JP XII Physical&Inorganic Chemistry (28) - Prev Chaps + Inorg. Chem PDF

PHY./INO.
CHEMISTRY
TARGET : JEE (Main + Advanced) 2016
Course : VIJETA (JP) NO. 44 & 45
This DPP is to be discussed in the week (05.10.2015 to 10.10.2015)
DPP No. # 44 (JEE-ADVANCED)

Total Marks : 65 Max. Time : 41 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.7 (3 marks, 2 min.) [21, 14]
Multiple choice objective ('–1' negative marking) Q.8 to Q.13 (4 marks, 2 min.) [24, 12]
Integer type Questions ('–1' negative marking) Q.14 to Q.16 (4 marks 3 min.) [12, 09]
Match the Follow ing (no negative marking) Q.17 (8 marks, 6 min.) [08, 06]
ANSWER KEY
DPP No. # 44 (JEE-ADVANCED)
1. (B) 2. (A) 3. (C) 4. (B) 5. (C) 6. (D) 7. (A)
8.* (ABCD) 9.* (ABD) 10.* (BCD) 11.* (AD) 12.* (ABD) 13.* (ACD) 14. 7
15. 1 16. 38 17. (D)
DPP No. # 45 (JEE-MAIN)
1. (B) 2. (C) 3. (D) 4. (D) 5. (D) 6. (B) 7. (B)
8. (A) 9. (D) 10. (D) 11. (B) 12. (B) 13. (A) 14. (C)
15. (D) 16. (D) 17. (D) 18. (A) 19. (A) 20. (C) 21. (D)
1. A sample of copper is used to prepare 100 ml of 0.02 M CuSO4(aq) solution. 10 ml of this CuSO4(aq) solution
is mixed with excess of KI to show the following changes.
CuSO4 + 2KI  K2SO4 + CuI2
2CuI2  Cu2I2 + I2

The liberated iodine is titrated with hypo solution (Na2S2O3) and requires V ml of 0.01 M hypo solution for its
complete reduction. The volume (V) of hypo required is :
0.02 M CuSO4 ¼tyh;½ foy;u dk 100 ml cukus ds fy;s dkWij ds ,d uewus dk mi;ksx gksrk gSA cus CuSO4(tyh;)
foy;u ds 10 ml dks KI ds vkf/kD; ds lkFk feykrs gSa ftlls fuEu ifjorZu gksrs gSa %
CuSO4 + 2KI  K2SO4 + CuI2
2CuI2  Cu2I2 + I2

eqDr vk;ksMhu dk gkbiks foy;u (Na2S2O3) ds lkFk vuqekiu djkrs gSa rFkk blds iw.kZ vip;u ds fy;s 0.01 M gkbiks
foy;u dk V ml vko';d gksrk gSA gkbiks dk vko';d vk;ru (V) gksxk %
(A) 2 ml (B*) 20 ml (C) 1 ml (D) 10 ml
Sol. meq of hypo = meq of I2 = meq of CuSO4.
So, meq of hypo = meq of CuSO 4.
M × V × v.f. = M × V × v.f.4
0.01 × V ×1 = 0.02 × 10 × 1. volume of hypo = 20 ml.
Sol. gkbiks ds feyhrqY;kad = I2 ds feyhrqY;kad = CuSO4 ds feyhrqY;kad.
blfy,, gkbiks ds feyhrqY;kad = CuSO4 ds feyhrqY;kad.
M × V × la;kstdrk xq.kkad = M × V × la;kstdrk xq.kkad
0.01 × V ×1 = 0.02 × 10 × 1. gkbiks dk vk;ru = 20 ml.
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PAGE NO.- 1
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2. Which configuration represents an atom with smallest radius ?
ijek.kq dk dkSulk foU;kl fuEure f=kT;k dks iznf'kZr djrk gS\
2 5 2 2 1 2 2 2 2 6 2 5
(A*) 1s2, 2s , 2p (B) 1s , 2s , 2p (C) 1s , 2s (D) 1s , 2s , 2p , 3s , 3p
3. Which of the following is incorrect order ?

(A) F2 > Cl2 > Br2 > 2 (oxidising power) (B) F2 < Cl2 < Br2 < 2 (bond length)
(C*) F2 > Cl2 > Br2 > 2 (bond energy) (D) F2 < Cl2 < Br2 < 2 (boiling point)
fuEu esa ls dkSulk Øe lgh ugha gS \
(A) F2 > Cl2 > Br2 > 2 (vkWDlhdkjh {kerk) (B) F2 < Cl2 < Br2 < 2 (ca/k yEckbZ)
(C*) F2 > Cl2 > Br2 > 2 (ca/k ÅtkZ) (D) F2 < Cl2 < Br2 < 2 (DoFkukad)
N
4. 20 ml of H2O2 after acidification with dil H2SO4 required 30 ml of KMnO4 for complete oxidation. The
12
volume strength of H2O2 solution is :
N
ruq H2SO4 ds lkFk 20 ml. H2O2 ds vEyh;dj.k ds i'pkr~ iw.kZ vkDlhdj.k ds fy, KMnO4 dk 30 ml vko';d gS
12
rks H2O2 foy;u dh vk;ru lkeF;Zrk gksxh %
(A) 3.5 V (B*) 0.7 V (C) 5.6 V (D) 0.35 V
Sol. Equivalent of KMnO4 = Equivalent of H2O2
(KMnO4 ds rqY;kad = H2O2 ds rqY;kad)
N1V1 = N1V1
1
30 × = 20 × N
12
30 1
N = =
12  20 8
1
 Volume strength (vk;ru lkeF;Zrk) = N × 5.6 =
× 5.6 = 0.7 V
8
5. If by aerobic oxidation 75% Fe2+ in magnetite is converted to Fe3+ then what will be the empirical formula of
new solid. Assuming charge balance is valid.
;fn ok;qoh; vkWDlhdj.k }kjk eSXusVkbV esa mifLFkr 75% Fe2+, Fe3+ esa ifjofrZr gks tkrk gS rc u;s Bksl dk ewyuqikrh lw=k
D;k gksxk ? ekuk fd vkos'’ k larqyu ekU; gSA
(A) Fe14O35 (B) Fe7O30 (C*) Fe24O35 (D) Fe12O11
Sol. Fe3O4 = Fe12  Fe32  O24 
Formula after converting 75% Fe2+ to Fe3+
lw=k ds 75% Fe2+ ds Fe3+ esa cnyus ds i’'pkr~
2 3 2
= Fe1/ 4Fe2  3 O35 / 8 = Fe1/2 4Fe11/
3 2
4 O35 / 8
4
= Fe2Fe22O35 = Fe24O35
6. Ka of HIO (hypoiodous acid) is 10–11, while K a1 and K a 2 of H2S are 10–7 and 10–13 respectively at a perticular
temperautre. Relative strength of H2S to HIO in their equimolar solutions is –
fdlh fuf'’pr rki ij HIO (gkbiksvk;ksMl vEy) ds fy, Ka 10–11 gS tcfd H2S ds fy, K a1 o K a2 Øe’'k% 10–7 o 10–
13
gSA buds leeksyj foy;u esa H2S o HIO dk vkisf{kd lkeF;Z fuEu gS %&
(A) 1 : 10 (B) 1 : 100 (C) 10 : 1 (D*) 100 : 1
K a1 10 7
Sol. Relative strength of H2S to HIO = =  100
Ka 10 11
K a1 10 7
H2S o HIO dk vkisf{kd lkeF;Z = =  100
Ka 10 11
PAGE NO.- 2
7. A silver wire dipped in 0.1 M HCI solution saturated with AgCI develops an oxidation potential of – 0.25 V .
If E0Ag/Ag+ = –0.799 V, the solubility of AgCI in pure water will be
(A*) 7.16 × 10–6 mole/litre (B) 5.5 × 10–6 mole/litre
(C) 6.28 × 10–6 mole/litre (D) None
AgCI ds lkFk lar`Ir 0.1 M HCI foy;u esa fuyfEcr ¼Mwck gqvk½ ,d flYoj dk rkj – 0.25 V dk vkWDlhdj.k foHko mRiUu
djrk gSA ;fn E0Ag/Ag+ = – 0.799 V gS, rc 'kq) ty esa AgCI dh foys;rk D;k gksxhA
(A*) 7.16 × 10–6 mole/litre (B) 5.5 × 10–6 mole/litre
–6
(C) 6.28 × 10 mole/litre (D) buesa ls dksbZ ugh
0 0.0591 [CI– ]
Sol. E = E Ag|Ag + log [k ]
Ag| AgC l | CI – 1 sp
0.1
– 0.25 = – 0.799 + 0.0591 log k k sp = 5.136 × 10–111 solublity (foys;rk) = k sp = 7.16 × 10 –6 mol/liter
sp
8.* Which of the following statement(s) is(are) correct ?

(A*) The electron affinity for sulphur is more exothermic than that for oxygen.
(B*) Successive ionization energies of an atom always increase.
(C*) First ionization energy of As is greater than that of Se.
(D*) Chlorine has larger atomic size as well as electron affinity than that of fluorine
fuEu esa ls dkSulk@dkSuls dFku lgh gS@gS \
(A*) lYQj dh bysDVªkWu ca/kqrk vkWDlhtu ls T;knk Å"ek{ksih gksrh gSA
(B*) fdlh ,d ijek.kq dh mÙkjksÙkj vk;uu ÅtkZ,sa lnSo c<+rh gSA
(C*) As dh izFke vk;uu ÅtkZ Se ls vf/kd gksrh gSA
(D*) Dyksjhu dk ijekf.od vkdkj ,oa bysDVªkWu ca/kqrk nksuksa gh ¶yksjhu ls vf/kd gksrh gSSA
Sol. (A) Oxygen atom is smaller as compared to sulphur; so in oxygen there is more inter-electronic repulsion
than that of sulphur.
(B) Charge increases so size decrease and number of electrons per proton also decreases; so valence shell
electron gradually becomes more tightly held by the nucleus.
(C) Valance shell electron configuration of As is ns 2np3 (half filled stable configuration) and valence shell
electron configuration of Se is ns2np4 (partially filled less stable configuration).
As = 0.947 MJ/mole; Se = 0.941 MJ/mole.
(D) Down the group atomic size increases. Fluorine experiences more inter electronic repulsion than that of
chlorine; so fluorine has less electron affinity than that of chlorin.
(A) vkWDlhtu ijek.kq] lYQj ijek.kq dh rqyuk esa NksVk gksrk gS] blfy, vkWDlhtu esa lYQj dh vis{kk T;knk vUrj
bysDVªkWfud izfrd"kZ.k ik;k tkrk gSA
(B) vkos'k c<+us ij ijekf.od vkdkj ?kVrk gS rFkk izfr izksVkWu bysDVªkWu dh la[;k Hkh ?kV tkrh gS] blfy, la;ksth dks'k
ds bysDVªkWu ukfHkd ls vf/kd n`<+rkiwoZd caf/kr gks tkrs gSA
(C) As dk la;ksth dks'k bysDVªkWfud foU;kl ns2np3 (v)Ziwfjr LFkk;h foU;kl) gSA
Se dk la;ksth dks'k bysDVªkWfud foU;kl ns2np4 (vkaf'kd iwfjr de LFkk;h foU;kl ) gSA
As = 0.947 MJ/mole; Se = 0.941 MJ/mole.
(D) oxZ esa uhps tkus ij ijekf.od vkdkj c<+rk gSA ¶yksjhu esa Dyksjhu dh vis{kk vf/kd vUrj bysDVªkWfud izfrd"kZ.k ik;k
tkrk gS] blfy, ¶yksjhu dh bysDVªkWu ca/kqrk Dyksjhu ls de gksrh gSA
9.* Suppose Bohr theory is applicable to a negative charged particle of mass m e (mass of an electron) and
charge 2e– (twice the charge of electron) revolving around the nucleus of charge Ze (Z = atomic number of
atom). Let r1, V1, J1 and E1 be the radius, speed, angular momentum and energy of the particle in the orbit
respectively. The value of these variables for an electron revolving in the corresponding Bohr's orbit are r, V, J
and E respectively. Then which of the following is / are incorrect :
ekuk fd cksgj fl)kUr ,d _.kkosf'kr d.k ij ykxw gksrk gS] ftldk nzO;eku me (,d bySDVªkuW dk nzO;eku) rFkk 2e– vkos'k
(bysDVªkWu ds vkos'k dk nks xquk) gS tks fd] Ze vkos'k (Z = ijek.kq dk ijek.kq Øekad) ds ukfHkd ds pkjks vksj xfr djrk gSA
ekuk fd r1, V1, J1 rFkk E1 Øe'k% d{kk dh f=kT;k] osx] dks.kh; laosx rFkk d.k dh ÅtkZ gSA bu pj jkf'k;ksa ds eku ,d
?kewrs gq, bysDVªkWu dh cksgj d{kk ds r, V, J rFkk E ds lkFk lEcfU/kr gSaA rc fuEu esa ls dkSulk@dkSuls lEcU/k lgh ugha
gS@gSaA
(A*) r1 = r (B*) V1 = V (C) J1 = J2 (D*) E1 = E
PAGE NO.- 3
Sol. Angular moment of a revolving particle do not depend upon the mass as well as charge of that particle.
(,d ?kw.kZu djrs gq;s d.k dk dks.kh; laosx] d.k ds nzO;eku ds lkFk&lkFk vkos'k ij Hkh fuHkZj ugha djrk gSA)
nh
J=
2
10.* A fruit drink contain ascorbic acid (C6H8O6) is quantitatively analysed by iodimetric titration. 100 ml fruit drink
completely react with 0.02 M of 10 ml solution of I2 according to reaction :
C6H8O6 + 2  C6H6O6 + 2H
Which of the following statement(s) is/are correct for this reaction :
(A) Ascorbic acid is an oxidising agent.
Molecular weight
(B*) Equivalent weight of ascorbic acid =
2
(C*) Amount of ascorbic acid present in 100 ml fruit drink is 0.0352 g.
(D*) Oxidation of carbon of ascorbic acid takes place in the reaction.
ÝqV MªhaDl ¼Qyksa dk twl@is; inkFkZ½ esa mifLFkr ,LdksZfcd vEy (C6H8O6) dk fo'ys"k.k vk;ksMhferh; vuqekiu }kjk fd;k
tkrk gSA 100 ml is; inkFkZ] 0.02 M 2 ds 10 ml foy;u ds lkFk iw.kZr;k fuEu vfHkfØ;k ds vuqlkj fØ;k djrk gS %
C6H8O6 + 2  C6H6O6 + 2H
bl vfHkfØ;k ds fy, fuEu esa ls dkSulk@dkSuls dFku lgh gS@gSa %
(A) ,LdksZfcd vEy ,d vkWDlhdkjd gSA
(B*) ,LdksZfcd vEy dk rqY;kadh Hkkj = 2

(C*) 100 ml is; inkFkZ esa mifLFkr ,LdksZfcd vEy dh ek=kk 0.0352 g gSA
(D*) vfHkfØ;k esa] ,LdksZfcd vEy ds dkcZu dk vkWDlhdj.k gksrk gSA
Sol. Ascorbic acid is reacting as an reducing agent and its valency factor = 2.
According to balanced equation
0.02  10
Moles of ascorbic acid = moles of 2 used = = 2 × 10–4
1000
Mass of ascorbic acid = 2 × 10–4 × 176 = 0.0352 g
C6H8O6 oxidation no. of C  x × 6 + 8 × 1 + 6 × (–2) = 0
2
x=+
3
C6H6O6 oxidation no. of C  x × 6 + 6 × 1 + 6 × (–2) = 0  x = +1
Sol. ,LdksZfcd vEy] ,d vipk;d ds leku fØ;k djrk gS rFkk bldk la;kstdrk dkjd = 2.
lUrqfyr vfHkfØ;k ds vuqlkj
0.02  10
,LdksZfcd vEy ds eksy = 2 ds iz;qDr eksy = = 2 × 10–4
1000
,LdksZfcd vEy dk nzO;eku = 2 × 10–4 × 176 = 0.0352 g
C6H8O6 esa C dk vkWDlhdj.k vad  x × 6 + 8 × 1 + 6 × (–2) = 0
2
x=+
3
C6H6O6 esa C dk vkWDlhdj.k vad  x × 6 + 6 × 1 + 6 × (–2) = 0
11.* 50 ml of an aqueous solution of H2O2 was added into excess of a solution of KI in dil. H 2SO4. The liberated
iodine required 20 ml of 0.1 M Na2S2O3 solution for complete reaction. The same amount of H2O2 with exactly
titrate with :
(A*) 25 mL of 0.016M KMnO 4 solution in acidic medium
M
(B) 20 mL of K Cr O solution in acidic medium.
30 2 2 7
(C) 100 mL of 0.008M KMnO4 solution in acidic medium.
M
(D*) 10 mL of K Cr O solution in acidic medium.
30 2 2 7
PAGE NO.- 4
ruq H2SO4 esa KI ds ,d foy;u ds vkf/kD; esa H2O2 ds 50 ml tyh; foy;u dks feyk;k x;kA blls fudyus okyh I2
ls iw.kZ vfHkfØ;k ds fy, 0.1 M Na2S2O3 dk 20 ml foy;u vko';d gSA H2O2 dh leku ek=k fuEu esa ls fdlds lkFk
vuqekfir gksxh%
(A*) vEyh; ek/;e esa 0.016M KMnO4 foy;u ds 25 mL.
M
(B) vEyh; ek/;e esa K Cr O foy;u ds 20 mL.
30 2 2 7
(C) vEyh; ek/;e esa 0.008M KMnO4 foy;u ds 100 mL.
M
(D*) vEyh; ek/;e esa 30 K2Cr2O7 foy;u ds 10 mL.
Sol. meq. of H2O2 = meq. of I2 = meq. of Na2S2O3 (v.f. = 1) = 0.1 × 1 × 20 = 2
(A) meq. of KMnO 4 = 0.016 × 5 × 25 = 2
1
(B) meq. of K2Cr2O7 = × 6 × 20 = 4
30
(C) meq. of KMnO 4 = 0.008 × 5 × 100 = 4
1
(D) meq. of K2Cr2O7 = × 6 × 10 = 2
30
Only (A) and (D) options are correct.
H2O2 ds feyhrqY;kad = I2 ds feyhrqY;kad = Na2S2O3 ds feyhrqY;kad (v.f. = 1) = 0.1 × 1 × 20 = 2
(A) KMnO4 ds feyhrqY;kad = 0.016 × 5 × 25 = 2
1
(B) K2Cr2O7 ds feyhrqY;kad = × 6 × 20 = 4
30
(C) KMnO4 ds feyhrqY;kad = 0.008 × 5 × 100 = 4
1
(D) K2Cr2O7 ds feyhrqY;kad = 30 × 6 × 10 = 2
dsoy (A) rFkk (D) fodYi lgh gSaA
12.* The solubility of Mg(OH)2 in pure water is 9.57 × 10–3 g L–1. [Value of Kf and Kb for water at 25ºC = 2 K Kg
mol–1 and 0.52 K Kg mol–1]
(A*) Ksp, Mg(OH)2 = 17.96 × 10–12
(B*) Tf = 2.57 × 10–4
(C) If 0.02 Mol Mg(NO3)2 is added then Tf will decreases.
(D*) Tf will increases on complete neutralisation of Mg(OH)2 by HCl.
'kq) ty esa Mg(OH)2 dh foys;rk 9.57 × 10–3 g L–1 gSA (25ºC ij ty ds fy, Kf o Kb ds eku Øe’'k% 2 K Kg mol–
1
o 0.52 K Kg mol–1 gSa]
(A*) Ksp, Mg(OH)2 = 17.96 × 10–12
(B*) Tf = 2.57 × 10–4
(C) ;fn 0.02 eksy Mg(NO3)2 feykrs gS rks Tf esa deh gksxhA
(D*) HCl }kjk Mg(OH)2 ds iw.kZ mnklhuhdj.k ij Tf esa o`f) gksxh
Sol. (A) Ksp = 4s3 = 4(1.65 × 10–4)3 = 17.96 × 10–12
gL–1 9.57  10–3

Tf = iKfm , solubility foys;rk = =
Mw 58
(B) Tf = 3 × 0.52 × 1.65 × 10–4 = 2.57 × 10–4
(D) on neutralisation Tf increases  As number of particles in solution increase.
mnklhuhdj.k ij tSls gh Tf esa o`f) gksxh  oSls gh foy;u esa d.kksa dh la[;k esa o`f) gksrh gSA
Mg(OH)2 + HCl  MgCl2 + H2O
PAGE NO.- 5
13.* 5 mole of an ideal gas compressed adiabatically & irreversibly at 300 K from a volume of 2 L to 20 L. Then for
the process -
,d vkn'kZ xSl ds 5 eksy dks 300 K ij :)ks"eh; o vuqRØe.kh; :i ls vk;ru dks 2 L ls 20 L rd izlkfjr fd;k tkrk
gSA rc izØe ds fy, &
(A*) H > 0 (B) Ssys = 0 (C*) Ssurr = 0 (D*) T > 0
14. Number of chelate rings in K3[Fe(ox)3] = a

Number of chelate rings in [Cr(dien)2]Cl3 = b
Number of chelate rings in Hg[Co(CNS)4] = c
Number of chelate rings in K4[Fe(CN)6] = d
Calculate the value of (a + b + c + d) is..........
K3[Fe(ox)3] esa fdysV oy;ksa dh la[;k = a
[Cr(dien)2]Cl3 esa fdysV oy;ksa dh la[;k = b
Hg[Co(CNS)4] esa fdysV oy;ksa dh la[;k = c
K4[Fe(CN)6] esa fdysV oy;kas dh la[;k = d
(a + b + c + d) ds eku dh x.kuk djksA
Ans. 7
Sol. a = 3, b = 4, c = 0, d = 0  (a + b + c + d) = 7
15. Certain amount of H2 gas confined in a position filled cylinder is heated from 77ºC to 129°C keeping its
pressure constant and the gas expanded against a constant pressure doing 8.314 kJ of work on surroundings.
Find the mole of gas present in the cylinder (assuming ideal behaviour of gas) (report answer in integral
multiple of ‘10’).
H2 xSl dh ,d fuf'pr ek=kk dks ,d fiLVu ;qDr flys.Mj esa j[kk tkrk gS rFkk bldk nkc fu;r j[krs gq, 77ºC ls 129ºC
rd xeZ fd;k tkrk gS rFkk xSl fu;r nkc ds fo:) izlkfjr gksdj] ifjos'’k ij 8.314 kJ dk dk;Z djrh gSA flys.Mj esa
mifLFkr xSl ds eksy Kkr dhft;sA ¼xSl dk vkn'’kZ O;ogkj ekusa½ ¼mÙkj 10 ds iw.kZ xq.kt esa nsa½
Ans. 1
W = –PV
8.314  103
W = –nRT or n= = 10
8.314  100
16. Calculate the value of Van’t hoff factor (i) for infinity dilute solution of H3PO4 ( K a1 > K a2 > K a3 , 3 = 0.8).
Assuming ( K a1 ~
 K a2 ~
 )
H3PO4 foy;u dh vuUr ruqrk ( K a1 > K a2 > K a3 , 3 = 0.8) ds fy, okUVgkWQ xq.kkad (i) ds eku dh x.kuk fdft,A
eku fyft, ( K a1 ~ K a2 ~ )
Sol. i = 2 + (1 + 0.8) = 3.8
i × 10 = 38
17. Match Column-I with Column-II and select the correct answer with respect to hybridisation using the codes
given below :
Column - I Column - II
(Complex) (Hybridisation)
(I) [Ni(CN)4]2– (p) dsp2 hybridisation
(II) [Cu(CN)4]3– (q) sp3 hybridisation
(III) [Co(C2O4)3] 3–
(r) sp3d2 hybridisation
(IV) [Fe(H2O)5NO]2+ (s) d2sp3 hybridisation
dkWye-I dks dkWye-II ds lkFk lqesfyr dhft,] rFkk ladj.k ds izdkj ds lanHkZ esa uhps fn;s x;s dksM dk mi;ksx djrs gq;s
lgh mÙkj dk p;u dhft,A
dkWye- I dkWye- II
(lady
q ) (ladj.k)
(I) [Ni(CN)4]2– (p) dsp2 ladj.k
(II) [Cu(CN)4]3– (q) sp3 ladj.k
(III) [Co(C2O4)3]3– (r) sp3d2 ladj.k
PAGE NO.- 6
(IV) [Fe(H2O)5NO]2+ (s) d2sp3 ladj.k
Codes :
dksM%
(I) (II) (III) (IV) (I) (II) (III) (IV)
(A) q p r s (B*) p q s r
(C) p q r s (D) q p s r
Sol. (I) dsp2 hybridisation; Ni is in +2 oxidation state and complex is diamagnetic. (3d8 configuration)
(II) sp3 hybridisation; Cu is in +1 oxidation state and complex is diamagnetic.
(III) d2sp3 hybridisation; Co is in +3 oxidation state and complex is diamagnetic.(3d6 configuration has higher
CFSE).
(IV) sp3d2 hybridisation Fe in +1 oxidation state and paramagnetic with three unparied electrons.
(I) dsp2 ladj.k ; Ni, +2 vkWDlhdj.k voLFkk esa gS rFkk ladqy (3d8 vfHkfoU;kl) izfrpqEcfd; gS
(II) sp3 ladj.k; Cu, +1 vkWDlhdj.k voLFkk esa gS] rFkk ladqy izfrpqEcfd; gSA
(III) d2sp3 ladj.k; Co, +3 vkWDlhdj.k voLFkk esa gS] rFkk ladqy (3d6 vfHkfoU;kl mPp CFSE j[krk gS) izfrpqEcfd; gSA
(IV) sp3d2 ladj.k ; Fe ,+1 vkWDlhdj.k voLFkk esa gS rFkk rhu v;qfXer bysDVªkWu ds lkFk ladqy vuqpqEcfd; gSA
DPP No. # 45 (JEE-MAIN)

Total Marks : 68 Max. Time : 46 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.16 (3 marks, 2 min.) [48, 32]
Match the Following (no negative marking) Q.17 (8 marks, 6 min.) [08, 06]
ChemINFO : 4 Questions ('–1' negative marking) Q.18 to Q.21 (3 marks, 2 min.) [12, 08]
1. The time taken for a certain volume of a gas 'X' to diffuse through a small hole is 2 minutes. It takes 5.65
minutes for oxygen to diffuse under the similar conditions. The molecular weight of 'X' is.
,d xSl 'X' ds fuf'pr vk;ru dks ,d lw{e fNnz }kjk folfjr gksus esa yxk le; 2 feuV gSA leku ifjfLFkfr;kssa esa vkWDlhtu
xSl ds folj.k esa yxk le; 5.65 feuV gSA rc 'X' dk eksyj nzO;eku gSA .
(A) 8 (B*) 4 (C) 16 (D) 32
rX MO 2
Sol. rO 2 = MX
/2 32 5.65 32
 / 5.65 = MX , 2 = MX , MX = 4
2. ZnO is white when cold and yellow when heated. It is due to the development of :
ZnO de rki ij lQsn rFkk xeZ djus ij ihys jax dk gksrk gSA ;g fuEu esa ls fdl ds dkj.k gksrk gS \
(A) Frenkel defect (B) Schottky defect (C*) Metal excess defect(D) Metal deficiency defect
(A) Qzsady =kqfV (B) 'kkWVdh =kqfV (C*) /kkrq vkf/kD; =kqfV (D) /kkrq U;wurk =kqfV
Sol. ZnO on heating gives rise to metal excess defect.
ZnO dks xeZ djus ij blesa /kkrq vkf/kD; =kqfV mRiUu gksrh gSA
3. The Bohr orbit radius for the H–atom (Z = 1) is approximately 0.53 Å. The redius for the first excited state
orbit is
H–ijek.kq (Z = 1) ds fy, cksgj d{kk fd f=kT;k yxHkx 0.53 Å gSA rc izFke mRrsftr d{kk voLFkk ds fy, f=kT;k gksxhA
(A) 0.13 Å (B) 1.06 Å (C) 4.77 Å (D*) 2.12 Å
Sol. 1st excited state means n = 2
1st mRrsftr voLFkk dk vFkZ gS n = 2
 r = r0 x 22 = 0.53 x 4 = 2.12 Å
PAGE NO.- 7
4. The correct order of bond angles is
ca/k dks.k dk lgh Øe gSA
(A) NO2– > NO2+ > NO2 (B) NO2+ > NO2– > NO2 (C) NO2 > NO2+ > NO2– (D*) NO2+ > NO2 >NO2–
Sol. This is because of NO2+ has no unshared electron and hence it is linear, NO 2 has one unshared electron
while NO2– has one unshared electron pair.
NO2+ jsf[k; gksrk gS] NO2 esa ,d vlgHkkftr bysDVªkWu gksrk gS tcfd NO2– esa vlgHkkftr bysDVªkWu ;qXe gksus ds dkj.k
vf/kd izfrd"kZ.kA
5. The freezing point of equimolal aqueous solutions will be highest for

leeksyy foy;uksa esa ls fdl ds fy, mPpre fgekad fcUnq gS \
(A) C6H5NH3Cl (anilinium chloride) ,uhyhuh;e DyksjkbM (B) Ca(NO3)2
(C) La(NO3)3 (D*) C6H12O6(glucose)Xywdksl
Sol. Out of the given compounds, glucose does not undergo dissociation.
fn;s x;s ;kSfxdkas esa ls] Xywdksl fo;ksftr ugha gksrk gSA
6. The enthalpy of neutralisation of acetic acid and sodium hydroxide is – 55.4 kJ. What is the enthalpy of
ionisation of acetic acid ?
,lhfVd vEy rFkk lksfM;e gkbMªksDlkbM ds mnklhuhdj.k fd ,UFkSYih – 55.4 kJ gSA ,lhfVd vEy ds vk;uu fd ,UFkSYih
D;k gS \s
(A) –1.9 kJ (B*) + 1.9 kJ (C) + 5.54 kJ (D) – 5.54 kJ
Sol. enthalpy of ionisation vk;uu fd ,UFkSYih = 57.3 – 55.4 = 1.9 kJ
7. For the reaction

vfHkfØ;k
2A (g) + B(g) 3C(g) + D(g) ds fy;s
two moles each of A and B were taken into a flask. The following must always be true when the system
attained equilibrium.
A rFkk B izR;sd ds nks eksy ,d ¶ykLd esa fy;s x;sA tc ra=k lkE;koLFkk izkIr djrk gS rc fuEu esa ls dkSulk lnS o lR;
gksuk pkfg;s \
(A) [A] = [B] (B*) [A] < [B] (C) [B] = [C] (D) [A] > [B]
Sol. The amount of A reacted is doubled the amount of B reacted therefore [B] is present in greater amount.
A fd vfHkd`r ek=kk] B fd vfHkd`r ek=kk dh rqyuk esa nqxuh gksrh gS vr% B dh ek=kk ges'kk T;knk jgrh gSA
8. The number of H+ in 1 cc of a solution of pH = 13 is ?

pH = 13 ds 1cc foy;u esa H+ vk;uksa fd la[;k D;k gS \
(A*) 6.023 x 107 (B) 1 x 10–13 (C) 6.023 x 1013 (D) 1 x 1016
+ –13 –1
Sol. pH = 13 means [H ] = 10 mol L
pH = 13 dk vFkZ [H+] = 10–13 mol L–1
or 10–13 x 6.023 x 1023/ 1000 H+ ions/c.c.
= 6.023 x 107
PAGE NO.- 8
9. The acid which gives phosphine on heating is
vEy ftls xeZ djus ij QkWLQhu izkIr gksrh gSA og gS % &
(A) H3PO4 (B) HPO3 (C) H4P2O7 (D*) H3PO3
Sol. 
4H3PO3  3H3PO4 + PH3
10. The oxidation potential of 0.05 MH2SO4 is

0.05 MH2SO4 dk vkDlhdj.k foHko gSA
(A) –2 x 0.0591 (B) –0.01 x 0.0591 (C) –2.321 x 0.0591 (D*) +1 x 0.0591
+
Sol. [H ] = 0.1 Applying Nernst equ. to
[H+] = 0.1 uLVZ lehdj.k ykxw djus ij
1
H + + e–  H
2 2
0.0591 1 0.059  1 
ERed = E° – log  = 0 – log  
n [H ] 1  0.1 
= – 0.0591 V
 EOX = + 0.591 V.
11. Cupellation process is used in the metallurgy of

[kiZj.k fof/k fdl /kkrq ds /kkrqdeZ esa iz;qDr gksrh gS \
(A) Cu (B*) Ag (C) Al (D) Fe
Sol. Impurity of Pb present in silver can be removed as volatile oxide PbO in the process called cupellation. Here
impure silver is heated in a cupel (boat shaped shallow crucible made of bone ash).
[kiZj.k izØe esa flYoj esa mifLFkr Pb fd v'kqf) ok"ihd`r vkWDlkbM PbO ds :i esa i`Fkd gksrh gS ;gk¡ v'kq) flYoj dks
[kiZj ¼gM~Mh fd jk[k ls cuk uko ds vkdkj dk mFkyk dqfycy½ esa xeZ fd;k tkrk gSA
12. Boric acid is polymeric due to

fuEu esa ls fdlds dkj.k cksfjd vEy cgqydh; gksrk gS \
(A) Its acidic nature (B*) The presence of hydrogen bonds
(C) Its monobasic nature (D) Its geometry
(A) bldh vEyh; izd`fr (B*) gkbMªkstu ca/k dh mifLFkfr
(C) ,d{kkjh; izd`fr (D) bldh T;kferh
Sol. Boric acid has a polymeric structure due to the presence of hydrogen bonds. Each B atom is sp 2 hybridized
and the structure contains BO 33 units which are bonded together through hydrogen bonds.
s u ca/k ds dkj.k cskfjd vEy dh cgqydh; lajpuk gS] izR;sd cksjkWu ijek.kq sp2 ladj.k voLFkk esa gS ,oa bldh lajpuk
gkbMªkt
esa BO 33 bdkbZ;ka ijLij gkbMªkstu ca/k }kjk tqMh jgrh gSa
13. Which of the following complex or the complex ion will show geometrical isomerism
fuEu es ls dkSulk ladqy ;k ladqy vk;u T;kferh leko;ork iznf'kZr djsxkA
(A*) [Pt(NH3)2Cl2] (B) [Pt(NH3)Cl5]– (C) [Pt(NH3)5Cl]3+ (D) [Co(NH3)6]Cl3
Sol. It is a distubstituted complex with square planer structure and will show geometrical isomerism.
;g oxZ lerfy; f}izfrLFkkih ladqy gS rFkk ;g T;kferh leko;ork n'kkZ;sxkA
14. The noble gas used for treatment of cancer is ?

dsalj ds mipkj esa dkSulh ukscy xSl iz;qDr gksrh gS \
(A) Helium (B) Argon (C*) Radon (D) Krypton
(A) ghfy;e (B) vkxZu (C*) jsMkWu (D) fØIVkWu
Sol. Radon is radioactive with half life period of 3.8 days and is used for treatment of cancer.
jsMkWu jsfM;ks ,DfVo gS ftldh v)Z vk;qdky 3.8 fnu gS rFkk ;g dsUlj ds mipkj esa iz;qDr gksrh gSA
PAGE NO.- 9
15. The true statement for the acids of phosphorus H3PO2, H3PO3 and H3PO4 is
QkLQksjl ds vEy H3PO2, H3PO3 rFkk H3PO4 ds fy;s dkSulk dFku lR; gSA
(A) The order of their acidity is H3PO4 > H3PO3 > H3PO2
budh vEyh;rk dk Øe H3PO4 > H3PO3 > H3PO2 gS
(B) All of them are reducing in nature
;s lHkh vipk;d izd`fr ds gSa
(C) All of them are tribasic acids
;s lHkh f=k{kkjh; vEy gSa
(D*) The geometry of phosphorus is tetrahedral in all the three
rhuks vEyksa esa QkLQksjl dh T;kferh pqrq"Qydh; gSA
Sol. The geometry of P in H3PO2, H3PO3 and H3PO4 is tetrhedral.
H3PO2, H3PO3 rFkk H3PO4 esa P dh T;kferh leprq"Qydh; gSA
16. A sample of HCN yields potassium cyanide (KCN) on titration against 100mL of 1M KOH. What volume of
5M KMnO4 may be required for titration against same amount of HCN in acidic medium yielding Mn2+ , K+
and NO3– ions, alongwith liberation of CO2(g).
(A) 40 mL (B) 120 mL (C) 200 mL (D*) 400 mL
HCN dk izkn'kZ 1M KOH ds 100mL ds lkFk vuqekiu djus ij ikSVsf'k;e lk;ukbM (KCN) dh yfC/k nsrk gSA vEyh;
ek/;e esa HCN dh leku ek=kk ds lkFk vuqekiu djus ds fy, 5M KMnO4 dk D;k vk;ru vko';d gksxk] tcfd ;g
Mn2+ , K+ o NO3– vk;uksa dks izkIr djus ds lkFk CO2(xSl) dks eqDr djrs gks\
(A) 40 mL (B) 120 mL (C) 200 mL (D*) 400 mL
17. Match List – I with List – II and select the correct answer using the codes given below the lists :
lkj.kh – I dks lkj.kh – II ls lqesfyr fdft;s rFkk fn;s gq;s dksM dk mi;ksx djrs gq, lgh mRrj p;fur fdft;s A
List – I List – II
lkj.kh – I lkj.kh – II
A. (SiH3)3N 1. 3 centre-2 electron bond f=kdsUnzh; nks bysDVªkWu ca/k
B. BF3 2. sp3- hybridization sp3- ladj.k
C. SiO2 3. p – p bond p – p ca/k
D. B2H6 4. p – d bond p – d ca/k
A B C D A B C D
(A) 4 2 1 2 (B) 2 3 2 1
(C) 1 2 3 4 (D*) 4 3 2 1
Sol. (SiH3)3N has p–d back bonding, BF3 has p – p back bonding, in SIO 2 each Si is sp3 – hybridized and in
B2H6 there are two 3c – 2e bonds present called banana bond.
(SiH3)3N , p–d i'p ca/ku j[krk gSA BF3 , p – p i'p ca/ku j[krk gSA SIO2 esa izR;sd Si , sp3 – ladj.k j[krk gS
rFkk B2H6 esa nks f=kdsUnzh; nks bysDVªkWu ca/ku mifLFkr gksrs gSA fTUgs cukuk ca/k dgrs gSaA
PAGE NO.- 10
ChemINFO-1.21 Special Concentration Units
Daily Self-Study Dosage for mastering Chemistry Hardness of Water
Hardness of water (Hard water does not give lather with soap)
Temporary hardness - due to bicarbonates of Ca & Mg
Permanent hardness - due to chlorides & sulphates of Ca & Mg. There are some method by which we can soften
the water sample.
(a) By boiling : 2HCO 3–  H2O + CO2 + CO32– or
By Slaked lime : Ca(HCO3)2 + Ca(OH)2  CaCO3 + 2H2O
Ca2+ + CO32–  CaCO3
(b) By Washing Soda : CaCl2 + Na2CO3  CaCO3 + 2NaCl
(c) By ion exchange resins : Na2R + Ca2+  CaR + 2Na+
(d) By adding chelating agents like (PO3–)3 etc.
Ex. Temporary hardness is due to bicarbonates of Mg2+ and Ca2+. It is removed by addition of CaO as follows
Ca(HCO3)2 + CaO  2CaCO3 + H2O
Mass of CaO required to precipitate 2 g CaCO 3 is :
(A) 2 g (B*) 0.56 g (C) 0.28 g (D) 1.12 g
1
Sol. mole of CaCO 3 = 2/100 = 0.02 ; so mole of CaO = × 0.02 = 0.01
2
so mass of CaO = 0.01 × 56 = 0.56 g
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
18. One litre of a sample of hard water contain 4.44 mg CaCl2 and 1.9 mg of MgCl2. What is the total hardness
in terms of ppm of CaCO3 ?
(A*) 6 (B) 3 (C) 1 (D) 10
19. One litre hard water contains 1 mg CaCI 2 and 1 mg MgSO 4 . Find hardness of water sample (in ppm).
(A*) 1.734 ppm (B) 1.934 ppm (C) 1.534 ppm (D) 1.334 ppm
20. Calculate the amount of Ca(OH)2 required to remove the hardness in 60 litre of pond water,containing 1.62
mg of calcium bicarbonate per
100 mL of water.
(A) 0.246 g (B) 0.897 g (C*) 0.444 g (D) 1.286 g
21. If 100 Kg of a hard water sample contains 5g MgSO 4, find hardness of water (in ppm).
(A) 33.46 ppm (B) 52.24 ppm (C) 64.26 ppm (D*) 41.66 ppm
PAGE NO.- 11
ChemINFO-1.21 Special Concentration Units
Daily Self-Study Dosage for mastering Chemistry ty dh dBksjrk
ty dh dBksjrk ¼dBksj ty] lkcqu ds lkFk >kx ugha nsrk gS½ %

vLFkk;h dBksjrk & Ca rFkk Mg ds ckbdkcksZusV ds dkj.k gksrh gSA
LFkk;h dBksjrk & Ca rFkk Mg ds DyksjkbMksa rFkk lYQsVksa ds dkj.k gksrh gSA ;gk¡ dqN fof/k;k¡ nh xbZ gSa ftudk mi;ksx ty ds
e`nqdj.k esa fd;k tkrk gSA
(a) mckydj : 2HCO3–  H2O + CO2 + CO32– or
cq>s gqvk pwus }kjk : Ca(HCO3)2 + Ca(OH)2  2CaCO3  + 2H2O
Ca2+ + CO32–  CaCO3
(b) /kksou lksMk ds }kjk : CaCl2 + Na2CO3  CaCO3  + 2NaCl
(c) vk;u fofue; jsftu }kjk : Na2R + Ca2+  CaR + 2Na+
(d) dhysVhd`r ;kSfxd feykus ij : (PO3–)3 bR;kfnA
Ex. vLFkk;h dBksjrk Mg2+ vkSj Ca2+ ds ckbZdkcksZusVksa ds dkj.k gksrh gSA ;g CaO dks feykdj fuEu izdkj ls gVk;h tkrh gS %
Ca(HCO3)2 + CaO  2CaCO3 + H2O
2 g CaCO3 ds vo{ksi.k ds fy, CaO dk vko';d nzO;eku gS %
(A) 2 g (B*) 0.56 g (C) 0.28 g (D) 1.12 g
Sol. CaCO3 ds eksy = 2/100 = 0.02
1
blfy, CaO ds eksy = 2
× 0.02 = 0.01
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
18. dBksj ty dk ,d yhVj uewuk 4.44 mg CaCl2 o 1.9 mg MgCl2 ;qDr gSA CaCO3 ds :i esa ppm ds inksa esa dqy dBksjrk
D;k gS \
(A*) 6 (B) 3 (C) 1 (D) 10
19. ;fn ,d yhVj dBksj ty esa 1 mg CaCI2 rFkk 1 mg MgSO4 mifLFkr gSa] rks ty ds uewus dh dBksjrk (ppm esa) Kkr
dhft,A
(A*) 1.734 ppm (B) 1.934 ppm (C) 1.534 ppm (D) 1.334 ppm
20. izfr 100 mL ty esa 1.62 mg dSfY'k;e ckbdkcksZusV ;qDr] 60 yhVj rkykc ds ty esa ls dBksjrk dks gVkus ds fy, vko';d
Ca(OH)2 dh ek=kk ifjdfyr dhft,A
(A) 0.246 g (B) 0.897 g (C*) 0.444 g (D) 1.286 g
21. ;fn 100 Kg dBksj ty ds uewus esa 5g MgSO4 gks rks ty dh dBksjrk dh x.kuk djks ( ppm esa ).
(A) 33.46 ppm (B) 52.24 ppm (C) 64.26 ppm (D*) 41.66 ppm
PAGE NO.- 12

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PHY./INO.

TARGET : JEE (Main + Advanced) 2016

Course : VIJETA (JP) NO. 44 & 45

This DPP is to be discussed in the week (05.10.2015 to 10.10.2015)

DPP No. # 44 (JEE-ADVANCED)

CuSO4 + 2KI  K2SO4 + CuI2

2CuI2  Cu2I2 + I2

2CuI2  Cu2I2 + I2

3. Which of the following is incorrect order ?

8.* Which of the following statement(s) is(are) correct ?

(B*) ,LdksZfcd vEy dk rqY;kadh Hkkj = 2

gL–1 9.57  10–3

14. Number of chelate rings in K3[Fe(ox)3] = a

DPP No. # 45 (JEE-MAIN)

5. The freezing point of equimolal aqueous solutions will be highest for

7. For the reaction

8. The number of H+ in 1 cc of a solution of pH = 13 is ?

10. The oxidation potential of 0.05 MH2SO4 is

11. Cupellation process is used in the metallurgy of

12. Boric acid is polymeric due to

14. The noble gas used for treatment of cancer is ?

ty dh dBksjrk ¼dBksj ty] lkcqu ds lkFk >kx ugha nsrk gS½ %

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