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om
A D B A C B B B C A ABC AC
Q 56 57 58 59 60 61 62 63 64 65 66
A BC B C D D D B B B C A
c
(1) (A). (3) g. (A). 9a + 3b + c = 90
ng
ak = (k2 + 1) k! = (k (k + 1) – (k – 1)) k !
= k (k + 1) ! – (k – 1) k ! c
3a + b + = 30
ye
So k (k + 1) ! – (k – 1) k ! 3
a1 = 1 . 2! – 0 Now using GM ≤ AM for 3 numbers 3a, b and c/3
.m
a2 = 2 . 3! – 1 . 2!
a3 = 3 . 4! – 2 . 3! c
1/3 3a + b +
c
w
M ≤ 3
ak = k (k + 1) ! – (k – 1) k ! 3a.b. 3 3
w
––––––––––––––––––––
w
a1 + a2 + ...... + ak = k (k + 1) ! 30
Hence b k = k (k + 1) ! (abc)1 / 3 ≤ = 10
3
://
∴
bk k(k + 1)! k(k +1) k2 + k log a + log b + log c ≤ 3
⇒ log a + log b + log c |max = 3
ht
a100 10001 m
∴ b = 10100 = n ∴ (n – m) = 99 (4) (D).
100
n
f(x) π π nπ n π
(2) (A). Consider a function g(x) = (1 + i 3)n = 2 cos +isin =2n cos +
isin
x 3 3 3 3
as f (x) and x are differentiable hence g (x) is also differen-
tiable. nπ
f ((1 + i 3) n ) =realpartof z =2n cos
f(a) f(b) 3
Now g(a) = and g(b) =
a b 6a
nπ 6a nπ
f(a) f(b) ∴ ∑ log2 2 n cos = ∑ n +log2 cos
Since = ∴ g (a) = g (b) n= 1 3 n =1 3
a b
Hence Rolle’s theorem is applicable for g (x) 6a(6a + 1)
∴ ∃ some x0 ∈ (a, b) where g ' (x) = 0 = + ( − 1 − 1 + 0 −1 −1 +0)
2 144424443
a suchterm
xf ′ (x) − f(x) x 0f ′ (x0 ) − f ( x 0 )
but g ′ (x) = , g ′ (x 0 ) = =0
x2 x 20 = 3a (6a + 1) – 4a = 18a 2 – a
∴ x0 f ' (x0 ) = f (x0 )
1
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x
1 π/ 2
= [e (cos1+ sin1) −1]
2 x +1
Let = u ∈ (1, ∞) as x > 0
dy x
(6) (A). − y = 1 −e − x , I.F. = e–x Consider h (u) = ln u + 1 – u
dx
1
∴ y . e–x = ∫ (e− x − e −2x ) dx h'(u) =
u
– 1 < 0 in (1, ∞)
Hence, g (u) is a decreasing function in (1, ∞)
1
y.e− x = −e− x + e− 2x +C
om
h (u) < h (1)
2 h (u) < 0
If x = 0, y = y 0 ∴ g ' (x) < 0 ⇒ g is decreasing
∴ f is increasing and g is decreasing
c
1 1
y0 = −1 + +C ⇒ =y 0 +
g.
C (9) (B). m = 5 . 5. 8. 7 = 1400
2 2
ng
−x −x 1 1
+ e− 2x +y0
5 5 8 7
∴ y.e = −e + n = 1400 – (5 . 8. 7) = 1400 – 280 = 1120
2 2
ye
If x → ∞ , then y 0 = –1/2 0
(7) (C). 1400 5
⇒k= =
.m
A = ((5 +2 6) ) 2 1/4
=(5 2+ 6) 1/2
[(= 3 +2) ]
21/2
1120 4
(10) (ABC).
w
8 6 16
A= 3 + 2 , B=8 3 + + + ,∞
Hence, ........ x x
f(x) = ∫ e sin(x −t)dt = ∫ e sin(t)dt
t x− t
w
3 3
0 0
w
8 6 21 8 3 (8 3) 3
r= . = ∴ B= = x
− 3 − 2
://
f(x) = ex ∫ e − t sintdt
3 8 3 3 1 ( 2 / 3)
B = 24( 3 + 2) 0
tp
2 4 ( 3 + 2) 0
( 3 + 2 ) ( 3 − 2 ) x2 + x +C =0
( 3 + 2) f ' (x) = sin x + f (x) .......... (1)
x2 + 24x + C = 0 ........ (1) f '' (x) = cos x + f ' (x) = cos x + sin x + f (x)
[Using (1)]
Now, | α − β | =(6 6) k f '' (x) – f (x) = sin x + cos x .......... (2)
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x + y = 2 ⇒ (A) is correct ( | z | – 2) ( | z |2 – | z | – 2) = 0
uuur ( | z | – 2) ( | z | – 2) ( | z | + 1) = 0 ⇒| z | = 2
Now, AB = ˆi +kˆ
or | z | = – 1 (rejected)
ˆi ˆj kˆ
uuur r r 2
Now AB × V = n2 = 1 0 1 Now, if 0 < | z | < then equation (1) becomes
3
1 − 1 −1
| z |3 = 4 – 3 | z |2 ⇒ | z |3 + 3 | z |2 – 4 = 0
r | z |2 ( | z | – 1) + 4 | z | ( | z | – 1) + 4 ( | z | – 1) = 0
ˆ − 1) ⇒ rn = ˆi + 2jˆ − kˆ
n 2 = ˆi ( 0 + 1) − j(ˆ − 1− 1) + k( 2 ( | z | – 1) ( | z |2 + 4 | z | + 4) = 0
( | z | – 1) ( | z | + 2)2 = 0 ⇒| z | = +1 or | z | = – 2 (rejected)
n2 = AB × V Hence, | z | = {1, 2} where | z | = z1 + z2 + z3
2x + 2
(13) (C). f (x) = ln (2 + x) – is continuous in (–2, ∞)
x+3
^ ^ ^
V = i –j – k
^
B(j) 1 4 (x + 3) 2 − 4(x +2)
f ′ (x) = − =
P2 x + 2 (x + 3) 2
(x +2) ( x +3) 2
om
r x 2 + 2x +1 (x +1) 2
Hence equation of P2 is ( r − ˆj).(iˆ + 2jˆ −k)
ˆ =0
= >0 (f ' (x) = 0 at
=
c
r ˆ ˆ ˆ (x + 2)(x +3) 2 (x +2 ) ( x +3) 2
r . ( i + 2j − k) = 2 ⇒(B) is not correct.
If θ is the acute angle between P1 and P2 then
g. x = – 1)
⇒ f is increasing in (–2, ∞)
ng
r r Also, lim f(x) →−∞ and lim f ( x ) → ∞ ⇒ unique
(iˆ + ˆj).(iˆ +2ˆj −k)
ˆ x→ 2+
x→ ∞
ye
n1 .n 2 3 3
cos θ = r r = = =
| n1 | . | n 2 | 2. 6 2. 6 2 root
.m
π 1 −3 −4 1 −3 − 4 0 0 0
θ = cot − 1 3 = ⇒ (C) is correct
6 (14) (A). A = −1 3
2
4 −1 3 4 = 0 0 0
w
As L is contained in P2 ⇒ θ = 0 1 −3 −4 1 −3 − 4 0 0 0
w
1 ⇒ A is nilpotent
(AB). Given | z1 | = | z2 | = | z3 | = 1 ⇒ z1 = z
w
(12)
1 (15) (C). If f (x) is odd, then f ' (x) is even but converse is not true
://
Also, + + +1 =0
z2 z3 z1z3 z1z2 f (–x) = – sin x + x cos x + C
ht
= z1 z2 z3 [3z(z1 + z2 + z3 ) − 4] f ( − x) = −∫ 1 +y 2 dy
0
z3 = z1 z2 z3 =[3 | z |2 – 4] ........... (1)
∴ f (x) + f (–x) = 0 ⇒ f is odd and g is obviously even.
2
Now, if | z | ≥ (16) (A). ∆ = 12 5 using Heroes formula.
3
then | z | = 3 | z |2 – 4 ⇒ | z |3 – 3 | z |2 + 4 = 0
3
21 5 Q R = abc
R=
| z |2 ( | z | – 2) – | z | ( | z | – 2) – 2 ( | z | – 2) = 0 10 4∆
3
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om
Let P1 : x2 = – λ (y – 4) (λ > 0) ..... (1)
and P2 : (x – 6)2 = λy .... (2)
Solving the two equation x
–3√2 O 3√ 2 V(6,0)
c
2
(x − 6) 2
x2 = −λ
λ
−4 ⇒ x2 = −(x −6) 2 +4 λ
g.
ng
x + (x – 6) – 4λ = 0 ⇒ 2x2 – 12x + 36 – 4λ = 0
2 2 = (12 − 2.2 2) − (0) + 2(2 2 −8)
b 2 – 4ac = 0 ⇒ 144 = 4 × 2 (36 – 4λ) ⇒ 18 = (36 – 4λ) = (12 – 4) + (4 − 8 2) = 12 −8 2 = 4(3 −2 2 )
ye
⇒ 4λ = 18 ⇒ λ = 9/2
Hence the parabolas are (20) (D)., (21) (A)., (22) (B).
.m
P(E) = p
9 9
x2 = − (y −4 ) ; ( x −6) 2 = λ ⇒ Latus rectum = 9/2 P (F) = P (E ∩ F) + P (E ∩ F)
2 2
w
1 1
dy dy 2x 9
://
2x = − λ ⇒ = − 1 (where λ = ) E
dx dx ( x , y ) λ 2
1 1
tp
1 4p 1
= p.1 + (1 – p). = +
5 5 5
ht
dy dy 2(x1 − 6) 9
and 2(x − 6) = λ ⇒ = (where λ = ) (20) If p = 0.75
dx dx ( x1 , y1 ) λ 2
1 1
∴ 2 (x1 – 6) = – 2x1 P (F) = (4p + 1) = (4) =0.8
4x1 = 12 ⇒ x1 = 3 5 5
when x1 = 3 then y 1 = 2 P ( E ∩ F) 0.75 15
∴ point of contact = (3, 2) ⇒ sum = 5 ∴ P (E/F) = = =
P(F) 0.80 16
(19) Method I :
5p
6 3 6 (21) Now P(E/F) = ≥p
2 2 ( x − 6) 2 (4p + 1)
A1 = ∫ (x −6) 2 dx = = [0 (− 3)− ] =
3
2
3
9 9 3 3 27 Equality holds for p = 0 or p = 1
for all others value of p ∈ (0, 1), L.H.S. > R.H.S.
(A 1 ≡ Ar. PCV2 )
(22) If each question has n alternatives then
3 2
2x2 2 3
3 2
1 1 1 (n − 1) p + 1
A2 = ∫
4 −
9
dx = 4x − x
27 3
P(F) = p + (1 − p)
n
= p 1− + =
n n n
3
np
2 × 54 2 2 ∴ P (E/F) = (n − 1) p + 1 which increases as n increases
= 12 2 − −12 − 27 ×27 (A 2 ≡Ar.PCQ)
27
for a fixed p.
4
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1 1 1 1 1 1
60° = ( µ −1) − ; = ( µ −1) +
f R1 R 2 40 10 10
/2
(23) (A). 30° 1 2 9
T' = ( µ −1) ⇒ µ =
2T 3 40 10 8
2 (30) (C).
Sum of heat current at C is zero.
(T − T ′) A ( 2T − T ′) A q
+ =0
ρ×l ρ× ( 3 l /2)
( 2T − T ′ ) 2 2 + 3
⇒ (T − T ′ ) + 2 =0 ⇒T′ = T 100 –q –50 +q
3 2+ 3
(24) (D). In Case-I no horizontal external impulse on ball and –100 +q +50 –q
mass system while in Case-II friction is impulsive as normal
om
with ground is impulsive.
∴ both are wrong.
(25) (C).
3Q → P + energy (e)
c
g.
e = EP – 3EQ v2 100 − q 50 − q
(26) (B). −6
+ =0
v1 5 × 10 20 ×10−6
ng
2π 4
ω1 = rad/hr. 10 ⇒ q = 90 × 10–6 C
1 ∴ Final charge on 5µF top plate is 10µC.
ye
2π (31) (B).
ω2 = rad/hr.
8
.m
XL XC
2 3 tan θ1 = ; tan θ2 =
T1 R 1 R R R
T = R ⇒ 2 =4 ⇒R2 =4 10
× 4 km
w
2 2 R1 X C − XL
tan θ =
w
R
2πR1
v1 = = 2π ×104 km/hr tan θ = tan θ2 – tan θ1
w
1h
(32) (AB).
://
2πR 2
v2 = = π × 104 km/hr
8h
tp
At closest separation
ht
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H 3H p+ α 2 + 6
Li2 + 12
C3 +
(B) H = I ω, ω = = 2 a/2 a/2
(Md 2 /3) Md m2 m3 m 1 4 6 12
m1 x1 + m 2 x 2 m1 y1 + m 2 y 2 q +1 +2 +2 3+
(C) xCM = m1 + m 2 ; yCM = m + m
1 2
m
r∝
m z + m 2z 2 q
z CM = 1 1
m1 + m2 r1 = r2 < r4 < r3
(D) According to Newton’s third law they exert equal and 2πmvcos θ m
(43) (D). P = ⇒P∝
opposite forces on each other in both (a) and (b). qB q
(34) (ABCD)
∴ P1 < P2 < P3 < P4
W iaf + Uif = Hiaf
om
20 + Uij = 50 mvsin θ 2mqv m
Uif = 30 and W ibf + W if = Hibf (44) (C). r = = sin θ ⇒ r ∝
qB qB q
c
W ibf + 30 = 36
r1 < r2 < r3 < r4
g.
W ipf = 6
(A) W ibf = 6 (45) (D).
ng
(B) Hfi = W fi + Ufi = 13 + 30 = 43
(C) Uif = 30, Ui = 10, Uf = 40 H
ye
H
(36) (A). Work done by action reaction force may be zero only
if disp. of both bodies are same.
w
y y +
(37) (C). (B) N N O N=N=O
w
N
(38) (C). i = i0 (1 −e− t/ τ ) at t = 0, i = 0 z
://
(C)
N
OH
tp
di i0 L − t / τ
e = −L = e at t = 0, e ≠ 0
dt τ O
ht
(39) (A). A 1 v 1 = A 2 v 2 O
4cm2 × 1m/s = 1mm2 × 2m/s N v N sp ²
(D)
400mm2 × v = 1 mm2 × 2m/s O O
v=1.64 Å
2 20
v= = mm/s = 5mm/s v>x>z>y
400 4
N2 H4 exists in gauche conformation hence repulsion be-
(40) (C). Height of syringe = V/A = 5cm
tween l.p. and l.p. is reduced while in N 2 O4 all atoms being
Work done = ∆ KE of water + gain in PE of water + gain in
is same plane there is repulsion between two bonds hav-
1 ing B.O. = 1.5 each, hence N–N bond length in N2 O4 is
PE of piston = (Vρ)v 2 + m1 gh 1 + m2 gh 2 greater than N – N bond length in N2 H4 .
2
1 H
= [(20 × 10–6 ) 1000]22 + [20 × 10–3 × 10 × 2.5 × 10–2 ]
2 O
O N H
+ [0.1 × 10 × 0.05] = 0.04 + 0.005 + 0.05 = 0.095 J H
N N
N
(41) (B). Force exerted by external agent on the piston will O O H
continuously decrease
6
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H
+
N N N
– SN2 +
OH (B) Cl Cl + H2O Cl Cl OH 2 Cl Cl – OH
H Cl Cl Cl
–HOCl
CH3 – CH – CH – CH3 CH3 – CH = CH – CH3 (Cis/trans)
Trans is major N 2H 2O
Br H H + HOCl N
Br 2/CCl4 Cl H
H
Cl
CH3 Antiaddition at
H 3 0 0° C
H3C H Br trans obtained NF3 + 2H2 O → HNO2 + 3HF
Br Br
H Br erythreo product Mechanism by S N1 :
H
CH3 CH3 Step I :
k′ E 1
300°C
N+ + F–
1 N
(47) (A). ln 1 = 1 − ........ (1) F F slow F F
om
k1 R T1 T2
F
k2′ E 2 1 1 Step II
= −
c
ln ........ (2)
k2 R T1 T2
k2 k1 R T1 T2 H 2O
.m
H2 O H2O
HON=O N NF(OH) 2unstable
k1 2k'1 F– F O
Q for 2 : 1 molar ratio =
k2 k '2
w
(50) (B).
://
ln 2 = (1000) ;
300 × T2 10 T2 CH3 – C C – H
NaH –
CH3 – C C
ht
(X)
300 0.7 × 3
= 1 −
T2 10 O
CH 2 – C C– CH3 CH 2 – C – OH
300 × 10 O3
T2 = = 379.746 K = 379.75 K O
(10 − 0.7 × 3) H2 O2
+ CH3 – C – OH
(48) (C).Serpeck’s process is used when bauxite contains SiO2
(51) (B). ∆Tf = Kf.m.i
as impurity.
0.2406 = 1.86 × 0.1 (1 + α) ; α = 0.1
∆
Al2O3 + 3C +N 2
→2AlN +3CO ↑ HCOOH(aq) ƒ H+(aq) + OH– (aq)
1 8 0 0° C Cα 2 0.1 × (0.1) 2 1
SiO2 + 2C
→Si +2CO Ka = = × −2
= 10
(1− α ) 0.9 9
AlN + 3H2O
→Al(OH) 3 + NH3 ↑
Kw 10− 14
steam Kh = = × −12
=9 10
1
1 4 7 0° K
Ka × 10−2
2Al(OH)3
→ Al2 O3 + 3H2 O 9
7
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AquaRegia
(52) (C). (A) Ag + [Cl] →Noreaction
AquaRegia
Au + 3[Cl]
→AuCl3
soluble
(B) Ca 2 + + Na 2 CrO4
→Noppt.asCaCrO 4 is soluble (Ksp of SrCrO4 > 10–5 )
Sr 2+ + Na 2CrO 4
→ SrCrO 4 ↓ +2Na +
Yellowppt.
(K sp = 10− 5 ) both Sr2+ and Ba2+
give yellow ppt.
Ba 2 + + Na 2 CrO 4
→ BaCrO 4 ↓ +2Na + with Na2 CrO4
Yellowppt.
(K sp = 10− 10 )
∆
(C) Cl− + H2SO4 →HCl ↑+ HSO−4
→ Whitefumes
Br − + H2SO4
∆
→ HBr ↑ + HSO−4 with Br–
om
− ∆ −
2Br + 3H2SO4 → Br2 ↑ +2HSO4 + SO2 ↑ +2H2 O Reddish
(Reddishbrown) Brown vapour
c
∆
I − + H2SO4
→HI ↑+ HSO −4
g.
with I–
violet
∆
2I − + 3H2SO4 →I 2 ↑+ 2HSO−4 + SO2 ↑+ 2H 2O
ng
vapours
(violetvapours)
(D) Only NO2 is decomposed by dil. H2 SO4 , while dil. H2 SO4 has no action on NO3 – .
–
ye
NO −2 + H +
→HNO2 ↑ ; 3HNO 2
→ HNO 3 + 2NO ↑ + H 2 O
.m
↓ air
NO 2 ↑
w
Reddish-Brown
w
NO3− + dil.H2SO4
→noreaction
w
(53) (A).
://
H
tp
O
O O OH N
NaOH
ht
+ NH3
OH
–H2O
+
O O O O O NH2
+
NH2 O
NH2 NH2
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(55) (AC).
Me Me σ – C3 H5 can exist in two structures :
O a / 5
pOH = pKb + log
4 a / 5
om
O O O
5 = pKb + log (1/4) [Q pDH = 14 – pH = 14 – 9 = 5]
pKb = 5.6
c
(C) Me – C NaOH/I 2
Me – C Me – C
g.
CH 2 CI 2 CI2
Me – C Me – C Me – C 1
OH pH = [pKw – pKb – log C]
O O O 2
ng
4.5 × 2 = (14 – 5.6 – log C)
O– O O O
log C = – 0.6
ye
– I2 –
OH
+
C = 0.25
OH
Let V ml. of HCl is used
.m
O O
0.5 × V
= 0.25
– –
w
+ CHI3
V + 100
w
V = 100 ml.
(D) CH3 − CH − CH3
NH 4OH/I2
→ no reaction M. Moles of acid = M. Moles of base = 0.5 × 100 = 50
w
|
OH
50 × 10−3 × 45
://
NaOH + I2 is a good oxidising agent but NH4 OH + I2 is Wt. % of base in sample = × 100 = 90
2.5
not.
tp
(54) (ABC). (57) (B). There is large δ– charge developed (due to F-atom) on
ht
− +
H +
R.T.
(B) NO 2 + (dil.) →HNO2 O ∆ major
R.T.
3HNO2
→ 2NO ↑+ HNO3 + H2 O O
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(61) (D). x 3x 0 H
CO + 2H2 ƒ CH3 OH CH3 − C = C −CH3
2 → CH − CH − CH − CH
3 3
| | Ni | |
x–y 3x – 2y y CH3 CH3 CH3 CH3
y 2 2
= ; y = x = 103 mol/sec.
x 3 3 CH3 CH3
| |
3 CH3 − C − CH = CH2
H2
→ CH3 − C − CH2 − CH3
x= ×103 mol/sec. ; x = 1500 mol/sec | Ni
2 |
CH3 CH 3
(CO, β) = 1500 mol/sec.
(H2 , β) = 4500 mol/sec. (C) Neopentane cannot be prepared.
(62) (B). (CO, γ) = 1500 – 1000 = 500 mol/sec.
D
(H2 , γ) = 4500 – 2000 = 2500 mol/sec. H2
(63) (B). (D)
Ni
CO + 2H2 ƒ CH3 OH
D
q = ∆H × 1000 × 60 = 6 × 104 × 100 × 2 = 12 × 106 cal
q = 12000 kcal
om
CH3 CH3
(64) (B).
CH3
H D D H
H2 CH3 H2 CH2
CH – CH = CH2 CH – CH2 – CH 3 C – CH2 – CH3 +
c
CH3 CH3 CH3
H2 D H H D
g.
CH3
C = CH – CH3 CH3 CH3
ng
CH3
CH3 − CH − CH 2 − CH = CH 2
w
H |Pd
|
2 →
CH3 BaSO4 cis trans
://
H
2 → CH − CH − CH − CH − CH
3 2 2 3
Ni |
ht
CH3
H (excess)
2 →
CH3 − CH 2 − CH − CH = CH2 Ni Achiral so optically inactive
| (C)
CH3
H
2 → CH − CH − CH − CH − CH
3 2 2 3
Ni |
CH3
10
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