n most building construction, away in a regular maintenance by highly alkaline-hardened Port-
I concrete effectively protects re-
inforcement from damage caused by environmental factors or program. Although ACI 318 does not apply to all construction, it de- scribes the current consensus on land cement paste. Corrosion doesn’t occur while the passive layer is intact. This protective layer exposure to fire. In severe environ- concrete design and construction may be broken due to the effects of ments found in some industrial practice. It’s important to realize carbonation or chloride ions that plants, marine structures, bridge that building codes set minimum penetrate to the reinforcement. As decks and parking structures, de- requirements, and that extra pre- described in Reference 5, carbona- structive effects of reinforcement cautions are needed in some cases. tion occurs when carbon dioxide corrosion have been a problem. Re- In concrete, reinforcement is pro- in the air reacts with water to form search and field observations since tected by a passive layer of iron ox- a weak acid, then converts calcium the late 1960s have answered many ide that forms on steel surrounded hydroxide in the hardened cement questions about the mechanism, consequences, and repair of corro- Water to cementitious materials ratio sion of reinforcement in concrete. With proper design, mix selection, A relatively new term, water-cementitious materials ratios, w/cm, and construction practices, rein- is being referenced frequently. For many years, the water-cement ratio, forced concrete structures can per- w/c, was taken as the most important single parameter to describe form well in corrosive environ- concrete quality. To compute w/c, divide the mix water, except that ments. Concrete cover makes an contained in the aggregates, by the cement content in any mixture. important contribution to this per- Other things being equal, as w/c increases, strength and durability formance. decrease. Many mixes now include other cementitious materials to increase Environment and Corrosion strength, reduce permeability, or otherwise modify the properties of The American Concrete Institute fresh and hardened concrete. To compute w/cm divide the mix water Building Code, ACI 318 (Ref. 1), by the total amount of cementitious materials. Since the specific gravi- defines a corrosive environment as ty of other cementitious materials is different from portland cement, one where concrete is exposed to the details of mix proportioning may be a bit more complicated. chlorides from deicing chemicals, As defined in ACI 31S92, cementitious materials include portland salts, or brackish water or spray. and blended hydraulic cements, fly ash and other pozzolans, and Effects of corrosion may be espe- ground granulated blast furnace slag. Each of these components have cially severe for concrete exposed ASTM standard specifications. There was no ASTM standard for silica to wetting and drying, and to con- fume when ACI 318-92 was issued, and it isn’t counted as a cementi- crete where aggressive chemicals tious material in the current code. For now, w/cm excludes silica on the exposed surfaces are not fume where ACI 318-92 applies, but silica fume is frequently used as rinsed off with rain or washed an admixture, typically as 5% to 113% by weight of cement. paste to calcium carbonate. This re- action proceeds from the surface very slowly and is not usually sig- nificant for sound concrete with a low water-cement ratio. In most cases, reinforcement cor- rodes when chloride ions, often supplied by deicer chemicals or marine spray, penetrate to the steel in a sufficient amount, called the corrosion threshold. The chloride ions form an acid and break down the passive protective layer if moisture and oxygen are available Figure 1. For similar exposure, the time-to-corrosion, that is the time until chlorides to sustain the corrosion reaction. exceed the amount required to break down passive layer around the steel and Since corrosion products—iron ox- initiate corrosion, depends on concrete cover thickness and water-cement ratio. ides—take up more volume than the original iron, a bursting effect concrete mix, fewer chlorides have prove workability and ensure suc- occurs and concrete cover can then to penetrate the cover to reach the cessful consolidation. Even a well span or delaminate. corrosion threshold. For corrosion proportioned concrete mix won’t Concrete quality protection, chlorides contributed effectively protect reinforcement if to the concrete mix from water, ag- the concrete isn’t adequately com- Although concrete is not imper- gregates, cementitious materials, pacted. meable, conventional concrete and admixtures are limited as a with low permeability can be suc- Cover as Corrosion protec- percentage of the cement content. cessfully produced and placed. For tion ACI 318 limits of 0.15% for con- corrosion protection, use concrete crete exposed to chloride in ser- Figure 1 shows how concrete made with good quality materials vice, 1.00% for reinforced concrete cover thickness and water-cement and the lowest water-cementitious that will be dry or protected from ratio protect reinforcement from material ratio possible to meet moisture in service, and 0.30%, corrosion. Added cover and im- placing requirements (see box). Al- otherwise, are based on a specific proved concrete quality delay so follow proper consolidation, fin- test procedure. Experts in concrete chloride ion penetration. The fig- ishing, and curing practices (Ref. materials and durability disagree ure represents results of a 3). on the appropriate limits of and “time-to-corrosion” study involv- In 1989, ACI 318 was revised to the ways to measure chloride con- ing repeated application of deicer emphasize the importance of dura- tent in concrete mixes. For concrete salts (Ref.4). After about 800 appli- bility early in the process of select- mixes to be used in corrosive envi- cations, the protection provided by ing materials for a concrete struc- ronments, avoid intentional use of 1.5 inches of concrete with a ture. For corrosive environments, significant amounts of chlorides water-cement ratio (w/c) of 0.40, requirements for concrete quality and don’t exceed ACI 318 require- 2.75 inches with w/c of 0.50, and now include a compressive ments. But don’t panic if trace 3.5 inches with w/c of 0.60 is about strength of at least 5000 psi and a amounts of chlorides are present. the same. Another phase of the maximum water-to-cementitious Concern for concrete quality same study demonstrated the im- material ratio (w/cm) of 0.40. doesn’t stop with limits on water- portance of proper consolidation— These provisions specify a cementitious materials ratio and concrete proportioned with a very high-quality cement paste. For chloride content of the mix. It’s im- low w/c of 0.32, but poorly com- concrete exposed to deicing chemi- portant to place and consolidate pacted, was less effective in resist- cals, amounts of fly ash, pozzolan, concrete properly. Uncontrolled ing chloride penetration than well and slag are limited, but this is in- additions of water to improve consolidated concrete with w/c of tended to provide protection workability reduce concrete in- 0.60. against surface scaling and isn’t re- tegrity. High-range water-reducing For cast-in-place construction lated to corrosion protection. admixtures often are used to im- exposed to earth or weather, ACI If chlorides are present in the 318 requires a minimum concrete coatings, corrosion inhibiting ad- cover of 2 inches for #6 through mixtures, specialty concretes, coat- #18 bars, and 11⁄2 inches for #5 bars, ed reinforcement, and cathodic W31 or D31 wire, and smaller rein- protection. Reference 5 describes forcement. For corrosive environ- advantages, disadvantages, and ments or other severe exposure cost impact of various corrosion conditions, designers should con- protection strategies. In some cir- sider increased concrete cover, less cumstances, use of more than one permeable concrete, or other pro- approach is warranted. Currently, tective measures. ACI 318R (Ref.2) ACI 318 provides no guidance on recommends a minimum concrete the relative effectiveness of these cover for corrosion protection in measures for additional protection. cast-in-place construction of 2 Some designers feel that use of ad- inches in walls and slabs and 21⁄2 ditional protective measures are inches for other members. For equivalent to providing the addi- beams and columns, this is a sig- tional cover recommended by Ref- nificant increase in cover since re- erence 2. quirements don’t depend on bar size. For a column exposed to the References weather and using #4 ties,11⁄2 -inch 1. ACI 318-92, “Building Code Re- quirements for Reinforced Concrete,” cover on the tie also provides 2 American Concrete Institute (ACI), De- inches of cover to the main bars. troit. Where cover is increased for corro- 2. ACI 31 8R-92, “Commentary on sion protection,21⁄2 inches on the tie Building Code Requirements for Rein- forced Concrete,” ACI. is about 3 inches on the main bars. 3. ACI 222R-89, “Corrosion of Metals Special attention to bar place- in Concrete,” ACI. ment is warranted when corrosion 4. K. C. Clear, “Time-to-Corrosion of protection is a concern. ACI 318 Reinforcing Steel in Concrete Slabs, V. states tolerances for placement of 3: Performance after 830 Daily Salt reinforcing steel and cover in flex- Applications,” Report No. FHWA-RD-76-70, Federal Highway ural members (beams and slabs), Administration, Washington, D.C., walls, and compression members 1976. (columns). For members with ef- 5. Terence C. Holland, “Corrosion Pro- fective reinforcement depth, d, > 8 tection for Reinforced Concrete,” Con- crete Construction, March 1992, pp. inches, tolerance on effective depth 230-236. is ± 1⁄2 inch, and the cover tolerance is - 1⁄2 inch but not less than - 1⁄3 of the specified cover. Project specifi- cations may require closer toler- ances. The ACI tolerances are based on generally accepted field practices. Contractor quality-assur- ance inspections are necessary to verify placement within specified tolerances.
(Doi 10.1016 - B978-0!08!096532-1.01209-7) Ericsson, T. - Comprehensive Materials Processing - Residual Stresses Produced by Quenching of Martensitic Steels