PERHITUNGAN

1. Pembuatan Larutan NaOH 0,2 N

𝑁 0,2
M= = = 0,2 M
𝑒𝑘 1
𝑔𝑟 1000
M= x
𝑚𝑟 𝑣

𝑔𝑟 1000
0,2 = x
40 100

gr = 0,8 gram

2. Pembuatan Larutan C2H2O4 0,025 N

𝑁 0,025
M= = = 0,0125 M
𝑒𝑘 2

𝑔𝑟 1000
M= x
𝑚𝑟 𝑣

𝑔𝑟 1000
0,0125 = x
126 100

gr = 0,01575 = 0,2 gram

3. Standarisasi NaOH

Diketahui : V C2H2O4 = 5 ml

M C2H2O4 = 0,0125 M
1+1 𝑚𝑙
V NaOH rata rata = = 1 ml
2

Ditanya : M NaOH = ?

Jawab :

2 NaOH + H2C2O4  Na2C2O4 + 2 H2O

n NaOH = 2 n C2H2O4

=2(Mxv)

= 2 ( 0,0125 x 5 )
 = 2 ( 0,0625)

= 0,125 mol
𝑛 𝑁𝑎𝑂𝐻
M NaOH =
𝑉 𝑟𝑎𝑡𝑎 𝑟𝑎𝑡𝑎 𝑡𝑖𝑡𝑟𝑎𝑠𝑖

0,125
=
1

= 0,125 M

4. Kelarutan C2H2O4 Sebagai Fungsi Suhu

a. T = 50 OC

Diketahui : V C2H2O4 = 5 ml

M NaOH = 0,125 M
8,9+7,7
V NaOH rata-rata=
2

= 8,3 ml
Ditanya : n C2H2O4

Jawab :

2 NaOH + H2C2O4  Na2C2O4 + 2 H2O

1
n C2H2O4 = x n NaOH
2

1
M C2H2O4 . V C2H2O4 = x M NaOH Standarisasi x V NaOH
2

1
M C2H2O4. 5 = x 0,125 x 8,3
2

M C2H2O4. = 0,104 M

n C2H2O4 = M C2H2O4 x V C2H2O4

= 0,104 x 5

= 0,52 mol
b. T = 40OC

Diketahui : V C2H2O4 = 5 ml

M NaOH = 0,125 M
7,5+7,3
V rata-rata = = 7,4 ml
2

Ditanya : n C2H2O4

jawab :

2 NaOH + H2C2O4  Na2C2O4 + 2 H2O

1
n C2H2O4 = x n NaOH
2

1
M C2H2O4 . V C2H2O4 = x M NaOH Standarisasi x V NaOH
2

1
M C2H2O4. 5 = x 0,125 x 7,4
2

M C2H2O4 = 0,092 M

n C2H2O4 = M C2H2O4 x V C2H2O4

= 0,092 x 5

= 0,46 mol

c. T = 30 OC

Diketahui : V C2H2O4 = 5 ml

M NaOH = 0,125 M
5,4+3,5
V rata-rata = = 4,45 ml
2

Ditanya : n C2H2O4

Jawab :

2 NaOH + H2C2O4  Na2C2O4 + 2 H2O

 1
M C2H2O4 . V C2H2O4 = x M NaOH Standarisasi x V NaOH
2

1
M C2H2O4. 5 = x 0,125 x 4,45
2

M C2H2O4. = 0,056 M

n C2H2O4 = M C2H2O4 x V C2H2O4

= 0,056 x 5

= 0,28 mol

d. T = 20OC

Diketahui : V C2H2O4 = 5 ml

M NaOH = 0,125 M
4,1+2,5
V rata-rata = = 3,3 ml
2

ditanya : n C2H2O4

Jawab :

2 NaOH + H2C2O4  Na2C2O4 + 2 H2O

1
M C2H2O4 . V C2H2O4 = x M NaOH Standarisasi x V NaOH
2

1
M C2H2O4. 5 = x 0,125 x 3,3
2

M C2H2O4 = 0,021 mol

n C2H2O4 = M C2H2O4 x V C2H2O4

= 0,021 x 5

= 0,11 mol
T ( K) 1/ T ( K) mol Log mol
323 3,09 x 10 – 3 0,52 -0,29
313 3,19 x 10 -3 0,46 -0,33
303 3,30 x 10-3 0,28 -0,55
293 3,41 x 10-3 0,11 -0,96

Grafik 1/T vs log mol

0
0.003 0.0031 0.0032 0.0033 0.0034 0.0035
-0.2

-0.4
y = -2099.1x + 6.2843
log mol

-0.6 R² = 0.8921

-0.8

-1

-1.2
1/T

Hps 1
Log mol = x
2,303 x R 𝑇

Hps = -m x 2,303 x R

= -2099 X 2,303 X 8,314

= - 40,18 J/mol