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SULIT 4541/1

JABATAN PELAJARAN MELAKA


BUKIT BARU, MELAKA

PEPERIKSAAN AKHIR TAHUN 4541/1


TINGKATAN 4 2011
CHEMISTRY
Kertas 1
Oktober 2011

1 ¼ jam Satu jam lima belas minit

JANGAN BUKA KERTAS SOALAN INI SEHINGGA DIBERITAHU

1. Kertas soalan ini mengandungi 50 soalan.


2. Jawab semua soalan.
3. Jawab dengan menghitamkan ruangan yang betul pada kertas jawapan.
4. Hitamkan satu ruangan sahaja bagi setiap soalan.
5. Rajah tidak dilukis mengikut skala kecuali dinyatakan
6. Anda dibenarkan menggunakan kalkulator saintifik yang tidak boleh diprogramkan

Kertas soalan ini mengandungi 25 halaman bercetak

[Lihat sebelah
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INFORMATION FOR CANDIDATES

1. This question paper consists of 50 questions.

2. Answer all questions.

3. Answer each question by blackening the correct space on the answer sheet.

4. Blacken only one space for each question.

5. If you wish to change your answer, erase the blackened mark that you have made.
Then blacken the space for the new answer.

6. The diagrams in the questions provided are not drawn to scale unless stated.

7. You may use a non-programmable scientific calculator.

MAKLUMAT UNTUK CALON

1. Kertas soalan ini mengandungi 50 soalan.

2. Jawab semua soalan

3. Jawab dengan menghitamkan ruangan yang betul pada kertas jawapan.

4. Hitamkan satu ruangan sahaja bagi setiap soalan.

5. Sekiranya anda hendak menukarkan jawapan, padamkan tanda yang telah dibuat.
Kemudian hitamkan jawapaan yang baru.

6. Rajah yang mengiringi soalan tidak dilukis mengikut skala kecuali dinyatakan.

7. Anda dibenarkan menggunakan kalkulator saintifik yang tidak boleh diprogramkan

Question 1 to Question 50 are followed by four options A, B, C or D.


Choose the best option for each question and blackened the corresponding space on
the objective answer sheet.

Bagi Soalan 1 hingga Soalan 50, tiap-tiap soalan diikuti oleh empat pilihan jawapan A, B,
C dan D. Pilih satu jawapan yang terbaik bagi tiap-tiap soalan dan hitamkan ruangan yang
sepadan pada kertas jawapan objektif anda

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1. Which of the following statements best describes ‘Chemistry’?


Antara pernyataan berikut, yang manakah terbaik menerangkan ‘kimia’ ?

A Chemistry is the study gained through scientific investigations.


Kimia ialah kajian diperoleh melalui penyiasatan saintifik.

B Chemistry is a systemic study of natural phenomena.


Kimia ialah kajian sistemik bagi fenomena semulajadi.

C Chemistry is the study of the composition, structure, properties and interactions of


matter.
Kimia ialah kajian mengenai komposisi, struktur, sifat-sifat dan interaksi antara
jirim.

D Chemistry is an art of transforming metals.


Kimia ialah satu seni perubahan logam.

2. There are many industries involve chemistry include …


Terdapat banyak industri melibatkan kimia termasuk …

I Petroleum industry
Industri petroleum

II Nutritional industry
Industri pemakanan

III Mining industry


Industri perlombongan

IV Paint making industry


Industri membuat cat

A I and II only
I dan II sahaja

B I, II and III only


I, II dan III sahaja

C I, II and IV only
I, II dan IV sahaja

D I, II, III and IV


I, II, III dan IV

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3 Which of the following is the best solution for an arteriosclerosis patient?


Antara berikut yang manakah penyelesaian terbaik bagi pesakit arteriosklerosis?

A take food rich in calcium


makan makanan yang kaya dengan kalsium
B take food rich in iron
makan makanan yang kaya dengan zat besi
C reduce fatty food intake
kurangkan mengambil makanan berlemak
D reduce sugary food intake
kurangkan mengambil makanan bergula

4 Which of the following substance exists as atoms?


Antara bahan berikut, yang manakah wujud sebagai atom?

A Emas C Water
Gold Air

B Nitrogen D Chlorine
Nitrogen Klorin

5 The melting point of a substance X is -2oC and its boiling point is 75oC. What is the
physical state of substance X at -5oC and 85oC?
Takat lebur bahan X ialah -2oC dan takat didihnya ialah 75oC. Apakah keadaan fizikal
bahan X pada suhu -50C dan 850C?

At -5oC At 85oC
Pada -5oC Pada 85oC
A Solid Gas
Pepejal Gas
B Solid Liquid
Pepejal Cecair
C Liquid Gas
Cecair Gas
D Gas Solid
Gas Pepejal

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6 Diagram 1 below shows an atomic model.


Rajah 1 menunjukkan suatu model atom.

Diagram 1
Rajah 1

Which of the following is true about Diagram 1?


Antara penyataan berikut yang manakah benar tentang Rajah 6?

A The atomic model above was proposed by Neils Bohr.


Model atom di atas dicadangkan oleh Neils Bohr.

B The atom is a sphere of positive charge which contains a few electrons


Atom merupakan sfera bercas positif yang mengandungi sedikit elektron.

C The electrons in an atom move in shells around the nucleus.


Elektron dalam atom bergerak dalam petala-petala yang mengelilingi nukleus.

D The electrons move in a space that is larger than the space occupied by the nucleus.
Electron bergerak dalam ruang yang lebih besar daripada ruang yang ditempati
oleh nukleus.

7 This isotope produces gamma radiation to kill cancer cells. What is the isotope?
Isotop ini menghasilkan sinar gamma untuk membunuh sel kanser. Apakah isotop ini?

A Iodine-131
Iodin-131

B Cobalt-60
Kobalt-60

C Sodium-24
Natrium-24

D Carbon-12
Karbon-12

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8 Diagram 2 shows the symbol of fluorine atom.


Rajah 2 menunjukkan simbol bagi atom fluorin

19
F
9

Diagram 2
Rajah 2

Which of the following is true based on the symbol in Diagram 2.


Antara berikut yang manakah benar berdasarkan simbol dalam Rajah 2.

Proton number Nucleon number Number of electron


Nombor proton Nombor nukleon Bilangan elektron
A 9 19 9
B 9 19 19
C 9 10 9
D 19 9 9

9 Diagram 3 shows the electron arrangement of atom X.


Rajah 3 menunjukkan susunan elektron bagi atom X.

Diagram 3
Rajah 3

How many valence electrons are there in the atom of X?


Berapakah bilangan elektron valens yang terdapat dalam atom X?

A 2 C 5

B 3 D 7

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10 Diagram 4 is a graph which shows the cooling curve for gas X.


Rajah 4 ialah satu graf yang menunjukkan lengkung penyejukan bagi gas X.

Diagram 4
Rajah 4

Which of the following statements is true?


Antara pernyataan yang berikut, manakah benar?

A From point P to point Q, kinetic energy increases as temperature decreases.


Dari titik P ke titik Q, tenaga kinetik bertambah apabila suhu menurun.
B From point Q to point R, forces of attraction between particles become weak
Dari titik Q ke titik R, semua daya tarikan antara zarah-zarah menjadi lemah.
C At point R, all the gas X has completely melted
Pada titik R, semua gas X telah melebur keseluruhannya.
D From point R to point S, heat is released to the surroundings
Dari titik R ke titik S, haba dibebaskan ke persekitaran

11 The following equation represents the chemical process to extract aluminium from
aluminium oxide.
Persamaan dibawah menunjukkan proses kimia untuk mengekstrak aluminium dari
aluminium oksida

2 Al2O3 → 4 Al + 3 O2

What is the volume of oxygen gas evolved when 204 g of aluminium oxide is used in the
extraction ?
Berapakah isipadu gas oksigen yang terbebas apabila 204 g aluminium oksida digunakan
di dalam proses ini?
[ Relative atomic mass ; O = 16 ; Al = 27, 1 mol of gas occupies 24.0 dm3 at room
temperature ]
[Jisim atom relatif ; O = 16, Al = 27, 1 mol gas menempati 24.0 dm3 pada suhu bilik.]

A 36 dm3 C 48 dm3
B 144 dm3 D 72 dm3

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12 Diagram 5 shows the electron arrangement of a molecule of compound XY2. ( Only


the valence electrons are shown ).
Rajah 5 menunjukkan susunan elektron bagi molekul sebatian XY2 (hanya
elektronvalens yang ditunjukkan).

Diagram 5
Rajah 5
X and Y could be :
X dan Y mungkin :
X Y
A Carbon Oxygen
B Carbon Chlorine
C Carbon Hydrogen
D Chlorine Carbon

13 Which of the following represents the electron arrangement of a noble gas?


Antara berikut, yang manakah mewakili susunan elektron gas adi?

A C

R R

B D

R R

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14 Diagram 6 shows the set-up of the apparatus to determine the empirical formula of substance Y.
Rajah 6 menunjukkan susunan radas untuk menentukan formula empirik bahan Y.

SubstanceY
Bahan Y
Hydrogen gas
Gas hidrogen

Diagram 6
Rajah 6

What could be substance Y ?


Apakah mungkin bahan Y?

I Copper(II) oxide
Kuprum(II) oksida
II Magnesium oxide
Magnesium oksida
III Potassium oxide
Kalium oksida
IV Lead (II) oxide
Plumbum (II) oksida
A I and IV only
I and IV sahaja
B II and III only
II and III sahaja
C III and IV only
III and IV sahaja
D I, II, III and IV
I, II, III and IV

15 Table 1 shows the mass of element P and Q which react with each other.
Jadual 1 menunjukkan jisim bagi unsur P dan Q yang bertindak balas.

Element P Q
Unsur
Mass(g) 0.32 0.36
Jisim(g)
Table 1
Jadual 1
What is the empirical formula for the substance formed?
Apakah formula empirik bagi sebatian yang terbentuk?
[Relative atomic mass :P = 64 ; Q = 35.5]
[ Jisim atom relatif: P =64; Q = 35.5]
A PQ C PQ4
B PQ2 D P2Q3

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16 2.7 g of element X reacts with 2.4 g element Y to form a substance with empirical formula
of X2Y3. What is the atomic mass of Y?
2.7 g unsur X bertindak balas dengan 2.4 g unsur Y untuk membentuk sebatian dengan
formula empirik X2Y3. Berapakah jisim atom relatif bagi Y?
(Relative atomic mass : X = 27)
( Jisim atom relatif : X = 27)

A 8 C 24

B 16 D 31

17 The chemical symbol of an element T is as shown :


Simbol unsur T ditunjukkan seperti di bawah:

24
T
12

What would be the electron arrangement of the ion formed by an atom of T ?


Apakah susunan elektron bagi ion yang terbentuk oleh atom T?

A 2.8

B 2.8.2

C 2.8.8

D 2.8.8.8

18 Which of the following elements are located in group 17 of the Periodic Table?
Manakah antara unsur-unsur berikut diletakkan di dalam kumpulan 17 Jadual Berkala?

A Neon and Argon


Neon dan Argon

B Lithium and Potassium


Litium dan Kalium

C Iodine and Bromine


Iodin dan Bromin

D Nitrogen and Phosphorus


Nitrogen dan Fosforus

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19 The following statement is about the arrangement of the elements in the Periodic Table of
elements.
Pernyataan berikut adalah mengenai susunan unsur di dalam Jadual Berkala Unsur.

“Elements are arranged in order of increasing proton number in The


Periodic Table. Unsur-unsur disusun mengikut nombor proton menaik
dalam Jadual Berkala.”

Which of the following scientist made the above statement?


Antara saintis berikut siapakah yang membuat pernyataan di atas?

A Newlands

B Meyer

C Mendeleev

D Dobereiner

20 Table 2 shows the proton number and number of electrons of several particles.
Which of the following particles is an anion?
Jadual 2 menunjukkan nombor proton dan bilangan elektron bagi beberapa zarah.
Manakah di antara berikut merupakan anion?

Particles Proton Number Number of electrons


Zarah Nombor Proton Bilangan elektron
P 3 2
Q 9 10
R 11 11
S 20 18

Table 2
Jadual 2

A P

B Q

C R

D S

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21 Table 3 shows the elements in Period 3 of the Periodic Table of elements. The elements can
react with oxygen to form oxides.
Jadual 3 menunjukkan unsur-unsur Kala 3 dalam Jadual Berkala Unsur. Unsur-unsur
tersebut bertindak balas dengan oksigen membentuk oksida.

Element
Na Mg Al Si P S Cl
Unsur
Table 3
Jadual 3

Which of the following element forms amphoteric oxide?


Antara berikut unsur manakah membentuk oksida amfoterik?

A S C Si

B P D Al

22 The number of neutrons of atom X is 20. If the number of electrons of ion X2+ is 18, what
is the relative atomic mass of X?
Bilangan neutron bagi suatu atom X ialah 20. Jika bilangan elektron ion X2+ ialah 18,
berapakah jisim atom relatif X?

A 18 C 38

B 20 D 40

23 Which of the following is true about elements in the Periodic Table?


Antara berikut yang manakah benar tentang unsur-unsur dalam Jadual Berkala?

A The metallic properties increases from left to right across a period


Sifat kelogaman bertambah apabila merentasi Jadual Berkala dari kiri ke kanan

B Elements of the same group have the same physical properties


Unsur dalam kumpulan yang sama mempunyai sifat fizik yang sama

C Group 18 elements have low melting and boiling points


Unsur kumpulan 18 mempunyai takat lebur dan takat didih yang rendah

D Group 17 elements exist naturally as monoatoms


Unsur kumpulan 17 wujud semulajadi sebagai monoatom

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24 What happens to a sodium atom when chlorine combines with sodium?


Apakah yang berlaku kepada atom natrium apabila klorin berpadu dengan natrium?

A Accepts an electron
Menerima satu elektron

B Donates an electron
Menderma satu elektron

C Accepts two electrons


Menerima dua elektron

D Shares a pair of electrons


Berkongsi sepasang elektron

25 Sodium and sulphur have the proton number 11 and 16 respectively. They react to form
sodium sulphide. Which of the following statements are true?
Natrium dan sulfur masing-masing mempunyai nombor proton 11 dan 16. Mereka
bertindakbalas membentuk natrium sulfida. Antara pernyataan berikut, yang mana adalah
benar?

I A sodium atom donates an electron to form a sodium ion


Satu atom natrium menderma satu elektron untuk membentuk ion natrium

II A sodium atom donates two electrons to the sulphur atom


Satu atom natrium menderma dua elektron kepada atom sulfur
III A sulphur atom receives two electrons to form a sulphide ion
Satu atom sulfur akan menerima dua elektron untuk membentuk ion sulfida

IV Sodium and sulphur combine to form an ionic compound


Natrium dan sulfur bergabung untuk membentuk sebatian ion.

A I and IV only
I dan IV sahaja

B I, II and III only


I, II dan III sahaja

C I, III and IV only


I, III dan IV sahaja

D II, III and IV only


II, III dan IV sahaja

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26 Table 4 shows the electron arrangement of atoms G, H, J and K


Jadual 4 menunjukkan susunan elektron bagi atom G,H, J dan K

Atom G H J K

Electron arrangement 1 2.5 2.8.2 2.8.8.1


Susunan elektron
Table 4
Jadual 4

Which of the following pairs of elements can combine to form a covalent compound?
Yang manakah antara pasangan unsur-unsur berikut boleh membentuk sebatian kovalen?

A G and H

B H and J

C G and K

D H and K

27 Which of the following set of apparatus is the most suitable to be used in electrolysis of
copper(II) sulphate solution?
Antara susunan radas yang berikut, yang manakah paling sesuai digunakan dalam proses
elektrolisis larutan kuprum(II) sulfat?

A B
Carbon rod
Rod karbon

Copper(II)
sulphate solution
Larutan
kuprum(II) sulfat

C D

Carbon rod
Rod karbon

Copper(II)
sulphate solution
Larutan
kuprum(II) sulfat

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28 Table 5 contains information on the melting points and boiling points of substances P, Q, R
and S.
Jadual 5 mengandungi maklumat tentang takat lebur dan takat didih bagi bahan-bahan
P,Q,R dan S

Electrical
Substance Melting point (ºC) Boiling point (ºC) conductivity
Bahan Takat lebur (ºC) Takat didih (ºC) in molten
state
P -30 174 Cannot conduct
Q 43 182 Cannot conduct
R 119 444 Can conduct
S 688 1100 Can conduct
Table 5
Jadual 5

Which of the following classifications of substances P, Q, R and S is correct?


Antara pengkelasan berikut, yang manakah benar bagi bahan P, Q, R dan S?

Ionic compound Covalent compound


Sebatian ion Sebatian kovalen

A P and Q R and S
B R and S P and Q
C P, Q and R S
D S P

29 What is the percentage of nitrogen by mass in ammonium nitrate, NH4NO3?


Apakah peratus nitrogen dalam ammonium nitrat NH4NO3 mengikut jisim?
[ Relative atomic mass: H = 1, N = 14 ,O = 16]
[ Jisim atom relatif : H = 1, N = 14, O = 16]

A 17.50 %

B 21.21 %

C 35.00 %

D 53.85 %

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30 Aqueous sodium chloride solution is an electrolyte because it has


Larutan natrium klorida berair ialah sejenis elektrolit kerana ia mempunyai
A Free moving ions
Ion yang bebas bergerak
B Free moving electrons
Elektron yang bebas bergerak
C Free moving atom
Atom yang bebas bergerak
D Free moving molecules
Molekul yang bebas bergerak

31 Diagram 7 shows a chemical cell.


Rajah 7 menunjukkan sebuah sel kimia.

X plate Y plate
Plat X Plat Y

Electrolyte
Elektrolit
Diagram 6
Diagram 7
Rajah 7
Which of the following is true?
Di antara berikut, yang manakah adalah benar?
Metal X/Y Negative Terminal
Logam X/Y Terminal negatif
A Iron/Zinc Iron
Ferum/Zink Ferum
B Iron/Aluminium Iron
Ferum/Aluminium Ferum
C Zinc/Copper Zinc
Zink/Kuprum Zink
D Magnesium/Aluminium Aluminium
Magnesium/Aluminium Aluminium

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32 Diagram 8 shows the set–up of apparatus of a chemical cell.


Which of the following are not true of a chemical cell?
Rajah 8 menunjukkan susunan radas suatu sel kimia.
Antara berikut yang manakah tidak benar mengenai sel kimia?

Electrodes
Elektrod

Liquid H
Cecair H

Diagram 8
Rajah 8

I The electrodes are of the same metal.


Elektrod-elektrod adalah logam yang sama.

II The electrodes are of different metals


Elektrod-elektrod adalah logam yang berlainan.

III Liquid H is an electrolyte.


Cecair H ialah sejenis elektrolit.

IV Electrical energy change to chemical energy


Tenaga elektrik bertukar kepada tenaga kimia

A I and III only


B I and IV only
C II and IV only
D I, III and IV only

33 Which of the following substances is acidic?


Antara bahan berikut yang manakah bersifat asid?

A Ammonia
Ammonia
B Potassium oxide
Kalium oksida
C Carbon dioxide
Karbon dioksida
D Sodium hydroxide
Natrium hidroksida

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34 It is discovered that a compound with formula AB dissolves in water. What inference can
you make about the compound ?
Didapati satu sebatian dengan formula AB larut dalam air. Apakah inferens yang boleh
dibuat tentang sebatian itu?

A It is a covalent compound
Merupakan sebatian kovalen
B The compound ionizes in water
Sebatian mengion dalam air
C The compound will dissolve in an organic solvent
Sebatian yang larut dalam pelarut organik
D The intermolecular forces between the particles are very weak
Daya antara molekul pada zarah-zarah adalah sangat lemah

35 During the electroplating of an iron key with copper, which of the following should be
done?
Semasa menyadurkan kunci besi dengan kuprum, yang manakah antara berikut perlu
dilakukan?

I The iron key should be made the cathode


Kunci besi perlu dijadikan katod

II Molten copper is used as the electrolyte


Kuprum lebur dijadikan elektolit

III An aqueous solution of copper (II) sulphate is made the electrolyte


Larutan berair kuprum (II) sulfat dijadikan elektrolit

IV Two copper plates should be used as electrodes


Dua kepingan kuprum digunakan sebagai elektrod

A I and III only


B II and IV only
C I, II and IV only
D I, III and IV only

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36 Diagram 9 shows the set-up of the apparatus of an electrolytic cell.


Rajah 9 menunjukkan susunan radas bagi satu sel elektrolisis.

Diagram 9
Rajah 9

Which of the following half-equations represents the reaction that occurred at electrode Q?
Antara persamaan setengah berikut, yang manakah mewakili tindak balas yang berlaku di
elektrod Q?

A Na+ + e- → Na

B 2H+ + 2e- → H2

C 2Cl- → Cl2 + 2e-

D 4OH- → O2 + 2H2O + 4e-

37 Which of the following equations does not involve neutralisation?


Antara persamaan kimia berikut yang manakah tidak melibatkan peneutralan?

A 2HCl (aq) + MgO(s) MgCl2(aq) + H2O(l)

B H2SO4(aq) + BaCl2(aq) BaSO4(s) + 2HCl(aq)

C HNO3(aq) + NaHCO3(s) NaNO3(aq) + CO2(g) + H2O(l)

D HCl(aq) + NH3(aq) NH4Cl(aq)

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38 Diagram 10 below shows the set-up of apparatus for electrolysis.


Rajah 10 di bawah menunjukkan susunan radas untuk elektrolisis.

Substance
bahan
s

Diagram 10
Rajah 10

Which of the following substance could light up the bulb?


Antara bahan berikut, yang manakah boleh menyalakan mentol?

A Potassium chloride solution


Larutan kalium klorida
B Glucose solution
Larutan glukosa
C Magnesium oxide
Magnesium oksida
D Tetrachloromethane solution
Larutan tetraklorometana

39 Table 6 shows the degree of dissociation of four solutions of alkalis which have the same
concentration.
Jadual 6 di bawah menunjukkan darjah penceraian empat larutan alkali yang sama
kepekatan.

Solution Degree of dissociation


Larutan Darjah penceraian
W Low
Rendah
X Medium
Sederhana
Y High
Tinggi
Z Very high
Sangat tinggi
Table 6
Jadual 6
Which solution has the highest pH value?
Larutan yang manakah mempunyai nilai pH yang paling tinggi?
A W C Y

B X D Z

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40 Diagram 11 shows two electrolytic cells which use two different type of electrodes, cell A
uses carbon electrode while cell B uses copper electrode.
Rajah 11 menunjukkan dua sel elektolisis yang mana menggunakan dua jenis elektrod yang
berlainan. Sel A mengunakan elektrod karbon manakala sel B mengunakan elektrod
kuprum.

Copper
Carbon Copper(II) Electrode
Electrode sulphate Elektrod
Elektod solution kuprum
karbon Larutan
Ce kuprum (II)
Cell A sulfat Cell B

Diagram 11
Rajah 11

What are the half equation that represented the reaction at anode for both cells?
Apakah setengah persamaan yang mewakili tindak balas di anod pada kedua-dua sel?

Cell A Cell B
Sel A Sel B
A 4OH-→ 2H2O + O2 + 4e- Cu2+ + 2e-→ Cu

B 4OH-→ 2H2O + O2 + 4e- Cu → Cu2+ + 2e-

C Cu2+ + 2e-→ Cu 4OH-→ 2H2O + O2 + 4e-

D Cu → Cu2+ + 2e- 4OH-→ 2H2O + O2 + 4e-

41 What is the mass of sodium hydroxide, NaOH which is required to prepare 250 cm3 sodium
hydroxide solutions with a concentration of 100 gdm-3?
[Relative atomic mass: Na = 23; O = 16; H = 1]
Berapakah jisim natrium hidroksida, NaOH yang diperlukan untuk menyediakan 250 cm3
larutan natrium hidroksida dengan kepekatan 100 gdm-3?
[ Jisim atom relatif Na = 23; O = 16; H = 1]

A 25g C 20g

B 35g D 40g

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42 50.0 cm3 of 0.4 moldm-3 potassium hydroxide solution, KOH is titrated with sulphuric acid,
H2SO4. What is the volume of 1.0 moldm-3 sulphuric acid which is needed to neutralise this
potassium hydroxide solution?
50.0 cm3 larutan kalium hidroksida, KOH 0.4 moldm-3 dititratkan dengan asid sulfurik,
H2SO4. Berapakah isipadu asid sulfurik 1.0 moldm-3 yang diperlukan untuk meneutralkan
larutan kalium hidroksida ini?

A 10.0 cm3 C 40.0 cm3

B 20.0 cm3 D 50.0 cm3

43 Which of the statements are true about a weak alkali?


Antara pernyataan berikut, yang manakah benar tentang alkali lemah?

I It dissociates partially into hydroxide ions in water


Ia terurai separa kepada ion hidroksida di dalam air

II Its pH value is higher than that of sodium hydroxide


Nilai pH nya adalah lebih tinggi daripada nilai pH natrium hidroksida

III It has low OH- ion concentration


Ia mempunyai kepekatan ion hidroksida yang rendah

IV Most of its molecules remain unchanged in the water


Kebanyakan molekulnya kekal tidak berubah di dalam air

A I and II only

B I, II and III only

C I, III and IV only

D II, III and IV only

44 The formula for a sulphate ion is SO42- and for a nitrate ion is NO3- . If the formula of the
sulphate salt of M is MSO4, what is the formula of nitrate salt of M?
Formula bagi sulfat ion adalah SO42- dan bagi nitrat ion adalah NO3-. Jika formula bagi
garam M sulfat adalah MSO4, apakah formula bagi garam M nitrat?

A MNO3

B M2NO3

C M(NO3)2

D M(NO3)3

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45 The following is chemical equation for a reaction.


Berikut ialah persamaan kimia bagi satu tindak balas.

CaCO3 + 2HNO3 Ca(NO3)2 + H2O + CO2

Which of the following are the products?


Antara berikut, yang manakah hasil tindak balas?

A H2O and CO2

B HNO3 and CO2

C CaCO3 and HNO3

D Ca(NO3)2, H2O and CO2

46 Which of the following salts can be prepared by using double decomposition method?
Yang manakah di antara garam-garam berikut boleh disediakan dengan menggunakan
kaedah penguraian ganda dua?

I Zinc chloride
Zink klorida
II Barium sulphate
Barium sulfat
III Sodium nitrate
Natrium nitrat
IV Magnesium carbonate
Magnesium karbonat
A I and III only

B II and IV only

C I, II and III only

D II, III and IV only

47 Excess magnesium oxide is reacted with 25.0 cm3 of 2.0 moldm-3 nitric acid. Calculate the
maximum mass of magnesium nitrate salt formed.
[Relative atomic mass: N=14, 0=16, Mg=24]
Magnesium oksida berlebihan bertindak balas dengan 25.0 cm3 asid nitrik berkepekatan
2.0 moldm-3. Kira jisim bagi garam magnesium nitrat yang terbentuk.
[Jisim atom relatif : N=14, 0=16, Mg=24]

A 7.40 g C 3.70 g

B 4.30 g D 1.48 g

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48 When heated, solid S gives off a gas that turns lime water milky. What is solid S?
Apabila dipanaskan, pepejal S membebaskan gas yang menukarkan air kapur menjadi
keruh. Apakah pepejal S?

I Sodium carbonate
Natrium karbonat
II Calcium carbonate
Kalsium karbonat
III Potassium carbonate
Kalium karbonat
IV Magnesium carbonate
Magnesium karbonat

A II only

B II and IV only

C I and IV only

D II, III and IV only

49 The equation shows a reaction between silver nitrate solution and sodium chloride solution.
Persamaan di bawah menunjukkan tindak balas di antara larutan argentum nitrat dan
larutan natrium klorida

AgNO3 (aq) + NaCl(aq) → NaNO3 (aq) + AgCl(s)

Calculate the mass of silver chloride formed when 0.1 mol of silver nirate solution is added
to 0.1 mol of sodium chloride solution?
Hitungkan jisim argentum klorida yang terbentuk apabila 0.1 mol larutan argentum nitrat
di tambah ke dalam 0.1 mol larutan natrium klorida?
[ Relative atomic mass : Cl = 35.5; Ag = 108]
[ Jisim atom relatif : C =,35.5; Ag =108]

A 28.70 g

B 43.05g

C 21.50 g

D 14.35g

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50 Which of the following catalyst is used in the Haber process?


Yang manakah di antara mangkin berikut digunakan dalam proses Haber ?

A Platinum
Platinum
B Nickel
Nikel
C Iron
Besi
D Vanadium (V) oxide
Vanadium (V) oksida

END OF QUESTION PAPER


KERTAS SOALAN TAMAT

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SULIT 4541/2

Nama

Kelas
JABATAN PELAJARAN MELAKA
BUKIT BARU, MELAKA

PEPERIKSAAN AKHIR TAHUN 4541/2


TINGKATAN 4 2011
CHEMISTRY
Kertas 2
Oktober 2011
2 ½ jam Dua jam tiga puluh minit

JANGAN BUKA KERTAS SOALAN INI SEHINGGA DIBERITAHU

1. Kertas soalan ini mengandungi tiga bahagian: Untuk kegunaan pemeriksa


Bahagian A, Bahagian B and Bahagian C. Bahagian No. Markah
2. Jawab semua soalan dalam Bahagian A. Tulis 1
jawapan dalam Bahagian A dalam ruangan
yang disediakan..
2
3. Jawab satu soalan dalam Bahagian B dan satu 3
soalan dalan Bahagian C. Jawab soalan dalam A 4
Bahagian B dan Bahagian C dengan 5
terperinci. Anda boleh menggunakan 6
persamaan kimia, rajah, jadual, graf dan Jumlah
kaedah yang bersesuaian untuk menerangkan 7
jawapan anda.
B 8
4. Tunjukkan jalan kerja. Ia dapat membantu anda
mendapat markah.
5. Rajah dalam soalan tidak dilukis mengikut 9
skala. C 10
6. Markah yang diperuntukan bagi setiap soalan Jumlah
ditunjukkan dalam kurungan.
7. Anda boleh menggunakan kalkulator saintifik Jumlah Markah
yang tidak diprogramkan.
8. Serahkan kertas jawapan pada akhir waktu
peperiksaan.

Kertas soalan ini mengandungi 17 halaman bercetak

[Lihat sebelah
SULIT 2 4541/2

Section A
[60 marks]
Answer all questions
Jawab semua soalan

1 Table 1 shows the proton number and nucleon number for atoms P, Q , R and S.
Jadual 1 menunjukkan nombor proton dan nombor nukleon bagi atom P, Q, R dan S.

Atom Proton number Nucleon Number


P 16 32
Q 17 35
R 17 37
S 18 40
Table 1
Jadual 1

(a) (i) What is meant by proton number?


Apakah yang dimaksudkan dengan nombor proton ?

...............................................................................……………................…................

[ 1 mark ]
(ii) What is the number of neutrons in atom P?
Apakah bilangan neutron dalam atom P?

.................................................................................................………………….....….

[ 1 mark ]
(b) (i) Which atoms are isotopes? Explain your answer.
Atom-atom yang manakah adalah isotop? Terangkan jawapan anda.

.......................................................................................................................................

.......................................................................................................................................

[ 2 marks ]
(ii) Write the isotopes in the form of AZ XA.
Tuliskan isotop-isotop dalam bentuk Z X.

.......................................................................................................................................

[ 2 marks ]
(c) (i) Write the electron arrangement for atom R.
Tuliskan susunan elektron bagi atom R.

......................................................................................................................................

[ 1 mark ]

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(ii) Draw the electron arrangement of atom R.


Lukiskan susunan elektron bagi atom R.

[ 2 marks ]
(d) S is an inert gas which chemically unreactive
S merupakan gas lengai yang tidak reaktif secara kimia

Explain the above statement.


Terangkan kenyataan di atas.

................................................................................................................................................

[ 1 mark ]

2 Diagram 2 shows the apparatus set-up used in an experiment to determine the empirical formula
for an oxide of lead.
Rajah 2 menunjukkan susunan radas yang digunakan dalam eksperimen bagi menentukan
formula empirik bagi oksida plumbum.
oxide of lead
oksida plumbum

dry hydrogen
hidrogen kering

Diagram 2
Rajah 2

The following data was obtained based on the experiment :


Data berikut diperolehi berdasarkan suatu ekperimen:

Mass of an oxide of lead = 4.78 g


Jisim oksida plumbum
Mass of lead = 4.14 g
Jisim plumbum

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(a) What is meant by empirical formula ?


Apakah yang dimaksudkan dengan formula empirik ?

………………………….………………………………………………………....................

…………………………………………………………………………………………….....

[ 1 mark ]
(b) Name one substance that can be used to dry the hydrogen gas.
Namakan bahan yang boleh digunakan untuk mengeringkan gas hidrogen.

.................................................................................................................................................

[ 1 mark]
(c) Why does the hydrogen gas need to be passed through the combustion tube for a few
minutes before heating ?
Mengapakah gas hidrogen dialirkan ke dalam tiub pembakaran beberapa minit sebelum
pemanasan ?

.................................................................................................................................................

.................................................................................................................................................

[ 1 mark]
(d) How to ensure the reaction is complete ?
Bagaimana untuk memastikan tindak balas adalah lengkap?

.................................................................................................................................................

.................................................................................................................................................

[ 2 marks]
(e) Determine the empirical formula for oxide of lead ?
Tentukan formula empirik bagi oksida plumbum ?
[Relative atomic mass for O = 16 and Pb = 207]
[Jisim atom relatif bagi O = 16 dan Pb = 207]

[ 4 marks]

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(f) Why does the empirical formula of magnesium oxide cannot be determined using the
above method ?
Mengapa formula empirik magnesium oksida tidak boleh ditentukan menggunakan
kaedah di atas ?

.................................................................................................................................................

[ 1 mark]

3 Diagram 3 shows the positions of 6 elements represented by the letters A, B, C, D, E, F in the


Periodic Table of Elements.
Rajah 3 menunjukkan kedudukan 6 unsur yang diwakili oleh huruf A,B,C,D,E, F dalam Jadual
Berkala Unsur.

A B C D E
F

Diagram 3
Rajah 3

Using these letters, answer the following questions.


Menggunakan huruf-huruf tersebut, jawab soalan-soalan berikut.
(a) State the element which exists as a diatomic molecule under room condition.
Nyatakan unsur yang wujud sebagai molekul dwiatom pada keadaan bilik.

……………………………………………………………………………………………….

[ 1 mark ]
(b) State one special characteristic of element F .
Nyatakan satu ciri istimewa bagi unsur F.

…………………………………………………………………………………………….....

[ 1 mark ]
(c) (i) Arrange atoms A, B, C, D and E in decreasing order of atomic size.
Susun atom A, B ,C , D dan E mengikut tertib pengurangan saiz atom.

………………………………………………………………………………………...

[ 1 mark ]
(ii) Explain your answer in (c)(i).
Huraikan jawapan anda dalam (c)(i).

…………………………………………………………………………………….…..

………………………………………………………………………………………...

[ 3 marks ]

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(d) Write the chemical formula for the ion formed by element D.
Tuliskan formula kimia bagi ion yang terbentuk dari unsur D.

………………………………………………………………………………………….........

[ 1 mark ]
(e) Write the chemical equation for the reaction between the oxide of A and water.
Tuliskan persamaan kimia untuk tindakbalas antara oksida A dan air.

…………………………………………………………………………..…………………...

[ 3 marks]

4 Table 4 below shows the electron arrangement of 6 elements T,U,V,W, X and Y.


Jadual 4 menunjukkan susunan elektron bagi unsur-unsur T,U,V,W, X dan Y

Elements Proton number Electron arrangement

T 6 2.4
U 17 2.8.7
V 11 2.8.1
W 12 2.8.2
X 2.8.8
Y 19
Table 4
Jadual 4

(a) Based on Table 4, answer the following questions.


Berdasarkan Jadual 4, jawab soalan-soalan berikut.
(i) What is the proton number of element X ?
Berapakan nombor proton bagi unsur X?

......................................................................................................................................

[ 1 mark ]
(ii) What is the electron arrangement for ion Y?
Apakah susunan elektron bagi ion Y?

............................................................................................................………………...

[ 1 mark ]
(b) Element T reacts with element U to form a compound
Unsur T bertindakbalas dengan unsur U untuk membentuk satu sebatian
(i) Give the molecular formula of compound formed.
Berikan formula molekul bagi sebatian yang terbentuk.

.......................................................................................................................................

[ 1 mark ]

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(ii) State the type of bonding in the compound formed in (b)(i).


Nyatakan jenis ikatan yang terbentuk bagi sebatian yang terbentuk dalam (b)(i).

………………………………………………………………………………………...

[ 1 mark ]
(iii) Give two physical properties of the compound formed.
Berikan dua sifat fizikal sebatian yang terbentuk.

………………………………………………………………………………………...

………………………………………………………………………………………...

[ 2 marks ]
(iv) Illustrate the electron arrangement of the compound formed in (b)(i)
Lukis susunan elektron bagi sebatian yang terbentuk dalam (b)(i)

[ 2 marks ]
(c) Element W reacts with element U to form a compound. Write the chemical formula of the
compound formed by U and W.
Unsur W bertindakbalas dengan unsur U membentuk satu sebatian. Tuliskan formula
kimia bagi sebatian yang terbentuk oleh U dan W.

……………………………………………………………………………………….............

[ 1 mark ]
(d) State an element that can form a cation.
Nyatakan satu unsur yang boleh membentuk kation.

………………………………………………………………………………………...

[ 1 mark ]

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5 Table 5.1 shows incomplete observation for two sets of electrolysis of sodium chloride solution
with different concentration using carbon electrode.
Jadual 5.1 menunjukkan pemerhatian yang tidak lengkap bagi dua set elektrolisis larutan
natrium klorida dengan kepekatan yang berbeza menggunakan elektrod karbon.

Concentration of
sodium chloride
solution Observation
Set (mol dm-3) Pemerhatian
Kepekatan larutan
natrium klorida
(mol dm-3)

Anode Bubbles of colourless gas is released


Gas tanpa warna dibebaskan
Set 1 0.002
Cathode Bubbles of colourless gas is released
Gas tanpa warna dibebaskan

Anode ........................................................................
Set 2 1.0

Cathode ........................................................................

Table 5.1
Jadual 5.1
(a) (i) Complete Table 5.1
Lengkapkan Jadual 5.1

[ 2 marks ]
(ii) Describe a chemical test to identify the product formed at anode in set 2.
Huraikan satu ujian kimia untuk mengenalpasti hasil yang terbentuk di anod pada
set 2.

.......................................................................................................................................

.......................................................................................................................................

.......................................................................................................................................

[ 2 marks ]
(b) Based on experiment in set 1:
Berdasarkan eksperimen dalam set 1:
(i) Name the colourless gas formed at the cathode.
Namakan gas tanpa warna yang terbentuk di katod.

.......................................................................................................................................

[ 1 mark ]

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(ii) Write a half equation for the formation of gas at the cathode.
Tulis setengah persamaan untuk pembentukan gas di katod.

.......................................................................................................................................

[ 1 mark ]
(c) In another experiment, a student using apparatus and materials in Table 5.2 to produce an
electrical energy from chemical energy.
Dalam satu eksperimen lain, seorang pelajar menggunakan radas dan bahan dalam
Jadual 5.2 untuk menghasilkan tenaga elektrik dari tenaga kimia.

Apparatus Beaker, connecting wire, galvanometer


Radas Bikar, wayar penyambung, galvanometer
Materials Zinc , copper strip, copper (II) sulphate solution
Bahan Zink, kepingan kuprum, larutan kuprum (II) sulfat
Table 5.2
Jadual 5.2
(i) Diagram below shows incomplete apparatus set-up used in (c).
Rajah di bawah menunjukkan susunan radas tidak lengkap yang
digunakan pada (c).

Complete the diagram below.


Lengkapkan rajah di bawah.

[ 2 marks ]
(ii) State the direction of electron flow in this experiment.
Nyatakan arah pergerakan elektron dalam eksperimen ini.

................................................................................................................................................

[ 1 mark ]

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(iii) State the observation in the copper (II) sulphate solution.


Nyatakan pemerhatian pada larutan kuprum(II) sulfat.

................................................................................................................................................

[ 1 mark ]

6 An experiment is carried out to find the end point of acid-base titration. 25.0 cm3 of 1.0 moldm-3
sodium hydroxide solution reacts with hydrochloric acid. Table 6 shows the results of the
experiment.
Satu eksperimen dijalankan untuk menentukan takat akhir peneutralan antara asid dan alkali.
25.0 cm3 bagi 1.0 moldm-3 larutan natrium hidroksida bertindak balas dengan asid hidroklorik.
Jadual 6 menunjukkan keputusan bagi eksperimen tersebut.

Second Third
Volume of hydrochloric acid First reading
reading reading
Final burette reading/ cm3 21.00 41.60 25.80
3
Initial burette reading/ cm 0.00 21.00 5.00
Volume of hydrochloric acid used/ cm3
Table 6
Jadual 6

(a) Draw the set-up of apparatus that is used in the experiment.


Lukiskan gambar rajah susunan alat radas yang digunakan di dalam eksperimen ini.

[ 2 marks ]
(b) (i) State the indicator solution that is suitable to be used in the experiment.
Nyatakan larutan penunjuk yang sesuai untuk digunakan di dalam eksperimen ini.

………………………………………………………………………………………...

[ 1 mark ]

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(ii) Based on the indicator solution mentioned in (b)(i), state the colour change at the
end point.
Berdasarkan larutan penunjuk yang dinyatakan di dalam (b)(i), nyatakan
perubahan warna pada takat akhir.

………………………………………………………………………………………...

[ 1 mark ]
(c) (i) Complete Table 6 to find the volume of hydrochloric acid used.
Lengkapkan Jadual 6 untuk menentukan isipadu asid yang digunakan.
[ 1 mark ]
(ii) Calculate the average volume of hydrochloric acid used.
Kira isipadu purata bagi asid hidroklorik yang digunakan.

[ 1 mark ]
(d) Write the chemical equation for this experiment.
Tulis persamaan kimia bagi eksperimen ini.

……………………………………………………………………………………………….

[ 1 mark ]
(e) Find the concentration of hydrochloric acid used.
Tentukan kepekatan bagi asid hidroklorik yang digunakan.

[ 2 marks ]
(f) Hydrochloric acid is classified as a strong and monoprotic acid. State another example of
monoprotic acid.
Asid hidroklorik dikelaskan sebagai asid kuat dan asid monoprotik. Nyatakan contoh asid
monoprotik yang lain.

………………………………………………………………………………………....…….

[ 1 mark ]

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Section B
[20 marks]
Answer any one question from this section
Jawab mana-mana satu soalan dari bahagian ini

7 (a) Diagram 7 shows the electron arrangement of a molecule PQ2.


Rajah 7 menunjukkan susunan elektron bagi satu molekul PQ2.

Diagram 7
Rajah 7

Based on Diagram 7, write the electron arrangement for atoms of element P and element
Q.
Explain the position of element Q in the Periodic Table.
Berdasarkan Rajah 7, tulis susunan elektron bagi atom unsur P dan unsur Q.
Terangkan kedudukan unsur Q dalam Jadual Berkala
[6 marks]
(b) Table 7 shows the electron arrangement for atoms W, X and Y.
Jadual 7 menunjukkan susunan elektron bagi atom W,X dan Y.

Element Electron arrangement


W 2.4
X 2.8.7
Y 2.8.8.2
Table 7
Jadual 7

Using the information in Table 7, explain how two compounds can be formed from these
elements based on their electron arrangements.
The two compounds should have different bond types.
Menggunakan maklumat dalam Jadual 7, terangkan bagaimana dua sebatian dapat
terbentuk dari unsur-unsur ini berdasarkan susunan elektron.
Dua sebatian ini mestilah berbeza jenis ikatan.
[10 marks]
(c) Compare the physical properties for both chemical compound formed in (b).
Bandingkan sifat-sifat fizikal bagi kedua-dua sebatian yang terbentuk dalam (b).
[ 4 marks ]

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8 Table 8 shows the information on two type of acids.


Jadual 8 menunjukkan maklumat tentang dua jenis asid.

Acid Concentration (moldm-3) pH value


Asid Kepekatan (moldm-3) Nilai pH
Hydrochloric acid, HCl
0.1 1
Asid hidroklorik, HCl

Ethanoic acid, CH3COOH


0.1 4
Asid etanoik, CH3COOH
Table 8
Jadual 8

(a) One of the acids is a strong acid, while the other is a weak acid.
Satu daripada asid tersebut ialah asid kuat dan satu lagi ialah asid lemah.
(i) What are the definition for a strong acid and a weak acid?
Apakah takrifan bagi asid kuat dan asid lemah?
[ 2 marks ]
(ii) Identify the strong acid and weak acid.
Kenalpasti asid kuat dan asid lemah.
[ 2 marks ]
(iii) Explain why the pH values of the two acids are different.
Jelaskan tentang perbezaan nilai pH kedua-dua asid.
[ 4 marks ]
(b) (i) What is the definition of molarity?
State the formula and the unit of molarity.
Apakah takrifan kemolaran?
Nyatakan formula dan unit bagi kemolaran.
[ 3 marks ]
Explain how you would prepare 100.0 cm3 of 0.05 moldm-3 of hydrochloric acid
(ii)
from 0.50 moldm-3 of hydrochloric acid.
Terangkan bagaimana anda menyediakan 100.0 cm3, 0.05 moldm-3 asid hidroklorik
daripada 0.50 moldm-3 asid hidroklorik.
[ 5 marks ]
(iii) Calculate the volume of 40.0 gdm-3 of sodium hydroxide solution required to
neutralise the solution in b (ii).
[Relative atomic mass: H=1; O=16; Na=23]
Kira isipadu bagi 40.0 gdm-3 larutan natrium hidroksida yang diperlukan untuk
meneutralkan larutan dalam b(ii).
[Jisim atom relatif: H=1; O=16; Na=23]
[ 4 marks ]

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Section C
[20 marks]
Answer any one question from this
section
Jawab mana-mana satu soalan dari
bahagian ini

9 (a) State 3 factors that affects the selective discharged of ions during electrolysis .
Nyatakan 3 faktor yang mempengaruhi pemilihan ion untuk nyahcas semasa elektrolisis.
[ 3 marks ]
(b) Diagram 9 shows the set-up of apparatus of two experiments to investigate the electrolysis
process by using different electrodes.
Rajah 9 menunjukkan susunan radas bagi dua eksperimen untuk mengkaji proses
elektrolisis dengan menggunakan elektrod-elektrod yang berlainan.

Experiment
Apparatus set-up
Eksperimen
Susunan radas

I Copper electrodes
Elektrod kuprum

Copper(II) sulphate solution


Larutan kuprum(II) sulfat

Carbon electrodes
II Elektrod karbon

Copper(II) sulphate solution


Larutan kuprum(II) sulfat

Diagram 9
Rajah 9
Compare the observation and product formed at the anode for both experiments
Bandingkan pemerhatian dan hasil yang terbentuk di anod bagi kedua-dua eksperimen.

Write the half equation at the anode for both experiments.


Tuliskan setengah persamaan di anod bagi kedua-dua eksperimen.
[ 6 marks ]

4541/2 © 2011 Hak Cipta Jabatan Pelajaran Melaka


SULIT 15 4541/2

(c) Table 9 shows the voltage of chemical cell using metals A, B and C as the electrode.
Jadual 9 menunjukkan nilai voltan bagi sel kimia menggunakan logam A, B dan C
sebagai elektrod.

Pairs of metal Voltage (V) Positive terminal


Pasangan logam Nilai voltan (V) Terminal positif
B/C 0.1 C
A/C 0.8 C

Table 9
Jadual 9

Based on the information given,


Berdasarkan kepada maklumat yang diberikan,

(i) state the voltage of a chemical cell using metal A and B as the electrodes.
nyatakan nilai voltan yang akan dihasilkan oleh sel kimia yang menggunakan
logam A dan B sebagai elektrod.
(ii) state the negative terminal in (c)(i) and explain your answer.
nyatakan terminal negatif pada (c)(i) dan terangkan jawapan anda.
[ 3 marks ]
(d) A student has an inattractive ring and it is easy to corrode. To solve the problem, he uses
an electrolysis process in a laboratory.
Seorang pelajar mempunyai sebentuk cincin yang tidak menarik dan mudah berkarat.
Untuk mengatasi masalah ini, dia menggunakan proses elektrolisis di dalam makmal.

A student may used the apparatus and chemical as follow:


Pelajar boleh menggunakan radas dan bahan kimia seperti berikut:
Beaker, connecting wire and crocodile clip, battery, silver metal,
silver nitrate solution,
Bikar, wayar penyambung bersama klip buaya, bateri, kepingan
argentum , larutan argentum nitrat,

Describe an experiment on how to solve these problem. In your description include a


diagram to show the set-up of apparatus.
Huraikan satu eksperimen bagaimana untuk mengatasi masalah ini. Dalam penerangan
anda sertakan gambarajah untuk menunjukkan susunan radas.
[ 8 marks ]

4541/2 © 2011 Hak Cipta Jabatan Pelajaran Melaka [Lihat sebelah


SULIT
SULIT 16 4541/2

10 (a) (i) What is meant by ‘salt’ ?


Apakah yang dimaksudkan dengan ‘garam’?
[ 2 marks ]
(ii) Name salt derived from
• Nitric acid
• Hydrochloric acid
Namakan garam yang dihasilkan dari
• Asid nitrik
• Asid hidroklorik
[ 2 marks ]
(b) The following are three examples of sulphate salts that can be prepared in the
laboratory.
Berikut adalah tiga contoh garam sulfat yang boleh disediakan di dalam makmal.
• Potassium sulphate, K2SO4
Kalium sulfat, K2SO4
• Lead (II) sulphate, PbSO4
Plumbum (II) sulfat, PbSO4
• Zinc sulphate, ZnSO4
Zink sulfat, ZnSO4
(i) From these examples, identify the soluble and insoluble salts.
Daripada contoh-contoh ini, kenal pasti garam terlarutkan dan garam tak larut.
[ 2 marks ]
(ii) State the reactant for the preparation of the insoluble salt in 10(b)(i)
Nyatakan bahan tindak balas bagi penyediaan garam tak larut di 10(b)(i).
[ 2 marks ]
(c) With the aid of a labelled diagram, describe the procedure of experiment to prepare
the named insoluble salts by using the reactant in 10(b)(ii).
Your answer should include the
• list of materials and apparatus
• chemical equation
• ionic equation for the reaction.

Dengan bantuan gambarajah berlabel, huraikan langkah-langkah eksperimen untuk


menyediakan garam tidak larut yang dinamakan dengan menggunakan bahan
tindak balas dalam 10(b)(ii).
Jawapan anda mestilah mengandungi
• senarai bahan dan alat radas
• persamaan kimia
• persamaan ion bagi tindak balas.
[12 marks]

END OF QUESTION PAPER


KERTAS SOALAN TAMAT

4541/2 © 2011 Hak Cipta Jabatan Pelajaran Melaka


SULIT 17 4541/2

INFORMATION FOR CANDIDATES


MAKLUMAT UNTUK CALON

1. This question paper consists of three sections: Section A, Section B and Section C.
Kertas soalan ini mengandungi tiga bahagian: Bahagian A, Bahagian B dan Bahagian C.

2. Answer all questions in Section A. Write your answers for Section A in the spaces provided
in the question paper.
Jawab semua soalan dalam Bahagian A. Tuliskan jawapan bagi Bahagian A dalam ruang yang
disediakan dalam kertas soalan.

3. Answer one question from Section B and one question from Section C.
Write your answers for Section B and Section C on the `writing paper’ provided by the
invigilators.
Answer questions in Section B and Section C in detail.
You may use equations, diagrams, tables, graphs and other suitable methods to explain your
answer.
Jawab satu soalan daripada Bahagian B dan satu soalan daripada Bahagian C. Tuliskan jawapan
bagi Bahagian B dan Bahagian C pada kertas tulis yang disediakan. Jawab Bahagian B dan
Bahagian C dengan terperinci. Anda boleh menggunakan persamaan, gambar rajah, jadual, graf
dan cara lain yang sesuai untuk menjelaskan jawapan anda.

4. Show your working. It may help you to get marks.


Tunjukkan kerja mengira.Ini membantu anda mendapatkan markah.

5. If you wish to change your answer, neatly cross out the answer that you have done. Then
write down the new answer.
Sekiranya anda hendak membatalkan sesuatu jawapan, buat garisan di atas jawapan itu.

6. The diagrams in the questions are not drawn to scale unless stated.
Rajah yang mengiringi soalan tidak dilukiskan mengikut skala kecuali dinyatakan.

7. Marks allocated for each question or part question are shown in brackets.
Markah yang diperuntukkan bagi setiap soalan atau ceraian soalan ditunjukkan dalam kurungan.

8. The time suggested to answer Section A is 90 minutes, Section B is 30 minutes and Section
C is 30 minutes.
Masa yang dicadangkan untuk menjawab Bahagian A ialah 90 minit, Bahagian B ialah 30 minit dan
Bahagian C ialah 30 minit.

9. You may use a non-programmable scientific calculator.


Anda dibenarkan menggunakan kalkulator saintifik yang tidak boleh diprogramkan.

10. Hand in your answer sheets at the end of the examination.


Serahkan semua kertas jawapan anda di akhir peperiksaan.

4541/2 © 2011 Hak Cipta Jabatan Pelajaran Melaka [Lihat sebelah


SULIT
1 THE PERIODIC TABLE OF THE ELEMENTS
2
H
Hydrogen Proton number He
1 Helium
10 4
Symbol
3 4 Ne 5 6 7 8 9 10
Li Be Neon B C N O F Ne
Lithium Beryllium 20 Name of element Boron Carbon Nitrogen Oxygen Fluorine Neon
7 9 11 12 14 16 19 20
12 13 15
11 Relative atomic mass 14 16 17 18
Na Mg Al Si P S Cl Ar
Magnesiu Aluminiu Phosphor
Sodium Silicon Sulphur Chlorine Argon
m m us
23 28 32 35 40
24 27 31
23 25 32
19 20 21 22 24 26 27 28 29 30 31 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
Vanadiu Manganes Germaniu
Potassium Calcium Scandium Titanium Chromium Iron Cobalt Nickel Copper Zinc Gallium Arsenic Selenium Bromine Krypton
m e m
39 40 45 48 52 56 59 59 64 65 70 75 79 80 84
51 55 73
42 43 44
37 38 39 40 41 45 46 47 48 49 50 51 52 53 54
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
Molybden Technetiu Rutheniu
Rubidium Strontium Yttrium Zirconium Niobium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
um m m
86 88 89 91 93 103 106 108 112 115 119 122 128 127 131
96 98 101
57
55 56 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
Lanthanu
Caesium Barium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
m
133 137 179 181 184 186 190 192 195 197 201 204 207 209 210 210 222
139
106 107 108 109
87 88 89 104 105
Fr Ra Ac Unq Unp Unh Uns Uno Une
Unnil− Unnil−
Unnil−hex Unnilsepti Unnilocti Unnilenni
Francium Radium Actinium quadium pentium
ium um um um
223 226 227 257 260
263 262 265 266

60 61 64 66
58 59 62 63 65 67 68 69 70 71
Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
Praseo−
Neodymiu Promethiu Gadoliniu Dyprosiu
Cerium dymium Samarium Europium Terbium Holmium Erbium Thulium Ytterbium Lutetium
m m m m
140 141 150 152 167 165 167 169 173 175
144 147 157 163
91 93 95 98 99 101 103
90 92 94 96 97 100 102
Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
Protactini Neptuniu Americiu Californiu Einsteiniu Mendelev Lawrenci
Thorium Uranium Plutonium Curium Berkelium Fermium Nobelium
um m m m m ium um
232 238 244 247 247 253 254
231 237 243 249 254 256 257
Reference: Chang, Raymond (1991). Chemistry. McGraw−Hill
4541/1, 4541/2
CHEMISTRY 1,
CHEMISTRY 2
Oktober
2011

JABATAN PELAJARAN MELAKA

BUKIT BARU, MELAKA


____________________________________________________________
PEPERIKSAAN AKHIR TAHUN

TINGKATAN 4

2011

CHEMISTRY 1
CHEMISTRY 2

PERATURAN PEMARKAHAN

Skema Pemarkahan ini mengandungi 10 halaman bercetak


2

MARKING SCHEME OF CHEMISTRY PAPER 1

1 C 11 D 21 D 31 C 41 A

2 D 12 A 22 D 32 B 42 A

3 C 13 D 23 C 33 C 43 C

4 A 14 A 24 B 34 B 44 C

5 A 15 B 25 C 35 A 45 D

6 D 16 B 26 A 36 D 46 B

7 B 17 A 27 B 37 B 47 C

8 A 18 C 28 B 38 A 48 B

9 C 19 A 29 C 39 D 49 D

10 D 20 B 30 A 40 B 50 C
3

MARKING SCHEME OF CHEMISTRY PAPER 2

Scheme Marks Sub-


total

1. (a) (i) The number of protons in the nucleus of an atom 1

(ii) 16 1 2

(b) (i) Q and R, 1

Q and R have same number of protons but


different number of neutrons/ different nucleon
number 1

(ii)
35
Q 1
17

37
Q 1
17
4

(c) (i) 2.8.7 1

(ii)

Number of shells(3) 1

Number of electrons 1 3

(d) Because S has 8 valence electrons // has achieved 1 1


[stable] octet electron arrangement.
Total
10 m
4

2 a Empirical formula is a chemical formula that shows


the simplest ratio of the number of atom for each 1 1
element in the compound
b Anhydrous Calcium chloride // concentrated 1 1
sulphuric acid

c To ensure that the combustion tube has been filled


with hydrogen gas 1 1

d The process of heating, cooling and weighing are


repeated 1
until a constant mass of substance and its container is 2
obtained 1
e

Pb O
Mass (g) 4.14 0.64 1
No of mole n=4.14/207 n= 0.64/16
=0.02 =0.04 1
Simplest 1 2
ratio 1
Empirical PbO2
formula 1 4

f Because Mg is at higher position than H in the


electrochemical series. 1 1

Total
10m

3 a D 1 1
b - has more than one oxidation number //
- can act as catalyst//
- can formed complex ion
- can formed coloured ion 1 1
[ any one ]
c (i) A,B,C,D,E 1
(ii) - Across the period, the proton number of
each atom increase 1
- Nuclei charge in the nucleus increase 1
- Force of attraction between nucleus and
outermost shell become stronger //
outermost shell are pulled closer to the 1 4
nucleus

d D-1 1 1
e A2O + H2O 2AOH
5

- formula of reactant 1
- formula of product 1
- balance equation 1 3

Total
10 m

4 a (i) 18 1 2
(ii) 2.8.8 1
b (i) TU4 1
(ii) Covalent bond 1
(iii) - low melting and boiling point// 1
- cannot conduct electricity in any state // 1
- insoluble in water // soluble in organic
solvent.
[any two of the above]
(iv) - correct number of electron in each shell 1 6
- four atom U combine with one atom T
[ the atom is labelled] 1
c WU2 1 1
d V // W // Y 1 1
[ any one ]
Total
10m

5 a (i) Anode : Greenish yellow gas is released 1


Cathode : Colourless gas is released 1
(ii) - Insert a damp blue litmus at [the anode] 1
- Blue litmus paper turn red and [bleached] 1 4

b (i) Hydrogen 1
(ii) 2H+ + 2e → H2 1 2

c (i) Functional diagram 1


Labelled diagram – zinc strip, copper strip ,
copper(II) sulphate solution 1
(ii) Zinc to copper through connecting wire 1
(iii) Blue turn colourless 1 4

Total
10m
6

6 a - Functional diagram with correct shaded solution in 1


conical flask and burette
- label of sodium hydroxide solution in conical flask 2
and hydrochloric acid in the burette 1

b (i) - Phenolphtalein solution// 1


[ accept any suitable indicator solution ] 2
(ii) pink to colourless 1
c (i) 21.00, 20.60, 20.80 1 1
(iii) =21.00 + 20.60 + 20.80 //
3
3
= 20.80 cm 1 1

d NaOH + HCl NaOH + H2O 1 1


- correct formula and reactant
e MaVa = na
MbVb nb

Ma x 20.80 = 1 1
1.0 x 25.0 1
Concentration of HCl, Ma = 1.20 moldm-3 1 2

[ accept another suitable method ]


f Nitric acid 1 1
Total
10m

7 a - The electron arrangement of P atom is 2.4 1


- and Q atom is 2.6. 1
- Q atom is in group 16 because it 1
- has 6 valence electron and 1
- it is in period 2 because 1 6
- it has 2 shells occupied with electron. 1

b Ionic bond:
- X atom has 7 valence electron and Y atom has 2
valence electron. 1
- These electron arrangement are unstable. 1
- To achieve a stable electron arrangement, Y atom
donate 2 valence electron and form Y2+ ions 1
- 2 atom X receive 1 electron each and form X- ions. 1
- Y2+ ion and X- ions are attract to each other 1
- to form an ionic compound with formula YX2 1
7

Covalent bond:
- W atom has 4 valence electron and X atom has 7 1
valence electron.
- To achieve a stable electron arrangement, one W 1
atom share 4 valence electron with 4 atom X. 1 10
- They will form 4 single covalent bond 1
- with a formula WX4

c Ionic compound Covalent compound


1. soluble in water Insoluble in
water 1
2. insoluble in organic Soluble in
solvent organic solvent 1
3. conduct electricity in Cannot conduct
molten and aqueous state electricity in any state 1
4. high melting and boiling Low melting 4
1
point and boiling point

Total = 20m

8 a (i). - strong acid is an acid which ionises /dissociates


completely in water to produce a high
concentration of hydrogen ions, H+ 1

- weak acid is an acid which ionises / dissociates


partially in water to produce a low
concentration of hydrogen ions, H+ 1 2

(ii). Strong acid - hydrochloric acid / HCl 1


Weak acid - ethanoic acid / CH3COOH 1 2

(iii). - hydrochloric acid ionises completely in water


and produced high concentration of hydrogen
ions 1
- the high concentration of hydrogen ions causes
the pH value to become lower 1
- ethanoic acid ionises partially in water and
produced lower concentration of hydrogen 1
ions.
- the lower concentration of hydrogen ions
causes the pH value to become higher 1 4
8

b (i). Molarity is the number of moles solute present in


1 dm3 solution. 1

- Molarity = no of moles of solute (mol) 1 3


Volume of solution (dm3)

- Unit , moldm-3 1

(ii). - Calculation: M2 = 100 X 0.05


0.5
= 10 cm3 1
- Using pipette, 10.0 cm3 of 0.50 moldm-3 of
hydrochloric acid is transferred to a 100 ml
volumetric flask. 1
- Distilled water is then added to the acid in the
volumetric flask until near the calibration mark 1
- Add distilled water dropwise to the volumetric
flask until water level exactly reach its 5
calibration mark 1
- Stopper the flask and shake well the solution by
up side down the flask to ensure thorough mixing 1

(iii). - Molarity of NaOH = 40 gdm-3


23 + 16 + 1
= 1.0 moldm-3 1

NaOH + HCl NaCl + H2O 1

MaVa = na
MbVb nb
4
- 0.05 X 100.0 = 1 1
1.0 X Vb 1

- Volume of NaOH, Vb = 5.0 cm3 1


[ Accept another suitable method ]

Total
20m
9 (a) i. concentration of ion 1
ii. type of electrode 1
iii. position of ion in electrochemical series 1 3

(b)
I II
Anode becomes thinner Gas bubbles are released 1+1
Copper (II) ion Oxygen 1+1
2+
Cu  Cu + 2e 4OH-  O2 + 2H2O + 4e 1+1 6
9

(c) (i) 0.8 - 0.1 = 0.7V // 0.7V 1

(ii) - Electrode A, 1 3
- A is more electropositive than B 1
(d) Procedure of experiment:

i. [50-200 cm3] dilute silver nitrate solution is


poured into a beaker. 1
ii. An iron ring is cleaned using sand paper. 1
iii. Iron ring is connected to negative terminal of
battery // silver metal is connected to positive
terminal of battery 1
iv. Iron ring and silver metal is immersed into the
silver nitrate solution 1
v. The circuit is completed using connecting wire 1
vi . Using small current/turn the ring steadily 1
vii. Diagram:
- Functional diagram contain two different metals
as electrode ( no need with correct electrode) and
the solution is shaded correctly. 1
- iron spoon as cathode, silver as anode and silver 8
nitrate solution are labelled. 1

Total = 20m

10 a (i). - An ionic compound formed when the 1


- hydrogen ion in an acid is replaced by the
metal ion or ammonium ion 1

(ii) ● sodium nitrate / potassium nitrate etc 1


● silver chloride / sodium chloride etc 1 4

b (i) Soluble salts : potassium sulphate and zinc


sulphate 1
Insoluble salts : lead (II) sulphate 1

(ii) Lead (II) nitrate and sodium sulphate. 1+1 4


[ any suitable and correct answer ]

c - Alternative Diagram :
(i) Process of mixing the solution, contains:
• Diagram shows the mixture of lead (II)
nitrate in and sodium sulphate in a beaker
with glass rod 1
• shade the solution / mixture correctly 1
10

OR OR

(ii) Diagram shows the filtration process, contains:


● Labelled;
Lead (II) sulphate in filter paper (as
residue), Sodium nitrate solution in the
beaker (as filtrate and shaded ) 1
● The set of apparatus contain filter paper,
filter funnel ( clamped at retort stand) and
beaker. 1

- Materials and apparatus:


[0.1 – 1.0moldm-3 ] sodium sulphate solution,
[0.1 – 1.0 moldm-3] lead (II) nitrate solution,
50 ml beaker, 50.0 ml measuring cylinder,
rod, filter paper, filter funnel, conical flask. 1

- Procedure:
i. [ 50.0 cm3 of 0.5 moldm-3] of sodium sulphate
solution is measured using 50.0 ml measuring
cylinder and pour into a beaker, A. 1
ii. [50.0 cm3 of 0.5 moldm-3] of lead (II ) nitrate
solution is measured using 50.0 ml measuring
cylinder and pour into another beaker, B. 1
iii. Solution in beaker A is poured into the
solution in beaker B. 1
iv. Stir with glass rod, precipitate formed. 1
v. The precipitate is filtered into a conical flask
using filter paper and filter funnel and rinsed the
residue with distilled water 1
vi. Dry the residue by pressing between two filter
papers. 1

- Chemical equation:
Na2SO4 + Pb(NO3)2 PbSO4 + 2NaNO3

- Correct reactant and product 1


- Balance equation 1
12
- Ionic equation:
Pb2+ + SO42- PbSO4 1 Total
20

END OF MARK SCHEME


SULIT 4541/3

Nama

Kelas
JABATAN PELAJARAN MELAKA
BUKIT BARU, MELAKA

PEPERIKSAAN AKHIR TAHUN 4541/3


TINGKATAN 4 2011
CHEMISTRY
Kertas 3
Oktober 2011

1 ½ jam Satu jam tiga puluh minit

JANGAN BUKA KERTAS SOALAN INI SEHINGGA DIBERITAHU

1. Tuliskan nama dan tingkatan pada


ruang yang disediakan. Untuk kegunaan pemeriksa sahaja
Markah Markah
Soalan
2. Kertas soalan ini adalah dalam dwi Penuh diperolehi
bahasa.
1 33
3. Calon hendaklah membaca arahan pada
halaman 2 .
2 17

Jumlah 50

Kertas soalan ini mengandungi 9 halaman bercetak


[Lihat sebelah
2

INFORMATION FOR CANDIDATES

1. This question paper consists of two questions. Answer all questions.


Kertas soalan ini mengandungi dua soalan. Jawab semua soalan.

2. Write your answer for Question 1 in the spaces provided in the question paper.
Tulis jawapan anda bagi Soalan 1 pada ruang yang disediakan dalam kertas soalan ini.

3. Write your answers for Question 2 on the writing paper provided by the invigilators.
Tulis jawapan anda bagi Soalan 2 pada kertas tulis yang disediakan.

4. You may use equations, diagrams, tables, graph and other suitable methods to explain
your answer.
Anda boleh menggunakan persamaan , rajah, jadual, graf dan cara lain yang sesuai
untuk menjelaskan jawapan anda.

5. Show your working, it may help you to get marks.


Tunjukkan kerja mengira, ini membantu anda mendapatkan markah.

6. If you wish to change your answer, cross out the answer that you have done. Then write
down the new answer.
Jika anda hendak menukar jawapan, batalkan jawapan yang telah dibuat. Kemudian
tulis jawapan yang baru.

7. Marks allocated for each question or part question are shown in brackets.
Markah yang diperuntukkan bagi setiap soalan atau ceraian soalan ditunjukkan dalam
kurungan.

8. The time suggested to answer each of the questions is 45 minutes.


Masa yang dicadangkan untuk menjawab setiap soalan ialah 45 minit.

9. You may use a non-programmable scientific calculator.


Anda dibenarkan menggunakan kalkulator saintifik yang tidak boleh diprogram.

10. Hand in your answer sheets at the end of the examination.


Serahkan kertas jawapan anda di akhir peperiksaan.

4541/3 © 2011 Hak Cipta Jabatan Pelajaran Melaka


SULIT 3 4541/3

Answer all question


Jawab semua soalan
For Examiner’s
Use
1 A student carried out three experiments to study the reaction of alkali metal with water.
Seorang pelajar menjalankan tiga eksperimen untuk mengkaji tindak balas di antara logam
alkali dengan air.

Set up of apparatus Observation of the alkali metal


Susunan alat radas Pemerhatian terhadap logam alkali
Lithium
Litium

Water
Air

Set I
Sodium
Natrium

Water
Air

Set II

Potassium
Kalium

Water
Air

Set III

Diagram 1.1
Rajah 1.1

(a) Look at Diagram 1.1. Complete Diagram 1.1 by stating the observations for the reaction of
group 1 metals with water based on the movement on the water surface , flame and the sound
produce.
Perhatikan Rajah 1.1. Lengkapkan Rajah 1.1 dengan menyatakan pemerhatian bagi tindak 1(a)
balas di antara logam kumpulan 1 dengan air berdasarkan kepada pergerakannya di atas
permukaan air, nyalaan, dan bunyi yang terhasil.
[3 marks] 3

4541/3 © 2011 Hak Cipta Jabatan Pelajaran Melaka [Lihat sebelah


SULIT
SULIT 4 4541/3

For Examiner’s
Use
(b) Based on data in Diagram 1.1, complete the table below.
Berdasarkan data dalam Rajah 1.1, lengkapkan jadual di bawah.
Name of variables Action to be taken
Nama pembolehubah Tindakan yang perlu diambil
Manipulated variable Method to manipulate variable
Pembolehubah dimanipulasi Kaedah memanipulasikan pemboleh ubah

………………………………………... ...........................................................................

………………………………………... …………………………………………………

………………………………………... ………………………………………………….
Responding variable What to observe in the responding variable
Pembolehubah bergerak balas Perkara yang perlu diperhati dalam
pembolehubah bergerak balas
………………………………………...
.............................................................................
………………………………………...
.............................................................................
………………………………………...
.............................................................................
Constant variable Method to maintain constant variable
Pembolehubah dimalarkan Kaedah untuk menetapkan pemboleh ubah
dimalarkan
………………………………………... .............................................................................

………………………………………... ............................................................................. 1(b)

………………………………………... ………………………………………………….
[3 + 3 marks] 6

(c) State the hypothesis for this experiment.


Nyatakan hipotesis bagi eksperimen ini.

.......................................................................................................................................................
1(c)
………………………………………………………………………………………...................
[3 marks]
3

4541/3 © 2011 Hak Cipta Jabatan Pelajaran Melaka SULIT


SULIT 5 4541/3

For Examiner’s
Use
(d) State two inferences based on the results of the reaction between lithium and water
Nyatakan dua inferens berdasarkan kepada keputusan tindak balas antara litium dengan air.

…………………………………………………………………………………………………...
1(d)
…………………………………………………………………………………………………...
[3 marks]
3

(e) Based on the observation in Diagram 1.1, arrange lithium, potassium and sodium in
descending order of reactivity towards water.
Berdasarkan pemerhatian dalam Rajah 1.1, susunkan litium, kalium dan natrium mengikut
tertib kereaktifan logam terhadap air secara menurun.
1(e)
……………...……………………………………………………………………………………
[3 marks]
3

(f) The experiment is repeated using a small piece of rubidium to react with water.
Rubidium is an alkali metal which is placed below potassium in the periodic table.
Eksperimen diulangi menggunakan seketul kecil rubidium untuk ditindakbalaskan dengan air.
Rubidium ialah logam alkali yang terletak di bawah kalium dalam jadual berkala.

Predict the observation for this experiment.


Ramalkan pemerhatian bagi tindak balas ini.
1(f)
...................………………………………………………………………………………………
[3 marks]
3

(g) The student continued the experiment to determine the pH value of the solution formed in the
basin.
Pelajar tersebut meneruskan eksperimen untuk menentukan nilai pH bagi larutan yang
terhasil di dalam besen.

Diagram 1.2 shows the reading of pH meter when the pH meter is dipped into the solution in
the basin.
Rajah 1. 2, menunjukkan bacaan meter pH apabila meter pH dicelupkan ke dalam larutan di
dalam besen.

4541/3 © 2011 Hak Cipta Jabatan Pelajaran Melaka [Lihat sebelah


SULIT
SULIT 6 4541/3

Set Set-up of apparatus


Set Susunan radas

pH value
Nilai pH 13.13

pH meter
Meter pH
I

Litium hydroxide
solution
Larutan litium
hidroksida

13.43
pH value
Nilai pH
pH meter
II Meter pH
Sodium hydroxide
solution
Larutan natrium
hidroksida

13.63
pH value
Nilai pH

pH meter
III Meter pH

Potassium hydroxide
solution
Larutan kalium
hidroksida

Diagram 1.2
Rajah 1.2

4541/3 © 2011 Hak Cipta Jabatan Pelajaran Melaka SULIT


SULIT 7 4541/3

For Examiner’s
Use
(i) Record the pH value to one decimal place for Set I, Set II and Set III.
Catatkan nilai pH pada satu tempat perpuluhan bagi Set I, Set II dan Set III.

Set I : ………………………………………………………………………………

Set II : ………………………………………………………………………………
1(g)(i)
Set III : ……………………………………………………………………………….
[3 marks]
3

(ii) Construct a table to record the pH value for Set I, Set II and Set III.
Bina satu jadual untuk merekod nilai pH bagi Set I, Set II dan Set III.

1(g)(ii)

[3 marks] 3

(iii) State the operational definition for the alkali.


Nyatakan definisi secara operasi bagi alkali.

.................…………………………………………………………………………………

1(g)(iii)
………….…………………………………………………………………………………
[3 marks]
3

4541/3 © 2011 Hak Cipta Jabatan Pelajaran Melaka [Lihat sebelah


SULIT
SULIT 8 4541/3

For Examiner’s
Use
(iv) The following is a list of chemical substances with pH value:
Berikut ialah senarai beberapa bahan kimia dengan nilai pH

Chemical substance pH value


Bahan kimia Nilai pH
Ammonia solution, NH3
10
Larutan ammonia, NH3
Potassium hydroxide solution, KOH
14
Larutan kalium hidroksida KOH
Sodium hydroxide solution, NaOH
13
Larutan natrium hidroksida NaOH

Classify these substances into strong alkali and weak alkali.


Kelaskan bahan-bahan ini kepada alkali kuat dan alkali lemah.

1(g)(iv)

[3 marks]
3

4541/3 © 2011 Hak Cipta Jabatan Pelajaran Melaka SULIT


SULIT 9 4541/3

2 For Examiner’s
Use
Experiment Result
Eksperimen Keputusan

Molten lead(II)bromide Bulb lights up


Plumbum(II)bromida lebur Mentol menyala

Molten naphthalene
Naftalena lebur Bulb does not light up
Mentol tidak menyala

Diagram 2
Rajah 2
Diagram 2 shows the apparatus set-up for an experiment to compare the electrical conductivity
between two types of chemical compound.
Rajah 2 menunjukkan susunan radas bagi satu eksperimen untuk membezakan kekonduksian
elektrik di antara 2 jenis sebatian kimia.
Refering to the situation above, plan a laboratory experiment to investigate the difference in
electrical conductivity between an ionic compound and a covalent compound.
Merujuk kepada situasi di atas, rancang satu eksperimen dalam makmal untuk mengkaji perbezaan
kekonduksian elektrik di antara sebatian ionik dan sebatian kovalen.

Your planning should include the following aspects:


Perancangan anda hendaklah mengandungi aspek-aspek berikut:

(a) Problem of statement


Pernyataan masalah
(b) All the variables
Semua pembolehubah
(c) Hypothesis
Hipotesis
(d) List of materials and apparatus
Senarai bahan dan radas
(e) Procedure
Prosedur
(f) Tabulation of data 2
Penjadualan data
[17 marks] 17
[17 markah]

END OF QUESTION PAPER


KERTAS SOALAN TAMAT

4541/3 © 2011 Hak Cipta Jabatan Pelajaran Melaka [Lihat sebelah


SULIT
4541/3
Chemistry 3
Oktober
2011

JABATAN PELAJARAN MELAKA


BUKIT BARU, MELAKA
____________________________________________________________
PEPERIKSAAN AKHIR TAHUN
TINGKATAN 4
2011

CHEMISTRY 3

PERATURAN PEMARKAHAN

Skema Pemarkahan ini mengandungi 11 halaman bercetak


2

MARKING SCHEME OF PAPER 3

Question Details Score


[Able to state all the observations correctly]
Sample answer :

Set Observation
I Lithium moves slowly on the water surface 3
1(a) II Sodium moves faster on the water surface with a hissing sound
and ignites with a yellow flame.
III Potassium moves vigorously on the water surface with a hissing
and ‘pop’ sound and ignites with a lilac flame
[Able to state any two observations correctly] 2
[Able to state any one observation incompletely] 1
[No response given or wrong response] 0

[Able to state three variables and the way to control them correctly]
Sample answer:
Manipulated variable:
Use different type of alkali metals
Type of alkali metals
6
Responding variable: Observe the reactivity of alkali
metals when react with water
Reactivity of alkali metals
1 (b)
Fixed variable: Use water // same size of metals
in each experiment .
Water// size of alkali metals
[Able to state any 5 of the above information correctly] 5
[Able to state any 4 of the above information correctly ] 4
[Able to state any 3 of the above information correctly] 3
[Able to state any 2 of the above information correctly ] 2
[Able to state at least 1 of the above information correctly ] 1
[No response given or wrong response] 0
3

Question Details Score


[Able to state the relationship between the manipulated variable and the
responding variable correctly with direction]
Sample answer: 3
When going down Group 1, alkali metals become more reactive in their
reactions with water //
The lower the position of an alkali metal in the Periodic Table, the more
reactive it is when reacts with water

[Able to state the relationship between the manipulated variable and the
responding variable]
1 (c) Sample answer: 2
The lower position of an alkali metal in the Periodic Table, the more
reactive is the metal.

[Able to state an idea of hypothesis]


Sample answer:
1
Alkali metal have different reactivity.
Alkali metal reacts with water

[No response given or wrong response] 0

[Able to state two inferences correctly ]

Sample answer:
1. Lithium is the least reactive metal towards water
2. Lithium hydroxide is formed.
3. Hydrogen gas is released 3
4. Alkali solution is produced

1 (d) [Able to state one inference correctly]


Or
2
[Able to state two inferences incompletely]
[Able to state an idea of inference]

Sample answer:
1
Reaction occurs

[No response given or wrong response] 0


4

Question Details Score


[Able to arrange the position of all metals in descending order of
reactivity correctly]
Sample answer: 3
Potassium/K, Sodium/Na, Lithium/Li
[Able to arrange the position of at least two adjacent metals in
descending order of reactivity correctly]

Sample answer:
2
1 (e) Lithium/Li, Potassium/K, Sodium/Na //
Sodium/Na, Lithium/Li , Potassium/K

[Able to give an idea to arrange the metals]

Sample answer:
Lithium/Li, Sodium/Na, Potassium/K
1
Potassium/K Lithium/Li, Sodium/Na,
Sodium/Na, Potassium/K , Lithium/Li

[No response given or wrong response] 0

[Able to predict the observation for the reaction between rubidium and
water correctly ]
3
Sample answer:
Rubidium moves more vigorously / violently / produces white fume.

[Able to predict the observation for the reaction between rubidium and
water]
2
1(f) Sample answer:
Rubidium moves vigorously.

[Able to state an idea to predict the observation for the reaction between
rubidium and water]
1
Sample answer:
Rubidium is more reactive.

[No response given or wrong response] 0


5

Question Details Score


[Able to record all the pH meter reading with one decimal place
accurately]:

Sample answer:
Set I : 13.1
Set II : 13.4 3
Set III : 13.6
1 (g)(i)

[Able to record any two readings accurately] 2


Or
[Able to record all the pH meter readings without one decimal place
correctly]
[Able to record at least one reading correctly] 1
[No response given or wrong response] 0

Able to construct a table to record the pH value for Set I, Set II and
Set III of experiment that includes the following :
1. Correct titles
2. pH values
Sample answer:
Set pH 3
I 13.1

II 13.4

III 13.6
1(g)(ii) Able to construct a table that contains the following:
1. Titles
2. pH values
Sample answer:
pH
2
I 13.1

II 13.4

III 13.6
Able to construct a table with at least one title/reading. 1
[No response given or wrong response] 0
6

Question Details Score


[Able to state the operational definition for alkali correctly]

Sample answer: 3
pH value that is more than 7 when pH meter is dipped into a solution.

[Able to state the operational definition for alkali incompletely]

Sample answer: 2
1(g)(iii) pH value that is more than 7.

[Able to state an idea of operational definition for alkali ]

Sample answer: 1
pH that is 13.

[No response given or wrong response] 0

[Able to classify all the substances correctly]


Sample answer:

Strong alkali Weak alkali 3


Sodium hydroxide solution Ammonia solution
1(g)(iv) Potassium hydroxide solution

2
[Able to classify any two substances correctly]
[Able to classify any one substance correctly] 1
[No response given or wrong response] 0
7

Question Details Score


Able to give the problem statement accurately and in question
form.
3
Sample answer:
What is the difference in electrical conductivity between ionic
compound and covalent compound?

Able to give the statement of the problem correctly.


2
Sample answer:
How does different type of chemical compound affect the electrical
2(a)
conductivity?

Able to give an idea of statement of the problem .

Sample answer: 1
To investigate the electrical conductivity between different type of
chemical compound.

No response or wrong response 0

Able to state all the three variables correctly.

Sample answer:
Manipulated variable: Type of chemical compound/ molten 3
lead(II)bromide and molten naphthalene
Responding variable : Electrical conductivity / the light of
2(b) the bulb
Controlled variable : Mass/state of the chemical compound //
lead(II)bromide and molten naphthalene

Able to state any two variables correctly 2


Able to state any one variable correctly 1
No response or wrong response 0
8

Question Details Score


Able to state the relationship between the manipulated variable and
the responding variable correctly with direction.

Sample answer:
3
Molten ionic compound / lead(II)bromide can conduct electricity /
while molten covalent compound / molten naphthalene cannot
conduct electricity

Able to state the relationship between the manipulated variable and


the responding variable with direction .
2(c) 2
Sample answer:
Ionic compound can / cannot conduct electricity while covalent
compound cannot / can conduct electricity
Able to state the idea of the hypothesis.

Sample answer: 1
Different compound have different property of electrical
conductivity.

No response or wrong response 0


9

Question Details Score


Able to give adequate list of materials and apparatus.

Sample answer:
Materials
1 Lead (II) bromide
2 Naphthalene
Apparatus
1 Crucible
2 Batteries 3
3 Bulb
4 Switch
5 Carbon electrodes
6 Tripod stand
7 Bunsen Burner
8 Pipe-clay triangle
9 Connecting wire

Able to give a list of materials and apparatus.

Sample answer:
Materials
1 Lead (II) bromide
2(d) 2 Naphthalene
Apparatus 2
1 Crucible / Any container
2 Batteries
3 Bulb/voltmeter/ammeter
4 Electrodes
5 Bunsen Burner
6 Connecting wire

Able to give an idea of materials and apparatus.

Sample answer:
Material
Lead (II) bromide / naphthalene
Apparatus
1 Any container 1
2 Batteries
3 Ammeter / bulb / voltmeter
4 Electrodes
5 Bunsen burner

No response or wrong response 0


10

Question Details Score


Able to state the following steps:

Sample answer:
1 Fill a crucible with a solid lead(II)bromide, PbBr2 until it is
half full.
2 Complete the circuit. 3
3 Heat the solid lead(II)bromide until it melts.
4 Observe whether the bulbs light up or not.
5 Record the observation.
6 Repeat steps 1 to 5 / the experiment using naphthalene.

Able to state at least the following steps:


2(e)
Sample answer: 2
Steps 2, 3,5 and 6

Able to state at least the following steps:

Sample answer: 1
Step 2, 3 and 5

No response or wrong response 0


11

Question Details Score


Able to tabulate the data that includes the following information:
1. Correct titles
2. Complete list of chemical compound

Sample answer :
2
Chemical compound Observation
Lead(II)bromide
Naphthalene
2(f)

Able to construct a table with:


1. At least one title
2. Incomplete list of chemical compound

Sample answer :
1
Observation
lead(II)bromide/
Naphthalene

No response or wrong response 0

END OF MARK SCHEME

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