Test Name: 18OR-I02-AD1-07

PHYSICS, CHEMISTRY AND MATHEMATICS

Class II IIT-JEE Achiever (Regular) 2018-19 Max. Marks 186
Solution to Test - 07 Duration 3 Hours
Advance Paper Code: 20162 Date 15-07-2018

PART - I: PHYSICS
Section A
Multiple choice questions with one correct alternative

1. A particle of mass M is moved under constant power P0. At some instant after the start, its speed is v and
at a later instant, the speed is 2v. Neglecting friction, distance travelled by the particle as its speed
increases from v to 2v is
12Mv3 7Mv3 9 Mv3 Mv3
(A) (B) (C) (D)
5P0 3P0 5 P0 3P0
Ans (B)
P0 = Fv
 dv 
  Mv  v  P0
 dx 
2v x
7Mv3
 M v 2 dv  P0 dx 
  x 
v 0
3P0

2. Four resistances are connected to an ideal battery of emf 50 volt as shown in the figure. The current in
wire AB is

(A) 1 A (B) 2 A (C) 3 A (D) 4 A

Ans (B)
3 8 25
Req =  =
4 6 12
V
 i0 = = 24 A
R eq
3
i1 = × 24 = 18 A
4
4
i2 = × 24 = 16 A
6
Current in the branch AB
i = 2 A

1
3. AB is potentiometer wire of resistance per unit length 0.09  cm1 and  is
an unknown emf of a battery to be measured.  cannot be measured using the
potentiometer shown if the value of  is (select the most appropriate answer)
(A) greater than 8.0 V (B) greater than 8.5 V
(C) greater than 9.0 V (D) greater than 9.5 V
Ans (C)
Potential on wire AB is 9 V
Hence  greater than 9 V cannot be measured.
4. In the circuit shown, the reading of the ammeter is doubled after the switch is closed. Each resistor has a
resistance = 1  and the ideal cell has an e.m.f. = 10 V. Then the ammeter has a resistance equal to

switch

A
(A) 2  (B) 1  (C) 2.5  (D) 5 
Ans (A)
When switch is open current through ammeter
10
I1 = , x = Resistance of ammeter
2x
10
After switch is closed I2 =
x
I2 = 2I1 ; x = 2 

5. The power dissipated in resistor R is 16R watt, whether the switch S is closed or
open. The unknown e.m.f.  of the cell in the circuit is
(A) 4 V (B) 6 V (C) 7 V (D) 9 V
Ans (C)
I²R = 16R  I = 4 A
Clearly the two currents are in opposite directions. when S is open
 E = 4 + 4R
 –10 × 1 + 4 × R + 4 + 4R = 0
3
 R    E  4  4R  7 V
4
6. For a cell, the graph between the potential difference (V) across the terminals
of the cell and the current (I) drawn from the cell is shown in the figure. The
e.m.f. and the internal resistance of the cell are
(A) 2 V, 0.5  (B) 2 V, 0.4 
(C) > 2 V, 0.5  (D) > 2 V, 0.4 
Ans (B)
E.m.f. is the value of voltage, when no current is drawn from the circuit so E = 2V.
2
Also r = slope =  0.4 
5

2I(R)1819PCMT07(A)S 2
Section B
Multiple choice questions with one or more than one correct alternatives
7. An earth satellite is revolving in a circular orbit of radius a with a velocity v0. Mass of earth is M. A gun
v
in the satellite is directly aimed toward earth. A bullet is fired from the gun with muzzle velocity 0 .
2
Assume that mass of the satellite is very-very large with respect to the mass of the bullet.
Choose the correct option(s) :
4a
(A) Maximum distance of bullet from the centre of earth is
3
v0
(B) Minimum speed of bullet (relative to earth) is
2
3v0
(C) Minimum speed of bullet (relative to earth) is
4
3/2
2  4a 
(D) Time period of motion of bullet around earth is T =  
GM  3 
Ans (B) and (D)
GM
v0 
a
mv0a = mvr
1  2 v02  GMm 1 GMm
m  v0    = mv2 –
2  4  a 2 r
2a 4a
Solving, rmax= 2a, rmin = . Length of semi-major axis =
3 3
8. In the circuit shown in figure, E1 and E2 are two ideal sources of
unknown emfs. Some currents are shown. Potential difference
appearing across 6  resistance is VA – VB = 10 V. Choose
correct options.
(A) The current in the 4.00 resistance between C and B is 5 A
(B) The unknown emf E1 is 36 V
(C) The unknown emf E2 is 54 V
(D) The resistance R is equal to 9 
Ans (A), (B), (C) and (D)

After redrawing the circuit

3
 (a) I4 = 5A
(b) From loop (1)
– 8(3) + E1 – 4(3) = 0  E1 = 36 volt
From loop (2)
+4(5) + 5(2) – E2 + 8(3) = 0
E2 = 54 volt
(c) From loop (3)
–2R – E1 + E2 = 0
E  E1 54
R= 2 = – 36 = 9 
2 2
Ans (a) 5.00 A (b) 36.0 V, 54.0 V (c) 9.00 
l
9. In a potentiometer, primary cell has internal resistance of as shown in figure. The potentiometer
a 2
wire is a combination of two wires connected in series as shown in figure. The common cross sectional
radius of both wires used for potentiometer is 'a'. Then, 
5  a2
(A) range of potentiometer is
6
2
(B) range of potentiometer is
3
,  2, 2
 A B
(C) if null point is at midpoint of longer wire then  ' =
2
G

(D) if null point is at midpoint of longer wire then  ' =
4
Ans (A) and (C) '
  5l  5
(A) VAB   2 
VAB 
 6l   a  6
 2
 a 
 l 2l  
(C)  '  (i)  2  2  
 a a  2
2
10. In the figure shown, there is no friction between B and ground and  = between A and B. Then,
A M
3
(A) The net work done on block A with respect to B is zero B 2M F = Mg
MgS
(B) The net work done on block A with respect to ground for a displacement ‘S’ is
3
2MgS
(C) The net work done on block B with respect to ground for a displacement ‘S’ is
3
(D) The work done by friction with respect to ground on A and B is equal and opposite in sign.
Ans (A), (B), (C) and (D)
For the situation A and B move together and force of friction
between A and B is static M

Mg Mg 2Mg 2M F Mg
Net force acting on A= . Net force on B = Mg  
3 3 3
Since displacement is same.

2I(R)1819PCMT07(A)S 4
11. Three large identical conducting plates of area A are closely placed parallel to left right
each other as shown (the area A is perpendicular to plane of diagram). The net
charge on left, middle and right plates are QL, QM and QR respectively. Three
QL QM QR
infinitely large parallel surfaces SL,SM and SR are drawn passing through middle
of each plate such that surfaces are perpendicular to plane of diagram as shown.
Then pick up the correct option(s).
(A) The net charge on left side of surface SL is equal to net charge on right side
of surface SR. SL SM SR
(B) The net charge on left side of surface SL is equal to net charge on right side of surface SM.
(C) The net charge on left side of surface SL is equal to net charge on right side of surface SL.
(D) The net charge on right side of surface SL is equal to net charge on left side of surface SR.
Ans (A), (B), (C) and (D)
Since electric field on plate at surface SL is zero, net charge on left side of SL is equal
to net charge on right side of SL. Further net charge between any two dotted surfaces 1 2 3 4 5 6
(out of SL, SM and SR) is zero from Gauss theorem.
 Charge on left most surface q1 is equal to q
1 q 6

charge on right most surface q6, that is, q1 = q6

SL S M S
R
Hence all statements are true.
12. In the figure shown
5
(A) the ratio of energy density in Ist dielectric to second dielectric is
3
1
(B) the ratio of energy density in Ist dielectric to second dielectric is
1
2
(C) total induced surface charge on the interface of the two dielectric is
15
2
(D) total induced surface charge on the interface of the two dielectric is –
15
Ans (A) and (D)
2
e1  E2 k E2 k  k  k 5
(i) = 1 12 = 1 12 =  1   2  = 2 =
e2 2 E 2 k2 E2  k 2   k1  k1 3
 1  1 
(ii) B =  1   –  1  
 k1   k2 
 1 1 2
=    = –
 k 2 k1  15

13. A black box contains combination of cells and resistances. There are two terminals A and B through
which an external load resistance can be connected to black box.
In an experiment a load resistance RL is connected between A and B and A
potential difference across load is noted. Following are the ready observed:
R
RL (in ) 1.5 4
Voltmeter reading (in V) 3 4
Based on the above information mark the correct options

5
 (A) If a capacitor of 1 F is connected between A and B then the maximum A and B then the maximum
acquired by it will be 5 C
(B) If a load resistance of 1  is connected between A and B then maximum power is transferred across
the load.
(C) If a capacitor of 2 F is connected between A and B then the charge on capacitor reaches 63% of
maximum charge at t = 2 s (t = 0 being the time when it was connected)
(D) If a capacitor of 2 F is connected between A and B then the charge on capacitor reaches 37% of
maximum charge at t = 2 s (t = 0 being the time when it was connected).
Ans (A), (B) and (C)
The equivalent Thevinin circuit for the two cases will be
A Case I A

1.5 
Eth 4
Eth

rth B

rth

Hence, Eth = 5V
rth = 1 
14. An uncharged solid conducting sphere of radius R is connected to earth with the help of an ideal
ammeter. A point charge q is moving towards the sphere with a constant velocity v as shown in the
figure. At t = 0 separation between charge and sphere is x0. Then,
(A) the direction of flow of current is from the sphere to the ground
R
(B) the direction of flow of current in from the ground to the sphere q v
x
(C) ammeter reading increases 4 times at the instant t  x 0
2v
(D) Rate of work done by external agent is inversely proportional to A

the cube of separation between the sphere and charge

Ans (A), (C) and (D)
If q is the induced charge on the sphere at any instant then
Kq KQ
x

R  Vsphere  0 
qR
or q  
x
Hence, ammeter reading
dq qR (from sphere to ground)
 2 v
dt x
Also potential energy of system
kqq Kq2
U 
x 2R
Kq R Kq 2 R
2
 2 
x 2x 2

2I(R)1819PCMT07(A)S 6
 Kq 2 R

2x 2
Hence dU   Kqr v
dt 2x 3
From work energy theorem, U+W=K
or dU  dW  O or dW   dU  KqR v
dt dt dt dt 2x 3

Section C
Read the passage given below and answer questions 15 and 16 by choosing the correct
alternative
Consider the given arrangement of very large no. of identical capacitors, each of capacitance C.
S1 S2 S3 S4 S5 S6

V0

All the switches are initially opened and all capacitor are initially uncharged.
To charge the capacitors we can follow 2 methods
Method - 1: All the switches are closed simultaneously
Method - 2: First switch S1 is closed, then S1 opened, then S2 closed, then S2 opened, then S3 closed, then S3
opened, the process keeps on going till last switch.
Answer the following questions based on the above arrangement
15. Total heat loss in method-1 will be
 2 –1 2
 3 1 2
 5 1  2
 6 –1 2
(A)   CV0 (B)   CV0 (C)   CV0 (D)   CV0
 4   4   4   4 
Ans (C)
16. Total heat loss in method-2 will be
51 53 55 57
(A) CV02 (B) CV02 (C) CV02 (D) CV02
192 192 192 192
Ans (D)

Solution to Passage Questions 15 and 16

Method-1
A P

V0

B Q
A P
Lets find equivalent capacitance between A and B. Let CAB = xC then CPQ = xC
C  x  1 C xc
C AB   xC
C   x  1 C C

B Q
C

7
 x 1
 x  x + 1 = x2 + 2x
x2
–1  1  4
x2+ x 1  x 
2
 5 –1
x =  
 2 
 5 –1
C AB    C
 2 
1  5 –1
Heat produced, H1 = C AB V02   2
 CV0
2  4 
By method-2 CV0
After switch S1 closed V0 V0 2
2 CV0
1  C  2 CV02
Heat produced, H21 =   V0 = 2
2 2  4
CV0 CV0
Now switch s1 opened, switch s2 closed 2 2
q  CV  q  q
  0
C C c
+ +CV – q +q
q  CV  q  q  0 C,V =
V 0

2 – –(CV – q) –q
CV
q
3
2CV CV
+ + –q +q
V0 3 V 3
C,V = 3
2 2CV CV
– –
3 3

CV CV
– +
3 3

Heat produced
1 2
 1  2V  2 1  V  2 1  V  2 
H22 = CV   C   C  C 
2  2  3  2  3  2  3  
 
2
1 6CV 2 1 1 1 1 V  1
 CV 2   CV 2  CV 2 H 22  CV 2  C  0   CV02
2 18 2 3 6 6  2  24
Now switch S2 opened switch S3 closed
2
1 1 V  1 1 1 
H 23  CV 2  C  0   CV02   CV02  2CV +
CV
6 6  6  216 9  24 +
 V 3 0
V 3
C,V = 3
1 6 2CV CV
H 23  H 22 –
3
–
9 3

1 1
Similarly, H24 = H 23  2 H 22
9 9 +
CV
–
CV
3 3
1 1
H25 = H 24  3 H 22
9 9
1 1
H24 = H 2(n 1)  n  2 H 22
9 9
Here, H2n represents heat loss after (n–1)th switch is opened and nth switch in closed.

2I(R)1819PCMT07(A)S 8
Total heat produced
H2 = H21 + H22 + H23 + H24 ..............................
1 1 1
= H21 + H22+ H 22  2 H 22  3 H 22 ..........................
9 9 9
 1 1 1 
= H 21  H 22 1   2  3 ............. 
 9 9 9 
 
 1  9
= H 21  H 22    H 21  H 22
1
1  8
 9
CV02 9  1  57
=   CV02  = CV02
4 8  24  192

Read the passage given below and answer questions 17 and 18 by choosing the correct
alternative
 v 
Consider a very large block of conducting material of resistivity ‘’.
Figure shows a small part of it. Current ‘I’ enters at ‘A’ and leaves from a b a
A B C D
‘D’. We apply superposition principle to find voltage ‘V’ developed
between ‘B’ and ‘C’. The calculation is done in the following steps:
(i) Take current ‘I’ entering from ‘A’ and assume it to spread over a hemispherical surface in the block.
(ii) Calculate field E(r) at distance ‘r’ from A by using Ohm’s law E = J, where J is the current per unit
area at ‘r’.
(iii) From E(r), obtain the potential V(r) at r.
(iv) Repeat (i), (ii) and (iii) for current ‘I’ leaving ‘D’ and superpose results for ‘A’ and ‘D.
17. V measured between B and C is
      
(A)  (B)  (C)  (D)
a (a  b) a (a  b) 2a 2(a  b) 2(a  b)
Ans (A)
18. For current entering at A, the electric field at a distance ‘r’ from A is
   
(A) 2
(B) 2 (C) (D)
8r r 2r 2 4r 2
Ans (C)

Solution to Passage Questions 17 and 18


Choose A as origin E = j = 
2r 2
(a  b)
 1   1 1
VC – VB = 
2 
a
r 2
dr    
2  (a  b) a 
  1 1 
VB – VC = 
2  a (a  b) 

 
By super position net potential difference between B and C will be 
a (a  b)

9
 PART - II: CHEMISTRY
Section A
Multiple choice questions with one correct alternative

19. Pure water freezes at 273 K and 1 bar. The addition of 34.5 g of ethanol to 500 g of water changes the
freezing point of the solution. Use the freezing point depression constant of water as 2 K kg mol–1. The
figures shown below represent plots of vapour pressure (V.P.) versus temperature (T). [molecular weight
of ethanol is 46 g mol–1]
Among the following, the option representing change in the freezing point is

(A) (B)

(C) (D)

Ans (D)
34.5g 1000 g
M, molality  1
  1.5 mol kg 1
46 g mol 500 g 1 kg
Tf  K f  m
= 2 K kg mol1  1.5 mol kg1
Tf = 3 K.
So, depression is freezing point is 3 K. that means freezing point of water will be 270 K.
In the phase diagram, we know for water, as vapor pressure increases boiling point also increase.
Therefore, option “D” is correct.
20. Pure benzene freezes at 5.3 C. A solution of 0.223 g of phenylacetic acid (C6H5CH2COOH) in 4.4 g of
benzene (kf = 5.12 kg mol1) freezes at 4.47 °C. From the observation, one can conclude that
(A) phenylacetic acid exists as such in benzene.
(B) phenylacetic acid undergoes partial ionisation in benzene.
(C) phenylacetic acid undergoes complete ionisation in benzene.
(D) phenylacetic acid undergoes association in benzene.
Ans (D)
Depression in freezing point, Tf = Kf m (where, m = molality)
0.223  1000
 5.12  = 5.12 × 0.372 = 1.91 C
4.4  136
 Theoretical Tf = 1.91

2I(R)1819PCMT07(A)S 10
 Actual Tf = 5.3 C  4.47 C
= 0.83 C
0.83
 i  0.43  i < 1  Association will take place.
1.91
Thus, it can be said that phenylacetic acid dimerises in benzene.
21. Consider the following cell Pt(s), H2(g) (1 atm) | H+ (1M) || Ag+ (aq) | Ag(s) whose emf was 0.62 V.
If E ocell is 0.80 V, what is the molar concentration of Ag+ ion?
(A) 3  10–3 M (B) 1  10–5 M (C) 2  10–5 M (D) 1  10–3 M
Ans (D)
 2Ag(s)  2H  (aq)
H 2 (g)  2Ag  
0.06 p H  [Ag  ]2
E  E  log 2  2
2 [H ]
1 [Ag  ]2
0.62  0.80  0.03 log
12
0.62  0.80
 2log[Ag  ]
0.03
0.18
 log[Ag  ]
0.03  2
– 3.0 = log [Ag+]
or [Ag+] = antilog 3.000
= 1.0  10–3 M
22. The correct order of increasing C – O bond length of CO, CO2 and CO 32 is
(A) CO 32 < CO2 < CO (B) CO2 < CO 32 < CO
(C) CO < CO 32 < CO2 (D) CO < CO2 < CO 32
Ans (D)
Since bond length increases as the bond order decreases that is CO < CO2 < CO 32 (bond order: 3, 2,
1.33 respectively)
23. Identify ‘C’ in the following reaction sequence:

Mg (i) CH3CHO HBr

Br A B C
dry ether (ii) H2O / H+
Br
CH CH3 CH2 CH3 Br
(A) (B)
CH3
CH3
(C) Br (D)
Br
Ans (C) OH
HBr
Br MgBr Br

11
24. In diamond, carbon atoms occupy fcc lattice points as well as alternate tetrahedral voids. The edge
length of the unit cell is 356.7 pm. The fraction of the total volume occupied by carbon atoms is
(radius of carbon atom = 77.225 pm)
(A) 0.52 (B) 0.68 (C) 0.74 (D) 0.34
Ans (D)
Number of carbon atoms per unit cell = 4 + 4(alternate Th voids)
volume of 8 carbon atoms
Fraction of total volume occupied by atoms =
volume of unit cell
4
8   3.142(77.225  10 12 ) 3
 3  0.34
(356.7  1012 ) 3
Section B
Multiple choice questions with one or more than one correct alternative/s

25. For the following compounds, the correct statement(s) with respect to nucleophilic substitution reactions
is(are)
CH3
CH3
Br Br Br
H3C C Br

CH3

I II III IV
(A) I and II follow SN2 mechanism
(B) The order of reactivity towards SN2 mechanism for I, III and IV is: IV > I > III
(C) I and III follow SN1 mechanism
(D) Compound IV undergoes inversion of configuration in SN2 reactions
Ans (A), (C) and (D)
26. For the first order reaction 2N 2O5 (g) 
 4NO 2 (g)  O 2 (g)
(A) the concentration of the reactant decreases exponentially with time
(B) the half-life of the reaction decreases with increasing temperature
(C) the half-life of the reaction depends on the initial concentration of the reactant
(D) the reaction proceeds to 99.6% completion in eight half-life duration
Ans (A), (B) and (D)
(A) is correct, because in a first order reaction, concentration of the reactant decreases exponentially with
time.
0.693
(B) is correct, because k  . Since k depends upon temperature, t1/2 also depends upon
t1/2
temperature.
(C) is incorrect. Half-life of a first order reaction is independent of the initial concentration.
(D) 100  1
 50  2
 25  3
12.5  4
 6.25  5 6
 3.125  1.5627  7
 0.7815 8
 0.3915(  0.4)

2I(R)1819PCMT07(A)S 12
27. Which of the following statements is/are correct about tetrahedral voids in an fcc unit cell?
(edge length = a ; body diagonal = b)
b
(A) Each tetrahedral void lies at a distance from the nearest corner
4
3b
(B) Each tetrahedral void lies at a distance from the farthest corner
4
3a
(C) Each tetrahedral void lies at a distance from the nearest corner
4
b
(D) The distance between two tetrahedral voids is
2
Ans (A), (B), (C) and (D)
A A
1 3a
1 1 3a AB 
AB AB or 4 4
4 4 4
Positions of two
Tetrahedral A tetrahedral voids
void 1 3a
AB  on one of the body
3 2 2
AB diagonals of the
4
cubic unit cell
b B

1
AB
4
B B
AB is one of the body
diagonals of the cube

28. The correct statement(s) for the following addition reactions is(are)
H3C H Br2/CHCl3
(i)
H CH3 M and N

H3 C CH3 Br2/CHCl3
(ii) O and P
H H
(A) (M and O) and (N and P) are two pairs of diastereomers
(B) Bromination proceeds through trans-addition in both the reactions
(C) O and P are identical molecules
(D) (M and O) and (N and P) are two pairs of enantiomers
Ans (A) and (B)

13
 CH3 CH3
H3C H Br2/CHCl3
(i) H * Br Br * H
H CH3 H * Br Br * H
CH3 CH3
M N

Meso identical

CH3 CH3
H Br Br H
CH3 CH3 Br2/CHCl3 Br H H Br
(ii)
H H CH3 CH3
O P

Enantiomers
(M, O), (M, P), (N, O), (N, P) are diastereomers
(O, P) = enantiomers (M, N) = identical
29. For a solution formed by mixing liquids L and M, the vapour pressure of L plotted against the mole
fraction of M in solution is shown in the following figure. Here xL and xM represent mole fractions of L
and M, respectively, in the solution. The correct statement(s) applicable to this system is(are)
(A) Attractive intermolecular interactions between L-L in pure liquid L and
M-M in pure liquid M are stronger than those between L-M when mixed
Z
in solution
(B) The point Z represents vapour pressure of pure liquid M and Raoult’s law p
is obeyed when XL  0
(C) The point Z represents vapour pressure of pure liquid L and Raoult’s law
1 xM 0
is obeyed when XL = 1
(D) The point Z represents vapour pressure of pure liquid M and Raoult’s law is obeyed from XL = 0 to
XL = 1
Ans (A) and (C)
It is obvious that the graph represents positive deviation from Raoult's law for the given binary solution
L-M. So, 'A' is correct option.
The point Z has mole fraction XM = 0 that means XL = 1 which inturn means the substance is a pure
solvent L. Further XL  1 implies XM  0 that indicates solution is very dilute and hence obey's
Raoult's law. Thus, option (C) is also correct.
30. Consider the following sequence of reactions
O O
OH
Cl ph3p/heat (i) Ph O H+/heat
P Q R S
heat (ii) H3O+

Which of the following statement/s is/are true?

(A) The intermediate (P) acts as strong nucleophile.
(B) The degree of unsaturation of compound (Q) is six.
(C) The compound (R) is 2-methyl-1-phenylbutane-1,2-diol
(D) The compound (S) is 3-phenylpentan-2-one

2I(R)1819PCMT07(A)S 14
 Ans (A), (C) and (D)
OH
.. +
Cl pph3
OH
(P) (Q)
(R)

O
(S)
31. Which of the following species are planar as well as non-polar?
(A) XeF4 (B) XeF2 (C) XeF5 (D) XeF5
Ans (A), (B) and (C)
Species Electron pairs Hybridisation Geometry Nature
XeF4 4bp + 2lp sp3d2 Square planar Non-polar
XeF2 2bp + 3lp sp3d Linear Non-polar
XeF5 5bp + 2lp sp3d3 Pentagonal bipyramidal Non-polar
XeF5 5bp + 1lp sp3d2 Square pyramidal polar

32. Which of the following statements is/are correct?

(A) Ethanol and water form non-ideal solution showing positive deviation
(B) Ethanol and water form ideal solution
(C) Minimum boiling azeotropic mixture shows positive deviation from Raoult’s law
(D) Maximum boiling azeotropic mixture shows negative deviation from Raoult’s law
Ans (A), (C) and (D)

Section C
Read the passage given below and answer questions from 33 and 34 by choosing the
correct alternative
The reaction of compound P with CH3MgBr (excess) in (C2H5)2O followed by addition of H2O gives Q. The
compound on treatment with H2SO4 at 0 °C gives R. The reaction of R with CH3COCl in the presence of
anhydrous AlCl3 in CH2C12 followed by treatment with H2O produces compound S. [Et in compound P is
ethyl group]
(H3C)3C
CO2Et
Q R S

33. The reactions, Q to R and R to S, are

(A) Dehydration and Friedel- Craft’s acylation
(B) Friedel-Craft’s alkylation, dehydration and Friedel- Craft’s acylation
(C) Aromatic sulfonation and Friedel- Craft’s acylation
(D) Friedel- Craft’s alkylation and Friedel- Craft’s acylation
Ans (D)

15
 Dehydration and Friedel-Crafts acylation
(A) Dehydration – Sulphuric acid brings about dehydration followed by acylation
(D) Sulphuric acid also acts as lewis acid. Therefore reaction undergoes alkylation followed by
acylation.

34. The product S is

HO3S
(H3C)3C O CH3 H3COC
H2 C CH3
(A) (B) (H3C)3C

COCH3
H3C
(H3C)3C CH3
COCH3
(C) (H3C)3C CH3 (D)

COCH3

Ans (D)

Solution to passage questions

 
O OEt CH MgBr O CH3 CH3MgBr
3
H2O
–Mg(Br)(OEt)
– Mg(OH) (Br)
P

OH2 H ..
 : OH CH
3

–H2O CH3
H2SO4

Q
O
H
CH3 Cl
AlCl3

R
O CH3
S

Read the passage given below and answer questions from 35 and 36 by choosing the
correct alternative
1
The following diagram shows the cubic unit cell of elemental gold. Atoms 1
and 2 represent gold atoms. One of the 8 octants is also shown with its 2
centre position, 4. Atomic radius of gold is R. The unit cell edge length
3
is ‘a’. 5

2I(R)1819PCMT07(A)S 16
35. Type of voids represented by position 3 and position 5 respectively are
(A) tetrahedral and octahedral (B) octahedral and tetrahedral
(C) octahedral and octahedral (D) octahedral and cubic
Ans (C)

36. What is the size r of a small sphere (in terms of R) that just fits into void 3?
(A) r = 0.414 R (B) r = 0.225 R (C) r = 0.732 R (D) none of these
Ans (A)
r
Since the void 3 is an octahedral void,  0.414
R

PART - III: MATHEMATICS

Section A
Multiple choice questions with one correct alternative

37. O is the circumcentre of the triangle ABC and R1, R2, R3 are the radii of the circumcircles of the triangles
a b c
OBC, OCA and OAB respectively. Then   is equal to
R1 R 2 R 3
abc abc abc a 2  b2  c2
(A) (B) (C) (D)
R R3 R R2
Ans (B)
abc
We know that, R  . Let 1, 2 and 3 represent the areas of triangles OBC, OCA and OAB
4
a R R a 4
respectively. Then R 1    21
41 R1 R
b 4 2 c 4
Similarly,  2 and  23
R2 R R3 R
a b c 4 4
    2 (1   2   3 )  2
R1 R 2 R 3 R R
4 abc abc
  
R 2 4R R 3
38. A circle of radius r passes through the origin O and cuts the axis at A and B. Then the locus of the foot
of the perpendicular from O to AB is
 1 1 
(A) x2 + y2 = r2 (B) (x 2  y 2 )2  2  2   4r 2
x y 
1 1 4
(C) 2
 2 2 (D) None of these
x y r
Ans (B)
Let us choose the coordinates of A and B as (a, 0) and (0, b) respectively. From the figure we can see
that the circle passing through O, A and B will have AB as its diameter.
Since the radius of this circle is given to be r, therefore we have
a2 + b2 = 4r2 … (1)
x y
Equation of AB is  1 … (2)
a b

17
 Let P(h, k) be the point whose locus is to be found (see figure)
Since P lies on AB, therefore we have
h k
 1 … (3)
a b
Also, since OP is perpendicular to AB, therefore we have
Slopes of OP  Slope of AB = 1
k b
i.e.,   1
h a
k h h2  k2 h2  k2
i.e.,   
a b a 2  b2 2r
k h
i.e., a  and b 
h2  k2 h2  k2
Putting these values in equation (iii) will eliminate the variables a and b, and then putting (x, y) in place
 1 1 
of (h, k) gives the equation of the required locus as (x 2  y 2 )2  2     4r 2
 x y 
x 2dx
39.  (x sin x  cos x)2 
sin x  x cos x x sin x  cos x
(A) c (B) c
x sin x  cos x x sin x  cos x
sin x  x cos x
(C) c (D) none of these
x sin x  cos x
Ans (A)
x 2dx d
Let, I    (x sin x  cos x)  x cos x, we write
(x sin x  cos x) 2 dx
 x   x cos x 
I    2 
dx
 cos x   (x sin x  cos x) 
x cos x
Integrating by part taking as second function, we get
(x sin x  cos x)2
 x  1  (x sin x  cos x) 1
I    2
 dx
 cos x  x sin x  cos x  cos x (x sin x  cos x)
x
  sec 2 xdx
cos x(x sin x  cos x) 
x
  tan x  c
cos x(x sin x  cos x)
x sin x
  c
cos x(x sin x  cos x) cos x
 x  sin x(x sin x  cos x)
 c
cos x(x sin x  cos x)
(sin x  x cos x)
 c
(x sin x  cos x)

2I(R)1819PCMT07(A)S 18
40. Let f(xy) = f(x). f(y)  x > 0, y > 0, where f(x) is not constant and f(x + 1) = 1 + x {1 + g(x)} where
f (x)
lim g(x)  0 then  dx is
x 0 f (x)
x2 x3 x2
(A) c (B) c (C) c (D) ln | x | + c
2 3 3
Ans (A)
f(xy) = f(x). f(y)
Put, x = y = 1
We get f(1) = (f(1))2  f(1) = 1
f(xy) = f(x).f(y)
Differentiate with respect to x partially,
y.f (xy) = f  (x).f(y)
Put x = 1,
y.f (y) = f (1).f(y)
f (y) y
 
f (y) f (1)
f (x) x 1  x2 
  f (x) dx   f (1) dx    c
f (1)  2 
f (1  h)  f (1)
Now, f (1)  lim
h 0 h
1  h  hg(h)  1
 lim 1
h 0 h
f (x) x2
  dx  c
f (x) 2

41. Let a, b, c be sides of a triangle. No two of them are equal and   R. If the roots of
x2 + 2 (a + b + c)x + 3 (ab + bc + ca) = 0 are real then
4 5 1 5  4 5
(A)   (B)   (C)    ,  (D)    , 
3 3 3 3  3 3
Ans (A)
| a  b | < | c |  a2 + b2  2ab < c2
b2 + c2  2bc < a2
c2 + a2  2ca < b2
By adding above three equations,
a2 + b2 + c2 < 2 (ab + bc + ca)
a 2  b2  c2
 2 … (1)
ab  bc  ca
and (a + b + c)2  3 (ab + bc + ca)  0 … (2)
from (1) and (2)
4
3  2 < 2   
3

19
42. If f (x)  lim n 2 (x1/n  x1/(n 1) ), x  0 then  xf (x) dx is equal to
n 
2
x x2 x2 x3 x2 x2
(A)  ln x  c (B)  ln x   c (C)  xl n x  c (D) ln x   c
2 4 2 3 2 4
Ans (D)
lim n 2 (x1/n  x1/(n 1) )
n 

 lim
1 h
h 0 h 2
x   x
h

h 1
 lim
h 0 h 2
x
 h 
1  h  h 1  
 1 x
h
h 1

 h2 
 x h 1  1   1  h
h 1
 lim  2  x
h 0
 h   h  1 
 h 1 
 a x 1 
= ln x.1.1  lim  ln a   f(x) = ln x
 x 0 x 
So, I   xf (x) dx   x ln x dx
x2 x2 1
 ln x   . dx
2 2 x
2 2
x x
 ln x   c
2 4

Section B
Multiple choice questions with one or more than one correct alternative/s

e{x}  {x}  1
43. Let f (x)  where {} fractional part of x and [.] is step function. Then
{x}2
1
(A) lim  f (x)  e  2 (B) lim f (x)  (C) lim f (x)  4 (D) lim f (x  4)  0
x [a ] x [a ] 2 x [a ] x [a ]

Ans (A) and (B)

e1h  (1  h)  1
lim f (x)  lim e2
x [a ] h 0 (1  h) 2
eh  h  1
lim f (x)  lim p … (1)
x [a] h 0 h2
Replace h by h in P in equation (1)
e h  h  1
P  lim … (2)
h 0 h2
(1) + (2)
(e h  1) 2
 2P  lim h 2  1
h 0 e  h

1
P
2

2I(R)1819PCMT07(A)S 20
  x
44. Let f(x) = x + x. ln  1    (1  x)ln(1  x) . Then
 2
 1
(A) f(x) increases on (0, ) (B) f(x) > 0  x   0,   n  N
 n
n 1
 1  1 
(C) 1    e  1   nN (D) f(x) decreases on (1, 0)
 n   2n 
Ans (A), (B) and (C)
Clearly f(0) = 0
 
x  1 x  x 1 x
f (x)   ln     1  0 { ln x < 1  x}
x2 1 x  x  2 1 x
 2 2
 1
 f(x) > 0  x   0, 
 n
1
  1 1  1   1  1
 f    0   ln  1     1   ln  1    0
n n n  2n   n   n 
 1   1
 ln e  ln 1    (n  1)ln  1  
 2n   n
n 1
 1  1 
 1    e 1  
 n  2n 

45. A function f(x) satisfies the condition f(x) = f (x) + f (x) + f (x) + ….. +  and if f(0) = 1. Then f(x)
is
 5 
(A) An increasing function (B) decreasing in  0, 
 11 
+
(C) domain = R (D) range = R
Ans (A), (C) and (D)
f(x) = f (x) + f (x) + …..
f (x) = f (x) + f (x) + …..
2f (x) = f (x) + f (x) + …..
2f (x) = f(x)
f (x) 1

f (x) 2
f (x) x
 f (x) dx  2  c
x
ln(f (x))  c
2
Put x = 0
0
ln(f (0))  c c = 0
2
x
ln(f (x)) 
2
x
f (x)  e 2

21
46. If f(x) = kx2  m such that f(1)  [4, 1], f(2)  [1, 5] then which of following are correct
(A) f(3)max = 19 (B) f (3)max = 20 (C) f(3)min = 1 (D) f(3)min = 2
Ans (B) and (C)
f(1) = k  m, f(2) = 4k  m
f (2)  f (1) f (2)  4f (1)
k ,m 
3 3
1
f(3) = 9k  m = (8f (2)  5f (1))
3
1
f (3)max  (8  5  5  4)  20
3
1
f (3) min  (8  5)  1
3
47. If tan1 y = 4 tan1x then, y is not finite, then
(A) x 2  3  2 2 (B) x 2  3  2 2 (C) x4 = 6x2  1 (D) x4 = 6x2 + 1
Ans (A), (B) and (C)
Let  = tan1x  x = tan 
2 tan 2
tan1y = 4  y = tan 4 =
1  tan 2 2
2  2 tan  4x
(1  tan 2 ) (1  x 2 )
y 2
 2
 2 tan   1  4x
1  
 1  tan 2   (1  x 2 ) 2
4x(1  x 2 )
y
1  x 4  2x 2  4x 2
 1 + x4 6x2 = 0
 x4 = 6x2  1
 x2  3  2 2
1 1
x.tan  .ln  
n n f (x)
48. If f (x)  lim e and  dx  g(x)  c . Then
n  3 11
sin x.cos x
 3
(A) g   
4 2
(B) g(x) is continuous for all x
 15
(C) g    
4 8
(D) g(x) is not differentiable at infinitely many points
Ans (C) and (D)
f (x)  lim e0  1
n 

sec4 x
 11
dx
3
tan x
f (x)
 11 1
.dx
3 3
sin x cos x

2I(R)1819PCMT07(A)S 22
 t = tan x
1 t2 3  83 3  23
 11 dt   t  t c
3
8 2
t
3  1  4 tan 2 x 
 g(x)    
8  tan 2 x. 3 tan 2 x 
 15 
g    and g(x) is not defined at x = 0, (2n + 1)
4 8 2

e x 1 ex
49. If  x 2  5x  4 .2xdx = AF (x  1) + BF (x  4) + c and F(x)   x dx . Then
2 4 2 8 3
(A) A   (B) B  e3 (C) A  (D) e
3 3 3 3
Ans (A) and (D)
 2 8 
 
e x 1 x 1 3 3 
 (x  1)(x  4) 2xdx   e  x  1  x  4  dx
 
2 8
  F(x  1)  e3 F(x  4)  c
3 3
50. Let P(x) = x4  ax3 + bx2  cx + 480 and all its zeros are integers which are greater than 1. Also given
that |P(4)| + |P(4)| = 0. Then
(A) least possible value of a is 19 (B) greatest possible value of a is 25
(C) least possible value of a is –4 (D) The least possible value of P(2) is 0
Ans (A), (B) and (D)
P (4) = 0, P(4) = 0
 4 is repeated root of P(x) = 0
P(x) = (x  4)2 (x2 + x + )
= (x2  8x + 16) (x2 + x + )
 16 = 480   = 30
P(x) = (x  4)2 (x2 + x + 30)
= (x  4) (x  4) (x  I1) (x  I2) {I1I2 = 30}
4 3
= x  (4 + 4 + I1 + I2)x + other terms
4 + 4 + I1 + I2 = a
I1I2 = 30 {2  15 or 10  3 or 5  6}
amin = 8 + I1 + I2 = 19
amax = 8 + 2 + 15 = 25
There are 6 possibles for I1, I2
P(2)min = 0 where I1 = 2 or I2 = 2

23
Section C
Read the passage given below and answer questions from 51 and 52 by choosing the
correct alternative
( x 8  1) m
I  xn
dx can be evaluated for m, n  Q by suitable trigonometric substitution. Using this

information answer the following questions

1
51. If m   and n  1 , then I is equal to
2
1 x8  1  1 1
(A) ln c (B)  ln x 8  1  1  ln | x | c
4 x4 4

1 x8  1 1 1 x8  1  1
(C) ln c (D) ln c
2 x4 8 x4

Ans (A)
1
m ,n=1
2
(1  x 8 ) 1 / 2
 x
dx

By putting x4 = tan , we get 4x3 dx = sec2  d

1 sec 2  d 1 1
I  
sec  4 tan 

4 
cos ec d  ln | cos ec  cot  | c
4
1 x8  1 1 1 x8  1  1
 ln 4
 4  c  ln c
4 x x 4 x4

1
52. If m   and n = 5, then I is equal to
2
1 x8 1 1 x8  1
(A) ln c (B) ln c
8 x4 4 x4

1 x8  1 1 x8 1
(C)  ln c (D)  ln c
4 x4 8 x4

Ans (C)
1
m ,n=5
2
(x 8  1)1/ 2 1 sec2  d
I dx   sec   4 tan 2 
x5
1 cos  1
 
4 sin 2 
d  4
cot  cos ec d

1
  ln | cosec | c 1 x8  1
4   ln c
4 x4

2I(R)1819PCMT07(A)S 24
Read the passage given below and answer questions from 53 and 54 by choosing the
correct alternative
Consider a family of circles passing through the point (3, 7) and (6, 5)
53. Number of circles which belong to the family and also touching x-axis are
(A) 0 (B) 2 (C) 1 (D) infinite
Ans (B)
Equation of the family of circle is
(x  3)(x  6) + (y – 7)(y  5) +  (2x + 3y  27) = 0 …(i)
2 2
i.e., x  y  (2  9)x  (3  12)y  (53  27)  0 …(i)
If (i) touches the x-axis, then the equation
(x  3)(x – 6) + (0  7)(0 – 5) +  (2x + 3(0)  27) = 0 has two equal roots
i.e., x 2  (2  9)x  (53  27)  0 has equal roots
Hence discriminant = 0 which gives two value of 
54. If each circle in the family cuts the circle x2 + y2  4x  6y  3 = 0, then the common chords pass
through the fixed point
 23   3  23 
(A) (1, 23) (B)  2,  (C)  3,  (D)  2, 
 2   2  3 
Ans (D)
Equation of common chord of (i) and x2 + y2  4x  6y  3 = 0 is given by
(5x  6y + 56) + (2x + 3y  27) = 0
This represents a family of lines which pass through the point of intersection of
5x  6y + 56 = 0 and 2x + 3y  27 = 0
 23 
which is  2, 
 3 
***

25