Q1/ Dr Adil

A) According to your study about MOT, answer the following:

1- What is the goal of MOT.
2- What are the important concepts of MOT.
3- What is the difference between MOT and LFT.
4- Draw a MO diagram show the effect of π-bonding on the energy levels for octahedral complexes.

B) Answer 1 or 2

1- Answer the following:

1- Discuss briefly the use of KSeCN in the preparation of various types of organoselenium
compounds

2- Classify the organic selenium compounds according to number of selenium- carbon bonds,
showing the most synthetic methods.

2- Answer the following:

a- Triorganylphosphine selenide can be used as mono- and bidentate with transition metals.
b- Sketch a scheme showing the most important diorganyl selenide reactions
c- Explain why using inert gas atmosphere such as argon o oxygen free nitrogen gas and super dried
solvents during preparation of organoselenium compounds.
d- Predict a method for the preparation of benzeneselenol.

Q2/ Dr Ali
A- Chose the correct answer:
1- Which of the following complexes formed by Cu ions is most stable?
a- Cu2+ + 4NH3 [Cu(NH3)4]2+ , logk = 11.6
b- Cu2+ + 4CN- [Cu(CN)4]2- , logk = 27.3
c- Cu2+ + 2 en [Cu(en)2]2+ , logk = 15.4
d- Cu2+ + 4 H2O [Cu(H2O)4]2+ , logk = 8.9

2- When 0.1 mol CoCl3 (NH3)5 is treated with excess of AgNO3 ,0.2 mol of AgCl are obtained. The
conductivity of solution will correspond to:

a- 1:3 electrolyte b- 1:2 electrolyte c- 1:1 electrolyte d- 3:1 electrolyte

3- The stabilization of coordination compounds due to chelation is called the chelate effect. Which
of the following is the most stable complex species?
 a- [Fe(CO)5] b- [Fe(CN)6]3- c- [Fe(C2O4)3]3- d- [Fe(H2O)6]3+

4- Due to the presence of ambidentate ligands coordination compounds show isomerism.

Palladium complexes of the type [Pd(C6H5)2(SCN)2] and [Pd(C6H5)2(NCS)2] are:

a- linkage isomers b- coordination isomers c- ionisation isomers d- geometrical isomers

5- Atomic number of Mn, Fe and Co are 25, 26 and 27 respectively. Which of the following
inner orbital octahedral complex ions are diamagnetic?
a- [Co(NH3)6]3+ b- [Mn(CN)6]3- c- [Fe(CN)6]4- d- [Fe(CN)6]3-

B- Answer 1 or 2
1- Describe in details how to prepare the following inorganic selenium reagents:
a- KSeCN b- H2Se c- NaHSe d- SeO2 e- Na2Se2

2- Complete the following reactions: