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Journal of Magnetism and Magnetic Materials 242–245 (2002) 33–40

Giant magnetoimpedance: concepts and recent progress


M. Knobel*, K.R. Pirota
Instituto de F!ısica ‘‘Gleb Wataghin’’ (IFGW), Universidade Estadual de Campinas (UNICAMP), C.P. 6165,
13.083-970 Campinas S.P., Brazil

Abstract

The giant magnetoimpedance effect (GMI) consists in drastic changes of the complex impedance of soft magnetic
materials upon the application of an external magnetic field. The GMI effect is strongly dependent on the frequency of
the applied current and the magnetic anisotropies present in the material, among other factors, which spawn a number
of interesting new magnetic phenomena. In this context, one can roughly separate the research on GMI into
approximately three aspects: (i) theory; (ii) applications and (iii) as a tool to investigate other magnetic parameters. In
this work, an updated review of all these aspects is given. r 2002 Elsevier Science B.V. All rights reserved.

Keywords: Magnetic measurements; Soft magnetic materials; Magnetic properties; Skin effect

1. Introduction tions in the effective magnetic permeability, a factor that


is relevant to determine the field and current distribution
Although the magnetic-field dependence of the within the samples. When a soft magnetic material is
electrical impedance Z of a ferromagnetic wire was first used, the magnetic permeability can change orders of
observed about six decades ago [1], the intense magnitude when a rather small field is applied, causing
investigation of what is now called giant magnetoimpe- strong variations in the internal fields and electrical
dance (GMI) dates only from 1994 [2–5], i.e., just current density, and consequently, on the sample’s
around 7 years. In spite of this fact, it is amazing to impedance. The effect is strongly dependent on the
notice the advances in the understanding of the under- frequency of the applied current and the magnetic
lying physical mechanisms of GMI and the development anisotropies present in the material, which generates a
of practical devices and applications using this effect. number of interesting new magnetic phenomena. In this
The adjective ‘‘giant’’ was employed following the well- context, one can split the research on GMI into
known giant magnetoresistance, which is a large approximately three aspects:
variation of the materials resistance upon the applica-
tion of an external magnetic field [6]. Analogously, in the (i) Theory: From the theoretical viewpoint, the
case of GMI, it is the material complex impedance that research on GMI began with phenomenological
suffers drastic changes as a function of an external models developed to understand some basic aspects
applied magnetic field. Although the practical results are found in experimental data, such as the frequency
very similar, i.e., in both cases one observes a large and field dependence of the effect, and the
variation of the voltage drop across the samples upon appearance of a double peak structure in materials
the application of the external field, the physical origin with specifically induced anisotropies, for example.
of both phenomena is completely different. Roughly Afterwards, the research on GMI evolved to more
speaking, in the case of GMI the overall effect of the accurate descriptions based on the formal equiva-
magnetic field application is to induce strong modifica- lence of GMI with ferromagnetic resonance. After
proper adaptations of the geometrical configura-
*Corresponding author. Tel.: +55-19-3788-5480; fax: +55- tion and boundary conditions, it is now possible to
19-3289-3137. have a more precise description of the phenomen-
E-mail address: knobel@ifi.unicamp.br (M. Knobel). on. This fact opened a completely new perspective

0304-8853/02/$ - see front matter r 2002 Elsevier Science B.V. All rights reserved.
PII: S 0 3 0 4 - 8 8 5 3 ( 0 1 ) 0 1 1 8 0 - 5
34 M. Knobel, K.R. Pirota / Journal of Magnetism and Magnetic Materials 242–245 (2002) 33–40

in the study of GMI, but brought together more [14]. In general, the inductive voltage is determined by
intricate mathematics to deal with. the internal inductance which, in turn, depends on the
(ii) Applications: After the observation of GMI in soft spatial distribution of the circular permeability within
magnetic amorphous ribbons and wires, the effect the wire. When a time-varying current with low
has been studied in several systems, including frequency is flowing through a ferromagnetic sample,
commercial materials, thin films, sandwich struc- an AC voltage VT (total voltage) appears between the
tures, single crystals, amorphous microwires, na- ends of the wire. This total voltage is a sum of a resistive
nocrystalline materials, among others. Each voltage, VR ; and an inductive voltage, VL ; so that VT ¼
different system displays peculiar properties, being VR þ VL ¼ RI  ðio=c2 ÞLi I; R being the DC resistance
interesting for several practical applications, many of the sample. When an external DC magnetic field Hex
of them already proposed and tested in laboratory is applied, the circular component of magnetization and
prototypes. the circular permeability change, giving rise to a large
(iii) As a tool: A deeper understanding of the mechan- change in the total voltage. If one defines the electrical
ism behind GMI allows one to predict some complex impedance as Z ¼ VT =I ¼ Z1 þ iZ2 ; one con-
expected behaviours, under particular assump- cludes that, at relatively low frequencies, the field
tions, and to use the GMI as an additional tool dependence of impedance is attributed to its inductive
to investigate some intrinsic and extrinsic magnetic term, which is simply proportional to the circumferential
properties of novel artificially grown soft magnetic permeability [14]. This basic and simple idea also applies
materials. to the other regimes, i.e., the external field acts only as
an agent to bring about changes in the effective
Some reviews on the subject were published [7–10]. In permeability.
this work, an updated overview covering all the above-
mentioned aspects will be given. 2.2. Moderate-frequency regime

In the moderate-frequency scale of few MHz, the


2. GMI: basic aspects and theories field-driven changes in the impedance of the samples
were the first to be identified as the GMI effect [2,5]. The
Depending on the frequency f of the driving AC drastic changes of impedance were soon interpreted in
current I that flows through the samples, the giant terms of the classical skin effect in a magnetic conductor
magnetoimpedance can be roughly separated into three with scalar magnetic permeability, as a consequence of
different regimes: (i) in the low-frequency range of 1– the change in the penetration depth of the AC current
10 kHz the changes on the voltage at the sample’s ends provoked by an external magnetic field. The complex
are mainly due to the so-called magneto-inductive effect impedance Z of a cylindrical magnetic conductor and
that was extensively studied by Mohri and co-workers infinite planar film are, respectively [15,16],
[11]. (ii) At higher frequencies, up to few MHz, one has
the earliest and intensively studied giant magnetoimpe- Z ¼ RDC kaJ0 ðkaÞ=2J1 ðkaÞ
dance, being the effect basically caused by variations of and
the magnetic penetration depth due to strong changes of kt
the effective magnetic permeability caused by an Z ¼ RDC cotðkt=2Þ; ð1Þ
2
external magnetic field [3]. (iii) At very high frequencies,
of the order of GHz, a huge variation of the penetration where k ¼ ð1 þ iÞ=d; J0 and J1 are the Bessel functions of
depth is observed, and strong changes of the sample’s first kind, a is the radius of the wire, t is the thickness of
impedance occur owing to the ferromagnetic resonance the film and d is the magnetic penetration depth, given
(FMR) [12]. Let us describe each regime in more detail. by
d ¼ cð4p2 smf f Þ1=2 ; ð2Þ
2.1. Low-frequency regime
where s is the electrical conductivity, f is the frequency
In the low-frequency range the main effect of the of the current along the sample and mf is the circular
current is simply to generate a circumferential time- magnetic permeability. Owing to the high magnetic
varying magnetic field. This field causes a circular permeability of soft magnetic materials, the skin effect
magnetic flux change and generates a longitudinal appears at frequencies orders of magnitude lower than
electric field Ez ; whose value at the surface determines those expected for a nonmagnetic conductor with similar
the inductive voltage across the wire: VL ¼ Ez ðaÞl ¼ conductivity. Hex again triggers changes in the circular
ðio=c2 ÞLi I; where l is the wire length and Li is the permeability and, therefore, the penetration depth also
internal inductance of the wire [13]. If the wire is changes, finally resulting in changes of Z: Thus, for a
homogeneous, the expression for Li is simply Li ¼ mf l=2 ferromagnetic material the magnetic field dependence of
M. Knobel, K.R. Pirota / Journal of Magnetism and Magnetic Materials 242–245 (2002) 33–40 35

the permeability is the main factor that controls the 13


GMI behaviour.
Therefore, the problem of explaining the GMI 12 (Fe Co ) Si B
900 kHz
response of a particular sample is equivalent to the 5 mA
problem of understanding the trend of its permeability.
11 after annealing
In ferromagnetic materials, owing to the involved
relationship between the magnetic field Hex and the H [O e]

Z [Ω ]
ex

induction B; the AC permeability is generally a complex 10


tensor, which depends not only on the frequency f and
the external magnetic field Hex ; but also on some other 9
parameters, such as the amplitude of the AC magnetic
field generated by the AC current, mechanical strains, 8
temperature, etc. To understand the experimental results
and to enable improvement of the novel GMI materials -100 -50 0 50 100
several theoretical models of GMI have been developed. (a) H ex [Oe]
The main task of a good theory is to find an
approximate expression for the effective circumferential
permeability meff
f ; which best describes the response of 16 16
(Fe Co ) Si B
the particular domain structure to the axial driving AC 14

[Ω ]
900 kHz 12
current and applied external field. Usually, both the 14 5 mA 10

Z
domain wall movement and magnetization rotation 8
before anealing
contribute to the permeability [14,17]: meff f ¼
6
0 300 600 900
12
Z [Ω ]

mrot mov rot


f þ mf ; where mf and mf
mov
are the corresponding f (k Hz)
contributions to the effective circumferential magnetic
permeability. At relatively low frequencies, f o500 kHz, 10
both contributions are responsible for the circumfer-
ential magnetization process. At higher frequencies, 8
when the skin effect is stronger, the domain wall
movements are strongly damped by eddy currents and 6
the magnetization rotations dominate the process [18].
The high-frequency expansion of the impedance expres- -100 -50 0 50 100
sion given by Eq. (1) reveals that Z is proportional to (b) Hex [Oe]
square root of the product of permeability and
Fig. 1. (a) Field dependence of impedance Z (double-peak
frequency [15]. In this simple scenario, considering the
behaviour) for a ribbon of composition (Fe0.053Co0.947)70Si12B18
circular permeability as a scalar quantity, let us consider submitted to a pre-annealing of 1 h at 3601C followed by 1 h
a sample with perpendicular magnetic anisotropy stress-annealing at 3401C (applied tensile stress of 400 MPa).
(circular magnetic domains for wires or transversal ones (b) The same for the ribbon before the mentioned annealing
for films). When Hex is increased along the longitudinal (single-peak behaviour) and the frequency dependence of the
direction, hard magnetic axis, the magnetization in each impedance at zero applied field (inset).
domain rotates towards the axis, increasing the circular
permeability and thus increasing the impedance Z: The 400 MPa) [21,22]. The thermal treatment induced a well-
maximum permeability is reached for a static applied defined magnetic anisotropy perpendicular to the ribbon
field that balances the transversal anisotropy field Hk ; axis [21,22]. On the other hand, if the sample has easy
the point where the impedance has its maximum value longitudinal axis magnetization (longitudinal magnetic
[19,20]. Further increase of Hex leads to the situation anisotropy), the transversal magnetization is always
where the circular magnetization process becomes dominated by rotational processes and the impedance
dominated by magnetization rotation and therefore mf displays a monotonous decrease from Hex ¼ 0 (single-
decreases, reaching a constant and very low value. The peak behaviour). Fig. 1(b) shows the single-peak beha-
impedance Z follows the same behaviour. Thus, if the viour for the same sample as in Fig. 1(a) but measured
applied external magnetic field takes values from Hex before the above-mentioned annealing.
to þHex in the longitudinal direction, the curve of the
impedance versus applied field displays two peaks (two-
peak GMI behaviour) as can be seen in Fig. 1(a) for an 2.3. High-frequency regime
(Fe0.053Co0.947)70Si12B18 amorphous ribbon submitted to
a pre-annealing of one hour at 3601C followed by one In order to fully understand the experimental data,
hour stress-annealing at 3401C (applied tensile stress of several authors [19,20] initially presented quasistatic
36 M. Knobel, K.R. Pirota / Journal of Magnetism and Magnetic Materials 242–245 (2002) 33–40

models based on the minimization of the free energy order to induce specific magnetic anisotropies, modify-
equation for some particular domain structure. ing the GMI response.
Although this kind of model does not consider the
dynamic effects related to the rapid motion of the 3.1. Recent experimental results
magnetization, they are useful to explain the experi-
mental results at low frequencies, and to obtain Since its discovery, GMI has been studied in a wide
important magnetic parameters (see Section 4 below). range of systems. Firstly, GMI was observed in single-
Panina and Mohri theoretically investigated the influ- phase bulk structures, like soft magnetic amorphous
ence of eddy current damping of domain wall motion on wires [2,5,17] and ribbons [4,29,30]. It was soon realized
GMI effect [13]. Their model is valid at the intermediate that the most important characteristic of a good GMI
frequency regime, where the circular magnetization by element is magnetic softness, and therefore it was
domain wall motion is still significant. At higher studied in soft nanocrystalline ferromagnets [31–33],
frequencies, when the magnetization rotation completely commercial crystalline Mumetal strips [34,35], sputtered
dominates the magnetization process, the dynamic thin films [30,36], sandwich structures [37,38]. Also, it is
characteristics play an important role, and a more well known that the magnetic anisotropy of the system
rigorous model must be based on a simultaneous (its intensity, direction and distribution) can strongly
solution of Maxwell equations and the Landau–Lifshitz affect the GMI behaviour [16,39,40]. Therefore, several
equation of magnetization motion. This procedure is studies have performed all kinds of annealings, in order
well known from theories of ferromagnetic resonance to induce specific anisotropies: field annealing [41], stress
[23]. To achieve this task, Panina et al. [14] derived the annealing [42,43], torsion annealing [44,45] and Joule
effective dynamic permeability meff of a wire with heating [35,46] and their combinations [47,48] in a
circumferential or helical anisotropy and of a thin film variety of systems were already tested, with very
with in-plane uniaxial anisotropy. This model, and interesting results. Furthermore, magnetoelastic aniso-
others [24,25], neglect the exchange interaction in the tropies can play an important role even at room
skin layer, and therefore are just approximations for temperature, and studies of GMI as a function of
ferromagnetic metals. Yelon et al. [12] showed that the applied tensile stress [17,49,50] or torsion angle [51,52]
theory of ferromagnetic resonance in metals, developed have revealed that the impedance can be a good
more than 40 years ago, and which explicitly takes into parameter to build sensitive stress or torsion sensors.
account the exchange effect, completely agrees with the Also, GMI has been extensively investigated in glass-
observed GMI effect at rather high frequencies. After covered amorphous microwires [46,53–55].
such elucidation, a number of papers using this More recently, much attention has been given to
approach appeared to explain the effect in many asymmetric GMI behaviour because it can be very
different situations. M!enard et al. [26] solved the interesting in sensor devices. In principle, asymmetrical
problem for an isotropic axially saturated wire and, GMI effect can be reached using a DC bias field
later on, for a nonsaturated anisotropic wire [27]. Kraus produced by coils or bias permanent magnets put
applied the approach to a planar geometry, considering around the sample. Sometimes this procedure can be
a film with uniaxial anisotropy [16] showing that the troublesome and another mechanism is needed. Asym-
exchange effect does play an important role in the GMI metrical GMI was found in twisted wires with helical
response. Britel et al. [28] recently reported the observa- anisotropy biased with a DC current [56]. Panina et al.
tion of both ferromagnetic resonance and antiresonance [57], based on the surface impedance tensor, analysed
in a magnetic metal using a GMI technique. the mechanism of the asymmetric GMI in those twisted
wires and in a wire without torsion (circular anisotropy)
driven by a pulse current flowing through the sample
and the coil mounted on it [58]. Several studies have
3. Recent experimental results and applications reported asymmetric GMI in ribbons and wires biased
by DC current [59–61]. Asymmetric GMI was also
It is remarkably difficult to make a complete review of found in Co-based amorphous ribbons annealed in air
all published experimental data on GMI, because a large with a weak field (maximum 3 Oe) in the direction of the
amount of works have been published in the last few sample axis [62], in Co-based wires annealed under a
years. Generally speaking, conventional measurements circumferential field produced by a DC bias current [63]
are explored to test the validity of some theoretical and torsion-annealed wires [64]. In some cases the origin
models, while different geometries and techniques are of the observed asymmetry is still under discussion
employed to gather new insights about some unclear [65–67].
points. Furthermore, a great number of investigations Although GMI seems promising for applications,
deal with different kinds of materials subjected to a there are some drawbacks that must be overcome in
broad variety of annealings, which are performed in order to design a material for a certain device. For
M. Knobel, K.R. Pirota / Journal of Magnetism and Magnetic Materials 242–245 (2002) 33–40 37

example, GMI presents relaxation due to the aftereffect The potential application of GMI effect as a research
of the permeability [68,69]. This GMI aftereffect is not tool was already realized in one of the initial works,
desired for technological applications, but can be where a fit of the impedance versus frequency curve gave
strongly reduced through appropriate annealing [22]. as a result the scalar circular permeability for an
An other nondesirable effect for some applications of FeCoSiB wire [2,74], a parameter which is difficult to
GMI is the hysteretic behaviour that is correlated with obtain using conventional magnetic techniques. By
the magnetization process [70]. Like the GMI aftereffect, means of simple approximations, it was possible to
hysteresis can be strongly reduced through adequate develop a useful model to visualize the GMI effect in
thermal treatments [71]. amorphous and nanocrystalline wires, which leads to
rough estimations of the magnetic penetration depth d
and also the circular permeability mf ; using one single
3.2. Applications
measurement instead of the whole frequency dependence
[31,74]. An alternative approach was developed by
Many applications of GMI have been proposed so
Valenzuela et al. [75] that investigated the GMI using
far. By choosing an appropriate material, and perform-
equivalent circuits. In this impedance spectroscopy
ing specific thermal treatments it is possible to tailor
formalism it was possible to show that a CoFeBSi wire
special impedance responses, depending on the desired
can be approximated by a series Rs Ls arrangement,
application. The high sensitivity of GMI to external DC
connected to a parallel Lp Rp arm. Ls and Lp are
field, drive current frequency and tensile stress makes
inductors associated with the rotational and domain
soft magnetic materials especially convenient for sensor
wall contributions of mf ; respectively. Rp is a resistive
applications. Therefore, from the application point of
element related to wall damping and Rs accounts for all
view, many uses of GMI materials have been idealized
resistances in the circuit like the wire itself, contacts and
and developed, with very interesting perspectives.
so on. This methodology allows one not only to evaluate
The first report concerning a technological application
the circumferential permeability as a function of the
of GMI appeared in 1991, before its interpretation, in
applied field but also to estimate the respective
the development of magnetic sensors [64]. Mohri
rotational and domain wall contributions to perme-
proposed a data table based on the magnetoinductive
ability [76].
effect for imputing hand-written characters into a
More recently, a novel approach was introduced to
personal computer removing the conventional key-
study the GMI effect [61]. In this method, the mean
board, the ‘‘pen-imputting personal computer’’ [47]. A
value of the circumferential permeability and the
position sensor based on GMI was developed with a low
circular hysteresis loops can be estimated by means of
negative magnetostriction CoFeSiB wire [10]. The stress
a Fourier analysis of the time derivative magnetization
dependence of GMI on an annealed CoFeB ribbon was
calculated from a simple rotational model, minimizing
found to be promising to develop a highly sensitive
the free energy equation. The simple model explains
stress-sensor [38]. A direction-sensitive sensor was
quite well the experimental results for an FeCoSiB joule
recently developed using the GMI effect in an FeCo-
heated wire biased by a DC current (asymmetric
SiBNd wire [39]. A wide variety of novel sensing
response), and it is now being tested in several soft
elements are under assessment [72], such as computer-
magnetic systems [77].
disk heads, rotary encoders, pin-hole detector, direction
Magnetoelastic parameters can also be studied
sensors for navigation (electronic compasses), current
through impedance measurements. The influence of
sensors, biomedical sensors, car traffic monitoring [73]
applied tensile stress on GMI effect has been investi-
and environmental sensors [74]. Good reviews concern-
gated in amorphous wires [17,19,49] and ribbons [78].
ing GMI element sensors can be found in Refs. [7,35,72].
The stress dependence of GMI can be easily applied to
A comparison among a number of magnetic sensors can
estimate the saturation magnetostriciton constant (ls ) of
be found in Ref. [50].
negative magnetostriction samples [79].
Pirota et al. [39] studied the GMI in stress-annealed
amorphous ribbons as a function of the angle of
4. GMI as a tool application of external magnetic field to verify the role
of induced anisotropies (and their distribution) and
Since the GMI phenomenon is now better under- demagnetizing factors in the GMI phenomenon. The
stood, it is possible to predict some expected trends, and authors proposed an experimental procedure for deter-
also use the GMI as an additional tool to investigate mining the easy-axis distribution function. Carara et al.
some intrinsic and extrinsic magnetic properties of novel [80] showed that relevant information about the
artificially grown soft magnetic materials. This section magnetization dynamics of soft magnetic materials
gives an overview of some works that make use of GMI could be obtained from the GMI measurements. More
to extract relevant parameters of the samples. recently, the GMI technique was applied to evaluate the
38 M. Knobel, K.R. Pirota / Journal of Magnetism and Magnetic Materials 242–245 (2002) 33–40

evolution of anisotropy field of FeNbB amorphous magnetic materials, including the distribution of
ribbons as a function of iron content [81], while GMI quenched-in and induced anisotropies, magnetoelastic
was combined with magnetic force microscopy to behaviour, ferromagnetic resonance and anti-resonance,
characterize the domain structure of electrodeposited and other intrinsic and extrinsic magnetic properties.
CoP microtubes [82]. Also, the progress on models and experimental data will
However, the great potential of GMI as a character- certainly lead to improved materials from the applica-
ization tool for soft ferromagnetic metals was only tions viewpoint, mainly highly sensitive magnetic
recently manifested, following the enormous advances in sensors. However, there are still many unsolved pro-
theoretical models. M!enard et al. [26] established a clear blems and questions that remain to be clarified during
correspondence between GMI and magnetization this challenging route to understand and develop better
curves, and used it to investigate and model the domain application-oriented soft magnetic materials.
structure in glass-covered amorphous wires. Ciureanu
et al. [83] measured the GMI of amorphous and
polycrystalline wires (current frequencies in the range
Acknowledgements
10–6 GHz). From the peak of the GMI curves, they were
able to estimate the saturation magnetization Ms ; with a
The authors acknowledge the stimulating collabora-
good agreement with the values directly measured using
tions and discussions with L. Kraus (Prague), C.
a vibrating sample magnetometer. They used a dynamic
!
Gomez-Polo (Pamplona) and M. Va! zquez (Madrid).
magnetization model for GMI based on ferromagnetic
Financial support from FAPESP and CNPq (Brazil) is
resonance, which predicts a straight line (whose slope
greatly acknowledged.
depends only on Ms ) on an f02 vs. H0 plot, f0 being the
resonance frequency and H0 the resonance field. Later
on, M!enard et al. [84] developed a model for the high-
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