and therefore can only describe spin-zero
particles.
For these reasons, the Klein-Gordon equation was rejected. One year later Dirac pro-
posed his equation for spin-1/2 fermions. He interpreted the negative energy solutions
by assuming that the unoccupied states of negative energy describe antiparticles. The
Klein-Gordon equation, though, is still suitable for describing mesons.
6.2. DIRAC EQUATION 145
1 - the density
∗∂
ρ= Ψ Ψ + c.c. ,
∂t
which contains the first time derivative, is positive definite;
2 - the equation is relativistic covariant. This means that its spatial derivatives are of
the same order as the time derivatives, that is, of first order.
The Dirac Hamiltonian (6.7) is linear in the momentum operator and in the energy at rest.
Therefore, αk and β cannot be scalar numbers. If they were, then the equation would not
be form invariant with respect to spatial rotations. αk and β must be hermitian matrices
for H to be hermitian.
(i) The components of Ψ must satisfy the Klein-Gordon equation, so that plane waves
fulfill the relativistic energy-momentum relation
E 2 = p2 c2 + m 2 c4 .
(iii) The equation must be Lorentz covariant, which means that it must have the same
form in all reference frames that are connected by a Lorentz (Poincaré) transforma-
tion. This requirement is fulfilled since (6.7) is of the first order.
146 CHAPTER 6. RELATIVISTIC QUANTUM MECHANICS
In order to fulfill condition (i), we consider the second derivative of eq. (6.7)
∂2 X1
−~2 Ψ = −~ 2 2
c (αi αj + αj αi )∂i ∂j Ψ
∂t2 ij
2
3
~mc3 X i
+ (α β + βαi )∂i Ψ + β 2 m2 c4 Ψ, (6.8)
i i=1
j µ ≡ (j 0 , j k ).
1∂ 0 ∂
∂µ j µ = j + k jk = 0 ,
c ∂t ∂x
which is a nice compact form. The density defined in eq. (6.10) is positive definite and
can be given the interpretation of a probabiliy density.
2 - From (αk )2 = β 2 = 1 follows that the matrices αk and β have only eigenvalues ±1.
Analogously,
T rβ = −T rβ.
So,
T rαk = T rβ = 0 ,
which means that the number of positive and negative eigenvalues must be equal,
and therefore N (the dimension of the matrix) must be even.
148 CHAPTER 6. RELATIVISTIC QUANTUM MECHANICS
N = 2 is not sufficient since among the 2 × 2 matrices that are known, 1, σx , σy , and σz ,
only three are mutually anticomuting; the 1 commutes with the rest. Thus, N = 4 is the
smallest dimension in which it is possible to fulfill (6.7)-(6.9).
0 σi
i 1 0
α = and β = , (6.11)
σi 0 0 −1
and 1 being the 2-dimensional identity. αi and β defined in this way satisfy the condition
(6.9)
0 −σ i 0 σi
i i
α β + βα = + = 0.
σi 0 −σ i 0
→ The Dirac equation (6.7) together with the definitions of αi and β (6.11) is called
“standart representation” of the Dirac equation.
−i ~ β ∂0 Ψ − i ~ β αi ∂i Ψ + mcΨ = 0
γ0 ≡ β and γ i ≡ βαi .
1 - γ 0 is hermitian and (γ 0 )2 = 1.
2 - γ k is anti-hermitian:
(γ k )† = −γ k and (γ k )2 = −1.
Proof :
(γ k )† = αk β = −βαk = −γ k ;
(γ k )2 = βαk βαk = −1.
6.2. DIRAC EQUATION 149
3 - γ 0 γ k + γ k γ 0 = ββαk + βαk β = 0.
γ µ γ ν + γ ν γ µ = 2g µν 1 .
Having introduced γ i and γ 0 , the Dirac equation (6.7) has now the form
mc
−iγ µ ∂µ + Ψ=0. (6.12)
~
This equation can be written in a more compact form using the following Feynman nota-
tion:
v ≡ γv ≡ γ µ vµ = γµ v µ = γ 0 v 0 − ~γ · ~v (v µ denotes any vector).
✚
The Feynman slash indicates multiplication by the matrix γµ . Eq. (6.12) thus becomes
mc
−i✓
∂+ Ψ=0,
~
with
0 σi
0 1 0 i
γ = and γ = .
0 −1 −σ i 0
Note: one can obtain other representations of the γ matrices by considering a non-singular
transformation M :
γ → M γM −1 .
For instance, the so-called Majorana representation of γ or the Chiral representation of γ
are also used.
∂Ψ
i~ = βmc2 Ψ.
∂t
150 CHAPTER 6. RELATIVISTIC QUANTUM MECHANICS
0 0
0 0
(−) imc2 0 (−) imc2 0
Ψ1 = e ~ t 1 ,
Ψ2 = e ~ t 0 .
0 1
(+) (+) (−) (−)
Ψ1 and Ψ2 are positive-energy solutions, and Ψ1 and Ψ2 are negative-energy solu-
tions. We examine now the positive-energy solutions. The negative-energy solutions will
be discussed later. It is experimentally shown that the negative solutions are physical
solutions and describe antiparticles (positrons).
- augmenting the rest energy in the Dirac Hamiltonian by the scalar electric field eΦ,
∂Ψ e ~ 2
i~ = c~
α · p~ − A + βmc + eΦ Ψ . (6.13)
∂t c
Here, e is the charge of the particle, with e = −e0 for the electron.
where
e~
~π = p~ − A
c
is the kinetic momentum operator.
6.2. DIRAC EQUATION 151
In the non-relativistic limit, the rest energy mc2 is the largest energy involved. Therefore,
we take as positive-energy solutions wavefunctions of the form
ϕ̃ − imc
2
t ϕ
=e ~ ,
χ̃ χ
where
ϕ
χ
are considered to vary slowly with time and satisfy the equation
∂ ϕ ~σ · ~π χ ϕ 2 0
i~ =c + eΦ − 2mc . (6.14)
∂t χ ~σ · ~π ϕ χ χ
∂
For the equation for χ, one may neglect ~ ∂t χ and eΦχ in comparison to 2mc2 χ and get
c ~σ · ~π ϕ = 2mc2 χ,
~σ · ~π
χ= ϕ. (6.15)
2mc
v
We see from this equation that χ is a factor ∼ c
smaller than ϕ. Therefore,
ϕ is the large component of the spinor and
with
σ i σ j = δij + iǫijk σ k ,
we get
e~ ~ .
(~σ · ~π ) (~σ · ~π ) = ~π 2 + i~σ (~π × ~π ) = ~π 2 − ~σ · B (6.17)
c
Note that we used
i −e
ǫijk ∂j Ak − Ak ∂j ϕ
(~π × ~π ) ϕ = −i~
c
~e ijk ~e
∂j Ak ϕ = i B i ϕ,
= i ǫ
c c
152 CHAPTER 6. RELATIVISTIC QUANTUM MECHANICS
with
B i = ǫijk ∂j Ak .
which is the Pauli equation for the Pauli spinor ϕ as is known from non-relativistic quan-
tum mechanics. The two components of ϕ describe the spin of the electron.
In this derivation, one obtains the correct gyromagnetic ratio g = 2 for the electron.
~ = ~x × p~,
L ~ = 1 ~~σ,
S
2
into eq. (6.18) and using the fact that
~
~
p~ · A = ~ ~
∇·A =0
i
is the Coulomb gauge and
~ · p~ = −2 1 B
~−A
−~p · A ~ · p~ = −2A ~ × ~x · p~
2
~
= − (~x × p~) · B = −L~ · B,
~
we get
p~ 2 e2 ~ 2
∂ϕ e ~ ~ ~
i~ = − (L + 2S) · B + A + eΦ ϕ . (6.19)
∂t 2m 2mc 2mc2
~ are ±~/2. The interaction with the electromagnetic
The eigenvalues of the spin operator S
field is, following eq. (6.19),
2
~+ e A
Hint = −~µ · B ~ 2 + eΦ,
2mc2
with the magnetic moment
e ~
~ .
µ
~ =µ
~ orbit + µ
~ spin = L + 2S (6.20)
2mc
6.2. DIRAC EQUATION 153
The non-relativistic limit approximation is good for atoms with small atomic number Z.
One cannot exclude these negative-energy states since the positive-energy states do not
represent a complete set of solutions. The physical consequence of these two sets of
solutions is that, when an external perturbation (measurement) causes an electron to enter
a certain state, this state will be a combination of positive- and negative-energy states.
In the case when the electron is confined in a region that is smaller than its Compton
wavelength, this interference between positive- and negative- energy components produces
an oscillatory motion known as “Zitterbewegung”. In order to see that let us solve the
Dirac equation in the Heisenberg representation. The Heisenberg operators O(t) fulfill
the equation of motion:
dO(t) 1
= [O(t), H] .
dt i~
We consider free particles, and therefore the momentum p~ conmutes with the Hamiltonian
α · p~ + βmc2
H = c~ (6.21)
and therefore
d~p(t)
=0
dt
what leads to p~(t) = p~ = constant.
Note also that
d~x(t) 1
~v (t) = = [~x(t), H] = c~
α(t)
dt i~
and
d~
α 1 2
= [~
α(t), H] = (c~p − H~ α(t))
dt i~ i~
Since H is time independent, we can integrate the previous equation:
2iHt
α(t) = cH −1 p~ + e
~v (t) = c~ ~ α(0) − cH −1 p~)
(~
c2 p~ ~c 2iHt c~p
~x(t) = ~x(0) + t+ (e ~ − 1)(~
α(0) − ) (6.22)
H 2iH H
Since
6.2. DIRAC EQUATION 155
α
~ H + H~
α = 2c~p
then
c~p c~p
(~
α− )H + H(~α− )=0 (6.23)
H H
We observe that the solution Eq. 6.22 contains a linear term in time which corresponds to
the group velocity motion, and an oscillating term which describes the ”Zitterbewegung”
of the free particle. Since the vanishing of the anticonmutator Eq. 6.23 implies that
the energies must be of opposite sign, the ”Zitterbewegung” is the result of interference
between positive and negative energy states.
Discussion about hole theory in class.
BIBLIOGRAPHY
• J. J. Sakurai: ” Modern Quantum Mechanics”, Addison-Wesley Publishing Com-
pany 1994.