i AAO KH FORMTP2009155 2 sesrcovs 020 10 MAYARUNE 2009 CARIBBEAN EXAMINATIONS COUNCIL "-ANCED PROFICIENCY EXAMEMATION CEMISTRY- UNITE. Paper 01 90 minutes 27 MAY 2009 (a.m) READ THE FOLLOWING INSTRUCTIONS CAREFULLY. This testconsists of 45 items. You will have 90 minutes to answer thera, Inaddition to this test booklet, youshould have an answersheet ‘Denote concemed that the answar sheet provides spaces formore answers than here areitemsin ‘histest. ‘Bach item in this estas four suggested answers lettered (A), (B),(C),(D}. Read eachitem youare about to answer md decide which choice is best. ‘On your answer sheet, find the number which corresponds to your item and shade the space heving, the same leer as the answver youbave ctosen. Look at the sample item below. ‘Samplelion Whichafthefollowingiethe HIGHEST cony transition nan organiccompound? (A) ntoot ‘Sempls Answer ®@) nom © cw @@ 68 @) xo ‘The best answer to this item is “erto a, so answer space (C) has been shaded, {Ifyou wantto change your answer, besureto erase yout tcompletcly before you fillinyournew choice. ‘Wheayouare old tobegin, tun thepageand workasquickdy andasearefullyas youcan. 7yeucannat answer an item, omititand go antethenextons. Youcan come back tothe omitted iternlater. Your sore will bethe total number of correct answers, “Youmay do any rough work in this booklet Piguresarenotuecessarily drewn to soale ‘Theusefnomprogrammmablecaloulatorsisatiowed. DO NOT TURN THIS PAGE UNTIL YOU ARE TOLD TO DO SO. Copyright® 2009 Caribiacanxaminations Council Allrightsreserved. (2112010/CAPE2009 GP APPOXSEAL TERE § bo memavucxuay $a 2, ‘Which of the following has the GREATEST = 2. ‘Aradioactive element, M, of mass number polarizing power? ‘Avand stone numberZ, undergoes B decay, ‘followed by a. decay. The final element, N, {A} Ca will be Bet aaa 2 uw w “GN @ “iN so ” © Mw sn a 3 refers to the mese spectrum of chlorine gas shown below, 4 wos 4) as 8S SSO mle 3, ‘peak A represents the ion 35+, which possible ions would give the peaks, B and E? @) Mer and (I~ CN? cr ~SCiyt and CCC" © Parad Faeyr” © Mar and (CIP CNY GOON TO THE NEXTPAGE 9211201 0/CAPE20096 “The electronic configuration ofthe Cx™ ion is represented as Iss 3a" fo [else apf set ae? @) [as]? apt 20? Which of the following factors increases the first ionisation energy of an atom? fA) Increased sereening by inner electrons ®) Larger number of valence electrons (©) Greater nuclear aliarge (D) Larger atomic radius ‘Which ofthe following describes potssium bromide? (A) A network of covatently bonded atoms (B) —_Asubstance which boils at 59°C and decomposes at high temperatures (©) A solid with a very high molar extn emperotoa ich does not conduct won in afc (0) Anemones anid whshne ‘to form a liquid that conducts elects How many hydrogea bonds can be formed with dieoxygenatom in anolectl of wer? ami. ~ @) 2 () 3 @ 4 021 120)07APE2002 8 % 10. Which oft following istebott Sd of hydrogen md 5 a of oxygen a'0°C and wee (A) Thoyreact to produce Sd’ obyiter (8) “Blity posgess the suanmttint of “Bibetie energy = (©) They contain the seme number of ‘motecales. D) They react completely with each thes, For complete reaction, 0.25 gof' monobasic acid requires 10cm" of 0.2mol dm? sodium ydrouide, What is the relative molecular sass ofthe acid? @ 125 Se as © 3% ©) Bo When 86 gofthe ionic salt, CaS0,. 284,08 healed so that al ofits water of erytalisation is driven off and 58.0 g of CaSO, remain, the value of xis @ i) © ©) GOON TOTHENEXT PAGE,