IN Educating for better tomorrow TARGET : JEE (Main + Advanced) 2018 Course : VIKAAS (JA) This DPP is to be discussed in the week (02-05-2016 to 07-05-2016) DPP No. #05 (JEE-ADVANCED) Total Marks : 63 Max. Time : 39 min. Single choice Objective ('-1' negative marking) Q.1 to Q.3 (3 marks, 2 min.) [09, 06] Multiple choice objective ('-1" negative marking) Q.4 to 0.6 (4 marks, 2 min.) [12, 06] Comprehension ('-1' negative marking) Q.7 to Q.8 (3 marks, 2 min.) 06, 04] Single Integer type Questions ('-1" negative marking) Q.9 toQ.11_ (4 marks, 3 min.) —_—[12, 08] Match the column (no negative marking) Q.12 (8 marks, 6 min.) __[08, 06] ChemINFO : 4 Questions ('-1" negative marking) .13 to.16 (4 marks, 2 min.) [18, 08] ques.No [a] 2[3]4]s][e[7]e [9 [tl] a] 2] 13] 14] 15] 16] total Mark obtained DPP No. #05 ANSWER KEY tm ©) 2 © 3m O 4% AO) 5» BC) 6 ABC) 7 @#® & © & 4 10% 4 (ine 42, A) pr (Bas; (C)as;O)p.r 13, A) 14m ©) 18 A) 16 @ 423 Fourdifferent containers contain four different gases with following parameters, Container | Volume | Pressure Temperature [Gas | Molar Mass A 448 101325 Nim 273K w 10 5 2.4L T bar 546K x 20 c 1120 1520 mm Hg, oC Y a D 56L T bar =136.5°C Zz 60 now they are mixed in a single container, then which of following option is correct (A) Mole % of gas X and gas Z are same. (C) Mole ratio of gas W and gas Zis 4: 1 ca fret ural 4 fei—fiet Ae oufters 2 forte arias Pre 2 — (O°) Allare correct. (B) Average molar mass of final mixture is 25, wa) sire ara a Fa | dee wore a 448 701325 Nim™ 273K Ww 10 B 22.40 T bar 346K x 20 c 720 7520 mm Hg oC Y 40 D 56L 1 bar 36 Zz 60 oa ga wow ora A freren oer &, aa Fe HS we ere eB? (AX th a 2 fa Ala HTB (©) ta Wate tat Zar erga 44 (04 wh aa 8) (8) caf Prosr apt fr store aA 25 8 Resonance” Educating for better tomorow nalewar Road, Kola (Raj) 324005Sol Sol. Sol. Using PV = nRT PV= nRT a1 oe ae we Container | Moles wi a a 2 B 05 c 1 D 05 =Mx Average molar mass (sta Hare #20) =x (102) +(20.«0.5) +(401)+ (600.5) _ 20+10+40+30 : : = 25 4 4 ‘One quantum is absorbed per gaseous molecule of Br; for converting into Br atoms, If light absorbed has wavelength 5000A, then the bond energy of Br, is abot... KJlmal (1 eVipartcle = 96 Kimo). Br, & we Aaa ory a Brows Hagar & fay yo aaien wi oy sravha eter Bi aA seed were ay aeT- ef SO00A 8, aa Br, BH a Gort SMT... KU/mol | (1 evi = 96 Kd. tte (6238 (357 0476 12400 Bond energy (ast sul) = —Eoog- x 96 = 238 Kimo. AA photon of 300 nm is absorbed by a gas and then, it re-emits two photons and attains the same initial energy level. One re-emitted photon has wavelength 600 nm. Calculate the wavelength of other photon re- emitted out Gm Fa aT 300mm a yw Nt skeet Fa are stk pe, at wets ga Tea FA a ae At sre ro ee wh gt aR A 8 | eH YH: Te we ere $00 nm | are grr Vo wre 3 aendel Bh vere aftr (a) 450 nm. (8)800nm. (©)200nm. (0+) 750 nm Photon absory = ——t@— = 88210-3107 ge ou ton APSO = 399x10° ~ 300x140 ee he One re-emitted photon energy = G59. 49-9 = 3:96 * 10°" Joule other photon have energy = 6.6 x 10-—3.93 x 10-?= 2.65 x 10° Joule. he 66x10 «3108 ° 300x109 ~ 300x109 = 10 Joule oo ye urea Seta ah gots "2s g5 10 co Soule wha a= Goh = 2.06 x 10° Joule a1 Bes BH wt = 6.6 x 10-" 3.93 x 10-% = 2.65 x 10 Joule, Identify the correct statement(s) IATS(P)] (A*) Cathode rays produce heating effect when they collide with a metal object. (B) Anode rays consist of fast moving protons. (C) For production of Cathode rays in a discharge tube, the gas filled should be at a very high pressure. (D*) The magnitude of e/m ratio for Cathode rays is 1.76 x 10" Cikg, PN Resonance {2 [corporate office : 66 Tower, a6 & IY Eating for better tomorrowSol. Sol. fr 4 8 wal werd or ar afore — (Ay dats fret eta wera oe wee 8 ore a Pe Cw Tg a cared 8 (B) vars Pexot cha wa B afrefter sree at wh ach 2) (C) dens fet & seen & fey Prva afar 4 tte wh oft Gea ara wR eT eT (04) eis Pett 3b fre es sre a aH 4.76 x 10" CIKg® | Inwhich of the following conditions, the de-Broglie wavelength of a charged particle Ail be less than that of another charged particle B ? Given that particle A is heavier than particle B (A) Linear momentum of these particles is same. (B*) Both particles move with same speed. (C*) Both particles have same kinetic energy. (D) Same potential difference has been applied across both the particles from rest. fam oR Raft a a fom, wo aaa wm Aw fey Sanh aire, ga ores oH BA ste 7H a? fea ara @ Fw A, 1 BA sate sito Te & (A) & ont a1 Ratha aH GFT 8) ar oi Bh a are (Cy ate or ears ao sat were (0) eet oot oe erarager Baars Rear ore Te B h h h inv ~ VamkE ~ J2mqv (A) Linear momentum (my) of these particles is same. So, i. is same. (@) Both particles move with same speed. So, particle having greater mass (A) will have lesser 2. (C) Both particles have same kinetic energy. So, particle having greater mass (A) will have lesser (©) Same potential difference (V) has been applied across both the particles from rest, But the charges of the two particles are not known, So, no comment can be made on value of 3. yet h a my ¥2mKE y2mqv (A) ret er tetra aan (ny) wa 8 gay, 2-91 ATT Ae | (©) St ot a ay vars BL ga, wT (A) BT OMT sR a ATA aH tT | (©) SF oo Ts a at wea | SHIR, | (A) wT MATT RT a A TAT Hee | (©) 2th ail we een rT PTArae (V) SN Ten /APHH tah aH a sar aA aren El | ie, 2 aH we EE AM oat seh a at Teme | Select the correct statement (A°) Orthosilicate ion (Si0,*) and Perchlorate ion (CIO,.) are isoelectronic species. (B*) According to Rutherford formula, volume of a nucleus is directly proportional to mass number of nucleus. (C*) Isotopes have different number of nucleons in them. (D) All atoms of Ar, K and Ca are isobars of each other. 8 er/we BT IH aA (A) sities orem ($10,4) 4 waee oF (C10) wHEsaRIRD ere E | @) eaeekd GS oa, safe aT oreTy, ate A gop vem} MI eT ears (Co serena 8 yfteitat aH shou Pry are & OAL, KaACas erh we UH BUR S wets ee B) Orthosilicate ion (SiO) and Perchlorate ion (CIO,-) are isoelectronic species (both contain 50 electrons). According to Rutherford formula, volume of a nucleus is directly proportional to mass numer of nucleus (R = AX, So, Ve RPA. Isotopes have different number of nucleons (equal to mass number) in them. (by definition) All atoms of Ar, K and Ca are not isobars of each other. Only #2ar, {2K & {9Ca atoms are isobars of each other. JN Resonance {2 [corporate office : 66 Tower, a6 & IY Eating for better tomorrow