386 INTERNATIONAL CRITICAL TABLES

PHASE-EQUILIBRIUM DATA
STBTEMS COMPOSED OF LIQUID
PHASES ONLY*
Two-component systems.
Solubilities of liquids in
liquids.
Systems containing more than
two components.
Miscibility relations.
Distribution coefficients.
* Including also systems of two liquid phases in the presence of the vapor phase but in most cases without determination of the pressure or composition of the vmpor.
SYSTÈMES COMPOSÉS UNIQUE-
MENT DE PHASES LIQUIDES
Systèmes à deux constituants.
Solubilités des liquides dans
les liquides.
Systèmes ayant plus de deux
constituants.
Rapports de miscibilité.
Coefficients de distribution.
SYSTEME DIE NUR FLÜSSIGE SISTEMI COSTITUITI SOLTANTO
PHASEN ENTHALTEN DI FASI LIQUIDE PAOE
Zweikomponenten Systeme. Sistemi a due component!.
Löslichkeiten von Flüssig Solubilità dei liquidi. nei
keiten in Flüssigkeiten. liquidi 386
Systeme mit mehr als zwei Sistemi con più di due com
Komponenten. ponenti.
Mischungsverhältnisse. Rapporti di niiscil lilii à . . 39$
Verteilungskoeffizienten . Coefficient! di riparti-
zione 418

SOLUBILITIES OF LIQUIDS EN LIQUIDS. TWO-COMPONENT SYSTEMS*

ARTHUR E. HILL
CONTENTS MATIÈRES INHALTSVERZEICHNIS INDICE pAGE
Sec. 1. The A-component is Sec. 1. Le constituant A est Sec. 1. Die A-Komponente ist Sez. 1. II componente A e
H2O. H2O. HíO. H20 387
Sec. 2. The key-formula of Sec. 2. La formule-clé d'aucun Sec. 2. Die Schlussclformel Sez. 2. Nessuno dei com-
neither component des constituants ne keiner der beiden ponenti ha una
begins with 16. commence par 16. Komponenten be formula chiave
ginnt mit 16. che comincia con
16 393
Sec. 3. The A-component key- Sec. 3. La formule-clé du con See. 3. Die Schlüsselformel der Sez. 3. La formula chiave
formula does not be stituant A ne com A-Komponente be del componente
gin with 16; the B- mence pas par 16; la ginnt nicht mit 16, die A non comincia
component key-for formule-clé du con der B-Komponente con 16; quella del
mula begins with 16. stituant В commence beginnt mit 16. componente В
par 16. comincia con 16. 394
Sec. 4. Both the A- and the B- Sec. 4. Les formules-clés des See. 4. Die Schlüsselformeln Sez. 4. Tanto il compo
component key-for deux constituants A der A- and B-Kom nente A, come il
mulae begin with 16. et В commencent par ponenten beginnen componente В
16. mit 16. hanno una for
mula chiave che
comincia con 16. 394

ABBREVIATIONS AND ABRÉVIATIONS ET ABKÜRZUNGEN UND ABBREVIAZIONI E

CONVENTIONS
Compositions are in Wt. %
unless otherwise noted.
In nearly all cases the experi
ments were performed in sealed
tubes, consequently, for values
at room temperature, the pres
sure equalled one atmosphere;
was greater than one atm. at
higher temperatures and less
than one atm. at lower tempera
tures.
CONVENTIONS
Les compositions sont expri
mées en % poids à moins d'une
autre indication.
Dans presque tous les cas, les
expériences ont été effectuées
dans des tubes scellés, par con
séquent pour les valeurs à la
température de la chambre, la
pression égale une atmosphère;
cette pression sera supérieure à
une atm. pour des températures
plus élevées et moindre qu'une
atm. pour des températures plus
FESTLEGUNGEN
Die Zusammensetzungen
sind, wenn nichts anderes be
merkt, in Gewichte-Prozenten
(Wt. %) angegeben.
In beinahe allen Fällen wur
den die Experimente in zuge
schmolzenen Röhren ausgeführt.
Es gilt deshalb der Wert für
Zimmertemperatur und dem
Druck von einer Atmosphäre.
Er war grosser als eine Atmo
sphäre bei höherer, kleiner bei
tieferer Temperatur.
CONVENTION!
Le composizioni, salvo i casi
in cui è indicato diversamente,
sono indicate in percentuale in
peso.
In quasi tutti i casi le espe-
rienze sono state esegute in tubi
chiusi, e perciô a temperatura
ordinaria la pressione era quella
di una atmosfera, inentre, a
temperature superior!, era mag-
giore di una atmosfera, e, a
temperature inferiori, minore.

Q, quadruple point with the
substance X present as crys
talline phase.
m metastable.
* Including some systems in which
one phase is a natural or commercial
oil.
Q! point quadruple avec la
substance X présente comme
phase cristalline.
m metastable.
* Sont inclus quelques systèmes
dans lesquels une phase est une huile
naturelle ou de commerce.
Q, Quadrupel- Punkt mit der
Substanz X als kristalline Phase.
m metastabil.
* Enthält einige Systeme in welchen
eine Phase ein vegetabilisches oder ein
sonst in Verwendung befindliches Öl
ist.
Qi punto quadruple in pre-
senza délia sostanza X allô stato
di fase cristallina.
m metastabile.
* Sono compreei alcuni eistemi nci
quali una délie faai è un olio naturale o
commerciale.
 MUTUAL SOLUBILITY OF LIQUIDS 387

Sec. 1. The A-coniponent is H2O. The В-compon ent, Br2, CAO, A crolein (l 0, 10.5) СзНтВг, I iopropyl t iromide
is given f rst and tb e remainii ig B -compon ;nts folio w in the Stabilized by 0.4% hydro- (105)
<£-arrangejnent (v. p. viii). quinol °C % В
Br, (», 11, 21, 23, 92, 63, CH2Br2, M ethvlene Bromide °C %B 0 0.416
10 1, 157, 159 ) (1¿S) 0 20 95 10 0.364
20 21.6 92.8 20 0.317
°C % В "С % В
0 4.03 0 1.15 40 23.6 90.4 30 0 317
5 3.73 10 1.13 50 25.8 87.8
60 29.1 84.3 CjHjCl, n- Propyl ch loride
10 3.58 20 1.13 (!*•)
15 3.48 30 1.16 70 33.2 79.8
80 40.4 72.4 0 0.375
20 3.41 CH2C12,M<¡thylene с iloride 10 0.322
22 99.954 85 46.8 65.8
(105) 56 .2 20 0.271
25 3.34 (159) 88
0 2.30 30 0.276
30 3.29 10 2.08 CjHsN, Propionitri] с (»O)
35 3.27 20 1.96 40 10.7 92.1 СДтС!, blopropyl с hloride
40 3.30 30 1.93 50 11.6 90.5 (105)
45 3.35 60 12.7 88.5 0 0.438
50 3.40 CH J, Me thyl iodid с («os; 70 13.2 86.1 10 0.361
0 1.54 80 14.9 83.4 20 0.304
ССШ, Cyanogen chloride 10 1.42
(102) 90 17.6 80.2 30 0.303
20 1.40 95 19.6 78.0
8 7-8 30 1.41 100 22.4 75.5 C3H7I, n-Propyl iodi de (ios)
CCljNO2, Chloropicr in (138) CHJIOj, Nitromethane (i«) 0 0.114
°C %B %A 105 26.0 72.1
ca. 103* ca. 65 110 32.0 66.5 10 0.103
0 0.2268 20 0.107
25 0.1620 * Consolute »emp. 113 1 4 8.3
С2НС1зС , Chloral (109) 30 0.103
32 0.1001 C3H„C1O, E sichloroh}•drin (")
36 0.1184 172.5 92.5 0 6.48 98.91 С H 1, Isop ropyl iod de (»e»)
41 0 1241 174 6 89.1 10 6.52 98.74 0 0.167
48 0.1645 179.8 84.5 20 6.58 98.53 10 0.143
50.8 0.1851 С H. Br O;, Bromal hydrate 30 6.66 98.30 20 0.140
55 0.2262 (146) 40 6.95 97.93 30 0.134
75 0 1140 Consolute temp. = 103.4°C 50 7.42 97.44
C,H«JÏ2, Succinon itrile
C(;i, (18, ios 1 C,H,C12, 1, 1-Dichloi•oethane 60 8.18 96.82
0 0.097 (105) 70 9.12 95.84 0 15, 143)
10 0.083 °C В 80 10.44 94.30 18.5QB 10.2 92.0
%
0.080 0 0.652 20 11.0 91.5
20 CsHeO, Propionaldehyde (1«)
24 0.010 10 0.591 25 11.5 90.4
22 16 30 13.2 89.1
28.5 0.013 20 0.547
30 0 085 30 0.537 C:,H«O2, Ethyl foi •mate 35 15.0 87.4
i 103, 148) 40 18.4 84.1
CS, (u , 16, 18, 5« , 105) C2H4Cla, Ijthylene с hloride 45 22.0 80.0
(105)
0 9.34
°C % В 10 9.07 50 28.2 74.0
0 0.242 0 0.914 20 55 42.5 59.5
8.58
10 0.230 10 0.875 30 7.34 55.5 (51 .1)
20 0.210 20 0.861
22 99.24t 30 0.885 C3H6O„ Methyl a cetate C;H О , Acetic anhydride (*1)
30 0.185 CsH4O„ Methyl fo rmate (5 6.5, 103) 15 10. 23 26
40 (0.111)* (103) - 6.55QA 25.6 93.8
C.H.o, n-Butyraldehyde («2)
49 (0.014)* 0 21.13 0 25.0 93.6
+ 10 24.8 93.0 20 3.0
* Data fro n (>»). 10 22.24 20 24.2 91.8
t AccordingI to('«i «> > "). 20 23.29 С ,H.O, Isobutyraldehyde (1«)
25 24.1 91.3
CHC1, (1 6, 18, 50, 8 4, IOS) 30 24.53 30 24.0 90.8 20 8.0
0 0.98 С H Br, Et (jyl bromi de (l«*) 40 24.2 89.4
1.45Q*
50 24.8 87.7 C,H,O, Me thyl ethy 1 ketone
0 1.055 60 25.1 85.9 (HO) i . also p. . 593
10 0.86 10 0.956 80 27.5 80.8
20 0.80 90 30.2 77.3 -20 40.1 89.4
20 0.906 30.6
30 0.76 100 35.2 71.8 0 89.6
30 0.888 105 40.3 ee.o +20 22.6 90.1
401 0.735
C,H .Cl, Ethyl chloride (61) 108 52. 5 40 18.6 89.6
50 0.745
55 0.77 ca. 11 0.2 С H,Br, n .-Propvl b romide 60 16.5 88.2
С2Л&1, ÍJ\ hyl iodide (105) (105) 80 15.7 85.8
* Solid - В hydrate,
t The figures for composition of the 0 0.339 0 0.297 100 16.4 82.6
organic phase are too irregular to 10 0.412 10 0.262 120 18.6 77.3
permit averaging; the percentage of
water at températures between 0 and
20 0.401 20 0.244 140 26.4 65.5
40° is 0.1 ± 0.05. 30 0.413 30 0 246 150 45
388 INTERNATIONAL CRITICAL TABLES

H2O.- -(Coniin ¿ed) C,H, О —(Contir\,ued) C4HUN, Di ethylamiE e (3, 47, CiHjaOti [sobutyl formate
С,Н,02,' n-Butyri с acid °c %В Щ (148)
( 34, 143) 80 73.53 6.89 °C %B °c %B
"С % В 90 69.9 7.9 143.5 37 .5 22 1.0
-7 60.6 100 66.2 9.2 144 30 45
110 62.4 10.5 145 27.6 49 С H, O:, Propyl .! cetate
-в 58.1 03, 148)
-5 24.6 55.3 115 59.0 12.8 150 23.6 55.4 P

-4 27.8 51.4 120 54.0 16.1 155 21.7 58.5 0 3.35

10 2.57
-3.5 30.8 48.6 125.15 32 .5 CíH.O,, F •urfural (« 2, 110) 20 2.30
-3 39 .5 СДюО, . Isobutyl a Icohol P varying 30 2.05
» The two-li îuid eyetem ie metaata- ( 3, 154) 10 7.9 96.1
Ые throughout
30 7.75 82.9 20 8.3 95.2 С,Н1гО, 1 soamyl a cohol*
С4Н,Ог, Isobutyr c acid (3, 6, 40, 50 , 64, 153, 158, 160,
40 7.25 81.8 30 8.8 94.3
(27, 34, 4 г,
no, is 5, 150J 40 9.1 93.4 0 3.6 91.6
50 71 80.6
-5 15.3 60 7.1 79.2 50 9.8 92.6 10 3.15 91.0
0 15.8 80 70 7.2 77.6 60 10.8 91.6 20 2.75 9O.4
+5 16.5 74.5 80 7.55 75.6 70 12.4 90.4 30 2.45 90.0
10 17.7 68.9 90 8.2 73.5 80 14.2 88.8 40 2.2 89.4
15 19.4 63.9 100 9.35 70.2 90 16.2 86.5 50 2.2 88.8
20 22.5 58.3 105 10.3 68.9 100 19.2 83.5 60 2.2 88.1
21 23.3 56.6 110 11.3 67.0 110 24 78.5 70 2.3 87.4
22 24.6 54.3 115 12.3 64.75 115 28 74.6 80 2.4 86 3
23 26.4 51.5 120 14.85 61.7 120 34.4 68.1 90 2.7 85.2
24 29.4 46.6 125 18.0 57.47 122.7 i ,1 100 2.8 83.8
24.5 38 130 23.6 51.25 СьН8О„ А« :etylaceto ae (4°) 120 3.4 8O.8
СЛ»0„ Е thyl acet itc (31, (132) 36 .8 140 4.9 76.4
30 15.4 95.1
32, S3, 8 3, 90, 103, 121) C^ioO, sec.-Butyl alcohol 40 17.4 160 7.4 69.8
93.8 170 9.9
0 10.08 97.72 (3,2 4, 143, 14 5) 50 20.0 92.0 64.8
180 12.0 57.5
5 9.49 97.56 -10 25.2 во 23.1 89.4 185 19.0 50.0
10 8.88 97.39 0 25.0 61.8 70 27.0 85.8
15 8.40 97.18 + 10 23.4 61.7 187.5 36 6
75 30.0 83.1
20 7.94 * The ieoan iyl alcohol contained
96.99 20 20.1 63.7 80 34.0 78.8 varying amoi nts of ac tive amyl
25 7.56 96.76 30 17 2 65.0 87.7 56 5 alcohol ; the am ount preaen inthemoet
30 7.22 96.53 40 15.0 65.5 CSH,„N,0, Nitrosopi peridine heavily weight« sd curve wa¿»16%.
35 7.01 96.27 50 14.0 65.7 (36) СЛ«К,Оь, 2, 3-Dini trophenol
40 6.86 96.00 60 13.3 65.7 40 (125)
93.6
45 6.76 95.75 70 13.2 65.4 60 91.3 94.5m 6.74
50 6.70 95.47 80 13.7 64.5 80 8.4 88.8 950в
55 6.66 95.19 90 14.9 63.3 100 9.1 86.2 108.2 10.90
60 94.90 100 17.4 59.3 120 10.7 81.8 116.7 60.44
C4H,Oa, Л' iethyl propionate 110 22.3 52.4 140 20.4 70.7 120.1 20.83
113.1 (35 .7)
о
7.80
03, 148)
CíHioO, Eth yl ether (1, 8, 25,
145 26 64.8 120.4
122.2 35.13
52.15
0 150.3 45
10 6.80 41, 50, 52, 5 Г, 64, 67, Г9, 80, 94, 122.5 (3 6)
96, 97, 98, 103, 113, 118, 141, CjHioO, Diethyl k etone
20 6.10 C,H.N,O , 2, 4-Dinitrophenol
30 5.60 142 147, 156
)
0 10, 148)
(125)
°c %A %B 20 4.6
CiHsOj, Propyl forniate (156) 40 3.4 97.4 100.5m 99.02
-20 0.747
с 03, 148) - 3.8] 60 3.0 96.2 104 2Qe
0 3.39 * 80 3.2 94.9 109 6 1.95
10 3.00 to [ QA t 117.6 98.24
+35 ! 100 3.7 93.1
20 2.79 120 4.0 90.2 121.7 97.70
30 2.70 40 1.50 4.50 126.1 2.98
50 1.66 4.04 140 4.7 87.0
C,H,oO, n-Butyl alcohol («) 160 6.1 83.3 131.2 97.14
60 1.72 3.60 137.7 3.81
-2.950л 70 2.00 3.10 CsH.oOj, Valerie acid (™)
+5 80.38 9.55 16 3.5 90.4 156.0 93.35
80 2.17 2.75 170.5 8.99
10 80.33 8.91 90 2.33
15 80.14 8.21 CsH.oO,, l îthyl pro 3Íonate 182.5* 12.98
20 79.93 7.81
* % A - 0.9 828 + O.OK (Olí (").
t % В = 11.60 - 0.299e* + 0
o 03, 148) * Coneolute point above 200°.
25 79.73 7.35 0.00301e!' (")
3.41 CeHJÍjOs, 2, 5-Dini Tophenol
30 79.38 7.08 C(Hi,.S, 1 , thyl sulfid e (ЮЗ) 10 2.78 (125)
20 2.32
35 78.94 6.83 "С % В
30 2.02
92.4m 97.50
40 78.59 6.60 0 0.394 97.5Qa
50 77.58 6.46 10 0.347 C..H ,„O , Methvl butyrate 113.5 96.72
во 76.38 6.52 20 0.310 (148) 124.7 2.33
70 74.79 6.73 30 0 296 22 1.7 135.8 2.97
 MUTUAL SOLUBILITY OF LIQUIDS 389

С, HiNjOi..— (Continued) CeHsClO.— (Continued) CeHa, Benzene (>». «*• ««• 50, C, H, O, Phenol
°C %B °C %B 52, 59, 60, 93) (3, 28, 42, 56, 76, 106, 110, 112,
146.4 3.91 94.51 17.0 85.42 °c %A 117, 136, 143)
162.1 5.69 35.5 84.02 5.4QB 0.0335 °c %B
172.2 91.73 65.0 3.91 10 0.041 Om 7.2 75.4
194.5* 12.24 97.0 74.03 20 0.057 1.66mQB 7.3 75.2
* ConBolute point above 200°. 107.7 69.36 30 0.082 10m 7.7 73.85
L H;N О , 2, 6-Dinitrophenol 113.8 10.66 40 0.114 12. 2Q* 7.8 73.5
(12S\ 115.5 65.05 50 0.155 15 7.95 73.0
\ /
59.2QB 122.4 59.62 60 0.205 20 8.2 72.1
71.1 0.703 125 20.50 70 0.270 25 8.45 71.05
84.5 98.42 125.8 53.49 °C %B 30 8.75 69.9
89.5 1.00 128.2 29.16 0 0.08 35 9.1 68.5
102.6 97.80 128.7 42.57 25 0.15 40 9.6 66.8
117.6 1.87 129 (38) 100* 0.176 45 10.45 65.0
138.3 95.96 150* 0.525 50 11.8 62.6
CcHiNOj, Nitrobenzene
139.7 3.24 (14. 22^
200* 1.81 55 13.8 59.2
147.9 3.97 QQ
' • ' . R9
• ~
250* 6.04 60 16.8 55.1
158 93.44 285* 8.53 65 23.9 45.8
20 0.19f 99.78 300* 11.4 34 .0
192.5* 12.26 66.0
30
tJVJ 0.22t 99.73 * Data from («i •«).
* Coneolute point above 200°. * Solid - BiA.
55 0.27f 99.47
С H N O_, 3, 4-Dinitrophenol 100 0.80 98.60 C,H,N20 s, o-Nitroaniline
(132) C: H;N, Aniline
(126) 120* 1.6 (2, 3, 50, 55, 68, 107, 117, 131,
48m 74.91 130* 2.1 °c %B —
1S1\
140* 2.7 63Qn 97.5 /
52.5Qe - 0.62QA 3.28 95.64
73.8 70.23 160* 4.0 93.0 68 97.23
91 96.16 + 10 3.38 95.18
82 6.05 180* 5.2 92.0 15 3.43 95.06
97.5 12.79 200* 8.2 88.0 128.4 2.95
142 92.06 20 3.49 94.93
101.6 55.40 220* 15.8 82.0
25 3.55 94.77
104.6 23.28 230* 24.0 74.0 160 89.5
' 19 164.5 7.19 30 3.63 94.62
105.2 36 .5 235* mm 40 3.83 94.29
1П ~ i
.5 10.74
CeHsCIO, o-Chloro ohenol * Data from 188.5 81.88 50 4.05 93.86
(134) t Data from 60 4.40 93.4
CeHsNO , o-Nitroi >henol 194.2 17.50
- 0.3Q> 86.5 206.2 66.89 70 4.91 92.75
(133) 80 5.59 91.95
+82.9 3.76 43.5Qu 0.35 99.48 208.6 36.71
91.5 85.9 210.3 52.30 90 6.36 91.0
60 0.46 99.24 100 7.18 89.7
106.3 5.12 80 0.69 98.80 211 4Í .4
118.9 82.82 110 7.95 88.05
100 1.08 98.22 C,H,NaO , тга-Nitro aniline 120 9.15 86.0
156.6 70.62 120 1.59 97.40 (132)
159.1 13.58 130 11.05 83.6
140 2.32 96.40 99Qn 93.5 140 13.6 80.6
165.8 16.95 160 3.75 95.00
166.2 60.72 125 90.02 150 17.0 76.4
180 6.80 93.12 136.5 6.04 160 23.9 69.1
170.1 54.95 200* (10.5) (89.5)
99 40 159.9 83.60 165 (30.6) (61.8)
Ш7 .i .-— . UÏ7
* Coneolute temp, above 200°.
172.9 45 04 164.2 13.08 167.5 (46.16)
C.H..NO ., m-Nitrophenol 169.3 79.82
173 33 (133) 176.7 75.77 CeH7N, /3-Picoline (36)
С Н..С1О, OT-Chlorophenol 41.5QB 3.16 74.0 180.5 25.39 49.4 26.4
(134) 50 3.7 72.7 185.2 36.94 51.4 35.5
— 0.4mQ» 83.4 60 4.5 70.7 185.8 57.55 53.7 42.3
+3.2QB (83.3) 70 5.75 68.3 186.1 50.57 54.5 16.4
11.8 82.9 80 7.85 64.6 187.5 (48.5) 61.0 12.7
23.1 82.3 90 11.7 58.8 C, II, N..O -, p-Nitroaniline 63.3 52.3
85.25 5.12 95 15.6 53.0 Г132) 83.5 59.7
109.8 71.23 98.7 (33)
115. 5Qn 90.0 125.7 12.7
123.0 13.56 CeH6NOa, p-Nitrophenol 123.5 5.16 133.3 59.7
127.5 17.84 (133, 143) 124.2 92.52 140.0 16.4
129.1 55.65 3.26 71.2 129.2 86.82 146.5 52.3
39.6QB
130.5 46.12 50 4.37 68.5 141.5 9.29 151 42.3
130.7 38.89 60 5.46 65.8 148.6 81.27 152 35.5
130.8 :?2.02 70 7.8 63.0 167.8 68.19 152.5 26.4
С H.CIO, p-Chlorophenol 80 11.2 59.4 169.5 28.82
(134) 85 15.5 55.7 170.4 62.58 CgHsNj, Phenylhydrazine (7)
-О.ЗОв 86.5 90 25.7 45.9 172 39.49 51.07 19.8 11.6 60.1
+5.5 86.19 91.6 35.8 172.5 (47) 55.2 33.6
390 INTERNATIONAL CRITICAL TABLES

H20.- •(Continued) C..H, N — (Conlir Ufa) CeHuO, .—(Conti irted) C7H,N2O6 3, 5-Dini troben-
С, H;, O , E ;hyl acetoacetate °c %В °C %В zoic acid '(38
(79) 92.4 7.8 110 11.7 55.2 °C %B
°с Wt. B/l soin. 94 52.4 120 14.7 48.5 87m 4.4
16-16 5 12.5 112 64.7 125 17.8 40.6 96m 80.2
[soamyl formate 165 72.3 127 20.2 32.6 111.4m 10
(148) 171 8.2 128 24 .8 114m 67.4
°С %B 188 9.7 120m 60
22 220 15.0 СвНцО2, Etl lylene gly col mono- 122QB 19.8
0.3 isobul yl ether ( ")
221 60.4 122.6 50
С H О , Isobutyl acetate 225 52.4 24.5 24 .6
(148) 123.6 40
227 20--28 26 16.5 40.4 123.8 30
22 0.5 14.3 50.0
C.H. .N, 3- Methylpi peridine C7H6C10, o-Chloro jenzoic
С, H,, О., Ethyl butyrate (36) 30 12.8 53.4
(148) 35 10.4 58.8 a cid (38)
56.9 19 .2 97m 5.5
22 0.5 57.5 29.2 40 8.8 62.4
CsH.jOî, I'ropyl propionate 50 7.6 67.2 104. 3Qe
58.1 9.9 115.2 62.9
(103)
59.9 38.1 80 7.4 70.8
0 1.05 100 7.6 70.0 125.9 19.3
69.8 50.5 126.0 48.7
10 0.84 80 4.8 120 8.8 66.3
20 130 10.5 63.0 126.2 3-19
0.68 82 58.2
30 0.60 115 70.1 140 13.8 58.0 С,Н,СЮ„ m-Chloro benzoic
cja,:03) i 'araldehycle
(ЮО) 142.2 74.8 145 16.7 53.3 a cid (38)
10 12.9 99.15 143 4.8 148 20.0 47.5 116m 75.8
20 10.4 98.9 184 74.8 150.4 28 122m 4.2
30 8.75 98.7 197 9.9 123. 7Qe
CiHuO,, 1, 2-Propyle ne glvcol 136 60.2
40 7.6598.45 204 70.1 1-pro эу! ether (19.5)'
50 6.85 98.1 226.5 58.2 142 18.9
34 4 37 142.6 51.3
60 6.30 97.7 228.5 19.2 36 24.7 52.4
70 5.95 97.3 232 50.5 142.8 3'1.3
40 19.6 61.2
80 96'.8 234 38.1 50 14.8 70.0 C7HSN03> o-Nitrobe nzalde-
C,H13N, 1- Methylpi )eridine 235 29 .2 60 12.6 73.0 hj •de (128)
(35) C.H.J4, 4- Methylpi jeridine 80 10.5 75.0 39.7Qe 99.9
48.3 16 .7
(36) 100 10.4 75.2 63.8 99.0
48.5 21.3 84.9 23 .7 120 10.5 74.3 66.9 0.70
48.7 13 26 9 85.1 16 140 12.3 71.0 103.1 1.53
49.5 37.2 85.9 30 150 14.0 67.9 113.5 96.49
50.3 10.3 87.6 11.6 160 17.0 62.0 145.1 94. 8O
51.2 46.3 88.8 36.2 165 19.5 58.0 161.7 93 56
54.1 8.0 94.2 8.9 171.8 S7 166.0 4.75
55 55.9 95.5 42.4 C7HJ403, m-Nitrob(;nzalde-
61.5 65.3 106.9 49.4 CiHuOz, 1, 2-Propylf ne glycol hj
63.6 6.4 122.7 55.0 2-prop; Л ether (' 9.5) 51QB 99.6
69.5 5.8 133.0 57.5 42.6 a5 60 99.2
70.0 74.2 146.0 8.9 45 22.8 51.2 80 1.2 98.2
77 5.3 157.8 11.6 50 18.2 61.8 100 1.65 97.1
85.5 83.4 168.5 57.5 60 14.3 67.9 120 2.1 96.0
112 89.6 178.0 16.0 80 12.0 71.0 140 3.2 94.3
176 89.6 183.6 49.4 100 11.8 70.8 160 5.4 91. в
178 5.3 186.2 23.7 120 12.0 70.0 180 10.2 86.4
196 187.5 42.4 140 14.1 65.4 200 18.4 74.8
8.8
230 83.4 188.8 30.0 150 17.0 60.8 210 31 62.0
236 13.5 189.5 36 .2 155 19.2 57.3 212 (4 6)
СДиО„ Acetal (95, 137) 160 48.4
C«H,,N, 2- Methylpi >eridine 162 г5 CjHJTO,, p-Nitrobe nzalde-
(37) 25 4.4 | hj de (128)
79.3 19 .4 C, H : .O ,, Etl lylene gly eol mono- CeH,sN, Triethyliimine 97. 1Q 98.2
(3, 4 S, 110, 14 3) 132.4 2.91
79.8 13.8 n-but yl ether ( 0)
80.4 10.6 49.1 % .8 18.7 (5 0) 134.2 96.70
81 24.0 50 18.2 34.4 20 14.0 81.0 164.6 92.74
82.4 9.5 52 14.4 41.5 25 7.15 95.4 172.6 90.65
83 29.2 55 12 5 47.2 30 5.55 176.5 8.78
86.5 8.6 60 10.9 51.6 40 4.0 95.5 205.4 20.67
87 39.7 70 9.4 56.2 50 3.0 95.6 213.4 63.19
87.2 33.7 80 9.2 58.0 60 2.0 95.7 215.5 37.77
88.8 47.0 100 10.2 57 3 70 1.75 96 216 (47 .5)
 MUTUAL SOLUBILITY OF LIQUIDS 391

CvHbNO., * o-Nitrol >enzoic C7H7NO,,* o-Amino benzoic C7H,0, p-Cresol (133) СаНвОз,* 0 -Aldehyde >benzoic
a cid (3*) acid (Зв) °c % в M :id (1*7)
"C %В °C « *,B 8.7Qn 2.0 85.85 "С %В
46.2 10 62.4 9.9 20 85.0 21.1 9.38
51.6 20 49.5 73.0 67.0 30 84.25 39.2 59.48
52.0 29.8 39.4 74.6 13.5 40 2.25 83.4 43.3 20.0
CjHjïo,, m-NitroV lenzoic 75.8 59.4 50 2.4 83.0 44 40.83
acid (3, 38, 12 ») 78 30.6 49.4 60 2.70 81.5 45.75 29 2
76.7Qe 5.0 69.75 78+ 38 70 3.05 80.3 * The two-1 quid systei n ie meta-
80 5.3 69.0 * The two-ll quid syetei n is meta- 80 3.50 79.1 stable through «it.
85 5.8 67.6 stable through* >ut. 90 4.1 77.4
90 6.8 65.5 C7H7NOt, о-Nitrotoh iene (1*) 100 4.85 75.0 CsH^O,, o-Nitroac etanilide
95 8.1 62.5 138 97.79 110 5.70 72.3 (132)
100 10.6 58.8 164 2.17 120 6.75 69.0 Sl.OQn 96.0
105 16.0 52.7 197 91.90 130 8.60 64.2 99.0 94.54
108 3 (3 4) 205 5.97 140 16.0 53.8 110.2 93.65
С H 0. Bcnzaldehyde (3») 222 85.36 142 20.8 49.4 120.0 3.97
Room 0.3 230 13.33 143.5 (3 4) 157.6 8.04
231 82 05 173.1 83.47
C7H602, Be nzoic acid (3, 129) С ,H N, 2, 6-Dimethy pyridine
64m 237 77 21 179.2 11.97
3.04 (36)
238 20.77 188.0 76.28
75m 3.9 45.3 27 .2
80m 242 29.93 191.2 24.06
4.2 (79.7) 50 16.3 46.0
243 69.21 195 65.04
85m 4.8 (78) 60 11.4 55.2
245 9 1) 197 41.16
950в 7.0 72.8 70 9.8 60.9 198 (4Í .2)
100 7.8 69.0 С7Н„ Toluene ( 60) 80 9.3 64.2
105 9.2 64.0 150 0.174 100 9.4 67.2
110 13.2 57.2 200 0.605 120 10.5 67.2 с,н,к,о„ m-Nitroac etanilido
115 23.6 45.2 130 11.7 66.9 (132)
250 2.38
116 2 34 300 10.1 140 13.4 65.1 118. 5Qn 90.0
C,H,O2, o- iydroxyb enzalde- 150 16.5 60.8 130.0 5.21
hj -de (»«) C,H,0, o-Cresol 133) 155 18.9 56.7 149.2 81.18
67.4 97.13 8Qn 2.5 87.0 160 21.2 49.7 163 5 14.52
85.8 1.68 20 2.7 86.4 164.9 35 .8 166.4 73.74
118.3 93.20 30 2.9 85.9 175.7 66.03
40 3.1 85.4 C7H,N, p -Toluidin« > (156) 176.9 31.13
136.5 3.59
146.3 50 3.25 84.85 44 1.775 180 (4.5 .6>
90 56
154 0 60 3.4 84.4 57.5 2.04
5.34
70 3.75 83.8 69 2.345 CsHgNjO, , p-Nitroa cetani-
C7HeO2, т-Hydroxyb enzalde- 80 4.25 83.0 li de (»32)
hj •de (I«) 4.6
СтНи, 3eptine ( • 9)
90 82.1 17 0.211 161. 5Qu 80
(59)Qn (11.2) (60.0) 100 5.1
62 4
80.95 40 0.038 164 2 14.36
53.9 110 5.7 79.6
63.5 19.2 171.7 65.84
120 6.3 78.0 C7HUO, E eptaldeh)rde («) 172.8 25.62
65.6 43.4 130 7.0 76.0 0 0.303 176.6 54.93
66.0 29.2 140 9.5 72.2 20 0.234 177.4 42 65
66.1 31.9 150 14.9 65.5 40 0.188
66 2 (; Î5) 160 26.5 52
C7H,O2, p- îydroxyb enzalde- C7H,4Oj, Heptylic acid («•) CsH.O,, I 'henylace Ac acid
162.8 (35 ».2) (129)
h> -de (»26) 20 0.29
52.8m 13.2 C7HSO, r«-Cresol ( 133) 45.5Qu
0.0 2.2 88.6 C7H,JÏ, 1-Е thylpiper dine (3*) 84.7 5.65
60.5m 20.7
61.8m 49.8 10 2.3 87.8 7.45 г0 94.8 61.94
62.4m 26.6 20 2.35 87.0 8 14.2 47.0 106.8 39.69
27.4 30 2.4 86.2 9 11.8 52.0 108.0 20. 00
62.8Qn 46.2
63.8 42.2 40 2.55 85.4 10 10.5 57.0
64 4 50 2.7 84.5 15 7.4 73.4 CsH8O2 , o-Toluic acid
(3fÍ.5)
60 2.95 83.5 20 5.8 82.3
С7НеО„*£> -Hydroxy senzoic 30 4.0 90.1 ( 38, 133)
acid (salic ylic acid) (3, 38, 70 3.35 82.3 94Qu 2.5 91.2
80 3.8 80.95 40 2.9 92.9 100 2.8 90.0
129)
90 4.4 79.6 50 2.2 93.9 110 3.8 87.5
65 5.1 65.9 60 1.8 94.8
70 6.0 63.9 100 5.1 77.4 120 5.4 84.9
110 5.9 75.2 70 95.4 130 6.9 81.2
75 7.1 61.6
80 8.7 58.1 120 7.0 72.0 CsH.O-, o- Phthalic a Idehyde 140 9.2 76.1
85 13.0 52.0 130 8.8 68.3 (120) 150 13.5 67.6
89.1 (3 2) 140 12.2 62.0 45 4Qn 4.94 86.85 155 18.7 59.6
* The two-liquid system ia meta- 145 22.0 50.2 57.0 88.16 157.5 23.8 54.8
•table throughout. 147 35 .5 60.0 4.54 160 7 (37 .6)
392 INTERNATIONAL CRITICAL TABLES

H20.~ •(Contintted) С,НчО ., 3-] Tydroxytt iluene-4- CgHiOj, Allocinnamic acid C12H,,NO, Phenylam monium
CsHsOj, тга-Toluic acid carbox'flic acid ( 129) (91, 92) ph enolate (3
1 38, 133) °C В °C Wt. B/l soin. °C В
°с В 125.3 5.53* 18 13.63 40 4.0 91 1
92.5QB 1.6 90.4 131Qn 25 14 43 50 4.5 89 . 2
100 2.0 88.3 138.4 9.75 35 16.05 60 5.2 87.4
110 2.6 85.4 139.4 54.40 45 18.11 70 5.9 85.6
120 3.2 82.5 144.6 19.89 41.46 55 20.50 80 6.6 83.8
130 4.0 79.5 145.2 (30 .2) 65 23.43 90 7.3 82.1
140 5.9 75.0 C.H,0 , 4-1ïydroxyte )luene-3- 75 27.69 100 8.0 80.3
150 8.0 68.3 carbox;flic acid ( 129) С,Нв04,* А cetylsalic ylic acid 110 9.5 77.7
160 18.8 52.7 106.8 3.16 (as )irin) (3», 120 12.7 73 2
161.9 (3 5) 107. 8Qn °C В 130 18.4 65.3
CeHsO, p-Toluic acid 117.5 4.53 25 4.8 135 24 .2 58.6
117.7 69.29 50 7.0 140 41 .2
( 38, 133)
142. 50в 5.0 73.8 120.2 67.91 60 8.5
145 6.2 70.9 131 5 59.85 70 9.7 67.5 H2O, 3, 5- Dimeth-
150 9.4 64.8 135.6 55.16 80 13.8 60.0 oxyacet.ophenetid e (9)
155 15.1 57.5 138.5 10.21 85 18.5 52.5 35.6 4.13
157 18.8 51.4 142.0 38.85 87.4 20.0 50.0 45.6 3.55
108. 9 35 142.5 24.55 89 + 34 58.1 3.28
142.8 (30) * The two-li quid systei D ia meta- 68.5 3.28
CsH.O,, 4- Hydroxyl oluene-3- stable throughi rat.
alde hyde (126 ) CsH,NO, Acetanilic e (114) 84.3 3.55
C.H.oOj.Hy dratropic »Cid (12 9) 87Qn
87.7 96.09 83.2Qe 5.2 87
86 34Qn 99.8 4.16
99.1 2.52 5.4 101.5 80.30
137.1 92.73 87 84.4 111.1 4.92
119.9 5.00 118.4 5 50
156 5 5.47 88 83.4 143.5 60.16
90 5.8 129.2 6 68
CsHsO,, 6-1 [ydroxyto luene-3- 149.2 19.31 173.6 22.89
91 5 81.9 150 39 .31
aide hyde (126 ) 95 6.1
79.5Qu 3.0 (59.9) 96 80.5 iN„ Nicot ine Ligroin (SO)
87.2 56.0 97.5 6.6
(58, 146, 149
99.3 5.45 For vapor pressure, ». («4.5). ./ - 0.6646
118 80 22 0.227 99 5О
127 16.5 52.5 127 5 75 60.8 29
133.5 23.5 65 14.8 51.2 Gasol sne (18)
134 20 d = 0.70; B. P. =4O-145°C
136.8 35 .4 142 30 60 70 12.1 63.0
C-H-O •, 5-. iydroxytc )luene-2- 75 10.3 70.9 °C %A
143.5 50 50 25 0.0098
aide hyde (126 ) 144 40 80 9.0 75.9
69.1QB 6.9 50.6 85 8.1 79.1 35 0.0141
78.8 50.3 CjHio, Xylene 1 во) 90 7.4 80.5 37.5 0.0160
85.8 7.95 150 0.088 100 7.1 81.2
116.3 14.3 200 0.307 125 7.5 81.3 Kerosene (A merica n) (4*)
121.1 48.5 250 0.958 150 8.0 81.2 d\l = 0.792; B. P. -1 90-25OCC
124.5 44.6 CSH„N, 2, 4, 6-Trim ethylpyr- 175 10.0 77.0 - 2 С .0012
125 34 id ine (»O) 190 12.9 68.4 +18 t 1.005
С,Н80„* i>-Methoxj benzoic 5.7 17 .2 200 16.3 56.5 23 { .007
a cid (38) 10 7.82 41.66 205 ' 20.4 48.0 30 С .008
136 19.7 20 3.42 54.92 208 i2 36 (1.012
137 50 30 2.51 62.80 ), Cineole (30) 53 с .026
137.6 30 40 1.93 70.03 1.5 0.64 59 с .031
138.2 40 60 1.78 80.19 7.5 0.57 61 с .035
* The two-liquid system is meta- 80 1.73 86.12 10 0.54 66 с .043
stable throughout. 100 1.78 87.07 21 0.35 79 с .063
С .Н.О , Methyl salicylate (12 1) 120 1.82 88.98 40 0.21 85 с .075
15-30 0.1 140 2.19 89.10 50 0.19 94 G .097
îydroxyti jluene-3- 160 2.93 87.2 C12HnN, D iphenylanline (14)
carbox ylic acid 129) 180 3.67 150 97.3 Paraffii \ oil («)
120.3 69.52 C-H .N, 1-P)•opylpipei idine (3S) 175 95.5 d\l = 0.883; B. Р. =200-300°С
129. 2QB -30 3.2 200 93.2 at К ) mm.
131.8 5.07 +0.5 2.7 230 1.5 90.0 16 0.003
143.0 59.73 9.5 97.4 250 2.0 88.0 50 0.013
149.3 10.18 11 1.4 270 4.4 85.6 65 0.022
151.3 50.51 15.5 97.9 290 11.6 77.2 73 0.030
153.3 29.81 30 98.4 300 22 66.2 77 0.035
153.5 (31 .5) 32 0.6 303 44 94 0.055
 MUTUAL SOLUBILITY OF LIQUIDS 393

VARIATION OP THE CRITICAL SOLUTION TEMPERATURE (°C) WITH IШ.С1 Cu

PRESSURE (14e) В = AlCl, (85) В = Cu,S («)
°c %A °c %А
B-component °C kg/cm1
Др 192. 5Qt 0.08 | 94 1150 3.7 94.8
-0.008 1200 4.7 91.3
CH,NOS, N itromethan e 103.3 1-150 91 0
-0.02 1300 7.2
CjHsN, Pro pionitrile 111.0 5-165 ГïH4Br 8.1 81.7
160.3 20- 64 -0.21 1425
CiH»Oj, Me thylal в = AlBr, (65) 1485 72 79.9
C4H<N,, Si iccinonitrile 52.3 10-160 -0.003 >0.092 9.0
98Qt
159.5 8.7 Ag
CAO, Methyl ethyl ketone 0.093
160.5 В = AgCl (io*)
Lower / 0.30
236.5 1000 0.1
°C kg/cm* °C kg/cm*
Др Др
-13.8 78.2 37.3 700 0.071 SbCl, AgCl
- 6.1 150 0.107 44.1 800 '0.068 В = SnCU (65) В = A1CU (6S)
- 0.7 225 0.091 51.3 900 0.072 °C %B 192. 9Q* 0.75 18.6
-4- 7.8 300 0.095 61.6 1000 0.103 243. IQt 1.2 89.6
16.05 400 0.083 66.9 1050 0.106 В = SnCl«t (86) AgBr
23.2 500 0.072 80 1085 62.9 39.1 В = AlBr, (65 )
30.2 600 0.070 63.0 67.9 105.9QAB, 1.2 12.6
Upper t 64.5 64.4 120.4 2.2
141 136.8 132.8 86.5 65.4 56.4 139.7 12 0
°C
1075 65.9 48.7 156.3 3.2
kg/cm1. . . . 10 78.2 150 10.8
159.7
At -0.062 -0.052 -0.050 161.9 3.6
Др SnCl2 173.0 9.8
В = AlCl, (85) 183.6 5.5
B-component °C kg/cm1 7 1
Zp °C % A 186.0
С,Н,0„ 1в<íbutyric ac d 2(Í.4 1-525 -0.055 192. OQt 2.1 19.1
С ,H ii.O, Is« )butyl aleo loi 134t.2 10-180 -0.03 SnBr2 AlCla
С ,H O, sei .-Butyl ale ohol IK !.8 1-800 -0.07 В = BaCli (65)
-0.05 В = AlBr, (65)
С H n 0 , Ьlovaleric ac id .. 91i.O 5-60
161.0QAB] 1.9 14.7 °с %B
»-Nitrophei ю1.... & 1.3 1-120 +0.01 191. 50л2в 3.1 18.9
10-1000 0.00456 169.1 2.2
СбН.О, Ph « i.09 185.4 13.7
CsHyN, An ¡line 161 10-210 0.009 В - Na Cl
-0.009 187.3 3.6
lenylhydrazine 7< i.5 (sic) 5-155
198.0 4.9 193. 5Q* 0.09 8.8
11 5.35 5
201.4 11.1
2!2.36 200 +0.205 10.7 В = КС1
21 ).19 600 0.171 202.4
CJBiJü, Tiriethylamine 204.5 8.7 193Q* 0.22 11.1
3- 1.26 1000 0.127
31 ).40 1500 0 103 AlBrs
4 Î.45 2000 0.080 PbBr2
0.006 В = CaBr, (85)
C7H«N5O6, Dinitroben zoic acid . 12 3.3 10-110 В = = AlBrs (65) 208. 8Q* 0.6 10.9
C7HSN04, m-Nitroben zoic acid . 10 7.3 5-125 0.008 210.4QAB, 1.1 21.0
С H, 0 , B.enzoic acid 11 3.5 5-200 0.0025
0.0045 В = BaBr2
4, 6-Trimet hylpyridini 1.3 1-200
269.4Q&,B 1.0 17.5
Nicotine . . . 6 1.3 1-200 0.01 T1C1
В = = AlCls (85) I i = NaBr
Sec. 2. ' Che key-formula of ne ither comp jnent begin s with 16. 192. OQt | 2.1 236
95. 4Q* 1.0 7.0
Standard iarrangement (v. p. vii i). 110.9 1.2
02 NH3 TIBr 125.6 6.5
В = Na (70, til) 166.4 1.6
В = Oj(108, 119)
i Го В в . = AlBr, (85) 166.9 6.1
"С %A °c 103. 9Qf >0.64 23.9
-158 Consolute temp. -72 16.6* 0.64 23.5 202.7 5.4
118 222.1
-183 30 -65 13.6* 22.5 2.2
260 230 4.3
—ou 2.15 10.9
S02 -55 2.5 10.0 231.9 3.2
В = KI(155 ) -50 3.0 8.9 HgBr 232 3 .25
°C 9 3B -46 3.6 7.8 В = АШГз (85)
77.3 L2 -42 4.7 6.2 1.9 34.9 ]В = КВг
238.1QAB 98. IQ* 0.18 11.2
78 8.5 15.0 -41.6 5.4 275.5 3.5
80 6.8 17.6 «According to (Mt).
189.6 9.7
21.1 t Solid = double compound, 265.9 0.39
84 4.5 t The two-liquid system is meta-
88Qu 2.7 24.0 Btable throughout. * Solid ** double compound.
394 INTERNATIONAL CRITICAL TABLES

Sec. 3. TI ie A -com; >onent key -formula does not begiii with 16. В = С; Н., Naphtha lene (") ]MgBr2
The B-comp onent key -formula b egins with 16. A -comilonents in °c A В = С «Н 100, Ethy 1 ether
standard arr ïngement ; В -compon ents in (Г -arraïngement [v. p. viii). 132.8 25.4 (87)

S В = C,H 14. (Cotll ,mued)

190.0 44.2 79.7 °c В
°c A 195.0 47.6 78.0 -10 58 98.2
В = C4HJIS, Musts rd oil (3) 200 52.8 75.0
-20 15.5 96.7 0 59 97.7
°C В 202.7 64 .3
10 20.7 96.1 + 10 59.9 97.2
80 73.4
0 27.3 95.6 В = С, ,Н -, Decane (*») 20 60.7 96.7
90 10.5 69.8
100 13.0 66.0 + 5 34.2 95.4 Consolute temp. = >300°C 22. 8Q*
8 42.0 94.0 В = С ;H i , Phenantl irene (sl) 30 61.3 96.2
110 16.8 60.8
10.1 71 °с A 40 61.8 95.7
120 23.6 51.4
В = C8H,8, n-Octane (1<J2) 198 74.7 50 62.2 95.3
125 36 .5
199.1 66.6 60 62.4 94.9
В = CsHs' Л, Chloro benzene В = C,,E [J2, Ceten в (l24) 199.2 47.4 70 62.4 94.6
67 81.2 - 2.2Qu 12.0 97.1 199.5 49.5 80 62.3 94.4
90 15 69.6 0.0 13.6 97.0 200 56 .7 90 62.1 94.3
100 20.5 63 6 + 10.0 21.2 96.7
110 27.3 55.7 20.0 30.4 96.0 SbBr,
117 42 30.0 39.8 94.0 В = СИ, . Cycloheji ane (89)
35.0 44.7 92.0 92.5 17.4 97.6
В - С H, , Benz ene 40.0 52.8 87.8 ПО 25.8 96.5
86 78.5 42 0 59.0 84.0 130 36.4 95.0 MgI2
100 8.0 74.5 42.7 72 .0 150 47.8 92.7 В = С H, О , Ethyl e ther («»)
ПО 10.0 71.2 170 62.3 86.3 14.8 64.5
120 11.8 68.0 NH3 175 74 .0 18.6 86.43
130 13.6 64 В = С¡sHio, m-Xylene 20.0 64.2
140 15.6 59.7 °c %A SbCls
23. 6Q*
150 18.0 53.9 -33.5 1.73 96.61 1.0 CjHi2) Cvclohex ane 24.4 85.4
160 25.9 43.7 + 8 17.36 70.09 5.5 1 88", 89) 28.4 64.5
162.8 34 .8 10 19.63 65.46 5.8 70 13.7 97 32.4 84.18
12 22.04 60.43 6.2 80 19.5 96.1 33.0 64.3
В = С H, N, An line 100 32.3 92.7
14 29.00 52.89 6.7 37.3 80.6
72 85.9 120 57.1 83.2
14.7 41.23 6.85 38.0 67.2
100 6.0 76 124 58.9 76.7 38.5 72 .5
110 8.6 71.2 125.5 68 * Solid - ABi.
120 11.3 64.7 ВГ"в /SI
1
130 15.4 54.5 °C A VARIATION OP THE CRITICAL Sot Спок TEMPERATURE (°C) WITH
135 20.3 45.2 -7.8 9.4 PRESSDI IE ("в)
138 31 6 7 46.1 85.2 At
В = С 7H„ Toluene -6.6 50.3 82.3 Components °C kg/cm« Др
°с A 55.6 77.9
-6.4 62.0 70.3 S
60 22 В = C,,H5C1, Chlorobenzene 117 5-85 -0.025
100 30 94.0 -6.38* 65 .7
SO,
но 31.6 93.0 * -8.5° (")
В = С, Hi:, Hexane 11.9 10-130 -0.023
120 33.6 91.8 , Ethylen s bromide
(51) В = C|i,Hj;, Diisoamvl 34.1 10-130 +0.03
130 35.8 90.5
140 38.8 88.7 151.7 77.9 Sec. 4. Во h A- and B-compon ent key-formialae begiii with 16.
150 43.5 86.4 162.0 52.9 (¿-arrangera jnt for both compon silts i r. p. viii
160 49.0 83.7 163.0 36.9
34.2 CC14 В = CH,О.—(Сол '.inued)
170 56.0 80.2 165.0
179 5 70 165.5 45.6 В = CH2Oj , Formic acid (44) °c % A
169.6 31.4 °с %A 20 53.3 97.2
SO2 Consolute temp, ca . 165°. 25 6.5 96.7 25 57.3 96.0
В = CeHi:, Cyclohex ane (69) 30 62.7 94.0
В = CeHJBr t, p-Dibr amoben- CS2 35 72.7 88.9
-17QA 9.0 96.0
z ene (51) В - СН О , Formic acid (44) 36.5 8C .8
10 11.5 94.0
154.3 26.7 25 4.45 98.7
- 5 13.7 92.8 В = C2H( O, Ethyl alcohol
159 33.1 55.3 (4 7, 72, 86)
0 16.7 91.0
161 36.4 52.3 В = СН«(), Methyl alcohol
+ 5 22.7 87.2 (2Í , 86, 110) -108.04 99.09
31.7 78.4 163 45 .1
10 1ПП 32.0 99
12 38.5 72.1 В = C.H4C1, -73.6 18.7
-38.7 28.8 - 80 38.5 98.7
13.5 55 .6 p-Dichlorobenzene (51) - 60 46.7 98.0
-IS ЯЧ 99.64
Consolute temp. = 163°C 4 АО - 40 57.4 96.1
В = С H , n-Hexai .. (123) 41.3
В = С„Н6С1 98.74 - 30 67.1 93.0
-73.5QA 99.2 + 6.46
99.0 Chlorobenzene (sl) 10 47.7 98.4 - 26 76.3 87.6
-60
-30 11.3 97 2 Consolute temp. = 264°C 15 50.2 97.9 - 24.3 es'.3
 MUTUAL SOLUBILITY OF LIQUIDS 395

<DHBr,, B = Cot :onseed oil (44) В = Tt rpentine oil.— В = C,H,C i, Salicyli ildehyde
В = CHsO , Formic acid (44) °C %B (C iii/iitiii'rh (85)
«с % A 25 7.79 95.0 °c %A °c %A
25 20.2 97.8 74.0 10.16 88.53 100 92.8
(s-¿H.4\Jz 94.8 19.50 110 3.2 90.8
(^HsOo A« :etic acid 95.3 80.54 120 4.7 88.7
Fo rmic acid B =1 kerosene (44) 101.9 27.79 130 6.3 86.6
В = C.E t, Benzen e (33) °C %A 104.4 68.90 140 8.0 84.2
"С % В
25 17.8 88.8 105.6 33.89 150 10.0 81.3
3.8 10.2 B = Cottonseed oil (44) 107.9 57.44 160 13.6 77.0
25 14.1 90.4
eo %B 108.2 50 22 170 22.2 68.0
30 15.1 89.6 25 5.3 64.2 175 30.0 59.8
40 17.8 87.0
< :,н,о 176 6 44 .8
50 21.0 83.4 (*/2-НбО íAcetone В = C,H «О, Anisole (85)
60 Ett iyl alcoho 1 В = C,H, Oj, Glyce rol (84) °c
25.7 77.9
10 10.9
%В
70 35.1 68.6 B = CiH« 4t, Succir onitrile 160 5.6
(lie) 20 12.3
73.2 51 .8 180 10.1
<*«)
°c % A 30 13.7 200 14.6
25 87.3 13.4QB 20.2 40 15.1 89.6 220 19.2
13.1
13.5 87.5 50 16.8 88.6 240 24.2
В = C7I [„ Toluene (44) 87.7
19.3 25.0 60 19.0 86.4 31.5
°с %A 20.0 84.0 70 21.3 83.0
260 80.7
25 9.9 91.6 270 38.2 73.8
24.6 80.1 80 25.1 78.0 275.5 ó6
В - Cst[,„, Xylene (4«) 28.2 75.1 90 34.0 69.8
25 8.04 93.2 29.2 95 44.0 59.5 В = C7H, -'.-, Guaia COI (»S)
39.8
В = Kerosene (««) 30.8 51.1 95.7 51 .7 °C %A
25 0.89 98.4 31.2 59 .2 39.5 44
С'aHgOs 40 37.2 52.0
В = Cotítonseed oil (44J B = СШаС :i2s, DÍ-ÍÍi-chloro- < îlycerol 45 28.5 66.6
°С %B ethyl) suifide (musti ird gas) в = сш.о 50 25.2 69.5
25 0 76 92.0 (139)
Ethyl me thyl ketoi le («4) 55 23.7 70.4
•G % В
CHJ °C %В 60 23.5 70.7
6 45.3 40 4.0 65 24.1 70.4
Mel ,hyl iodid в 7 46.6
В = С>Н JT, Pyrid ine (4) 50 4.5 92.2 70 25.6 69.4
8 48.3 60 5.2 91.8 75 28.3 67.3
"С % А 9 50.4
78.4m 32 17 80 6.8 90.2 80 32.5 61.8
10 52.9 100 8.6 89.4 82 35.7 54.0
79m 29.23 11 56.0
80.4m 23.92 120 9.8 88.0 83 . 5 4Î
12 59.7 130 11.4 84.0
81. OQ* В = C7H9 N, Mcthy laniline
13 64.1 140 13.6 80.4 (99)
86.6 16.94 14 69.1 94.2
87.0 37.31 150 17.0 78.6 190 85.5
15 75.9 90.1 160 32.0 64.4
117.0 42.90 15.6
200 11.2 84.3
К .5 164.5 48 .4
* Solid - AI J. 210 15.4 79.9
В = C«Hio, n-Butane (") В = С,ДП0 , Isoamj 1 alcohol 215 19.5 75.3
CH4O Consolute temp. = 37.5°C (84) 220 26.5 67.4
Met hyl alcoh< jl 20 2.6 81.8 224.5 46
В = CtHií, Isopentane (™)
В = C«H i2i Cyclol lexane Consolute temp. = — 30°C 30 4.7 78.5 В = С7Н9Г< , o-Toluk line i9»)
(
Г5, 92.5) 40 6.8 75.2 100 7.8 87.6
°c % B В = C7HsN60,, 2, 4, 6,-Tri- 50 8.9 70.7 110 8.8 86.8
16 31 nitrophenylmethylnitramine
(20.1)
60 11.0 63.8 120 10.7 85.2
21.8 95.9 70 17.2 53.2 130 13.9 82.2
29.0 38.3 Consolute temp. = 105°C 74.2 34 140 18.4 77.2
38.5 91.0 В = C.H .N , О,; В — С?Нб O, Benza dehyde 150 26.6 69.7
39.9 50.6 Trinitrotoluene (20) (85) 154.4 4"'.2
47.0 81.3 Consolute temp. = 96.5°C 67.5 4.5
47.2 В = C,H ,N, то-То uidine
62.7 85.5 97.0 (99)
48.2 77.6 В = Cott onseed oil (161)
°C %B 90 5.2 96.6 6.7 46
49.1 71 100 7.2 95.6
25 8.45 81.3 10 28.0 69.5
В - C.H и, Нехаш ,(110) 110 9.0 94.1 20 19.5 84.4
10 26.5 96.8 С 2H604S 120 11.6 92.1 30 16.6 86.7
20 31.6 95.9 Dime thyl sulfa te 130 16.2 89.2 40 16.0 87.2
25 34.7 95.1 В = Turpentine o U (29) 140 21.1 85.3 50 16.0 87.6
30 38.3 93.7 °C %A 150 27.7 79.5 60 16.0 87.0
35 43. в 91.2 25.2 2.80 155 33.9 73.7 70 16.0 86.0
40 52.7 85.5 38.0 93.99 160 48.0 60.0 80 16.2 84.3
42.6 68 9 50.3 5.28 160.7 54 .1 90 17.0 81.7
396 INTERNATIONAL CRITICAL TABLES

CsHgOs. —(Согйг nued) С (HgCljS °C %A B =CeHu—(Coni inued)

В = СтН Д.—(Con United) Di-(2-chl oroethyl) sulfide -1 36 88.5 °c %B
°с %A (muistard gas ) 0 36.5 88 15.5 29 72
100 19.8 77.8 В = l.¿groin ' ' 40) +1 37 87.5 16.1 67.21
110 25.4 71.2 В. P. = >1 00°C; d% = 0.6677 2 38 87 17.7 34.21
115 29.5 66.2 °С %A 3 39.5 86.5 18.7 57.29
120.5 47 9.00л (31.5) 86.4 4 42 85 21.02 48 43
9.6 84.5 5 44 84
82.5 CeH6
В = С,Н iNO, о-Аг isidinc 10.3 32.5 6 48
7 55 80.5 ] ienzene
(99) 12 82.6
°С 14 80.9 8 (65) (77) в = сл.о г, Resorci ttol («<•)
% В °c %A
141.0 34.25 14.5 39.3 8.3 (72 .5)
40m 16 60
142.5 73.09 16 43.7 50m 18.16
17.22 76.1 СбНю
143.0 43.57 60m 20 04 95.41
144.5 51.69 17.5 49.4 ¿onylene
В = C.H .N, Anilii IB (•») 70m 22.46 93.36
145.0 61 25 18.3 56.8 80m 25.51 90.73
19 (66) "С %A
01 ч 18.5 90m 29.02 87.20
В = СцН8О, Acetop henone
(84) В = G asolene ( 140) +3.9 79.8 95.5QB
В. Р. = 60-180 °c 10.1 71.8 100 34.17 81.30
90 97.2
96.4 4.2 30.08 10.7 28.5 108.9 58 .1
100 4.7
110 5.6 95.6 4.5 30.14 14.15 39.6 B = C.HJЧг, та-Phe nylene-
120 6.7 94.3 7.3 87.34 14.3 52.3 diät nine ("O 1
130 8.0 92.6 7.8 87.17 14.5 48 .4 53.8QB 25.00
140 9.7 90.4 9.0 36.46 54.7 25.16
150 11.8 87.9 9.5 36.51 CiHii 55.5 25.44
160 14.6 84.5 13.5 46.21 Isopentane 58.8 27.86
170 18.4 79.3 14 46.32 В = CeHjNO, 59.8 80.64
180 26.3 70.2 18 77.53 Nitrobenzene (144, »45, 146) 60.0 28.96
185.5 48 18.7 53.49 Consolute temp. = 32.6°C, 64.2 34.09
20.4 66 02 with 50.37% B in solution 66.5 38.40
в = cja. loOi, Mon oethyl В = Kerosene ( 140) В = C«H eO, PheniЛ (") 68.8 49.09
ругос atechol (! 0) °С %B 69.0 60 96
I°C
172.5 20.0
8.9 91.88 17.55 12.41 в = cja 10N:O, m- Mono
175 21.1
9.5 33.13 26.60 91.87 acetylphen) lenediam me (»s»)
180 23.8 82.6 29.35 16.95 °C Я B
185 27.6 76.3 14.2 39.79
14 3 89.68 39.15 86.10 184. 9Qu 77.5
190 33.5 68.0 49.20 24.58 188.4 76.86
192.9 49 .5 21.9 84.93
24.3 81.42 54.95 28.46 193.4 76 16
25 68.67 55.85 73.86 201.9 74 65
1Í — Сь*~* i iN, Dime hylani- 60.75 35.70 227.8 68. 9O
1me (в») 25.6 75
62.25 45.33 228.5 22.75
°с %A В = Raun>ad light < >il (1*0) 62.55 61.92 257.6 57.03
200 8.0 В. Р. = 160-301)°C 63.25 52.15 263.4 39.10
220 10.6 90.6 9.3 21.64 63.5 SI .0 265.1 49.23
240 13.3 87.7 14.5 24.33 265.5 44.31
260 16.2 84.4 В = CiaHiiN, Dipheilylamine
20.9 29.88 (13) 266 (46 4)
270 20.1 80.3 23.6 38.49
280 29.0 71.4 "С %A B = C»H 10N2O, p- Vlono-
25.0 90.78 15т 13.0 87.0 acetylphenj 'lenediam me (»s«)
285 38.3 61.8 28.0 88.74
287 50 20т 16.4 84.7 146. 8Qu 74.0
31.3 86.58 25т 19.4 81.7 147.1 72 71
33.0 47.95 30т 22.5 80.2 150.1 71.05
В == CíHisN 35 54.48
Ethylbe nzylamine (»•) 35т 26.8 77.9 155.9 67.66
37 63 .8 40т 33.8 72.0 163.5 63.07
"С %В
50 34 41. 9Qa 37.2 68.9 170.0 59.95
С4НюО 42.5 40.3 67.4 180.8 17.36
60 5.8 72.8 Ethyl ether
80 3.6 86.8 44.9 54 .2 181.3 51.70
В = С H, , Chrysene 186.3 41.23
100 3.5 88.8 (12, 144, 145) С (HbNOz
140 4.4 88.2 187.8 30.12
Consulate temp. = 207- Nitrobenzene l 188 (35 .3)
180 6.5 86.2 218°C with 21 % В in solution - С..Н i :, Hexane ( 143, 145)
220 11.6 84.2 °с (:eH6o
260 21.5 81.5 %B
Chlorinated mustard oil -0.2 17.76 Phenol
270 26.5 79.2 B. P., 112° at 17mm; dJS = 1.355 +5.0 80.08 B = C¿E u, Hexan e (»4)
275 31.0 77.5 В = Railroad light oil (»40) 5.8 19.47 14.40 17.58
281 56 14.0 70.94 20.75
B. P. = 160-300°C 88.57
 MUTUAL SOLUBILITY OF LIQUIDS 397

В = C.H „.—(Coni inued) C;.H,..., Isopentane (I7) Ai

°c Components °С kg/cm2
V ,B Consolute temp. = 77°C Др
29.20 83.94 В = С, H. CH..O,, Formic acid (146)
31.70 26.11 Methylcyclopentane (i7) В = С H CI, Chlorobenzene 106.6 5-65 0.035
34.20 29.98 Consolute temp. = 35°C В = C.H. , Benzene 82 5-65 0 03
37.00 68.78 В = С, H 1 1, Hexane (l 7, 26, 66) CH2I:, Méthylène iodide (I46j
37.65 40.20 64.96
38.65 41.64
°c % A В = С .H : О, Ethyl alcohol 93 8 5-75 -0 004
20 7.2 В = С H-O, Propyl alcohol 75.7 1-100 +0.006
42.15 50.14 В = С H-O, Isopropyl alcohol 0 012
30 10.0 89.6 93 2 1-200
42.5 51 В = С |H i..O, Isobutyl alcohol
40 14.0 86.8 77 5 1-80 0 012
В = C,H it, Heptai 1C (14) 50 23.1 80.6 В = C.H-., Cyclohexane 34 5 5-120 0 01
13.20 23.81 55 29.0 74.8 В = C.H., Hexane 105 4 5-155 -0.02
14.45 79.36 58 37.6 68.0 В — CiuHî2, Diisoamyl 119 5 5-65 -0 015
17.95 74.02 59.6* в2 CH,O, Methyl alcohol
20.05 65.41 В = СеНм, Isohexane (") В = CtHio, n-Butane (73> 146) .. 16 6 20-150 +0 007
22.05 33.31 Consolute temp. = 73.8°C В = СШю, Isobutane (!«•) 20 1 10-140 0 004
23.40 43.69 В = С . H i ., Cvclohexane (l 46) 59 5 50-1000 0.0227
B = C;H| ;
23.50 45 .8 В = C«Hi4, Hexane (146)
Dimethylcyclopentane (l7) 42.2 1-105 0.032
В = С.Е tie, Octan 0(14) Consolute temp. = 45°C B = C, H.Br, Bromonaphthalene
19.65 14.0 (146) 62 5-195 -0 025
B = C;H .
22.6 15.1 86.7 B = C,oH22, Diisoamvl (146) 86.8 10-150 +0 04
Methylcyclohexane (l7» 146)
25 16.0 85.3 С H ;O., Acetic acid
30 17.8 82.4 Consolute temp. = 35°C
B = C7H,e, Heptane (l7) В = Ci.H.Br, Bromonaphthalene
35 20.2 79.2 (146) 42 5-210 0 025
40 23.6 74.3 Consolute temp. = 70°C
45 29.4 66.8 B = C7Hie, Isoheptane (l7) C2HtO, Ethyl alcohol
48 36.5 58.4 Consolute temp. = 72.8°C В = C«H<Nt, Succinonitrile (146) . .. 24.3 10-160 -0.005
49.5 47 B = CeH„ С H .N, Propionitrile
Dimethylcyclohexane (t7) B = С H , Diisoamyl (146) 55 1 1-150 +0 016
с:eH6o2 Consolute temp. = 49°C СзН6О, Acetone
В = С,., H.., Diisoamyl (14в). . 18 1-90 0 01
Resorcinol B = CeH.s, Octane (")
в = cja, g, m-Xyleile (13) Consolute temp. = 72°C С ,H ,N ., Ethylene cyanide
°с %A B = CsH,s, Isooctane (l7) В = CiHioO, Isobutyl alcohol (>*•). . 67.0 5-155 -0.004
60m 2.95 88.2 Consolute temp. = 74°C C«H,o, n-Butane (146)
70m 3.80 87.1 В — С, H. .NO-, Nitrobenzene 28 3 15-150 -0 04
80m 4.77 85.5 В = С, H .N, Aniline 83 15-90 -0 08
90m 6.35 83.9 c,oH7NO2 CtHioO, Isobutyl alcohol
100m 7.75 82.3 Nitro naphthale ne B = C,.H;Br, Bromonaphthalene
100. 3QA 8.1 81.8 B = ]Paraffin ( l4) ("•) 8.6 1-180 -0 01
110 10.1 80.2 ec %B С .H ,,,, Amylene
120 12.9 77.3 43.4 11.65
1:30 16.5 73.9 B = C.H N, Aniline (146) 21 8 1-165 -0 02
54.0 94.52 С H , , Isopentane
135 19.2 71.4 59.0 16.65
140 22.3 67.6 B = C,.H:.NO,, Nitrobenzene (144,
72.0 92.01 l«) 32.6 1-300 -0.026
145 28.4 59.7 75.0 25.01
148.7 43 .6 76.0 91.32 CtHbNOj, Nitrobenzene
B = CeHu, Hexane (143, ив) 20.81 1-825 -0 008
90.0 36.10
CeH7N 45.38 20.8 1-825 -0.01
98.5
Aniline B — CiuH..-,, Diisoamyl (146) 28 37 1-1225 -0 ООН
B = СьНю, Cyclopentane (l7) 99.0 83.97 B - Petroleum (14в) . ..
101.0 74.33 13 95 1-725 +0 0014
Consolute temp. = 18°C С с, H., Benzene
102.0 54.54
B = СьН12, Pcntane O7) 103.0 6Í ).5 В — СсН, О , Resorcinol (14«) 109.1 10-170 -0 03
Coneolute temp. = 72°C »89° (l'); p - T. С H, О., Resorcinol
В = С.Н .„, Ethylbenzene (146) 151.5 5-65 -0.025
C6H7N, Aniline
VARIATION OF THE CRITICAL Soi JUTION TEMPERATURE (°C) WITH В = СШи, Cyclohexane (". 14в) 32.37 1.8-250 +0.0068
PRES .SURE В = CtHu, Methylcyclohexane (146) 41.3 1-140 0.003
A< В — CioHit, Diisoamyl (14в). 82 5-180 -0 001
Components °C kg/cm1 Др C7H9N, m-Toluidine
CO¡ ("в) В = С „Л.:, Diisoamvl (146) 38.5 10-75 -0.003
В = CtHJÏOi, o-Nitrophenol 24.8 83-1275 0.33
CS, (»4 »)
В = CH40, Methyl a! cohol 48.5 5-85 0.015
В = С,НвО, Acetone. -39.5 10-110 0.01