Solutions AIATS JEE (Adv) - 2019 (P) Test-1A (Code-E & F) Paper-2 (04!11!2018)

Test - 1A (Paper - 2) (Code-E) (Answers) All India Aakash Test Series for JEE (Advanced)-2019
All India Aakash Test Series for JEE (Advanced)-2019

TEST - 1A (Paper-2) - Code-E
Test Date : 04/11/2018
ANSWERS
PHYSICS CHEMISTRY MATHEMATICS
1. (A, B, D) 19. (D) 37. (A, B, D)
2. (A, B, C) 20. (A, B, D) 38. (B, D)
3. (A, C, D) 21. (A, D) 39. (A, C)
4. (A, C) 22. (B, D) 40. (B, C, D)
5. (A, D) 23. (A, B, C) 41. (A, C)
6. (A, D) 24. (B) 42. (B, C, D)
7. (13) 25. (44) 43. (12)
8. (20) 26. (40) 44. (64)
9. (25) 27. (26) 45. (04)
10. (16) 28. (64) 46. (92)
11. (80) 29. (16) 47. (51)
12. (12) 30. (60) 48. (72)
13. (22) 31. (10) 49. (09)
14. (45) 32. (06) 50. (06)
15. (D) 33. (D) 51. (C)
16. (B) 34. (B) 52. (B)
17. (A) 35. (C) 53. (A)
18. (C) 36. (B) 54. (B)
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All India Aakash Test Series for JEE (Advanced)-2019 Test - 1A (Paper - 2) (Code-E) (Hints & Solutions)
HINTS & SOLUTIONS

PART - I (PHYSICS)
1. Answer (A, B, D) Tmin = mg (–ve)
Hint :
mv 2
maaA = 10 – mag =0
l
Solution :
2 × aA = 10 – 4 mv 02
= 4mg
aA = 3 ms–2 l
2. Answer (A, B, C) Tmax= 4mg + mg = 5 mg
Hint : Tmin = mg (compression)
Work energy theorem 4. Answer (A, C)
Solution : Hint :
When chain becomes vertical
Ycm
l mg l 1 tan θ =
mg – = mv 2 X cm
2 2 4 2
3 1 Solution :
mgl = mv 2
8 2
C D
3 1
v = gl = 3gl l/2 
4 2 cm
3. Answer (A, C, D) l/4
Hint :
At highest point velocity of bob is zero and A B E
compression T = mg in the rod Let us assume mass of each section is m.
Solution : Torque about C
l l
1 1 mg × + mgl – mg = I α
mv 02 = mgl + mv12 2 2
2 2
⎡ ml 2 ml 2 ⎛ l 2 ⎞⎤
1 I =2⎢ + + m ⎜l 2 + ⎟⎥
mgl = mv12 ⎝ 4 ⎠⎦
2 ⎣ 3 12
v12
2mgl = mv12 ⇒ = 2g ⎡ ml 2 ml 2 5 2 ⎤
l I =2⎢ + + ml ⎥
⎣ 3 12 4 ⎦
At horigontal position
⎡ 4ml 2 + ml 2 + 15 ml 2 ⎤
I =2⎢ ⎥
a=
2
g 2 + ( 2g ) ⎣ 12 ⎦
a= 5g 20 2 10 2
= ml = ml
l 6 3
At highest point
10 2
1 1 mgl = ml α
mv 02 = 2mgl + mv 2 3
2 2
mv 2 3 g
= T + mg m =α
l v0
10 l
2/15
Test - 1A (Paper - 2) (Code-E) (Hints & Solutions) All India Aakash Test Series for JEE (Advanced)-2019
k
⎛ l⎞ ⎛ l ⎞ v2 =
m ⎜ l – ⎟ + m × 0 + m ⎜ – ⎟ + ml 3
⎝ 2 ⎠ ⎝ 2⎠ l
xcm = = m. R 2
4m 4
k 1
v = 3
⎛ l⎞ ⎛ l⎞ m
m (–l ) + m ⎜ – ⎟ + m × 0 + m ⎜ – ⎟ (R ) 4
⎝ 2⎠ ⎝ 2⎠ l
y cm = = 7
4m 2
2πR 2π . R 4
T = =
v k
l 4
tan θ = =2 m
2 l
7
= tan–1 (2)
T ∝R4
5. Answer (A, D)
7
2
Hint : T ∝R2
Torque of force is zero as it is passing through the 7. Answer (13)
centre.
Hint :
Solution :
2Mmg
T =
fH = ∫ ρ. g . y . l . dy M+m
Solution :
⎡ y2 ⎤
fH = ∫ ρ. g . l . ⎢ ⎥
⎣ 2 ⎦
ρ.gl ⎡ 2 ⎤ 3R
fH = ⎣ y ⎦R
2
ρ.g.l m
fH = [9R 2 – R 2 ]
2
M
= 4glR2
2Mmg
πR 2 T =
B = Fv = ρ. l .g M+m
2
2Mmg
1 σ=
= ρπR 2 lg (M + m ) A
2
2 × M × 10 × m
6. Answer (A, D) 2 × 109 =
(M + m ) A
Hint :
2 × 109 × 15 × 10 –19 Mm
mv 2 k =
= 5 20 M+m
R
R2 2 1 1
= +
Solution : 3 M m
mv 2 k 2 1 1
= 5 – =
R 3 8 M
R2
16 – 3 1
=
k 24 M
mv 2 = 3
24
R2 M = kg
13
3/15
8. Answer (20) l2 sin 53º = 2m

Hint : 10
l2 =
4
v A = v 02 – 2g × 10
10 10 40 – 30 10
l = – = =
3 4 12 12
v2
AB = 10
g (1 – sin α ) Work done = 60 ×
12
Solution : = 50 J
The speed of projection is minimum when the stone 10. Answer (16)
touches the building at A and B. Hint and Solution :
v
A The displacement of ball is same in y direction.
Let t = 0 x = (l1 – l2)cos

B
1
10 m x = g sin θ cos θ (t12 – t22 )
v0 5m 2
The distance between them will be minimum when
2
v2 = v 0 – 2g × 10 = v 02 – 20g
1
x= x – ax t 2
2
v = v 02 – 20g ...(i)
2 1 1
x= (t1 – t2 ) g sin θ cos θ – ( 2g sin θ cos θ ) l
2 2
For AB is the max inclined range 2 2
is minimum i.e x = 0
v2
AB = , AB sin  = 10 – 5
g (1 – sin α ) t12 – t22
=t
2
v2
AB = 5 1 242 – 162
⎛ 1⎞ sin α = = t = = 160
g ⎜1 – ⎟ 25 5
⎝ 5⎠ 2
11. Answer (80)
⎛ 1⎞
25 × g ⎜1 – ⎟ = v 2 ...(ii) Hint :
⎝ 5⎠
4 The blocks and wedge will move with different
25 × 10 × = v 02 – 20 × g acceleration, pseudo force will act on both the
5
blocks.
v12 = 200 + 200, v0 = 20ms–1
Solution :
9. Answer (25) T
Hint :
T
w = F(l) 4m T = 4ma
⎛ 2 2 ⎞ a1
= F ⎜⎝ – ⎟
sin 37º sin 53º ⎠ ma
m
Solution : T
l1 sin 37º = 2m a1
m
2 10
l1 = 2 × =
3 3
mg
4/15
T + ma = ma1 13. Answer (22)

Hint :
5ma = ma1
The acceleration along the string is zero
a1 = 5a
Solution :
ma1 = mg – T The acceleration along the string is zero
5ma + 4ma = mg m × l + 2m × 2l
Xcom =
3m
g 5
a= Xcom = l
9 3
⎛5 ⎞
4 (ml2 + 8ml2)  = 3mg × ⎜⎝ l ⎟⎠
T = mg 3
9
9ml2  = 5 mgl
5g
4 αl =
T = × 18 × 10 9
9
3macm = 3mg – T
T = 80 N
⎛5 ⎞
acm = . ⎜⎝ l ⎟⎠
12. Answer (12) 3
Hint : ⎛5 g ⎞ ⎛5 ⎞
= ⎜⎝ ⎟⎜ l⎟
9 l ⎠ ⎝3 ⎠
1 2 25
mgR = µ (v rel ) acm = g
2 27
25
Solution : T = 3 mg – g 3m
27
1 2 25
mgR = µ (v rel ) = 3 mg – mg
2 9
2 22
1 mM N T = mg = mg
mgR = (vrel )2 9 99
2M +m 14. Answer (45)
mg
Hint :
⎛M + m⎞ 2
⎜⎝ ⎟ 2gR = v rel
M ⎠ 4k . k
keq = k +
4k + k
2
mv rel Solution :
= N – mg
R
4k.k
keq = k +
4k + k k
m ⎛M + m⎞
N = ⎜ ⎟ 2gR + mg
R⎝ M ⎠ 4
=k+ k m
5
m
N = ( 2m + 3M ) g
M 9 k
keq = k
5
3
N = ( 6 + 18 ) × 10
6 5m
T = 2π
9k 4k
N = 120 N
5/15
(S) Angular momentum is not conserved about cm

2 π 5m × 9
T = and point of contact due to component of weight
9 k and friction at point of contact. But friction is
static so work done by it zero.
2π 45m
= 17. Answer (A)
9 k
Hint :
15. Answer (D)
Y = Kx is plane motion and velocity may be
16. Answer (B) constant.
Hint : 18. Answer (C)
Torque of friction about the point of the contact is Hint and Solution :
zero.
For completely submerged object, if resulting force is
Solution : downward direction (i.e weight is greater than
(P) On a rough surface when slipping is there, torque buoyancy force), then centre of mass must lie below
of friction about point of contact is zero so centre of gravity.
angular momentum conserved. But for partially submerged body center of buoyancy
(Q) Vcm = r, KE = constant, P = constant friction is always below the center of gravity. So stable
is zero at point of contact configuration will be such that these both center must
form a vertical line and their separation should be
(R) Same as (Q) minimum.
PART - II (CHEMISTRY)
19. Answer (D) Solution :

Hint : X( )  X(g)
H°vap = 10.3 – 2 = 8.3 kJ
Rate (at constant pH)  k ⎡⎣Cr2O72 ⎤⎦ I 
x y
S°vap = 20.75 J
Solution :
Hº vap 8.3  103
From exp. 1 and 2 Boiling point =  = 400 K
Sº vap 20.75
x=1
Y( )  Y(g)
From exp. 1 and 3
H°vap = 17.96 – 10.30 = 7.66 kJ/mol
y=2
S°vap = 20 J/mol K
Rate at constant pH  k ⎣⎡Cr2O ⎦⎤ I 2 1

 2
Hovap
7
Boiling point =  383 K

20. Answer (A, B, D) Sovap
Hint :
Y is more volatile than X
Cation and anion pair escape from solid called
Schottky defect. For ideal solution PTotal = PX + PY
Solution : PX  PXo X X , PY  PYo XY

In Schottky defect density decreases but in Frenkel XX = 0.5 XY = 0.5
defect remains constant.
21. Answer (A, D) Pxo at 27°C
Hvap ⎛ T2 – T1 ⎞ ⎛ P ⎞ H ⎛ T2  T1 ⎞
Hint : ln(P2 / P1 )  ⎜ ⎟ ln ⎜ 2 ⎟  ⎜ ⎟
R ⎝ T1T2 ⎠ ⎝ P1 ⎠ R ⎝ T1T2 ⎠
6/15
3
Solution :
⎛ 1 ⎞ 8.3  10 100 5
ln ⎜ o ⎟   
⎝ Px ⎠ 8.3 300  400 6 Under condition-I
S sys  S surr  S T  0
1 1
 e5/6  2.3 ⇒ Pxo   0.435 atm
Pxo 2.3 Under condition-II (Irreversible process)
o
For Py at 27°C Ssurr  0
Ssys  0 and ST  0
H ⎛ T2  T1 ⎞

ln 1/ Pyo   R ⎜⎝ T1T2 ⎟⎠ 24. Answer (B)
7.66  103  83 2 0.059 [Anode]

ln(1/ Pyo )   º
Hint : Ecell = Ecell – log
8.3  300  383 3 n [Cathode]
1 Solution :
Pyo   0.5 atm
2
0.059 ⎛ Ag ⎞
P  PXo X X  PYo XY (A) Ecell = E  n
log ⎜ anode ⎟
⎜ ⎟
⎝ Agcathode ⎠
= (0.435 × 0.5) + (0.5 × 0.5)
0.059 ⎡109 ⎤
= 0.47 atm
Ecell = log10 ⎢ 3 ⎥  0.059   6 
1 ⎣10 ⎦
22. Answer (B, D)
Hint : = 0.354 V
A  B = isochoric process (heating)
(B) Eocell  0.8 V
B  C = isothermal process (compression)
C  D = isochoric process (cooling) 0.059 ⎛ 1012 ⎞

Ecell  0.8  log ⎜ 2 ⎟  0.8  0.059 10 
1 ⎝ 10 ⎠
D  A = isothermal process (expansion)
Solution : = 1.39 V
A  B isochoric heating (as T ) (C) Eocell  0
U = q = positive > 0 and H > 0
0.059 ⎛ 103 ⎞
C  D isochoric cooling (as T ) Ecell  0  log ⎜ 6 ⎟  0.177 V
1 ⎝ 10 ⎠
U = q < 0
B  C volume is decreasing at constant T 0.059 ⎛ 1018 ⎞
(D) Ecell  0.34  log ⎜ 2 ⎟  0.132 V
w = positive  0 2 ⎝ 10 ⎠
23. Answer (A, B, C) 25. Answer (44)
Hint : Hint :
S T  S sys  S surr K.E.i  P.E.i  K.E.f  P.E.f
ST  0 for reversible process (P.E.) i = 0
ST  0 for irreversible process (K.E.) f = 0
7/15
Solution : I2Cl6 – Cl  Cl  Cl
1 KZe.2e
m v 2  I I
2 R  
Cl Cl Cl
4KZe2 Planar
 R
m v 2
Al2CI6 – Non planar
5v
When velocity  XeF4 – Square planar
6
4KZe2 36 CO32 – Trigonal planar
⇒ R  
m  v 2 25
PO34 – Tetrahedral and non-planar
= 1.44 R
 % error = 44% SF4 – See-saw and non-planar
26. Answer (40) O2F2 – Non-planar (Open book like structure)
Hint : XeO3 – Pyramidal and non-planar

Cl
Gº = Hº – TSº = Hº = –aFEº
(BeCI2) – Cl B Be Cl
1.2 Cl
% efficiency   100
Eº Planar
29. Answer (16)
Solution :
Hint :
Hº 289.5  1000
Eº   Tb  Tsolution  T0  iK bC
aF a  96500
T0 = Boiling point of pure water
100  a  96500  1.2
% efficiency   40a
289.5  1000 Tsolution = Boiling point of solution
 Solution :
⇒  40
a Tsolution = iKbC + T0
27. Answer (26) In the graph of Tsolution versus C (Straight line)
Hint : Slope = iKb = tan 45º
In NaCI structure CI– forms CCP and Na+ occupy all
the octahedral voids. 1 1
⇒ i 
K b 0.5 = 2
Solution :
No. of nearest neighbour of Na+ = 6
 CrCl2  4NH3  Cl  CrCl2  4NH3   Cl

No. of 2nd neighbour of Na+ = 12

30. Answer (60)
No. of 3rd neighbour of Na+ = 8
Hint & Solution :
28. Answer (64)
Hint & Solution : A 
100%
B  C
x x
I3 – Linear and planar B 

80%
D
x 0.8x

N 3
– Linear and planar D 
50%
E
0.8x 0.4x
NO2 – Linear and planar
Moles of E formed = 0.4x = 0.4

NO 2
– Bent shape and planar x=1
NH3 – Pyramidal and non-planar  Mass of A required = 60 g
8/15
31. Answer (10) 34. Answer (B)

Hint : Hint :
After time t ng
K p  K c (RT)
Nt  N0 e t (Radioactive decay follows 1st order kinetics) Increase in pressure shifts the reaction towards less
no. of gaseous molecules
Solution :
Addition of inert gas at constant pressure and
N1 t N  e t 1 temperature condition shifts the reaction towards more
 0 1  t
N2 t N0 2 e 2 no. of gaseous molecules.
Solution :
 (N0)1 = (N0)2

N2 (g)  3H2 (g)
2NH3 ; ng   ve
N 
ln 1 t    2  1  t  –2.303  2
N2 t

H2 (g)  I2 (g)
2HI(g); n g  0
N1 t N1 t 1 CaO(s)  CO2 (g); ng = +ve

CaCO3 (s)
⇒ log  –2  ⇒ 
N2 t N2 t 100

PCl3 (g)  Cl2 (g)
PCl5 (g) ; ng = –ve
32. Answer (06)
35. Answer (C)
Hint :
Hint :
 
2I  O3  H2O 
 2OH  I2  O2 For species having total e– and  14 (including N2– –)
energy order:
I2  2Na2S 2O3  2NaI  Na 2S 4O 6
1s  1s
*
 2s  2s
*
 2py  2pz  2px  2py
*
 2pz
*
 2px
*
Moles of I2 formed in 1st reaction will be used in 2nd

reaction. For species having number of e– > 14 (including O2+ +)
Solution : energy order:
Moles of Na2S2O3 1s  1s

*
  2s   2s
*
  2p x   2p y   2pz   2p
*
  2p
*
  2p
*
Moles of I2 formed 
y z x
2 Solution :
60  0.2 Electronic configuration

1000  2
C2 – 1s2 1s2 2s2 2s2 2p2y  2p2z
* *
6
Moles of O3 
B2 – 1s2 1s2 2s2 2s2 2p1y  2p1z
* *
1000
6  22.4
O2 – 1s2 1s2 2s2 2s2 2p2x 2p2y  2p2z 2p1y  2p1z
* * * *
% of O3 in mixture   100  6%
1000  2.24
O2  – 1s2 1s2 2s2 2s2 2p2x 2p2y  2p2z
* *
33. Answer (D)
Hint : 36. Answer (B)
Graph of (r) versus r for s-orbitals starts from non- Hint :
zero positive points, while that of p and d orbitals
start from origin Compare the relative Eº value to get the desired
product after electrolysis
No. of intersection of graph (other than origin and
infinity) with r-axis gives the no. of radial nodes. Solution :
Solution : EºK  / K  ve  H2 liberated
Graph of 1s and 2s will start from non-zero points at
r = 0 and have 0 and 1 radial nodes respectively. Eº Ag /Ag   ve  Metal produced
Graph of 3p and 3d will start from zero and have 1
and 0 radial nodes. EºCu2 /Cu   ve  Metal produced
9/15
PART - III (MATHEMATICS)

37. Answer (A, B, D) f(x) = 2x4 – 3x3 – 2x2 + 3x – 2x5 + 5x4 – 2x2 + 5x –
Hint : 4x5 – 8x – 4
f(x) = – 6x5 + 7x4 – 3x3 – 4x2 – 4
i ⎛⎞
1 e  2sin ⎜ ⎟
⎝2⎠ f(x) + 6x5 – 7x4 + 3x3 – 8x = – 4x2 – 8x – 4
Solution : = – 4 (x2 + 2x + 1) = – 4 (x + 1)2
⎛⎞
39. Answer (A, C)
i ⎛  ⎞  i⎜ ⎟
1  e  2i sin ⎜ cos  i sin ⎟   2i sin e ⎝ 2 ⎠ Hint :
2⎝ 2 2⎠ 2
(1 + x)n(x2 – 1)m = (1 + x)m + n (x – 1)m

 1 e i
 2sin Solution :
2
(1 + x)n (x2 – 1)m = ( nC0 + nC1 x + nC2 x2 + .... nCn
⎡  2 3
then, Sn  2 ⎢2sin  2sin  2sin  .....  xn) · (mC0x2m – mC0 x2m–2 + mC2 x2m–4 – ..... + (– 1)m
⎣ n n n mC )
m
⎛ ⎛ n  1⎞  ⎞⎤ Comparing coefficient of x2m on both sides

2 sin ⎜ ⎜ ⎟ · ⎟⎥
⎝ ⎝ 2 ⎠ n ⎠⎦ Coefficient of x2m in (1 + x)n (x2 – 1)m = nC0 mC0 – nC2
n
mC + nC4 mC2 – ..... +  1 2 nCn · mC n
⎛  ⎛ n 1 ⎞  ⎞ ⎛ n 1  ⎞ 1
sin ⎜  ⎜  1⎟ ⎟ · sin ⎜ · ⎟ 2
⎝ n ⎝ 2 ⎠ 2 n ⎠ ⎝ 2 2n ⎠
= 4
⎛  ⎞ (if n is even) …(i)
sin ⎜ ⎟
⎝ 2n ⎠ n1
= nC0 mC0 – nC2 mC1 + nC4 mC2 – ..... +  1 2 Cn1
n
⎛ (n  1) ⎞ ⎛ (n  1) ⎞ · mCn1 (if n is odd)

4 sin ⎜ ⎟ sin ⎜ ⎟
⎝ 4n ⎠ ⎝ 4n ⎠ 2
=
⎛  ⎞
sin ⎜ ⎟ Coefficient of x2m in (1 + x)n · (x – 1)m (x + 1)m
⎝ 2n ⎠
= Coefficient of x2m in (1 + x)m + n (x – 1)m
⎛  ⎞⎡  ⎤
= 2cosec ⎜
2n ⎟ ⎢cos 2n  cos 2 ⎥ = Coefficient of x2m in ( m + nC0 + m + nC1x m + nC2x2 +
⎝ ⎠⎣ ⎦ .... + m + nCm + n xm + n ) (mC0xm – mC1xm – 1 + mC2
xm – 2 +..... + (– 1)m mCm)
⎛  ⎞
= 2cot ⎜ ⎟ = mC m + nC – mC m + nC m m + nC –
⎝ 2n ⎠ 0 m 1 m + 1 + C2 m+2
m
..... + Cm m + nC2m (if m is even and m  n) …(ii)
38. Answer (B, D) mC m + nC – mC m + nC m m + nC
= 0 m 1 m + 1 + C2 m+2– .....
Hint : m
– Cm m + nC2m (if m is odd and m  n)
Expand the determinant
Put m = n = 8
Solution :
 8C0 8C0 – 8C2 8C1 + 8C4 · 8C2 – ..... + 8C8 8C4 =
8C 16C – 8C · 16C 8 16C 8
x x 2x  1 2
3
0 8 1 9 + C2 10 – ....+ C 8 ·
16C
f (x)  x  x
4
2x  1 2 16
x  2x  1
5
2 1 40. Answer (B, C, D)
Hint :
= (x3 – x) [2x + 1 – 4] – (x4 + x) [2x –1 – 4] + (x5 +
2x + 1) [4x – 2 – 4x – 2] A·M·  G·M·
10/15
Solution : m > 0, D > 0, Sum of roots > 0, Product of roots > 0

 x1x2 = 12, x1x2x3x4 = 4
  
 m > 0, m   , 3  2 2  3  2 2,  
x1x2  x1x3  x1x 4  x2 x3  x2 x 4  x3 x 4 1
6

3 3 3 3
 x1 x2 x3 x 4  6
m  (– , 0)  (1, ), m > 0
Here A.M· = G.M·
 x1x2  x1x3  x1x4  x2 x3  x2 x4  x3 x4


 m  3  2 2,  
 x1  x2  x3  x4  2 y y
 a  x1  x2  x3  x4  4 2 (0, 1) (0, 1)
x OR x
b  ∑ x1x2 x3  4  2 2  8 2
41. Answer (A, C)
Hint : m < 0, D > 0, Product of roots < 0
    m1  0
Location of roots
m  0, m   , 3  2 2  3  2 2, 
Solution :
y  m  (– , 0)
42. Answer (B, C, D)
(0, 1)
x Hint :
0
⎡n ⎤ ⎡ n ⎤ ⎡ n ⎤
m > 0, D > 0 E p (n !)  ⎢ ⎥  ⎢ 2 ⎥  ⎢ 3 ⎥  .....
⎣p⎦ ⎣p ⎦ ⎣p ⎦
Sum of roots < 0, Product of roots > 0
 m > 0, (m – 1)2 > 4m Solution :
 m2 + 1 – 2m > 4m Exponent of a prime p in n! = Ep(n!)

 m – 6m > – 1
⎡n ⎤ ⎡ n ⎤ ⎡ n ⎤
 (m – 3)2 > 8 … (i) = ⎢ ⎥  ⎢ 2 ⎥  ⎢ 3 ⎥ + .........
⎣p⎦ ⎣p ⎦ ⎣p ⎦
m3  2 2
where [·] represents greatest integer function
  
 m   , 3  2 2  3  2 2,  …(ii)  110!
 110C12 
m 1 98! 12!
0
m
 m  (0, 1) …(iii)  E2 () = (55 + 27 + 13 + 6 + 3 + 1) – (49 + 24 +
12 + 6 + 3 + 1) – (6 + 3 + 1) = 0
1
0 E3 () = (36 + 12 + 4 + 1) – (32 + 10 + 3 + 1) –
m
(4 + 1) = 2
m > 0 …(iv)
E5 () = (22 + 4) – (19 + 3) – (2) = 2,

From (i), (ii), (iii) and (iv) m  0,3  2 2  E7 () = (15 + 2) – (14 + 2) – (1) = 0
y E53 () = 2 – 1 = 1, E59() = E61() = E67() =
E71() = E73() = E79() = E83() = E89() =
x E97() = 0
0
E101 () = E103() = E107() = E109() = 1
11/15
43. Answer (12) 45. Answer (04)
Hint : Hint :
SP + SP = 2a, SS = 2ac < 2a

Half angle formula, sin 2x + cos 2 x = 1, cos2x =
2cos2x – 1 Solution :
Solution : SP + SP = 2A
sin2x (sin2x – 3) + 1 = 0   
S  2  3, 2  5 , S 2  3, 2  5 , A  2 
(1 – cos2x) [1 – cos2x – 3] + 1 = 0
SS = 2Ae
(cos2x – 1) (cos2x + 2) + 1 = 0
2 3 3
 e 
⎛ 1  cos 2 x ⎞ ⎛ 1  cos 2x ⎞ 4 2
⎜  1⎟ ⎜  2⎟  1  0
⎝ 2 ⎠⎝ 2 ⎠
⎛ 3⎞
b2  4 ⎜ 1  ⎟  1
⎝ 4⎠
⎛ cos 2x  1 ⎞ ⎛ cos 2 x  5 ⎞
⎜ 2 ⎟⎜ 2 ⎟ 1 0
⎝ ⎠⎝ ⎠  z lies on an ellipse
cos22x + 4cos2x – 5 + 4 = 0  Equation of ellipse is
y  2  5 
2
 x  2
2
1  cos 4 x
 4cos 2 x  1  0  1
2 22 12
1 + cos4x + 8cos2x – 2 = 0
y
cos4x + 8cos2x = 1
44. Answer (64) x

0
Hint : C(2, 2  5)
|A – I| = 0
Solution : Equation of tangent to the ellipse is
A  I  0
 y  2  5   m( x  2)  4m 2  1 passes through
O (0, 0)
1  3 2
 2m  2  5 
2
 2 2 3 0   4m 2  1
3 1 1 
4 m 2  4  5  8 m  4 5  4 5 m  4m 2  1
 3 – 42 – 10 – 12 = 0
84 5
 A3 – 4A2 – 10A –12I = 0 m 1
84 5
 A3 – 4A2 – 10A – 8I = 4I

 |A3 – 4A2 – 10A – 8I| = |4I| = 64   Arg( z ) max 
4
12/15
46. Answer (92)  The roots of the equation x4 + ax5 + bx2 + cx +
Hint : d = 0 are 1  2i , 2  3
Make all possible cases  x4 + ax3 + bx2 + cx + d  (x2 – 2x + 3) (x2 – 4x
+ 1)
Solution :
= x4 – 6x3 + 12x2 – 14x + 3
EE, LL, I, P, S
 a = – 6, b = 12, c = – 14, d = 3
4!
2 alike  2 alike  1 diff. 2
C2·3 C1 2
C2·3 C2·  36 a + 2b – 3c + 4d = – 6 + 24 + 42 + 12 = 72
2!
2 alike (2E)  3 diff. 1
C1·4 C3 1
C1·4 C3 ·4!  96 49. Answer (09)
4! Hint :
2 alike (2L)  1E  2 diff 1
C1·1C1·3 C2 1
C1·1C1·3 C2·  36
2!
1E  4 diff 1
C1·4 C4 1
C1·4 C4 ·4!  24 Partial fraction
Solution :
47. Answer (51)
1 1 4 9
Hint :   
(1  x )(1  2x ) (1  3 x ) 2(1  x ) 1  2x 2(1  3 x )
S = (22 – 42) + (62 – 82) + (102 – 122) + .....
1
Solution : = ⎡1  x  x 2  x 3  .....  ⎤⎦ – 4
2⎣
S = 22 – 42 + 62 – 82 + 102 – 122 + ..... 100 terms
S = 4[(1 2 – 2 2) + (3 2 – 4 2) + (5 2 – 6 2) + ..... 50 9
⎡⎣1  (2 x )  (2 x )2  (2 x )3  ..... ⎤⎦ +
terms] 2
= – 4[3 + 7 + 11 + ..... 50 terms] ⎡⎣1  (3 x )  (3 x )2  (3 x )3  .....  ⎤⎦
50
=  4·
2
2  3  (50  1)4  100  202 1 9
 Coefficient of x 3   32   27
2 2
S
 100
202 243  1
=  32
2
S
  50
404 = 122 – 32 = 90
S 50. Answer (06)

 1  51
404 Hint :
48. Answer (72)
aij = aji
Hint :
Solution :
a  b and a  ib For symmetric matrix
Solution :
tan    tan 
sin2  sin 
x2 – 2x + 3 = 0 2 tan 
2sin  cos   sin    tan 
1  tan2 
2  4  12 sin (2cos   1)  0
x  1  2i ⎛ 2 ⎞
2 1 tan  ⎜ 1  tan2   1⎟  0
sin   0, or cos   ⎝ ⎠
x2 – 4x + 1 = 0 2
tan   0 or tan  = 3
2
4  16  4 … (i) …(ii)
x 2 3
2 cos(2) = – cos
13/15
2cos2 – 1 = – cos =  
3  1 cos 2 x  sin2 x
2cos2 + cos – 1 = 0
2cos2 + 2cos – cos – 1 = 0 f ( x )  r cos(2 x   ), r  5  2 3 ,
2cos(cos + 1) – (cos – 1) = 0 ⎛ 1 ⎞
  tan1 ⎜ ⎟
1 ⎝ 3  1⎠
cos = – 1 or cos = …(iii)
2
From (i), (ii) and (iii)   5  2 3  f (x)  5  2 3
1 y
cos   1, cos  
2
2
5     5 
   ,  or   , , ,
3 3 3 3 1
51. Answer (C) x  x
0  3 2
Hint : 2 2
General term –1
Solution : y
(P) Number of terms = 19 53. Answer (A)
 10th term is middle term Hint :
9  r 1 r 1 Find rth term
⎛3 ⎞ ⎛ 1 ⎞
(Q) Tr  Cr 1 ⎜ x 2 ⎟
9
⎜  3x ⎟
⎝2 ⎠ ⎝ ⎠ Solution :
 For constant term 20 – 2r – r + 1 = 0 10
∑ ∑ ∑ (i  j  k )  ∑ (r  r  r  1)
 r=7 1  i  j  k  1  10 r 1
r⎞
⎛
⎜ 25  ⎟
r
3  10  11
(R) General term Tr+1 = 175
Cr 5 ⎝ 7⎠
· 75 · x r =  10
2
for integral coefficient, r = 0, 35, 70, 105, 140, 175 = 175 = 52 × 7
(S) S = (1 – 1 + 4)n = 1024
10
 22n = 210 ∑ ∑ ∑ (ij  jk  ki )  ∑ ⎡⎣r

1  i  j  k  1  10 r 1
2
 r ( r  1)  ( r  1)r ⎤⎦
 n = 5
= 1045
52. Answer (B)
= 5 × 11 × 19
Hint :
10
acos + bsin = rcos( – ) ∑ ∑ ∑ (ijk )  ∑ r ·r ·(r  1)
1  i  j  k  1  10 r 1
⎛b⎞
r  a 2  b 2 ,   tan1 ⎜ ⎟ = 2 × 5 × 11 × 31
⎝a⎠
10
Solution :
∑∑∑ (ijkˆ )  ∑ ⎡⎣r
1  i  j  k  1  10 r 1
2
(r  1)⎤⎦
⎡ ⎛  ⎞⎤ 
f ( x )  2 ⎢0  cos ⎜ 2 x  ⎟ ⎥  2cos 2 x sin
⎣ ⎝ 6 ⎠⎦ 6 = 24 × 3 × 5 × 11
14/15
54. Answer (B)
2  2
Hint :
(R)  2
   2 ( 2   )   (   )   2 (   2 )
1 2 1 1 1 1
 ,   2 , 1     2  0, 3  1
 
Solution : =–1–0+1–
1 2 1
3  1,   ,   2 , 1    2  0 =0
 
1  2
(P)  2 1  1( 3  1)   (  2   2 )  1 2 
2 1  1 1 ⎛ 1 1 ⎞
(S)  2 1  1(1  1)   2 ⎜  2  2 ⎟
  ⎝   ⎠
 2 (   4 )  0
1 1
1 
 2  2 
(Q) 2    (  )   2 (  2   )  (  2   )
1 1 1
⎛ 1 1⎞
= 0 –  + 1 + 1 – 2 = 3  ⎜  ⎟  4
⎝ ⎠

15/15
Test - 1A (Paper - 2) (Code-F) (Answers) All India Aakash Test Series for JEE (Advanced)-2019
All India Aakash Test Series for JEE (Advanced)-2019

TEST - 1A (Paper-2) - Code-F
Test Date : 04/11/2018
ANSWERS
PHYSICS CHEMISTRY MATHEMATICS
1. (A, D) 19. (B) 37. (B, C, D)
2. (A, D) 20. (A, B, C) 38. (A, C)
3. (A, C) 21. (B, D) 39. (B, C, D)
4. (A, C, D) 22. (A, D) 40. (A, C)
5. (A, B, C) 23. (A, B, D) 41. (B, D)
6. (A, B, D) 24. (D) 42. (A, B, D)
7. (45) 25. (06) 43. (06)
8. (22) 26. (10) 44. (09)
9. (12) 27. (60) 45. (72)
10. (80) 28. (16) 46. (51)
11. (16) 29. (64) 47. (92)
12. (25) 30. (26) 48. (04)
13. (20) 31. (40) 49. (64)
14. (13) 32. (44) 50. (12)
15. (C) 33. (B) 51. (B)
16. (A) 34. (C) 52. (A)
17. (B) 35. (B) 53. (B)
18. (D) 36. (D) 54. (C)
1/15
All India Aakash Test Series for JEE (Advanced)-2019 Test - 1A (Paper - 2) (Code-F) (Hints & Solutions)
HINTS & SOLUTIONS

PART - I (PHYSICS)
1. Answer (A, D) πR 2
B = Fv = ρ. l .g
Hint : 2
mv 2 k 1
= 5 = ρπR 2 lg
R 2
R2
Solution : 3. Answer (A, C)
Hint :
mv 2 k
= 5
R Ycm
R2 tan θ =
X cm
k
mv 2 = 3 Solution :
R2
C D
2 k
v = 3
l/2 
cm
m. R 2 l/4
k 1
v = 3
m A B E
(R ) 4
7
Let us assume mass of each section is m.
2πR 2π . R 4 Torque about C
T = =
v k l l
mg × + mgl – mg = I α
m 2 2
7
T ∝R4 ⎡ ml 2 ml 2 ⎛ l 2 ⎞⎤
I =2⎢ + + m ⎜l 2 + ⎟⎥
⎣ 3 12 ⎝ 4 ⎠⎦
7
T 2 ∝R2
2. Answer (A, D) ⎡ ml 2 ml 2 5 2 ⎤
I =2⎢ + + ml ⎥
Hint : ⎣ 3 12 4 ⎦
Torque of force is zero as it is passing through the

⎡ 4ml 2 + ml 2 + 15 ml 2 ⎤
centre. I =2⎢ ⎥
⎣ 12 ⎦
Solution :
fH = ∫ ρ. g . y . l . dy 20 2 10 2
= ml = ml
6 3
⎡ y2 ⎤ 10 2
fH = ∫ ρ. g . l . ⎢ ⎥ mgl = ml α
⎣ 2 ⎦ 3
ρ.gl ⎡ 2 ⎤ 3R 3 g
fH = ⎣ y ⎦R =α
2 10 l
ρ.g.l ⎛ l⎞ ⎛ l⎞
fH = [9R 2 – R 2 ] m ⎜ l – ⎟ + m × 0 + m ⎜ – ⎟ + ml
⎝ ⎠ ⎝ 2⎠
2 2 l
xcm = =
4m 4
= 4glR2
2/15
Test - 1A (Paper - 2) (Code-F) (Hints & Solutions) All India Aakash Test Series for JEE (Advanced)-2019
l mg l 1
⎛ l⎞ ⎛ l⎞ mg – = mv 2
m (–l ) + m ⎜ – ⎟ + m × 0 + m ⎜ – ⎟ 2 2 4 2
⎝ 2⎠ ⎝ 2⎠ l
y cm = =
4m 2 3 1
mgl = mv 2
8 2
l 4
tan θ = =2 3 1
2 l v = gl = 3gl
4 2
= tan–1 (2) 6. Answer (A, B, D)
4. Answer (A, C, D) Hint :
Hint : maaA = 10 – mag
At highest point velocity of bob is zero and Solution :
compression T = mg in the rod
2 × aA = 10 – 4
Solution :
aA = 3 ms–2
1 1
mv 02 = mgl + mv12 7. Answer (45)
2 2
Hint :
1
mgl = mv12 4k . k
2 keq = k +
4k + k
v12
2mgl = mv12 ⇒ = 2g Solution :
l
4k.k
keq = k +
At horigontal position 4k + k k
2 4
a= g 2 + ( 2g ) =k+ k m
5
a= 5g
9 k
l keq = k
At highest point 5
1 1
mv 02 = 2mgl + mv 2 5m
2 2 T = 2π
mv 2 9k 4k
= T + mg m
l v0
2 π 5m × 9
Tmin = mg (–ve) T =
9 k
mv 2
=0 2π 45m
l =
9 k
mv 02 8. Answer (22)
= 4mg
l Hint :
Tmax= 4mg + mg = 5 mg The acceleration along the string is zero
Tmin = mg (compression) Solution :
5. Answer (A, B, C) The acceleration along the string is zero
Hint : m × l + 2m × 2l
Xcom =
Work energy theorem 3m
Solution : 5
Xcom = l
When chain becomes vertical 3
3/15
⎛5 ⎞ 10. Answer (80)

(ml2 + 8ml2)  = 3mg × ⎜⎝ l ⎟⎠
3 Hint :
9ml2  = 5 mgl
The blocks and wedge will move with different
5g acceleration, pseudo force will act on both the
αl =
9 blocks.
3macm = 3mg – T
Solution :
⎛5 ⎞ T
acm = . ⎜⎝ l ⎟⎠
3
⎛5 g ⎞ ⎛5 ⎞ T
4m T = 4ma
= ⎜⎝ ⎟⎜ l⎟
9 l ⎠ ⎝3 ⎠
25 a1
acm = g ma
27
m
25 T
T = 3 mg – g 3m
27
a1
25 m
= 3 mg – mg
9
2 22 mg
T = mg = mg
9 99 T + ma = ma1
9. Answer (12)
5ma = ma1
Hint :
a1 = 5a
1 2
mgR = µ (v rel ) ma1 = mg – T
2
Solution : 5ma + 4ma = mg
1 g
μ (v rel )
2 a=
mgR = 9
2
1 mM N 4
mgR = (vrel )2 T =
9
mg
2M +m
mg
⎛M + m⎞ 2 4
⎜⎝ ⎟ 2gR = v rel T = × 18 × 10
M ⎠ 9
2
mv rel T = 80 N
= N – mg
R 11. Answer (16)
m ⎛M + m⎞ Hint and Solution :

N = ⎜ ⎟ 2gR + mg
R⎝ M ⎠ The displacement of ball is same in y direction.
Let t = 0 x = (l1 – l2)cos
m
N = ( 2m + 3M ) g 1
M x = g sin θ cos θ (t12 – t22 )
2
3
N = ( 6 + 18 ) × 10 The distance between them will be minimum when
6
1
x= x – ax t 2
N = 120 N 2
4/15
) 21 g sin θ cos θ – 21 (2g sin θ cos θ) l 2

For AB is the max inclined range
2
( 2
x= t1 – t2
v2
is minimum i.e x = 0 AB = , AB sin  = 10 – 5
g (1 – sin α )
t12 – t22
=t v2
2 AB = 5 1
⎛ 1⎞ sin α = =
2 2 g ⎜1 – ⎟ 25 5
24 – 16 ⎝ 5⎠
t = = 160
2
12. Answer (25) ⎛ 1⎞
25 × g ⎜1 – ⎟ = v 2 ...(ii)
⎝ 5⎠
Hint :
4
w = F(l) 25 × 10 × = v 02 – 20 × g
5
⎛ 2 2 ⎞
= F ⎜⎝ – ⎟ v12 = 200 + 200, v0 = 20ms–1
sin 37º sin 53º ⎠
Solution : 14. Answer (13)
l1 sin 37º = 2m Hint :
2 10 2Mmg
l1 = 2 × = T =
3 3 M+m
l2 sin 53º = 2m Solution :
10
l2 =
4
10 10 40 – 30 10
l = – = =
3 4 12 12
10
Work done = 60 × m
12
= 50 J M
13. Answer (20)
2Mmg
Hint : T =
M+m
v A = v 02 – 2g × 10
2Mmg
σ=
v2 (M + m ) A
AB =
g (1 – sin α )
2 × M × 10 × m
Solution : 2 × 109 =
(M + m ) A
The speed of projection is minimum when the stone
touches the building at A and B. 2 × 109 × 15 × 10–19 Mm
=
v 20 M+m
A 2 1 1
= +
 3 M m
B
2 1 1
10 m – =
5m 3 8 M
v0
16 – 3 1
=
v2 = v 02 – 2g × 10 = v 02 – 20g 24 M
24
v = v 02 – 20g ...(i) M = kg
13
5/15
15. Answer (C) 17. Answer (B)

Hint and Solution : Hint :
For completely submerged object, if resulting force is Torque of friction about the point of the contact is
zero.
downward direction (i.e weight is greater than
buoyancy force), then centre of mass must lie below Solution :
centre of gravity. (P) On a rough surface when slipping is there, torque
But for partially submerged body center of buoyancy of friction about point of contact is zero so
angular momentum conserved.
is always below the center of gravity. So stable
configuration will be such that these both center must (Q) Vcm = r, KE = constant, P = constant friction
form a vertical line and their separation should be is zero at point of contact
minimum. (R) Same as (Q)
16. Answer (A) (S) Angular momentum is not conserved about cm
and point of contact due to component of weight
Hint : and friction at point of contact. But friction is
Y = Kx is plane motion and velocity may be static so work done by it zero.
constant. 18. Answer (D)
PART - II (CHEMISTRY)
19. Answer (B) 20. Answer (A, B, C)

Hint :
º 0.059 [Anode]
Hint : Ecell = Ecell – log
n [Cathode] S T  S sys  S surr
Solution : ST  0 for reversible process

⎛  ⎞
0.059 Aganode ST  0 for irreversible process
(A) Ecell = E  n
log ⎜
⎜  ⎟⎟
⎝ Agcathode ⎠ Solution :
0.059 ⎡109 ⎤ Under condition-I

Ecell = log10 ⎢ 3 ⎥  0.059   6 
1 ⎣10 ⎦
S sys  S surr  S T  0
= 0.354 V
Under condition-II (Irreversible process)
(B) Eocell  0.8 V
Ssurr  0
0.059 ⎛ 1012 ⎞
Ecell  0.8  log ⎜ 2 ⎟  0.8  0.059 10  S sys  0 and ST  0
1 ⎝ 10 ⎠
= 1.39 V 21. Answer (B, D)

Hint :
(C) Eocell  0
A  B = isochoric process (heating)
0.059 ⎛ 103 ⎞
Ecell 0 log ⎜ 6 ⎟  0.177 V B  C = isothermal process (compression)
1 ⎝ 10 ⎠
⎛ 1018 ⎞ C  D = isochoric process (cooling)

0.059
(D) Ecell  0.34  log ⎜ 2 ⎟  0.132 V
2 ⎝ 10 ⎠ D  A = isothermal process (expansion)
6/15
Solution :
7.66  103  83 2
A  B isochoric heating (as T ) ln(1/ Pyo )  
8.3  300  383 3
U = q = positive > 0 and H > 0
1
C  D isochoric cooling (as T ) Pyo   0.5 atm
2
U = q < 0
B  C volume is decreasing at constant T P  PXo X X  PYo XY
w = positive  0 = (0.435 × 0.5) + (0.5 × 0.5)
22. Answer (A, D) = 0.47 atm
Hvap ⎛ T2 – T1 ⎞ 23. Answer (A, B, D)

Hint : ln(P2 / P1 )  ⎜ ⎟
R ⎝ T1T2 ⎠ Hint :
Solution : Cation and anion pair escape from solid called
Schottky defect.
X( )  X(g)
Solution :
H°vap = 10.3 – 2 = 8.3 kJ
In Schottky defect density decreases but in Frenkel
S°vap = 20.75 J
defect remains constant.
Hº vap 8.3  103 24. Answer (D)
Boiling point =  = 400 K
Sº vap 20.75 Hint :
Y( )  Y(g)
Rate (at constant pH)  k ⎡⎣Cr2O72 ⎤⎦ I 
x y
H°vap = 17.96 – 10.30 = 7.66 kJ/mol

Solution :
S°vap = 20 J/mol K
From exp. 1 and 2
Hovap x=1
Boiling point =  383 K
Sovap From exp. 1 and 3
y=2
Y is more volatile than X
Rate at constant pH  k ⎣⎡Cr2O72 ⎦⎤ I 
1 2
For ideal solution PTotal = PX + PY
PX  PXo X X , PY  PYo XY 25. Answer (06)

XX = 0.5 XY = 0.5 Hint :
Pxo at 27°C 2I  O3  H2O 

 2OH  I2  O2
⎛ P ⎞ H ⎛ T2  T1 ⎞ I2  2Na2S 2O3  2NaI  Na 2S 4O 6

ln ⎜ 2 ⎟  ⎜ ⎟
⎝ P1 ⎠ R ⎝ T1T2 ⎠ Moles of I2 formed in 1st reaction will be used in 2nd
reaction.
3
⎛ 1 ⎞ 8.3  10 100 5
ln ⎜ o ⎟    Solution :
P
⎝ x ⎠ 8.3 300  400 6
Moles of Na2S2O3
Moles of I2 formed 
1 1 2
 e5/6  2.3 ⇒ Pxo   0.435 atm
Pxo 2.3 60  0.2

1000  2
o
For Py at 27°C 6
Moles of O3 
1000
H ⎛ T2  T1 ⎞
 
ln 1/ Pyo 
R ⎜⎝ T1T2 ⎟⎠ % of O3 in mixture 
6  22.4
 100  6%
1000  2.24
7/15
26. Answer (10) 29. Answer (64)

Hint : Hint & Solution :
After time t
I3 – Linear and planar
t
Nt  N0 e (Radioactive decay follows 1st order kinetics)
N3 – Linear and planar
Solution :
NO2 – Linear and planar
N1 t N0 1 e 1t

N2 t N0 2 e t 2 NO2 – Bent shape and planar
 (N0)1 = (N0)2 NH3 – Pyramidal and non-planar
N1 t I2Cl6 –
ln    2  1  t  –2.303  2 Cl  Cl  Cl
N2 t
I I
 
N1 t N1 t 1 Cl Cl Cl
⇒ log  –2  ⇒  Planar
N2 t N2 t 100
27. Answer (60) Al2CI6 – Non planar

Hint & Solution : XeF4 – Square planar
A  B  C
100%
x x
CO32 – Trigonal planar
B 
80%
D
x 0.8x
PO34 – Tetrahedral and non-planar
D 
E 50%
0.8x 0.4x
SF4 – See-saw and non-planar
Moles of E formed = 0.4x = 0.4
x=1 O2F2 – Non-planar (Open book like structure)
 Mass of A required = 60 g XeO3 – Pyramidal and non-planar

28. Answer (16)
Cl
Hint :
(BeCI2) – Cl B Be Cl
Cl
Tb  Tsolution  T0  iK bC
Planar
T0 = Boiling point of pure water
Tsolution = Boiling point of solution 30. Answer (26)
Solution : Hint :
Tsolution = iKbC + T0
In NaCI structure CI– forms CCP and Na+ occupy all
In the graph of Tsolution versus C (Straight line) the octahedral voids.
Slope = iKb = tan 45º
Solution :
1 1 No. of nearest neighbour of Na+ = 6
⇒ i 
K b 0.5 = 2
No. of 2nd neighbour of Na+ = 12
 CrCl2  4NH3  Cl  CrCl2  4NH3   Cl

No. of 3rd neighbour of Na+ = 8
8/15
31. Answer (40) 34. Answer (C)

Hint : Hint :
For species having total e– and  14 (including N2– –)
Gº = Hº – TSº = Hº = –aFEº energy order:
1.2 1s  1s

*
 2s  2s
*
 2py  2pz  2px  2py
*
 2pz
*
 2px
*
% efficiency   100
Eº For species having number of e– > 14 (including O2+ +)
energy order:
Solution :
1s  1s
*
  2s   *2s   2p x   2p y   2pz   2p
*
y
  2p
*
z
  2p
*
x
Hº 289.5  1000
Eº   Solution :
aF a  96500
Electronic configuration
100  a  96500  1.2
% efficiency   40a C2 – 1s2 1s2 2s2 2s2 2p2y  2p2z
* *
289.5  1000
 B2 – 1s2 1s2 2s2 2s2 2p1y  2p1z
* *
⇒  40
a
O2 – 1s2 1s2 2s2 2s2 2p2x 2p2y  2p2z 2p1y  2p1z
* * * *
32. Answer (44)
O2  – 1s2 1s2 2s2 2s2 2p2x 2p2y  2p2z
* *
Hint :
K.E.i  P.E.i  K.E.f  P.E.f 35. Answer (B)

Hint :
(P.E.) i = 0
ng
K p  K c (RT)
(K.E.) f = 0
Increase in pressure shifts the reaction towards less
Solution :
no. of gaseous molecules
1 KZe.2e Addition of inert gas at constant pressure and
m v 2 
2 R temperature condition shifts the reaction towards more
no. of gaseous molecules.
4KZe2
 R Solution :
m v 2

N2 (g)  3H2 (g)
2NH3 ; ng   ve
5v
When velocity 
6

H2 (g)  I2 (g)
2HI(g); n g  0
4KZe2 36
⇒ R  
m  v 2 25 CaO(s)  CO2 (g); ng = +ve

CaCO3 (s)
= 1.44 R

PCl3 (g)  Cl2 (g)
PCl5 (g) ; ng = –ve
 % error = 44%
36. Answer (D)
33. Answer (B)
Hint :
Hint :
Graph of (r) versus r for s-orbitals starts from non-
Compare the relative Eº value to get the desired zero positive points, while that of p and d orbitals
product after electrolysis start from origin
Solution : No. of intersection of graph (other than origin and
infinity) with r-axis gives the no. of radial nodes.
EºK  / K  ve  H2 liberated Solution :
Eº Ag /Ag   ve Graph of 1s and 2s will start from non-zero points at

 Metal produced
r = 0 and have 0 and 1 radial nodes respectively.
EºCu2 /Cu   ve Graph of 3p and 3d will start from zero and have 1
 Metal produced
and 0 radial nodes.
9/15
PART - III (MATHEMATICS)

37. Answer (B, C, D)  (m – 3)2 > 8 … (i)
Hint : m3  2 2
⎡n ⎤ ⎡ n ⎤ ⎡ n ⎤
E p (n !)  ⎢ ⎥  ⎢ 2 ⎥  ⎢ 3 ⎥  .....
  
 m   , 3  2 2  3  2 2,  …(ii) 
⎣p⎦ ⎣p ⎦ ⎣p ⎦ m 1
0
Solution : m
 m  (0, 1) …(iii)
Exponent of a prime p in n! = Ep(n!)
1
0
⎡n ⎤ ⎡ n ⎤ ⎡ n ⎤ m
= ⎢ ⎥  ⎢ 2 ⎥  ⎢ 3 ⎥ + ......... m > 0
⎣p⎦ ⎣p ⎦ ⎣p ⎦ …(iv)
where [·] represents greatest integer function 

From (i), (ii), (iii) and (iv) m  0,3  2 2 
y
110!
 110C12 
98! 12! x
0
 E2 () = (55 + 27 + 13 + 6 + 3 + 1) – (49 + 24 +
12 + 6 + 3 + 1) – (6 + 3 + 1) = 0
m > 0, D > 0, Sum of roots > 0, Product of roots > 0
E3 () = (36 + 12 + 4 + 1) – (32 + 10 + 3 + 1) –
(4 + 1) = 2   
 m > 0, m   , 3  2 2  3  2 2,  
E5 () = (22 + 4) – (19 + 3) – (2) = 2,
m  (– , 0)  (1, ), m > 0
E7 () = (15 + 2) – (14 + 2) – (1) = 0
E53 () = 2 – 1 = 1, E59() = E61() = E67() = 
 m  3  2 2,  
E71() = E73() = E79() = E83() = E89() =
y y
E97() = 0
(0, 1) (0, 1)
E101 () = E103() = E107() = E109() = 1
x OR x
38. Answer (A, C)
Hint :
Location of roots m < 0, D > 0, Product of roots < 0
Solution :
y
  
m  0, m   , 3  2 2  3  2 2,   m1  0
 m  (– , 0)
(0, 1)
x 39. Answer (B, C, D)
0
Hint :
m > 0, D > 0 A·M·  G·M·
Sum of roots < 0, Product of roots > 0
Solution :
 m > 0, (m – 1)2 > 4m
 x1x2 = 12, x1x2x3x4 = 4
 m2 + 1 – 2m > 4m
x1x2  x1x3  x1x 4  x2 x3  x2 x 4  x3 x 4 1
 m – 6m > – 1 6

3 3 3 3
 x1 x2 x3 x 4  6
10/15
Here A.M· = G.M· 41. Answer (B, D)

Hint :
 x1x2  x1x3  x1x4  x2 x3  x2 x4  x3 x4 Expand the determinant
Solution :
 x1  x2  x3  x4  2
x3  x 2x  1 2
 a  x1  x2  x3  x4  4 2 f (x)  x4  x 2x  1 2
x  2x  1
5
2 1
b  ∑ x1x2 x3  4  2 2  8 2
= (x3 – x) [2x + 1 – 4] – (x4 + x) [2x –1 – 4] + (x5 +
40. Answer (A, C) 2x + 1) [4x – 2 – 4x – 2]
Hint : f(x) = 2x4 – 3x3 – 2x2 + 3x – 2x5 + 5x4 – 2x2 + 5x –
4x5 – 8x – 4
(1 + x)n(x2 – 1)m = (1 + x)m + n (x – 1)m f(x) = – 6x5 + 7x4 – 3x3 – 4x2 – 4
Solution : f(x) + 6x5 – 7x4 + 3x3 – 8x = – 4x2 – 8x – 4
= – 4 (x2 + 2x + 1) = – 4 (x + 1)2
(1 + x)n (x2 – 1)m = ( nC0 + nC1 x + nC2 x2 + .... nCn
xn) · (mC0x2m – mC0 x2m–2 + mC2 x2m–4 – ..... + (– 1)m 42. Answer (A, B, D)
mC )
m Hint :
Comparing coefficient of x2m on both sides ⎛⎞

1  ei   2sin ⎜ ⎟
⎝2⎠
Coefficient of x2m in (1 + x)n (x2 – 1)m = nC0 mC0 – nC2
Solution :
n
+ nC4 mC2 – ..... +  1 2 nCn · mC n
⎛⎞
mC ⎛  ⎞  i⎜ ⎟
1 1  ei   2i sin ⎜ cos  i sin ⎟   2i sin e ⎝ 2 ⎠
2
2⎝ 2 2⎠ 2

(if n is even) …(i)  1  e i   2sin
2
n1
= nC0 mC0 – nC2 mC1 + nC4 mC2 – ..... +  1 2 Cn1
n ⎡  2 3
then, Sn  2 ⎢2sin  2sin  2sin  ..... 
⎣ n n n
· mCn1 (if n is odd)
2 ⎛ ⎛ n  1⎞  ⎞⎤
2 sin ⎜ ⎜ ⎟ · ⎟⎥
⎝ ⎝ 2 ⎠ n ⎠⎦
Coefficient of x2m in (1 + x)n · (x – 1)m (x + 1)m
= Coefficient of x2m in (1 + x)m + n (x – 1)m ⎛  ⎛ n 1 ⎞  ⎞ ⎛ n 1  ⎞

sin ⎜  ⎜  1⎟ ⎟ · sin ⎜ ·
⎝ n ⎝ 2 ⎠ 2 n ⎠ ⎝ 2 2n ⎟⎠
= Coefficient of x2m in ( m + nC0 + m + nC1x m + nC2x2 + = 4
⎛  ⎞
.... + m + nCm + n xm + n ) (mC0xm – mC1xm – 1 + mC2 sin ⎜ ⎟
⎝ 2n ⎠
xm – 2 +..... + (– 1)m mCm)
mC m + nC – mC m + nC m m + nC – ⎛ (n  1) ⎞ ⎛ (n  1) ⎞
= 0 m 1 m + 1 + C2 m+2 4 sin ⎜ ⎟ sin ⎜ 4n ⎟
m
..... + Cm m + nC2m (if m is even and m  n) …(ii) ⎝ 4 n ⎠ ⎝ ⎠
=
⎛  ⎞
mC m + nC – mC m + nC m m + nC sin ⎜ ⎟
= 0 m 1 m + 1 + C2 m+2 – ..... ⎝ 2n ⎠
m
– Cm m + nC2m (if m is odd and m  n)
⎛  ⎞⎡  ⎤
Put m = n = 8 = 2cosec ⎜ ⎟ ⎢ cos  cos ⎥
⎝ 2n ⎠ ⎣ 2n 2⎦
 8C0 8C0 – 8C2 8C1 + 8C4 · 8C2 – ..... + 8C8 8C4 =
8C 16C – 8C · 16C 8 16C 8 ⎛  ⎞
0 8 1 9 + C2 10 – ....+ C8 · = 2cot ⎜ ⎟
16C ⎝ 2n ⎠
16
11/15
43. Answer (06) 45. Answer (72)
Hint :
Hint :
aij = aji
Solution : a  b and a  ib
For symmetric matrix Solution :
tan    tan 
sin2  sin  x2 – 2x + 3 = 0
2 tan 
2sin  cos   sin    tan 
1  tan2  2  4  12
sin (2cos   1)  0 x  1  2i
⎛ 2 ⎞ 2
1 tan  ⎜ 1  tan2   1⎟  0
sin   0, or cos   ⎝ ⎠
2 x2 – 4x + 1 = 0
tan   0 or tan2 = 3
… (i) …(ii) 4  16  4
x 2 3
cos(2) = – cos 2
2cos2 – 1 = – cos
 The roots of the equation x4 + ax5 + bx2 + cx +
2cos2 + cos – 1 = 0
d = 0 are 1  2i , 2  3
2cos2 + 2cos – cos – 1 = 0
2cos(cos + 1) – (cos – 1) = 0  x4 + ax3 + bx2 + cx + d  (x2 – 2x + 3) (x2 – 4x
+ 1)
1
cos = – 1 or cos = …(iii) = x4 – 6x3 + 12x2 – 14x + 3
2
From (i), (ii) and (iii)  a = – 6, b = 12, c = – 14, d = 3
1
cos   1, cos   a + 2b – 3c + 4d = – 6 + 24 + 42 + 12 = 72
2
5     5  46. Answer (51)
   ,  or   , , ,
3 3 3 3 Hint :
44. Answer (09)
Hint : S = (22 – 42) + (62 – 82) + (102 – 122) + .....
Partial fraction Solution :
Solution :
S = 22 – 42 + 62 – 82 + 102 – 122 + ..... 100 terms
1 1 4 9
   S = 4[(1 2 – 2 2) + (3 2 – 4 2) + (5 2 – 6 2) + ..... 50
(1  x )(1  2x ) (1  3 x ) 2(1  x ) 1  2x 2(1  3 x )
terms]
1
= ⎡1  x  x 2  x 3  .....  ⎤⎦ – 4
2⎣
= – 4[3 + 7 + 11 + ..... 50 terms]
9 50
⎡⎣1  (2 x )  (2 x )2  (2 x )3  ..... ⎤⎦ +
2 =  4·
2
2  3  (50  1)4  100  202
⎡⎣1  (3 x )  (3 x )2  (3 x )3  .....  ⎤⎦
S
 100
202
1 9
 Coefficient of x 3   32   27
2 2 S
  50
404
243  1
=  32
2 S
 1  51
= 122 – 32 = 90 404
12/15
47. Answer (92)
 2m  2  5 
2
  4m 2  1
Hint :
Make all possible cases
4 m 2  4  5  8 m  4 5  4 5m  4 m 2  1
Solution :
EE, LL, I, P, S
84 5
m 1
4! 84 5
2 alike  2 alike  1 diff. 2
C2·3 C1 2
C2·3 C2·  36
2!
2 alike (2E)  3 diff. 1
C1·4 C3 1
C1·4 C3 ·4!  96 
4!   Arg( z ) max 
2 alike (2L)  1E  2 diff 1 1
C1· C1· C2 3 1
C1·1C1·3 C2·  36 4
2!
1E  4 diff 1
C1·4 C4 1
C1·4 C4 ·4!  24 49. Answer (64)
48. Answer (04) Hint :
Hint : |A – I| = 0
SP + SP = 2a, SS = 2ac < 2a
Solution :
Solution :
SP + SP = 2A A  I  0
 
S  2  3, 2  5 , S 2  3, 2  5 , A  2 
1  3 2
SS = 2Ae  2 2 3 0
3 1 1 
2 3 3
 e 
4 2
 3 – 42 – 10 – 12 = 0
⎛ 3⎞
b2  4 ⎜ 1  ⎟  1  A3 – 4A2 – 10A –12I = 0
⎝ 4⎠
 A3 – 4A2 – 10A – 8I = 4I
 z lies on an ellipse
 Equation of ellipse is  |A3 – 4A2 – 10A – 8I| = |4I| = 64
y  2  5 
2 50. Answer (12)
 x  2
2
 1
22 12 Hint :
y Half angle formula, sin 2x + cos 2 x = 1, cos2x =

2cos2x – 1
Solution :
x
0
C(2, 2  5) sin2x (sin2x – 3) + 1 = 0
(1 – cos2x) [1 – cos2x – 3] + 1 = 0
Equation of tangent to the ellipse is (cos2x – 1) (cos2x + 2) + 1 = 0
 y  2  5   m( x  2)  4m 2  1 passes through ⎛ 1  cos 2 x ⎞ ⎛ 1  cos 2x

 1⎟ ⎜
⎞
 2⎟  1  0
⎜ 2 2
O (0, 0) ⎝ ⎠⎝ ⎠
13/15
52. Answer (A)

⎛ cos 2x  1 ⎞ ⎛ cos 2 x  5 ⎞
⎜ 2 ⎟⎜ 2 ⎟ 1 0
⎝ ⎠⎝ ⎠ Hint :
Find rth term

cos22x + 4cos2x – 5 + 4 = 0
Solution :
1  cos 4 x
 4cos 2 x  1  0 10
2 ∑ ∑ ∑ (i  j  k )  ∑ (r  r  r  1)r 1
1  i  j  k  1  10
1 + cos4x + 8cos2x – 2 = 0
3  10  11
cos4x + 8cos2x = 1 =  10
2
51. Answer (B)
= 175 = 52 × 7
Hint :
1 2 1 10


,   2 , 1     2  0, 3  1

∑ ∑ ∑ (ij  jk  ki )  ∑ ⎡⎣r
1  i  j  k  1  10 r 1
2
 r ( r  1)  ( r  1)r ⎤⎦
Solution :
= 1045
1 1
3  1,   ,  2  2 , 1     2  0 = 5 × 11 × 19
 
1  2 10
  2
1  1(  1)   (   ) 
3 2 2 ∑ ∑ ∑ (ijk )  ∑ r ·r ·(r  1)
(P) 1  i  j  k  1  10 r 1
2 1 
= 2 × 5 × 11 × 31
 (   )  0
2 4
10
 2  ∑∑∑ (ijkˆ )  ∑ ⎡⎣r

1  i  j  k  1  10 r 1
2
(r  1)⎤⎦
(Q) 2    (  )   2 (  2   )  (  2   )
1 1 1 = 24 × 3 × 5 × 11
= 0 –  + 1 + 1 – 2 = 3 53. Answer (B)
Hint :
2  2
(R)  2    2 ( 2   )   (   )   2 (   2 ) acos + bsin = rcos( – )
1 1 1
⎛b⎞
r  a 2  b 2 ,   tan1 ⎜ ⎟
=–1–0+1– ⎝a⎠
Solution :
=0
⎡ ⎛  ⎞⎤ 
f ( x )  2 ⎢0  cos ⎜ 2 x  ⎟ ⎥  2cos 2 x sin
⎣ ⎝ 6 ⎠⎦ 6
1 2 
(S) 1

1
 2

⎛ 1 1 ⎞
1  1(1  1)   2 ⎜  2  2 ⎟ =  
3  1 cos 2 x  sin2 x
⎝   ⎠
1 1
1  f ( x )  r cos(2 x   ), r  5  2 3 ,
2 
⎛ 1 ⎞
⎛ 1 1⎞   tan1 ⎜ ⎟
 ⎜  ⎟  4 ⎝ 3  1⎠
⎝ ⎠
14/15
Solution :
  5  2 3  f (x)  5  2 3
(P) Number of terms = 19
y
 10th term is middle term
9  r 1 r 1
2 ⎛3 ⎞ ⎛ 1 ⎞
(Q) Tr  9Cr 1 ⎜ x 2 ⎟ ⎜  3x ⎟
⎝2 ⎠ ⎝ ⎠
1
 For constant term 20 – 2r – r + 1 = 0
x  x
0  3 2  r=7
2 2
⎛ r⎞ r
⎜ 25  ⎟
–1 (R) General term Tr+1 = 175
Cr 5 ⎝ 7⎠
· 75 · x r
y for integral coefficient, r = 0, 35, 70, 105, 140, 175
54. Answer (C) (S) S = (1 – 1 + 4)n = 1024
Hint :  22n = 210
General term  n = 5

15/15

Solutions AIATS JEE (Adv) - 2019 (P) Test-1A (Code-E & F) Paper-2 (04!11!2018)

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Test - 1A (Paper - 2) (Code-E) (Answers) All India Aakash Test Series for JEE (Advanced)-2019

All India Aakash Test Series for JEE (Advanced)-2019

1. (A, B, D) 19. (D) 37. (A, B, D)

2. (A, B, C) 20. (A, B, D) 38. (B, D)

3. (A, C, D) 21. (A, D) 39. (A, C)

4. (A, C) 22. (B, D) 40. (B, C, D)

5. (A, D) 23. (A, B, C) 41. (A, C)

6. (A, D) 24. (B) 42. (B, C, D)

7. (13) 25. (44) 43. (12)

8. (20) 26. (40) 44. (64)

9. (25) 27. (26) 45. (04)

10. (16) 28. (64) 46. (92)

11. (80) 29. (16) 47. (51)

12. (12) 30. (60) 48. (72)

13. (22) 31. (10) 49. (09)

14. (45) 32. (06) 50. (06)

15. (D) 33. (D) 51. (C)

16. (B) 34. (B) 52. (B)

17. (A) 35. (C) 53. (A)

18. (C) 36. (B) 54. (B)

HINTS & SOLUTIONS

8. Answer (20) l2 sin 53º = 2m

T + ma = ma1 13. Answer (22)

(S) Angular momentum is not conserved about cm

19. Answer (D) Solution :

Boiling point =  383 K

Solution : PX  PXo X X , PY  PYo XY

7.66  103  83 2 0.059 [Anode]

C  D = isochoric process (cooling) 0.059 ⎛ 1012 ⎞

23. Answer (A, B, C) 25. Answer (44)

S T  S sys  S surr K.E.i  P.E.i  K.E.f  P.E.f

ST  0 for reversible process (P.E.) i = 0

ST  0 for irreversible process (K.E.) f = 0

26. Answer (40) O2F2 – Non-planar (Open book like structure)

Hint : XeO3 – Pyramidal and non-planar

No. of 2nd neighbour of Na+ = 12

I3 – Linear and planar B 

31. Answer (10) 34. Answer (B)

N1 t N1 t 1 CaO(s)  CO2 (g); ng = +ve

Moles of I2 formed in 1st reaction will be used in 2nd

Moles of Na2S2O3 1s  1s

PART - III (MATHEMATICS)

Solution : = – 4 (x2 + 2x + 1) = – 4 (x + 1)2

⎛ ⎛ n  1⎞  ⎞⎤ Comparing coefficient of x2m on both sides

⎛ (n  1) ⎞ ⎛ (n  1) ⎞ · mCn1 (if n is odd)

Solution : m > 0, D > 0, Sum of roots > 0, Product of roots > 0

 x1x2  x1x3  x1x4  x2 x3  x2 x4  x3 x4

 m2 + 1 – 2m > 4m Exponent of a prime p in n! = Ep(n!)

43. Answer (12) 45. Answer (04)

SP + SP = 2a, SS = 2ac < 2a

cos22x + 4cos2x – 5 + 4 = 0  Equation of ellipse is

44. Answer (64) x

Solution : Equation of tangent to the ellipse is

= – 4[3 + 7 + 11 + ..... 50 terms] ⎡⎣1  (3 x )  (3 x )2  (3 x )3  .....  ⎤⎦

S 50. Answer (06)

2cos2 + 2cos – cos – 1 = 0 f ( x )  r cos(2 x   ), r  5  2 3 ,

 For constant term 20 – 2r – r + 1 = 0 10

 22n = 210 ∑ ∑ ∑ (ij  jk  ki )  ∑ ⎡⎣r

All India Aakash Test Series for JEE (Advanced)-2019

1. (A, D) 19. (B) 37. (B, C, D)

2. (A, D) 20. (A, B, C) 38. (A, C)

3. (A, C) 21. (B, D) 39. (B, C, D)

4. (A, C, D) 22. (A, D) 40. (A, C)