Bapco Frontier Megatek 10W-40

1 - Identification of Substance / Mixture and of the Company / Undertaking

Material / Trade Name: Bapco Frontier Megatek 10W-40
Material Type: Diesel Engine Oil
Company: Bahrain Petroleum Company B.S.C. (Closed)
Address: P.O. Box 25555
Awali
Kingdom of Bahrain

Telephone: Lubricant Technology + 973 17753032

Web Site: www.bapco.net

2 - Hazard Identification

GHS Classification: Not Hazardous , Not Classified

GHS Label Elements /Symbols: No Symbol
Signal Words: No Signal Word

Hazard Statement

Physical Hazards: Not Classified as a Physical Hazard under GHS criteria

Health Hazards: Not Classified as a Health Hazard under GHS criteria
Environmental Hazards: Not Classified as an Environmental Hazard under GHS criteria
Other Hazards which do not result in classification: Not Classified as flammable but will burn

3 - Composition / Information on Ingredients

Preparation Description: Mixture of hydrotreated basestocks and additives.

COMPONENTS % WT. CAS EC REGISTRATION R PHRASES CLP CLASSIFICATION

Hydrotreated Neutral Oil C20-C50 >75 72623-87-1 276-738-4 None
Phosphorodithioic acid, mixed <2 283-392-8 01-2119493626-26 Nxi Aquatic Chronic 2 / H411
O,O bis (1-3 dimethylbutyl and iso -Pr) R 38,R41, R51/R53 Eye damage. 1 / H318
esters zinc salts Skin Irritation . 2 / H315
Phenol,dodecly - branched <1 310-154-3 01-2119513207-49 N Xn Aquatic Acute - 1 / H400
R36/38 R50/53 R 62 Aquatic Chronic - 1 / H410
Eye Irr. 2 / H319
Repro. - 2 / H361
Skin Irr. - 2 / H315
Olefin Sulfide <1 Trade secret Confidential Not Available None Aqua Chron 3 / H412
R52 / R53

R Phrases and CLP Classifications provided herein describe the classification each component in the lubricant additive. The concentration of each component which may
pose risk in the form of lubricant additive are much below their individual cut off level for physical, health and environmental hazard classes making resulting the
lubricant mixture " Not Classified" under GHS criteria.

4 - First Aid Measures

Inhilation: Remove to fresh air and rest. If recovery is not rapid call for prompt medical attention. Show this safety data
sheet to medical personnel.
Eyes: Gently rinse with water for at least 15 minutes. Take care not to wash chemical from one eye to another. If irritation
persists, seek medical attention.

Skin: Remove contaminated clothing. Wash with soap/cleanser and rinse with plenty
of water. If irritation persists, seek medical attention.

Ingestion: Do not induce vomiting. Give plenty of water to drink. Seek medical attention immediately.

5 - Fire fighting Measures

Suitable Extinguishers: Use media such as alcohol/aqueous foam, dry chemical, or carbon dioxide or water spray/fog. For
large fires, solid streams of water may be ineffective. Cool all affected containers with flooding quantities of water.

Unsuitable Extinguishers: Direct water jets may be ineffective under certain conditions.

Hazardous Decomposition: Highly dependent on combustion conditions. A complex mixture of airborne solids, liquids, and
gases including carbon monoxide, carbon dioxide, and unidentified organic compounds will be evolved.

Special Procedures/Information for firefighters: Do not breathe decomposition products and fumes. Use approved self-
contained breathing apparatus. Wear fire retardant clothing. Do not enter any enclosed or confined fire space without
proper protective equipment, including self-contained breathing apparatus. Use water spray to cool Use water fog to
disperse vapours and leaks that have not ignited. Prevent runoff from fire control from entering waterways. Large fires
should only be dealt with by trained personnel.

6 - Accidental Release Measures

Personal Protection and Precautions: Use suitable personal protective equipment (refer to Section 8 for details). Avoid
breathing vapours. Ensure adequate ventilation. Eliminate all sources of ignition near the spill or released vapour.

Environmental Precautions: Prevent further leakage or spillage if safe to do so. Do not let product enter drains or
watercourses. Where feasible and appropriate, remove contaminated soil. Place contaminated materials in disposable
containers and dispose of in a manner consistent with applicable regulations.

Containment, Cleaning up and Disposal Considerations: Absorb in inert material such as sand or non-combustible
absorbent granules. All equipment used when handling the product must be grounded. A vapour suppressing foam may be
used to reduce vapours. Scoop up and place in plastic container to await transfer.

7 - Handling and Storage

Handling: Avoid inhalation of vapour or mist.

Storage: Store in a cool, dry and well-ventilated area keeping containers tightly closed. Containers which are opened
carefully resealed and kept upright to prevent leakage.

8 - Exposure Controls / Personal Protection

Occupational Exposure Limit: 5 mg/m3 8hrTWA, 10 mg/m3 15min STEL OEL Oil mist.

Respiratory Protection: Use in well ventilated areas. Use mechanical ventilation if possible. If inhalation is likely then use a
respirator with filter type A to Standard EN14593/4, EN405 or equivalent. The use of suitable gas detectors and alarm
systems, especially in confined spaces and poorly ventilated areas is recommended.

Hand Protection: Wear polythene, PVC or nitrile gloves to Standard EN 374 (breakthrough time for total immersion in
excess of 8 hours).
Eye Protection: Wear suitable eye protection such as safety glasses or goggles to Standard BS EN 166 if splash or eye
contact likely.

Skin Protection: Wear suitable overalls or apron and change if contaminated. After contact with skin wash off
immediately. Wash hands before breaks and immediately after using the product

9 - Physical and Chemical Properties

Appearance: Amber, liquid Oxidizing properties: None

Odour: Slight Hydrocarbon Vapour Pressure: < 0.5 Pa @ 20°C
pH: n/e Density @ 15°C: 0.8578
Boiling Point range: Solubility in water: Insoluble in water
Initial Boiling Point: > 280 °C / 536 °F Partition Coeffic: > 6(estimated base on similar product)
Melting Point range: < - 30 °C / -22 °F Vapour Density: > 1 ( estimated value)
Flash Point: > 210 °C / 410 °F Viscosity (typ): 95 mm² / sec @ 40°C / 104 °F
Flammability: Non Flammable Evaporation rate: n/e
Autoflammability: n/e Explosive properties: n/e

10 - Stability and Reactivity

Chemical Stability: Stable at normal temperatures and under recommended storage conditions.

Conditions to Avoid: Extreme temperatures and direct sunlight.

Materials to Avoid: Strong bases and acids.

Hazardous Decomposition Products: No hazardous decomposition products when stored and handled correctly. Hazardous
decomposition products formed under fire conditions are highly dependent on combustion conditions. A complex mixture
of airborne solids, liquids, and gases including carbon monoxide, carbon dioxide, and unidentified organic compounds will
be evolved when this material undergoes combustion.

11 - Toxicological Information

Acute toxicity: Not acutely toxic by any routes.

Skin corrosion/irritation: Mechanically degraded mineral oil may cause skin dryness or cracking.

Serious eye damage/eye irritation: Not expected to cause any acute damage or irritation.

Respiratory or skin sensitisation: No data available

Germ cell mutagenicity: No data available

Carcinogenicity: IARC: No component of this product present (as supplied) at levels than or equal to 0.1% is identified as
probable, possible or confirmed greater human carcinogen by IARC. Substance not classified as carcinogen because it
contains less than 3% DMSO.

Reproductive toxicity: Small amount of material classified as toxic.

Specific Target Organ Toxicity Single Exposure: No data available.

Specific Target Organ Toxicity - Repeated Exposure: No data available.

Potential health effects

Inhalation: May be harmful if inhaled.

Ingestion: May be harmful if ingested.

Skin: May be harmful if absorbed through skin. Repeated skin contact may cause dermatitis.

Eyes: May cause eye irritation.

Signs and Symptoms of Exposure: May cause skin dryness or cracking, ingesting substance can cause severe
abdominal pains, nausea and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties
have not been thoroughly investigated

12 - Ecological Information

Toxicity
Harmful to aquatic life with long lasting effects

Persistence and degradability Mobility in soil PBT and vPvB assessment

Not expected to be inherently biodegradable No data available No data available

Bioaccumulative potential Other adverse effects

No data available No data available

13 - Disposal Considerations

Product: Do not discharge into drains or water courses, dispose of through properly licensed contractors.
Dispose of in accordance with the Hazardous Waste regulations 2005.

Contaminated Packaging: Dispose of as unused product.

14 - Transport Information

ADR/RID: Not classified as hazardous for transport

IMDG: Not classified as hazardous for transport
Marine pollutant: No
IATA: Not classified as hazardous for transport

15 - Regulatory Information

Label Elements: No statutory safety labels are required for this material in accordance with the provisions
of EC/1907/2006, EC/1272/2008 or 67/548/EEC as amended

Other Regulations: Classification, Labelling and Packaging of Substances and Mixtures

Regulations 2008 (as amended)
EH40/2005 Workplace Exposure Limits (as amended)
Hazardous Waste Regulations 2005
Chemical Inventories: All components comply with the following chemical inventory requirements:

AICS: Australia KECI: Korea

DSL: Canada PICCS: Philippines
EINECS: European Union TSCA: United States

16 - Other Information

Text of H-code(s) and R-phrase(s) mentioned in Section 3

H317: May cause an allergic skin reaction

H318: Causes serious eye damage
H411: Toxic to aquatic life with long lasting effects
H413: May cause long lasting harmful effects to aquatic life
R41: Risk of serious damage to eyes
R43: May cause sensitization by skin contact.
R53: May cause long-term adverse effects in the environment
R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment

Recommended restrictions on use:

Use in accordance with manufacturer’s technical instructions.

Note L

The classification as a carcinogen need not apply if it can be shown that the substance contains less than 3% DMSO
extract as measure by IP346 ‘Determination of polycyclic aromatics in unused lubricating base oils and asphaltene free
petroleum fractions – Dimethyl sulphoxide extraction refractive index method’, Institute of Petroleum, London. This note
applies only to certain complex oil-derived substances in Part 3.

Revision History

First Issue

Further Information

The information in this Safety Data Sheet should be provided to all who will use, handle, store, transport or otherwise be
exposed to this product. This information has been prepared for the guidance of plant engineering, operations,
management and for people working with or handling these products. This information is believed to be reliable and
updated at Revision Date, and represents the best information currently available and known by Bahrain Petroleum
Company B.S.C. (BAPCO). However, BAPCO makes no guarantee or warranty,express or implied, with respect to such
information and we assume no liability resulting from its use. The information related herein is based on proper handling
and anticipated uses and is for the material without chemical additions or alterations. Users should make their own
investigations to determine the suitability of the information for their particular purposes. It is the responsibility of the
user to undertake a suitable risk assessment/COSHH assessment prior to using this material.